BS 4250:1997 Specification for LPG
BS 4250:1997 Specification for LPG
| BS 4250 : 1997
|
|
|
|
|
|
|
|
|
|
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
|
|
|
|
|
Specification for |
|
|
|
|
|
|
Commercial butane and |
|
|
|
|
commercial propane |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
ICS 75.160.30 |
|
|
|
|
|
|
|
|
NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW
|
|
|
|
BS 4250 : 1997
British Standard
The preparation of this British Standard was entrusted to Technical Committee
PTI/10, Liquefied petroleum gases, upon which the following bodies were
represented:
BSI 1997
Amendments issued since publication
First published as BS 4250
January 1968 Amd. No. Date Text affected
Second edition August 1975
Third edition published as Part 1
September 1987
Fourth edition August 1995
Fifth edition as BS 4250
October 1997
Contents
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
Page
Committees responsible Inside front cover
Foreword ii
Specification
Introduction 1
1 Scope 1
2 References 1
3 Sampling 1
4 Composition 1
5 Properties of commercial butane and commercial propane 1
6 Precision and interpretation of test results 2
Annexes
A (normative) Method of calculation of gauge vapour pressure from
composition analysis of commercial butane or commercial butane or
commercial propane 4
B (normative) Method of test for odour of commercial butane or commercial
propane 4
C (normative) Method for determination of hydrogen sulfide in commercial
butane or commercial propane 6
D (informative) Explanatory notes on properties and test methods 8
Tables
1 Limiting requirements for properties of commercial butane and
commercial propane 3
A.1 Factors for determining the gauge vapour pressure of commercial butane
and commercial propane 4
D.1 Gauge vapour pressures 8
Figures
B.1 Apparatus for assessing odour of commercial butane or commercial
propane 5
C.1 Test paper holder 7
C.2 Apparatus for determination of hydrogen sulfide in commercial butane or
commercial propane 7
List of references 10
BSI 1997 i
BS 4250 : 1997
Foreword
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
This British Standard has been prepared by Technical Committee PTI/10. It supersedes
BS 4250 : Part 1 : 1995, which is withdrawn.
BS 4250 was first published in 1968 as a specification for commercial butane and
propane in response to a request from the Ministry of Defence. Revisions were
published in 1975 and 1987. In the 1987 revision, the standard was divided into two
Parts, Part 1: Specification for commercial butane and propane and
Part 2: Specification for automotive LPG. BS 4250 : Part 2 was superseded by
BS EN 589 : 1993.
The 1995 edition of the specification for commercial butane and propane introduced
technical changes intended to bring the safety warnings up to date with the guidance
on occupational exposure limits described in HSE Guidance Note EH40/93. The
maximum limit for dienes content was reduced to 0.5 % mole and extended to apply to
propane. A limit for ammonia was introduced. Guidance was given on the selection of
gas chromatographic equipment for the quantitative measurement of components not
described in published test methods. The attention of users of this standard was drawn
to the implications of EC Directive No. 67/548/EEC [1] for the potential classification of
commercial butane and commercial propane as carcinogenic substances.
The changes in this edition of BS 4250 are intended to correct a number of errors in
the text of the 1995 edition and to reflect the publication of several standards which
were previously `in preparation'. Maximum values for R number and O number are
now specified rather than given for guidance.
This British Standard calls for the use of substances and/or procedures that may be
injurious to health if adequate precautions are not taken. It referes only to technical
suitability and does not absolve the user from legal obligations relating to health and
safety at any stage. Attention is drawn to the safety warnings given in the introduction
to this standard.
Summary of pages
This document comprises a front cover, an inside front cover, pages i and ii,
pages 1 to 10, an inside back cover and a back cover.
ii BSI 1997
BS 4250 : 1997
Specification
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
Introduction 2 References
2.1 Normative references
SAFETY WARNINGS This British Standard incorporates, by dated or
undated reference, provisions from other
Attention is drawn to the risk of fire and explosion publications. These normative references are made
when handling commercial butane or commercial at the appropriate places in the text and the cited
propane, and to the hazard to health which arises publications are listed on the inside back cover. For
through inhalation of excessive amounts of dated references, only the edition cited applies; any
commercial butane or commercial propane. subsequent amendments to or revisions of the cited
Commercial butane and commercial propane are publication apply to this British Standard only when
highly volatile hydrocarbon liquids which are incorporated in the reference by amendment or
normally stored under pressure. If the pressure is revision. For undated references, the latest edition of
released, large volumes of gas will be produced the cited publication applies, together with any
which form flammable mixtures with air typically amendments.
over the range 2 % (V/V) to 10 % (V/V). The
2.2 Informative references
procedures described in this British Standard
involve the sampling, handling and testing of This British Standard refers to other publications
commercial butane or commercial propane. All such that provide information or guidance. Editions of
procedures should be conducted away from sources these publications current at the time of issue of this
of ignition such as naked flames, unprotected standard are listed on the inside back cover, but
electrical equipment and electrostatic hazards. reference should be made to the latest editions.
Testing should be performed as far as practicable
under an electrically-safe ventilation hood. 3 Sampling
Commercial butane or commercial propane in liquid For all test methods, sampling shall be carried out
form can cause cold burns to the skin. Protective from the liquid phase in accordance with the
clothing such as gloves and goggles should be worn procedures described for liquefied gases in BS 5309 :
if contact with the skin is likely to occur. Part 1 and section 6 of BS 5309 : Part 3 : 1976. All
Unnecessary inhalation of commercial butane or sample containers used shall be fitted with two
commercial propane vapour should be avoided. The valves and an ullage tube.
operator should not be exposed to atmospheres NOTE. The method described in ASTM D 3700 [3] may be used,
containing more than 1000 ppm (1750 mg/m3) over subject to agreement between supplier and customer.
an 8 h time-weighted average reference period WARNING. Attention is drawn to the need to
(long-term exposure limit), or greater than 1250 ppm observe relevant safety precautions for handling
(2180 mg/m3) over a 15 min reference period commercial butane or commercial propane during
(short-term exposure limit). One of the tests sampling operations.
described in this standard involves the operator
inhaling a mixture of air and commercial butane or 4 Composition
commercial propane vapour, and particular attention
is drawn to the cautionary statement in 5.3. 4.1 Commercial butane
NOTE. These exposure limits are taken from HSE Guidance Note The product shall consist of a hydrocarbon mixture
EH 40/97 [2], which is revised annually. The occupational containing predominantly butanes and/or butenes.
exposure limits given in the latest edition should be observed.
4.2 Commercial propane
The product shall consist of a hydrocarbon mixture
1 Scope containing predominantly propane and/or propene.
This British Standard specifies requirements for
commercial butane and commercial propane as
supplied for general domestic and industrial fuel
5 Properties of commercial butane and
purposes. It applies to these products in cylinders commercial propane
and in bulk. 5.1 General
NOTE. The requirements apply at the point of custody transfer. The properties of the commercial butane and
Withdrawal or loss of product from the vapour phase will change
the composition of the product remaining in the liquid phase.
commercial propane shall be in accordance with
Hence the product may cease to meet specified requirements. table 1.
This standard does not cover gases for testing gas For gauge vapour pressure, either the direct
appliances, for which reference should be made to measurement method described in BS EN ISO 4256 or
BS EN 437. the calculation procedure described in annex A of
this standard shall be used. The method described in
BS EN ISO 4256 is the reference method and shall be
used in cases of dispute.
BSI 1997 1
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
2 BSI 1997
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
Table 1. Limiting requirements for properties of commercial butane and commercial propane
Property Limit Test method
Commercial butane Commercial propane
BSI 1997 3
BS 4250 : 1997
Annexes
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
4 BSI 1997
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
BSI 1997 5
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
C.3 Reagents
Lead acetate test papers are required, and are prepared
from reagents of recognized analytical grade and water
conforming to grade 3 of BS EN ISO 3696 as follows.
Dissolve 10 g of lead acetate trihydrate,
Pb(CH3COO)2.3H2O, in 90 ml of water. Add 5 ml of
acetic acid (glacial, 17 mol/l) and 10 ml of glycerol to
the solution and mix well. Prepare this solution freshly
for each batch of test papers.
Immerse strips of chromatographic paper 20 mm wide
and about 100 mm long, vertically in the solution,
contained in a 100 ml measuring cylinder, for 1 min.
Withdraw the strips from the liquid, allow the excess
liquid to drain off, suspend them vertically and allow
6 BSI 1997
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
BSI 1997 7
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
Annex D (informative)
Explanatory notes on properties and test
methods
D.1 Gauge vapour pressure
The limits for gauge vapour pressure shown in
table 1 are given for a test temperature of 40 ÊC. For
comparison with previous data obtained at other test
temperatures, table D.1 shows equivalent gauge vapour
pressures.
8 BSI 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
blank
9
BS 4250 : 1997
Normative references
BSI publications
BRITISH STANDARDS INSTITUTION, London
10
BS 4250 : 1997
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
Informative references
BSI publications
BRITISH STANDARDS INSTITUTION, London
BS EN 437 : 1994 Specification for test gases, test pressures and categories of
appliance, for gas appliances
BS EN 589 : 1993 Specification for automotive liquefied petroleum gas
Other publications
[1] EC Directive No. 67/548/EEC Classification, packaging and labelling of dangerous substances
[2] Health and Safety Executive publication EH 40/97: Occupational exposure limits. 1997
[3] ASTM D 3700-94 Standard practice for containing hydrocarbon fluid samples using a floating piston cylinder
[4] ASTM D 3246-92 Standard test method for sulfur in petroleum gas by oxidative microcoulmetry
[5] EC Directive No. 88/379/EEC Classification, packaging and labelling of dangerous preparations
|
|
|
|
|
|
|
|
|
BSI Ð British Standards Institution
|
Licensed Copy: Mott Macdonald User, Mott Macdonald, Wed Nov 08 [Link] GMT+00:00 2006, Uncontrolled Copy, (c) BSI
|
|
|
|
|
| BSI is the independent national body responsible for preparing British Standards. It
|
| presents the UK view on standards in Europe and at the international level. It is
| incorporated by Royal Charter.
|
|
| Revisions
|
|
| British Standards are updated by amendment or revision. Users of British Standards
|
| should make sure that they possess the latest amendments or editions.
|
|
| It is the constant aim of BSI to improve the quality of our products and services. We
|
| would be grateful if anyone finding an inaccuracy or ambiguity while using this
| British Standard would inform the Secretary of the technical committee responsible,
|
| the identity of which can be found on the inside front cover. Tel: 020 8996 9000.
|
| Fax: 020 8996 7400.
|
|
| BSI offers members an individual updating service called PLUS which ensures that
|
| subscribers automatically receive the latest editions of standards.
|
|
| Buying standards
|
| Orders for all BSI, international and foreign standards publications should be
|
| addressed to Customer Services. Tel: 020 8996 9001. Fax: 020 8996 7001.
|
|
| In response to orders for international standards, it is BSI policy to supply the BSI
|
| implementation of those that have been published as British Standards, unless
|
| otherwise requested.
|
|
| Information on standards
|
| BSI provides a wide range of information on national, European and international
|
| standards through its Library and its Technical Help to Exporters Service. Various
|
| BSI electronic information services are also available which give details on all its
|
| products and services. Contact the Information Centre. Tel: 020 8996 7111.
|
| Fax: 020 8996 7048.
|
|
| Subscribing members of BSI are kept up to date with standards developments and
| receive substantial discounts on the purchase price of standards. For details of
|
| these and other benefits contact Membership Administration. Tel: 020 8996 7002.
|
| Fax: 020 8996 7001.
|
|
| Copyright
|
|
| Copyright subsists in all BSI publications. BSI also holds the copyright, in the UK, of
|
| the publications of the international standardization bodies. Except as permitted
| under the Copyright, Designs and Patents Act 1988 no extract may be reproduced,
|
| stored in a retrieval system or transmitted in any form or by any means ± electronic,
|
| photocopying, recording or otherwise ± without prior written permission from BSI.
|
|
| This does not preclude the free use, in the course of implementing the standard, of
|
| necessary details such as symbols, and size, type or grade designations. If these
|
| details are to be used for any other purpose than implementation then the prior
| written permission of BSI must be obtained.
|
|
| If permission is granted, the terms may include royalty payments or a licensing
|
| agreement. Details and advice can be obtained from the Copyright Manager.
|
| Tel: 020 8996 7070.
|
|
|
|
|
|
|
|
|
BSI |
|
389 Chiswick High Road |
|
London |
|
W4 4AL |
|
|
|
|
|
|