Island Energy Services

Barbers Point
Marine Terminal
Operations Manual
 ISLAND ENERGY SERVICES

MARINE TERMINAL OPERATIONS MANUAL FOR

BARBERS POINT OFFSHORE TANKER TERMINAL

OAHU, HAWAII

(NOVEMBER 2016)
2016 USCG Inspection Report*

*Inspection performed on legacy Chevron Operations Manual

 Island Energy Services
Barbers Point Marine Terminal Operations
Manual

Revision Log

Review Reviewed
Revision/Comments
Date By
Nov 1, 2016 Kurt Jacobson • Changed Chevron to Island Energy Services throughout manual
• Updated phone numbers and contact names in not
• Updated responsibilities for off-shore tankerman in Section 1
• Removed references to gut-water line, MTBE service and Chevron
ETD in Section 3
• Reduce maximum pressure in Section 4
• Corrected name of Hawaii Area Contingency Plan in Section 7 &
Appendix IV
• Revised training requirements of Mooring Masters in Section 8
• Updated product list and Safety Data Sheets in Section 9
• Revised authorization names in Appendix II
• Replaced Chevron policy with IES policy in Appendix III
• Updated OSRO Classification information and CIC equipment list in
Appendix V
• Updated checklist in Appendix XII

Jan. 17, 2017 Jay Chavez Updated Appendix II “Declaration of Inspection” Namely:
• Added “DECLARATION OF INSPECTION” header to first page
of DOI
• Item #17, Communications – tested and working, verbiage
changed to better conform to 33 CFR 156.120(q) and 33 CFR
154.560. Also added 33 CFR 154.560 to 33 CFR Reference
column.
• Item #25, specified that language to be spoken by PIC of vessel
and terminal will be ENGLISH.
• Item 26j. Paragraph (f) of 26j. deleted as there is no reference to
subject in CFR.
• Item #36, Removed galley fires from verbiage as there is no
reference to galley fires in CFR, only boiler fires. Verbiage revised
to conform to CFR.
• Item #45, Removed, no CFR reference and not applicable to
Mooring Master.
 PREFACE

This terminal manual provides information concerning the general conditions, facilities, services, and anti-
pollution requirements associated with the Barbers Point Marine Terminal Facility. It is intended for use
by owners, charterers, and masters of vessels calling at the facility for the purpose of loading or
discharging cargo, as well as by facility personnel. This document does not replace or modify official
publications covering any of the subjects discussed herein, but is intended only to assist in the use of
these official publications.

The information contained herein is believed to be accurate at the time of issuance, but IES
Downstream, LLC, makes no warranties and assumes no responsibilities with regard to any information
which may appear in this document or any referenced or supplemental publications, or in any
additions or corrections which may be supplied by the Company in any form.

IES DOWNSTREM, LLC

HAWAII REFINERY
IES DOWNSTREAM, LLC

OFFICIAL ADDRESSES

IES Downstream, LLC

Hawaii Refinery
91-480 Malakole St.
Kapolei, Hawaii 96707-1807

INQUIRIES REGARDING PORT INFORMATION SHOULD BE ADDRESSED TO:

Island Energy Services

Hawaii Refinery
91-480 Malakole St.
Kapolei, Hawaii 96707-1807
Telephone Number: 808-682-5711
TELEPHONE NUMBERS

U.S. COAST GUARD

National Response Center (Report all spills ................................................................l-800-424-8802

Sector Honolulu (24 Hrs) -...........................................................................................................842-2600
Captain of the Port -......................................................................................................................842-2640
Marine Safety Office .....................................................................................................................842-2672

HARBORS DIVISION (State of Hawaii)

Oahu District Manager, Pier l l ..............................................................................................587-2050

Harbor Master ...........................................................................................................................587-2070
after hours call ..........................................................................................................587-2076
Aloha Tower (Harbor Lookout) .............................................................................................587-2076
Harbor Police, Pier 10 ............................................................................................................538-2007

HONOLULU HARBOR PORT PILOTAGE

Hawaii Pilots Association

Daily (0730-1630) Duty Pilot or tape recording all other hours)
Office and Dispatcher .....................................................................................................537-4169
Pilot Boat Quarters & Boathouse Pier 18/19..................................................................537-3683
VHF Channel 16 & 12 (call sign WXZ-546)

FOSS MARITIME COMPANY VHF CHANNEL 16 & 18A (call sign WLX) ...........................543-9325

ISLAND ENERGY SERVICES - SHIPPING DEPARTMENT

Kurt T. Jacobson - Person in Charge

Port Captain................................................................................................ Office: (808) 527-2759
.................................................................................................Home: (808) 395-9120
.............................................................................................Cell: (808) 348-4876
TRANSMARINE NAVIGATION COMPANY (Agents for Island Energy Service, LLC)

Operations ……………………………………………………...………………….. (808) 599-5581

Kevin Kinerney ...............................................................................…..…..…Cell: (808) 479-3462
Kimo Pierson ............................................................................................…...Cell: (808) 330-2323

ISLAND ENERGY SERVICES

Hawaii Refinery
Blending & Shipping Control Operator.................................................................. (808) 682-2227
Area 2 Shift Team Leader…................................................................................... (808) 682-3137
Shift Team Leader (Cell)…………………………………………………………. (808) 349-3625
Emergency Phone Number….................................................................................. (808) 682-4711

In the event of oil spill pollution, the Qualified Individual can be contacted 24 hours a day
via the Central Control Building.

OTHER USEFUL NUMBERS

FIRE (Island-wide, including Fireboat) ........................................................................................911

AMBULANCE (Island-wide) ................................................................................................. .....911
POLICE (Island-wide) ............................................................................................................. .…911
FBI..………………………………………………………………………………….….521-1411
 EMERGENCY RESPONSE ACTION PLAN
For
Island Energy Services Hawaii Refinery

This emergency response action plan (ERAP) highlights portions of the spill response plan (SRP).
As such, all tables and figures that are identified in this ERAP utilize the same header and/or figure numbers
as used in the SRP for consistency purposes.

1. Notification of Qualified Individuals

The Qualified Individuals for implementation of this Spill Response Plan (SRP) are:
Name Scott Frank
Title Operations Manager
Address 91-480 Malakole Street, Kapolei, HI 96707
Work Telephone (808) 682-2212
Cell Phone (808) 349-3604

Alternate
Name Jon Mauer
Title C.E.O.
Address 91-480 Malakole Street, Kapolei, HI 96707
Work Telephone (808) 682-2215
Cell Phone (808) 349-3602

Alternate
Name Marshall McCormick
Title Technical Manager
Address 91-480 Malakole Street, Kapolei, HI 96707
Work Telephone (808) 682-2213
Cell Phone (808) 349-3603

Alternate
Name Todd Hauser
Title Reliability Manager
Address 91-480 Malakole Street, Kapolei, HI 96707
Work Telephone (808) 682-2239
Cell Phone (808) 220-1843
2. Facility Response Personnel
The following individuals are the Island Energy Services response personnel to be contacted in the event of a
spill. The emergency facility phone number is (808) 682-4711. The emergency response personnel will be
available immediately when an emergency occurs.
Name Position Work Number Cell Phone
Mark Hepburn Logistics Manager (808) 682-2303 (808) 349-3608
Jon Mauer CEO (808) 682-2215 (808) 349-3602
Scott Frank Operations Manager (808) 682-2212 (808) 349-3604
Marshall McCormick Technical Manager (808) 682-2213 (808) 349-3603

Todd Hauser Reliability Manager (808) 682-2239 (808) 220-1843

Peter Mirafuentes Area 2 Section Head (808) 682-3151 (808) 864-1734
Marc Dexter Health Environment & Safety (808) 682-3145 (808) 864-3591
Manger
Environmental On Call Environmental Specialist (808) 349-3627
Ryne Takeuchi Fire Chief (808) 682-2241 (808) 223-3767
Wilson Rivera Pipeline/Mooring Analyst (808) 682-2259 (808) 349-3618

The Qualified Individual will ensure the following notifications are made as necessary:
1. Call the National Response Center (NRC), U.S. Coast Guard, Washington, D.C. 1-800-424-8802
(NRC will notify local Coast Guard)
2. Call the Hawaii State Department of Health, Emergency Response Commission. (808) 586-4249, or (808)
247-2191 after hours
3. Call Coast Guard Sector Honolulu to assist in expediting any response efforts (formal federal notification
requirements are satisfied by calling the NRC). (808) 842-2600 (24 hrs)
4. Call the Local Emergency Planning Commission (LEPC) (808) 723-8960, or 911 after hours
5. Call the Harbors Division (Honolulu Harbor Master) (808) 587-2080
6. Call the following as needed:
Local Police Department 911 (if needed)
Local Fire Department 911 (if needed)
Local Ambulance, Paramedics 911 (if needed)
Board of Water Supply (if the public water supply may be contaminated) (808) 748-5010 (24 Hr)
Local Hospital
Queens Medical Center West Oahu (808) 691-3000
91-2141 Fort Weaver Road
Ewa Beach, Hi 96706
Other
National Weather Service Forecast Office (808) 973-5286
7. Call for Spill & Clean-up Assistance
Clean Islands Council (CIC) (808) 845-8465
179 Sand Island Access Road (808) 536-5814 (24 hour)
Honolulu, HI 96819
OSRV Clean Islands (Boat) (808) 536-5814 (24 hour)
Kim Beasley (Gen. Manager) (808) 479-0702 (cell phone)
(808) 927-0702 (hands free car cell)
(808) 735-2739 (home)

Capt. Pat Gillen (OSRV) (951) 907-1508 (cell phone)

Koa Beasley (Ops Manager) (808) 277-3141 (cell phone)

(808) 888-6500 (home)

Marine Spill Response Corporation (MSRC) (800) 645-7745

179 Sand Island Access Road (800) 259-6672
Honolulu, HI 96819 (703) 326-5609
DustyHenry(Response Supervisor) (808) 864-4444 (cell phone)

Penco (808) 545-5195 (office/main line)

65 N. Nimitz Hwy.
Pier 14, Honolulu Harbor
Honolulu, HI 96817

Rusty Nall (Executive VP) (808) 479-5195 (cell phone)

(808) 236-0711 (home)

Justin Souza (Ops Manager) (808) 792-1171 (work/direct line)

(808) 295-6009 (cell phone)
(808) 671-3595 (home)

Teal Cross (Executive VP) (808) 295-6008 (cell)

Stericycle (808) 845-0032 (office/main line)

Otto Audirsch (Location Manager) (808) 306-3880 (cellular)

Ben Kealoha (2nd 24hr contact) (808) 864-1825 (cellular)

8. Call for Information Assistance

Chemtrec (800) 424-9300
 ISLAND ENERGY SERVICES
MARINE TERMINAL OPERATIONS MANUAL
TABLE OF CONTENTS

SECTION 1 - GENERAL INFORMATION

I. Location
II. Time Zone
III. Charts and Publications
IV. Weather - Normal/Storm Conditions
V. Tides and Currents
VI. Visibility
VII. Rules of the Road

SECTION 2 - PORT REGULATIONS AND SERVICES AVAILABLE

I. Quarantine and Pratique

II. Launch Service
III. Medical Service
IV. Provisions
V. Water and Fuel Oil
VI. Repairs
VII. Pollution
VIII. Reporting Oil Discharges or Spills
IX. Declaration of Inspection/Safety Checklist

SECTION 3 - MOORING

I. Mooring Area Description

II. Use and Handling of Cargo Hoses
III. Berth Capacity - Mooring Analysis
IV. Mooring Equipment
V. Hose Handling and Cargo Transfer Equipment/Drip Pans
VI. Miscellaneous Vessel Requirements
VII. Tugboats
VIII. Pilotage
IX. Pilot Station
X. Liability
XI. Hours of Operation
XII. Anchoring
XIII. Ballast
XIV. Berthing Procedures
XV. Departure from Berth
 ISLAND ENERGY SERVICES
MARINE TERMINAL OPERATIONS MANUAL
TABLE OF CONTENTS

SECTION 4 - OPERATIONS AT MOORING

I. Minimum Personnel on Duty During Transfer Operation

II. Responsibility
III. Mooring Master Roles
IIIA. Mooring Master Assistant Role
IV. On Shore Personnel
V. Vessel Personnel Requirements
VI. Cargo Transfer Instructions and Declarations of Inspection (DOI)
VII. Transfer Rates, Pressure and Temperature Limits
VIII. Volume Checking
IX. Transfer Systems Pressure Protection
X. Lifting and Connecting Hoses
XI. Pressure Tests of Submarine Hoses
XII. Start/Stop Notice to Shore and Shipboard Personnel
XIII. Procedure for Discharging
XIV. Procedure for Loading
XV. Completion of Transfers
XVI. Emergency Shutdown Systems
XVII. Power Availability and Machinery
XVIII. Display of Code Flag "B" and Anchor Signals
XIX. Ballasting/Deballasting while Discharging/Loading
XX. Unauthorized Craft Alongside
XXI. Visitor to the Ship

SECTION 5 - COMMUNICATIONS

I. Radio Communications
II. Language

SECTION 6 - SAFETY

I. Personnel Safety Equipment

II. Fire Fighting Equipment
III. Minimum Personnel Aboard
IV. Illumination of Vessel
V. Dangerous Gas Hazards
VI. Smoking
VII. Radios and Electrical Equipment on Deck
VIII. Tank Hatches and Ullage Plugs
IX. Doors, Portholes and Ventilators
X. Fireboats
XI. Crude Washing
XII. Inert Gas System
XIII. Suspension of Off Loading During Hostile Mooring Conditions
 ISLAND ENERGY SERVICES
MARINE TERMINAL OPERATIONS MANUAL
TABLE OF CONTENTS

SECTION 7 - WATER POLLUTION CONTROL

I. Oil Spill Containment Equipment

II. Spill Avoidance Inspection
III. Oil-Tight Ship
IV. Responsibility for Oil Discharges or Spills
V. Drip, Discharge, and Spill Containment and Collection
VI. Oil Spill Contingency Plans

SECTION 8 - TRAINING PROGRAMS

SECTION 9 - DESCRIPTION OF CARGO HANDLED (SDS)

SECTION 10 - SUMMARY OF APPLICABLE LAWS & REGULATIONS

APPENDICES

I. Mooring Master's/Mooring Master Assistant’s Duties and Responsibilities

II. Marine Terminal Checklist, Certificate of Responsibility & Declaration of Inspection
III. Alcohol Policy & Alcohol Observation Procedures
IV. Federal Pollution Actions Plans
V. Clean Islands Council Equipage and Material Resources
VI. Summary of Minimum Line Requirements
VII. Summary of Emergency Plans and Procedures for Hurricanes/Tropical Storms
VIII. Over the Rail Pressure Calculations
IX. Marine Hose Change & Inspection Checklist (includes: Diver Preparation Materials
Checklist, Submarine Hose Change out Material Checklist & Submarine Hose
Checklist
X. Marine Terminal Inert Gas System (IGS) and Crude Oil Washing Operations
(COW) Checklist
XI. Barbers Point Mooring: Hose Operation Checklist
XII. Island Energy Services Pre-Mooring/Unmooring Checkoff List

DRAWINGS

Figure 1 - Barber’s Point Mooring Area Chart

Figure 2 - Vessel Moored in Berth
Figure 3 - Submarine Pipelines System Drawing
Figure 4 - Basic Berthing Sequence
Figure 5 - Typical Mooring and Hose Connection Schematic
Figure 6 - Typical Over-the-Rail Hose Connection Direct to Vessel’s Riser
Figure 7 - Bathymetric Survey of Island Energy Services Mooring Figure 8 -
Sub Hose Valve Arrangement & Ship Attachment
Figure 9 - Submarine Hoses Fittings & Attachments
 ISLAND ENERGY SERVICES
MARINE TERMINAL OPERATIONS MANUAL
TABLE OF CONTENTS SUMMARY
33 CFR 154.310

154.310 (a) Each Operations Manual required by 154.310 must contain:

1) The geographic location of the facility Section 1 - General Information

(I) Location

2) A physical description of the facility, including Section 1 - General Information

a plan of the facility showing mooring areas, (I) Location
transfer locations, control stations and locations (III) Charts & Publications
of safety equipment. (Drawing Section) Bathymetric & Seafloor
Feature Plan
Section 6 – Safety
(I) Personal Safety Equipment
(II) Fire Fighting Equipment

3) The hours of operations of the Facility Section 3 – Mooring

(X) Hours of Operations

4) The sizes, types and number of vessels that the Section 3 – Mooring
facility can transfer oil or hazardous material to (III) Berth Capacity
or from simultaneously.

5) For each product transferred at the facility:

a) The name of the cargo, generic or chemical Section 9 - Description of Cargo Handled
b) A description of the appearance of the cargo Section 9 - Description of Cargo Handled
c) A description of the odor of the cargo Section 9 - Description of Cargo Handled
d) The hazards involved in handling the cargo Section 4 - Operations @ Mooring
(VI) - Cargo Transfer Instructions and
Declaration of Inspections
(VII) - Transfer Rates, Pressure and
Temperature Limits
(VIII) - Volume Checking
(IX) - Transfer System Pressure Protection
(X) - Lifting & Connecting Hoses
(XII) - Start/Stop Notice to Shore and
Shipboard Personnel
(XIII) - Procedure for Discharging
(XIV) - Procedure for Loading
(XV) - Completion of Transfers
(XVI) - Emergency Shutdown System
e) Instructions for Safe Handling of Cargo Section 4 - Operations @ Mooring
f) Procedures to be followed if cargo spills or Section 4 - Operations @ Mooring
leaks (XVI) - Emergency Shutdown System
Section 7 - Water Pollution Control
g) List of firefighting procedures and Section 6 – Safety
extinguishing agents effective with fires (I) - Personnel Safety Equipment
involving the cargo (II) - Fire Fighting Equipment

6) The minimum number of persons on duty Section 4 - Operations @ Mooring

during transfer operations and their duties (I) - Minimum Number of Personnel on Duty
during Transfer Operations
7) The names and telephone number of facility, Telephone Number Section
Coast Guard, personnel who may be called by
employees of the facility in an emergency.
Section 4 - Operations @ Mooring
8) The duties of watchmen, required by 155.810 of (III) - Mooring Master Role
this chapter and 46 CRF 35.05-15, for (IIIA) – Mooring Master Assistant Role
unmanned vessels moored at the facility

9) A description of each communication system Section 5 – Communications

required by this part (I) - Radio Communications
(II) – Language

10) The location and facilities of each personnel Section 4 - Operations @ Mooring
shelter, if any; (IV) - On Shore Personnel Duties

11) A description and instructions for the use of Section 3 – Mooring

drip and discharge collection and vessel slop (V) - Hose Handling/Cargo Transfer
reception facilities, if any; Equipment Requirements, Item (D)

12) A description and the location of each Section 4 - Operations @ Mooring

emergency shutdown system (XVI) - Emergency Shutdown Systems

13) Quantity, types, locations and instructions for Section 4 - Operations @ Mooring
use of monitoring devices, if required by (VII) - Transfer Rates, Pressure and
154.525 Temperature Limits
(VIII) - Volume Checking
(IX) - Transfer Systems

14) Quantity, type, location, instructions for use and Section 7 - Water Pollution Control
time limits for gaining access to the (I) - Oil Spill Containment Equipment
containment equipment by 154.545 (VI) - (E) Containment Equipment
Appendices - Appendix V

15) Quantity, type, location and instructions for use Section 6 – Safety
of fire extinguishing equipment required by (II) - Fire Fighting Equipment
126.15(J) of this chapter

16) The maximum relief valve setting for each Section 3 – Mooring
transfer system (II) - Use and Handling of Cargo Hoses (275psi)

17) Procedures for: I. Not Applicable – loading arms not used

I. Operating each loading arm Section 4 - Operations @ Mooring
Vessel Personnel Requirements
II. Transferring oil or hazardous material (VI) - Cargo Transfer Instructions
(VII) - Transfer Rates, Pressure and
Temperature Limits
III. Completion of Pumping (VIII) - Volume Checking
(IX) - Transfer Systems Pressure Protection
(X) - Lifting and Connecting Hoses
IV. Emergencies (XV) - Emergency Shutdown Systems
18) Procedures for reporting and initial containment Section 2 - Port Regulations and Services Available
of oil or hazardous material discharge (VII) – Pollution
(VIII) - Reporting Oil Discharge or Spill

19) A brief summary of applicable Federal, state, Section 10 - Summary of Applicable Laws &
and local oil or hazardous material pollution Regulations
laws and regulations

20) Procedures for Shielding portable lighting Vessel Point of Transfer is equipped with fixed
authorized by the COTP under 154.570 lighting. All vessels are inspected annually and
issued a Safety Certificate by the USCG
21) a) A description of the training and a) Section 8 - Training Program
qualifications program for persons in charge.
b) Not applicable
b) If a facility collects vapors emitted from vessel
cargo tanks for recovery, destruction, or
dispersion, the Operations Manual must contain
a description of the vapor collection system at
the facility.
SECTION 1. GENERAL INFORMATION

I. LOCATION

Island Energy Services Downstream LLC a subsidiary of Island Energy Services (herein referred to
as “IES”, “Island Energy Services” or “Company”) has been granted the use of the following
anchorage for its Barbers Point Offshore Tanker Terminal:

The waters of the Pacific Ocean within an area beginning at a point in latitude 21o 16' 58" N
and longitude 158o 04' 39" W, thence on a bearing of 090o true, 850 yards, thence on a bearing
of 180o true, 450 yards, thence on a bearing of 270o true, 850 yards, thence on a bearing of 000o
true, 450 yards to the point of beginning.

The center of the above described area is on an "approximate" bearing of 119o true, 2.3 miles from
the Barbers Point light. Four corners of the mooring are marked by buoys. The two southerly corners
of the area are marked by lighted buoys which are painted yellow only and are in 84 feet of water.
The northerly corners of the area are marked by yellow spar buoys and are in 66 feet of water. The
area is designated as area "C" on Figure 1.

The off-shore terminal facilities in the above described area are owned and operated by the
Island Energy Services, and serve to handle cargo between the refinery at Barbers Point and
tankers calling at the terminal.

The off-shore tanker terminal is the responsibility of the Operations and Logistics Managers. The
marine representative in Hawaii is the Island Energy Services Port Captain. He is responsible for all
ship operations.

II. TIME ZONE

All islands in the State of Hawaii are on Zone plus 10 time (10 hours slow of Greenwich Mean
Time) throughout the year. All communications should be in local time.

III. CHARTS AND PUBLICATIONS

The anchorage area is shown on the following charts:

National Oceanic and Atmospheric Administration

19362 - Oahu, Ahua Point to Barbers Point
19357 - Island of Oahu
Drawings Section - Bathymetric & Seafloor Features

Publications of value and interest are:

Current edition of United States Coast Pilot 7 (Pacific Coast)

Hawaiian Refinery Emergency Plans and Procedures Manual
U.S. Coast Guard Regulations 33CFR153, 154, 155, and 156
IV. WEATHER--NORMAL/STORM CONDITIONS

The local weather is usually moderate with temperatures between 75o to 85oF and northeast trade
winds between 15 to 20 miles per hour. Tropical storms and hurricanes occasionally affect the islands
between June and November. They cause high surfs and wind conditions at the mooring. Specific
plans and procedures listed in Appendix IX need to be implemented and coordinated between the ship
and the refinery in the event a storm or hurricane approaches the mooring. See the Hawaii Refinery's
Emergency Plans and Procedures Manual for further details. In winter months, storms with strong
southerly winds called "Kona" winds may render the berth unusable for several days at a time. All
vessels must be especially alert to the dangers caused by this type of weather condition. Other violent
winds may occur with the passing of a frontal system or a trough. These are more localized and occur
from either the north or the south with violence and little warning.

A complete discussion of local weather is contained in the U.S. Coast Pilot 7. Up-to-date weather
information is broadcast by the National Weather Service on 162.55 MHz.

Any changes in the weather should be immediately brought to the attention of the Mooring Master
so he may take appropriate action.

V. TIDES AND CURRENTS

The maximum tidal range at the Mooring Area is approximately 3 feet. Mean higher high water is
2.0 feet, mean tide level is 0.8 feet and mean lower low water is 0.0 feet. The extreme low water is -
1.0 feet.

Currents normally set from east to west and are influenced more by wind than tide. However, they do
sometimes reverse. When setting from west to east, they are usually strongest when the wind velocity
is low and from the northeast or when the wind direction is from the south to west quadrant.

VI. VISIBILITY

The visibility in the mooring area is usually excellent with only rare occasions of limited visibility.

VII. RULES OF THE ROAD

All vessels should be aware that inland rules apply inshore of a line connecting the Diamond Head
light and Barbers Point light.
 SECTION 2. PORT REGULATIONS AND SERVICES
AVAILABLE

I. QUARANTINE AND PRATIQUE

Either the vessel or the agent is required to furnish the U.S. Coast Guard at least 96 hours'
advance notice of the ship's arrival time.

Should a vessel arrive from a foreign port with sickness on board, the U.S. Public Health Service
must be notified. This is usually done through the agent.

Documents required:

A. For Immediate Entry for Customs

(for Preliminary Entry Certificate Issuance)

Original + 3 copies of I-418 Crew List and Passenger List

Original + 1 copy of CF-1304, Customs Crew Effects Original + 1
copy of CF-1303, Customs Ship's

B. Required for Formal Entry and Clearance at U.S. Customs House

Entry
Original set of Preliminary Entry Manifest as prepared dockside (see above)
Port Clearance (last port)
Vessel's Certificate of Registry
U.S. Tonnage Tax Receipts (CF-1002), prior
voyages SOLAS Certificate (Safety Equipment
Certificate) Load Line Certificate
Certificate of Financial Responsibility (CFR)

Clearance
Masters Oath of Clearance, original + 2 copies, CF-1300, signed by Master
II. LAUNCH SERVICE

If shore leave is allowed, the vessel's master must make arrangements with the agent to provide
personnel launch service. A line boat is provided for line handling. The line boat does not leave the
terminal area while the ship is in the berth.

III. MEDICAL SERVICE

Arrangements must be made with the ship's agent for medical services. Medical services are normally
obtained by taking the patients to Honolulu in a launch. This is a distance of 12 miles (one way).
Ambulance service is provided by the City & County of Honolulu through the island-wide emergency
telephone number 911.

IV. PROVISIONS

Arrangements for provisions are made with the ship's agent. Provisions are brought from Honolulu to
the ship by launch. Weather conditions usually allow loading only on the vessel's port side. Terminal
regulations prohibit lifting stores with the hose boom during cargo transfer operations.

V. WATER AND FUEL OIL

Arrangements for bunkers are made with the ship's agent. No potable or boiler water is available at
 the Mooring Area.

VI. REPAIRS

Repairs which render the vessel incapable of getting underway are prohibited while the vessel is in the
berth.

VII. POLLUTION

It is imperative that no oil or pollutants of any type escape into the water. All regulations regarding
pollution of the sea or air must be complied with. See Section 7 and Appendices III to VII.

VIII. REPORTING OIL DISCHARGES OR SPILL

Any oil spill into the water from a vessel in the moorings, at anchor, or underway in the vicinity of
the Terminal shall be immediately reported to United States Coast Guard and the Terminal facility.
If a Mooring Master is embarked, he shall notify the shore facility by radio as appropriate. In addition,
the ship's Master shall in all cases notify the vessel's agent of the occurrence of the spill, no matter
how small nor from what cause. If no Mooring Master is aboard, the vessel shall inform the Terminal
facility by the most expeditious means available. Any other notifications required of the vessel by law
shall also remain the responsibility of the vessel to carry out.

IX. DECLARATION OF INSPECTION/SAFETY CHECK LIST

A Marine Terminal Check List has been prepared for vessels using the berth. It must be signed by the
Master, Chief Mate, Chief Engineer, Mooring Master and Mooring Master Assistant before cargo
can be handled. Its purpose is to insure that important safety and anti-pollution procedures are
followed by all personnel aboard the vessel. A copy of the Check List is included in Appendix II.
SECTION 3. MOORING

I. MOORING AREA DESCRIPTION

Within the mooring area there are seven mooring buoys. Vessels should moor by using both of the
ship's bow anchors and by running lines to the mooring buoys (See Figure 2). Two pipelines serve to
transfer products between the terminal and the refinery, one 20" diameter and one 30" diameter. Hose
strings attached to the ends of each of these pipelines are raised by lifting the free end of the hoses
by their attached buoys and chains. When the free end of the hose string is above the vessels deck,
the hose string is secured to the vessel by an attached chain bridle between the end and second lengths
of the hose string. The end of the hose is then lowered in smooth curve to the deck, the cap removed
and the hose connected to the vessel's piping system. Both pipelines and hose strings terminate on the
Port side of a vessel secured in the berth (see Figure 6).

The hose string description is as follows:

Hose Order Hose Hose Hose Total

Pipeline From Shore Count Diameter Length Length

20 inches 1 6 each 16 inches 30 feet 180 feet

2 2 each 12 inches 30 feet 60 feet
8 each 240 feet

30 inches 1 11 each 16 inches 30 feet 330 feet

2 2 each 12 inches 30 feet 60 feet
13 each 390 feet

Each hose string is terminated on the free end of the last 12-inch diameter section by a lever- operated,
blanked butterfly valve and a standard 12-inch 150# ANSI flange. The 20-inch system is normally
used for transferring clean products. The 30-inch system is normally used for transferring crude oil,
and residual products such as fuel oil.

The submarine pipelines extend nearly two miles to the shore and then approximately one additional
mile across flat land to the Island Energy Services refinery (see Figure 3).

II. USE AND HANDLING OF CARGO HOSE

This section describes procedures covering the use, handling, and storage of cargo hose for marine
and submarine use, for dock use and for use between ships (called lightering hose). It does not cover
hose for single point mooring systems or barge hose. (Size range in Company service currently runs
from 3-inch to 24-inch diameter hose.) These procedures were developed to minimize the chance of
failure during operation and to ensure maximum service life. For procurement of cargo hose, see
Model Specification PIM-MS-2923, Smooth Bore Cargo and Submarine Hose.
 For SPM hose, refer to Model Specification PIM-MS-3092 and "SPM Hose Standards," "Guide for
Handling, Storage, Inspection and Testing of Hose in Field" and "SPM Hose Ancillary Equipment
Guide," latest issue, for recommendation adopted by OCIMF Oil Ports Committee. The Oil
Companies International Marine Forum (OCIMF) is a voluntary association of oil companies having
an interest in the shipment and terminaling of crude oil and oil products.

All hoses are capable of transferring all petroleum products and crude oil that the refinery imports or
exports.

For barge hose, refer to PIM-MS-3133.

Operating Limitations

Pressure

Hose constructed in accordance with Specification PIM-EG-2923 is designed for a maximum

operating pressure of 275 psi and a test pressure of 425 psi. Pressure limitations of ANSI Class 150
flanges are dictated by temperature when product carried is in excess of 100°F.

Exceeding Maximum Working Pressure. Applying a continuous pressure to a hose above the
maximum working pressure may permanently damage the carcass. Although the burst pressure of
new hose is at least five times its maximum working pressure, used hose may burst at pressures as
low as 500 psi.

Hose Life. Hose that has been in service 12 or more years will be retired. This is because you can't
tell by looking at a hose that it is ready to fail. Continued use of hose may result in catastrophic failure
due to age deterioration of tube and carcass materials.

Federal Safety Requirements. U. S. Federal rules and regulations pertaining to safety define the
testing and pressure limitations in the use of hose in a cargo piping system (Federal Register, Volume
35, No. 177-9/11/70 Title 33, Chapter 1, Part 126.15, Paragraph 7-IV and 7-V). Hose must not be used
in a cargo piping system where the maximum available pressure (pump, static head, and surge or relief
valve setting) exceeds the maximum rated working pressure of the hose. Instead of installing relief
systems in the hard piping at wharves, the Company has elected to use hose designed as strong as the
Class 150 piping system.

Federal Pollution Control Rules. Federal rules and regulations covering pollution control
relating to hose are listed in the Federal Register Vol. 37, No. 246, 12-21-72, Title 33, Part II,
Chapter 1, Parts 154.500, 154.20, and 156.170. Paragraph 156.170 requires that information about
each hose be available in one of two ways:

• The hose must be stenciled with product(s) handled ("oil service") and “Maximum Allowable
Working Pressure”.

• The date of mfg., burst pressure, mfg. recommended pressure, last test, etc. must be recorded
elsewhere at the facility and the hose marked so as to identify it with the information in the record.

Test requirements (pressure and frequency of test) as stated in the Federal Register, Volume 35
(pertaining to safety) must take precedence over that stated in Volume 37 where there is an apparent
conflict.
 Transfer System Pressure Gage. Each piping system should have a recording pressure gage, in
operating condition with chart, in the transfer system.

Vacuum

Cargo and submarine hoses are designed to withstand a vacuum of 20 inches of mercury column.
This assures adequate resistance to vacuum in service and also gives an indication that the tube is
firmly attached to the rest of the carcass. Badly kinked hose may not withstand this much vacuum
without partial collapse.

Temperature

Recommended maximum temperatures vary by service:

Crude and heavy fuel oils 180°F

Diesel and light fuel oils 125°F
Gasolines and aromatics 85°F
Asphalt/tar 350°F

Hose for regular asphalt service should be purchased to Specification PIM-MS-2923, but the engineer
should specify "rough bore for 350°F asphalt service" so that the hose will be manufactured with an
internal metal reinforcement to hold the liner in place. Such hose has been giving satisfactory service.
Refer to ETD Materials Division for recommendations on use of high temperature Neoprene tube
carcass materials as an alternate to using rough bore hose.

Where operating requirements exceed normal temperature and pressure tolerances of hose,
articulated rigid pipe with ball bearing swivel joints has been used successfully.

Hose Lining Materials

An inner tube of Nitrile or Neoprene will provide continuous service for 1) crude and heavy oils at
180°F containing a maximum of 30% aromatics, 2) manufactured gasolines with a maximum aromatic
content of 45% at 85°F and 3) natural gas containing 25% butane at 85°F. When these limits will be
exceeded, even intermittently, hose with special liners (Viton) are required. Aromatic liquids such as
reformate, benzene, cumene, toluene, xylene and alkanes all fall in this category.

Leaks while in Service

Suspend operation and remove from service any hose developing bulges, sweating, or pin hole leaks
in the carcass, or leaks between the nipple and carcass.
Handling of Hose (General Conditions)

Cargo and submarine hose should not be dragged or rolled. Acceptable ways to move hose are with
rollers, dollies, or derrick. The following instructions are intended to aid in the prevention of hose
damage.

Lifting of Hose

Hose should be lifted in accordance with the following:

1. Never lift a hose by a single sling at the midpoint.

2. Support hose at no less than 10-foot intervals.
3. When attaching lifting bridles to hose, provide saddles at least 3 hose diameters in width.
4. Do not bend hose in service to a radius of less than 6 times its nominal diameter
5. Preferably, use more than one sling to suspend hose over the rail of a vessel, or in similar
situations. However, when a hose is being lifted vertically, a single sling may be used if it is
attached at the end and bend radius limits are not exceeded.
6. Provision should be made while lifting hoses, for the possibility of spills, including retention
and recovery of spilled material before it reaches navigable water.

Connecting of Hose to Vessel

When making vessel connections with hose, the following precautions apply:

1. Each time before placing a length of hose in service, inspect it externally for severe damage
such as corroded or broken reinforcing wires and tears or breaks in the carcass (layers of fabric
under the cover and breaker strip). Hose showing such damage is unsafe for service. Whenever
the cover of a submarine hose has circumferential ridges, remove it from service. This
deformation indicates broken reinforcing wires.

2. Use sufficient hose to compensate for vessel movement during cargo exchange and tides,
adjusting hose as necessary to avoid kinking and abrading or tearing of cover. As the ship
changes elevation adjust the support to keep the curvature evenly distributed. Avoid crimping
the hose.

3. Position and support hose so that no sharp bends will develop. This is most important at the hose
nipple.

4. Do not permit more than 50 feet of hose to be vertically suspended in the air without intermediate
support.

5. Prevent contact of hose with hot lines.

6. If the cargo hose comes in contact with the vessel's rail, deck edge, and dock edge, rollers or
chafing mats must be provided. These precautions will also help prevent abrasion of hose cover
due to pulsations from reciprocating pumps. If necessary, minimize pulsations by adjusting pump
speed and keeping air chambers charged at proper pressure.
Handling of Submarine Hose
(Special Conditions)

Most frequent damage occurring to submarine hose is kinking while in service. To prevent this, keep
adjusting mooring lines as the vessel changes position as a result of operations or variations in the
weather and tides, so that the vessel will not crush the hose, bend it too sharply, override it with the
keel, or cut it with the propeller. The larger the diameter of hose the more destructive the effect of
kinking will be.

Dragging hose across the bottom at any time must not be permitted because coral, rocks, debris, etc.
will severely cut and abrade the cover. The line boat should maintain a strain on the hose buoy to
enable suspending hose when bringing the hose alongside the vessel or returning it to its normal
seafloor position. Locate ship in close proximity to hose, whereupon raising hose, it will be suspended
in a gradual long curve.

Damaged Hose

Line Pull

Whenever a cargo or submarine hose system is damaged by a longitudinal pull or by other means, all
hose in the string should be removed from service. Such hose will require close visual examination
for defects and all inspection tests to determine if it is still serviceable. Longitudinal pulling may
dislocate helix wires, break or crack flanges, and tear reinforcing fabric.

Kinking

Once a hose has been kinked, its useful life may have been seriously reduced. Kinking damages inner
fabric strength plies and often breaks metal reinforcements, making it unsuitable for use. In addition,
if a hose is operated while kinked, the increased velocity of flow at that point may flag the tube, plug
the hose, and result in a rupture failure.

Tears, Cuts and Abrasions

Tears, cuts and abrasions penetrating through the hose cover will permit water to enter the carcass
and corrode the reinforcing metal. Corrosion results in deterioration of the fabric plies. Tears, cuts,
and abrasion through the cover should be repaired by vulcanized patching or cold vulcanizing
elastomeric putty to increase hose life and prevent failure in service.
Cleaning of Cargo Hose

All cargo hose should be thoroughly drained immediately after use to remove excess liquid and then
allowed to aerate for 24 hours. Then the hose should be blinded to slow down the drying and reduce
extraction of the plasticizers from the tube. Submarine hose should be filled with a non-aromatic
hydrocarbon.

Hose being aerated should be placed so that any spills from the hose will be contained and recovered.

No special cleaning procedures are necessary for hose in frequent service. When hose is to be placed
in storage for an indefinite period, cleaning procedures vary with the type of stock the hose carries.

Light Stocks

Evaporation will adequately cleanse hose that has handled light stocks when hose is laid straight and
level so that air may circulate freely. Hose being aerated should be placed so that any spills from the
hose will be contained and recovered.

Heavy Stocks

Hose which has handled heavy stocks normally requires special provisions for cleaning. In some
areas, this might be handled by the reclamation organization.

Storage

Hose stored for indefinite periods should be laid level and straight in a cool place protected from
direct sun. When necessary to store in sun, protect with canvas or reinforced building paper. The
cover of stored hose deteriorates faster by action of the sun and ozone than the hoses in service,
according to the manufacturers. Hoses should be stored in single height layers. Hose to be stored
should be free of oil accumulations which could cause a spill.

IN-SERVICE INSPECTION OF CARGO HOSE

This section gives a procedure for routine inspection of cargo and submarine hose during service.
Hose that passes this inspection should not be expected to fail before the next required inspection.

Frequency of Inspection

Testing shall be annual or not less than 30 days prior to the first transfer conducted past one year
from the date of last tests and inspections, per CFR 156.170(f)(1)”.

Frequencies given in Figure 500-1 (next page) apply to all active hose. Where unusual service
conditions warrant, to minimize the possibility of hose failure and resultant spillage, complete internal
and external inspection should be made at more frequent intervals, particularly at new submarine
terminals. Any hose which has been out of service and not tested for more than six months should
normally be hydrostatically tested prior to reuse.

When service conditions have been abnormally severe and hose has been subjected to unusual stress
or damage resulting from movement of the vessel, serious storm conditions, or excessive pressure, or
when appearance of exposed hose shows damage, a complete inspection, including a hydrostatic test,
should be made prior to reuse, unless local management deems otherwise.
 Inspection Procedure

External Inspection

1. Look for kinking of the carcass and indications of broken reinforcing, as evidenced by
circumferential ridges on the surface of the cover. Inspect for bulges, cuts, and abrasion through
the cover. Examine the external surfaces of all flanges and nipples which are not rubber covered,
for excessive corrosion, cracks, dents, scars, distortion, etc. Whenever circumferential ridges
protrude along the cover of any hose, remove it from service. This deformation may indicate
broken reinforcing wires. Broken helix wires may penetrate tube material and/or tear reinforcing
fabric, making the hose less leak and burst-resistant.

2. Submarine hose may be externally inspected without disconnecting, as follows:

a. Hoist as many lengths of hose from the water as possible and note condition.

b. When conditions warrant, have a diver examine the outside surface of those lengths
remaining below the water.

MAXIMUM INTERVALS BETWEEN INSPECTIONS

Submarine Hose
Type of Cargo
Inspection Hose
Hose at Surface* Hose at Depth
External 6 months 6 months 12 months

Internal 6 months 12 months 12 months

Vacuum and Hydrostatic Test 12 months 12 months 12 months

* Sections that can be lifted above water [Link]

Fig. 500.1 Maximum Intervals Between Inspections

c. Pay particular attention to the lengths closest to the vessel where possibility of damage is
greater due to movement. This applies particularly to the second, third, and fourth length
from the ship.
Internal Inspection

Disconnect each length of hose in the string and place it on a flat surface. Reflected sunlight or an
enclosed and gasketed lam should be used for illuminating the hose interior. Examine for bulges,
flagging, cuts or tears of the inner tube. (Flagging should not be confused with the extruded lip that
sometimes forms when rubber flows between the nipple and mandrel during vulcanization; this is not
harmful and may be cut off.) Examine the inner surface of all flanges and nipples for corrosion or
possible cracks.

Hydrostatic Test Procedure

U. S. Federal regulations require an annual hydrostatic test to 1-1/2 times maximum allowable
working pressure (Federal Register, Vol. 35, No. 177 - 9/11/70, Title 33, Chapter 1, Part 126.15).

Extend the hose horizontally on dollies or rollers. Blind both ends, connecting one end to a test pump
by means of a flexible hose and fitting the other end with an air vent valve. Fill the hose with water,
elevating the vent to assure removal of all air. With personnel at a safe distance perform the following
steps:

1. Establish the benchmark for the hose's Original Length Lo (if you do not already have it from
hose test inspection records):

a. Raise pressure to the rated working pressure and immediately release to zero pressure.

b. Raise the pressure in the hose to 10 psi and hold for 5 minutes. During this period measure
the length of the hose from end of flange to end of flange. This shall be recorded as the
Original Length, Lo.

2. Raise the pressure to 1-1/2 times the rated working pressure for the grade of hose being used
and hold this pressure for 15 minutes. During this hold period, the hose shall be examined for
any leaks at the couplings or nipples or for any indication of weakness in the hose structure
such as hard bulges, ridges, grooves and fitting movement.

Measure and record the length of hose from end of flange to end of flange. This shall be
recorded as the Test Pressure Length, Lt.

3. Reduce pressure to 25 psi and hold for 5 minutes. During this period, examine nipples for low
pressure leaks.

4. Reduce pressure to 10 psi, permit hose to rest for 15 minutes and then measure the length. This
will be recorded as the Permanent Elongated Length, Lp.
5. Using Equations 500-1 and 500-2, calculate:

a. Test pressure elongation, percentage

Lt - Lo
= x 100 Lo

(Eq. 500-1)

b. Permanent elongation, percent

Lp - Lo
= x 100 Lo

(Eq. 500-2)

7. Examinations of Elongations. After each periodic pressure test, compare the elongation test
results to those obtained when the hose was new. At the end of any periodic testing, if the
increase over the original value is greater than that shown below, the hose should be retired from
service.

a. When tested at 1-1/2 times rated working pressure, test pressure elongation at any periodic
test shall not be greater than the new hose test pressure elongation (5a) plus 4% or twice
(5a), whichever is greater.

b. Permanent elongation at any periodic test shall not be greater than the new hose permanent
elongation (5b), plus 4% or twice (5b), whichever is greater.

Excess values mean that hose carcass materials have been subjected to pressures
(tensions) greater than or at point of yield.

Electric Bond Test

At each stage of the hydrostatic test and on its completion, the electrical bond in submarine hose is
tested. Wires connected to each flange and to a flashlight battery and lamp in series are commonly
used for this test. For the hose to pass the test, the lamp should light.

Vacuum Test

After the pressure test the internal bore of cargo and submarine hose should be examined under
vacuum for bulges, or blisters, i.e., areas where the tube has separated from the carcass. For this test,
close one end of the hose with a plexiglass plate, use a flashlight in the hose to illuminate the interior
near opposite end, and close the opposite end with another plexiglass plate attached to a vacuum
pump or other aspirating device. Soft rubber gaskets may be used at each end. A vacuum of 20 inches
of mercury is adequate to disclose tube separation. Submarine hose, because of its larger diameter, is
more susceptible to internal damage as a result of kinking.
Inspection Results

Hose which has tears, cuts, or abrasions through the external cover only, but is otherwise in good
condition, is suitable for repair. After repair, it should be fully tested.

When inspection reveals any of the following defects, hose is normally condemned.

Internal Inspection

Bulges in tube. Cuts, tears, or splits through tube. Flagging of tube to point where pieces might tear
loose. Any flanges or nipples with cracks.

External Inspection (Solid Helical Wire Reinforced Hose)

Severe kinks. (These are kinks in which the minor outside diameter of the hose is reduced 20% or
more. They show up as a hinge action when the hose is secured a few feet away from the kink and
lifted.) Exposed carcass with broken strength wires or torn fabric. Evidence of severe corrosion of
reinforcing wires by exposure to sea water. Lumpy appearance of surface of cover caused by buildup
of corrosion products on reinforcing wires. Cracks in flanges or nipples.

External Inspection (Stranded Helical Wire Reinforced Hose or Helix Free "Kink Tolerant"
Hose)

With no internal pressure the hose must be generally round, free of 1) sharp kinks, 2) evidence of
crushing and 3) damage to hose cover such as cuts and tears. Under a vacuum of 20 inches of
mercury general flattening exceeding 55% of the nominal hose diameter and kinks which might be
obvious under the vacuum test and are indicated by a complete collapse of the carcass wall over a
short distance (generally less than 9 inches) shall be cause for rejection.

Hydrostatic Test

Any sweat or pinhole leak. Bulges that are hard or liquid filled.

Bond Test

Internal electrical bonding between nipples of submarine hose is necessary if the hose is to be an
integral part of a cathodically protected system. Failure of the electric bond in service, however,
would not justify condemning an otherwise acceptable hose. Instead, the hose would be placed at
the outboard end of the hose assembly. Internal electric bonding of hose is not required for static
protection.

The helix wire in the hose's carcass is part of the circuit. Loss of electrical bonding may mean that
the helix wire has broken.
 Disposition of Condemned Hose

Condemned hose should be immediately so marked in large letters and removed from service at
once.

Evaluation Test

When in doubt as to serviceability, condemn and apply a burst test to the hose. This information
should be reported through normal communication channels as a contribution to the Company's
accumulated experience on deterioration and adequacy of inspection criteria.

Hose Inspection Report

The hoses have brass identification tags that provide a reference to their records*. A carefully
supervised record should be kept for each hose on either a card or a log book. The record should
include:

• Data received

• Date placed in service

• Manufacturer's name

• Hose brand and serial number

• Hose size

• Hose length

• Rated working pressure

• Rated burst pressure

• Type of fitting

• Date and results of periodic hydrostatic testing and examination (Indicate items to be
measured; name of tester, agency name; comments on results)

• Date removed from service

• Date returned to service

• Comments

• Date of retirement

* These records are maintained at the Reliability Office.

III. BERTH CAPACITY - MOORING ANALYSIS

A. Maximum length overall 1,000 feet.

B. Maximum distance stern to center manifold 500 feet.

C. Maximum deadweight tonnage 150,000. Island Energy Services may allow vessels of a
larger size under special circumstances to be determined on a case-by-case basis by Island Energy
Services Port Captain.

D. Maximum Draft year round is 52 feet.

E. Maximum of one (1) tanker in the mooring berth at all times.

IV. MOORING EQUIPMENT – Island Energy Services reasonably believes, but does not
warrant, that vessels meeting the following criteria may safely moor at the berth.

A. All ground tackle must be in good working condition. Vessels up to 50,000 deadweight tons must
have at least 10 shots of chain on each anchor. Vessels over 50,000 deadweight tons must have
at least 12 shots of chain on each anchor. Windlass speed to heave at least one shot/3 minutes.

B. Mooring wire and rope specifications are shown on the "Summary of Minimum Wire
and Rope Requirements" in Appendix VII. Placement requirements:

PORT CENTER STBD

1.) Main deck forward 2 2

(1 on drum) (1 on drum)

Main deck aft 2 2

(1 on drum (1 on drum)

Poop 2 2 2
(1 on drum) (1 on drum)

2. Each synthetic line must be secured to a separate bitt, or on a drum.

3. For vessels larger than 70,000 DWT, fittings must permit doubling of all lines for a total
of fourteen (14) mooring lines.

C. Each mooring winch must be capable of heaving the first layer of wire or rope on the drum at a
no-load speed of at least 130 ft./min. and a loaded speed of at least 40 feet/minute. The
respective winch speed must be maintained during simultaneous operation of one winch on the
main deck forward, one winch on the main deck aft, two winches on the stern and one anchor
windlass operating.

D. Mooring winches must be capable of warping the vessel in position without tugboat assistance.
On a case-by-case basis the Mooring Master may wave this requirement and utilize tugboat
assistance instead. Tugboats will be on vessel's account.
V. HOSE HANDLING/CARGO TRANSFER EQUIPMENT REQUIREMENTS

A. Port hose boom and related equipment shall have minimum safe working load capacity of 10
long tons.

B. Bitts for hanging off the hose chain should be provided in front of the manifold port side.

C. Rail to manifold distance should not be less than 15 feet. Top of roll bar should not be higher
than the lower lip of the manifold flange(s).

D. All fittings, piping, and valves outside of and including the first valve on the ship's cargo and
bunker systems must be of steel construction and properly supported by a permanent installation
(i.e., vessel must meet the Arco Cast Iron Clause). No more than one reducer outside the vessel's
permanent installation will be allowed and in any case all connections must be made inside the
oil drip pan.

The facility side of hoses are in the water and no drip pans are required. Hoses are hard bolted
to hard piping on the bottom of the ocean floor.

E. All vessels must have the capability of loading segregated ballast during discharge equal to at
least 30% of vessel DWT. Those with the capability of handling segregated ballast quantity
above 30% will be less subject to delay during adverse weather conditions. Vessels may load
segregated ballast during discharge of cargo.

VI. MISCELLANEOUS VESSEL REQUIREMENTS

A. Vessels should be equipped with a search light on each bridge wing to assist in illuminating
buoys during unmooring at night.

B. The ship's crew is required to perform all hose handling work (including raising, connecting,
adjusting, disconnecting, and lowering the hoses), and adjusting of mooring wires and anchor
chains. In addition, the crew will be required to take aboard a gear basket (and if necessary an
oil spill containment boom) and to return it to the line boat after the visit. All of this work will
be done with the advice of the Mooring Master, or Mooring Master Assistant.

C. All vessels are required (at their expense) to provide feeding and separate accommodations for
one Mooring Master, one Mooring Master Assistant and one Surveyor. Also meals may be
provided for line launch crew for the duration of the visit.

D. All vessels shall comply with regulations and procedures set forth in this Operations Manual for
the Island Energy Services Barbers Point Offshore Tanker Terminal in addition to U.S. Coast
Guard regulations set forth in Title 33 of the Code of Federal Regulations (33 CFR). In the
event of conflicts between this Operations Manual and the USCG Regulations, the provisions
of the USCG Regulations shall prevail, except when provisions set forth in this Operations
Manual are more stringent than USCG's and other government regulations.
 E. All vessels are subject to inspection to confirm their suitability for the Barbers Point berth.
Vessels not meeting any one of the requirements may be refused berthing.

F. Vessels may be required to unberth and/or otherwise incur delay during adverse weather
conditions.

VII. TUGBOATS

In accordance with USCG Regulations one or more tugboats are normally used to assist the vessel in
mooring at this terminal. A line boat is used to attach the vessel's lines to the mooring buoys and
assist in picking up the submarine hoses. A line boat stands by continuously to assist in unmooring
and in any emergency which may arise while the vessel is in the berth. (See also Section XV -
DEPARTURE FROM BERTH).

VIII. PILOTAGE

Pilotage is compulsory for all vessels using the berth. This service is performed by the Island Energy
Services Mooring Master who remains aboard the vessel the entire time the vessel is in the berth.
As a condition for using the berth the vessel's Master explicitly agrees that the Mooring Master is a
servant of the Master of the vessel and shall be indemnified and held harmless from all liability,
loss or claim in the course of rendering his services. The Mooring Master will advise the vessel's
Master on approaching and departing the berth, mooring, and unmooring. With the concurrence of the
vessel's Master, this advice may take the form of directions to members of the vessel's crew. All
maneuvering within the mooring area should be done in accordance with the advice of the Mooring
Master. Never the less, in all cases the Master of the vessel shall remain solely responsible on behalf
of his vessel's owner, for the safety and proper maneuvering of the vessel. The vessel's Master and a
qualified deck officer must be on the bridge at all times while the vessel is maneuvering. Appendix I
summarizes many of the duties and responsibilities of the Mooring Master.

IX. PILOT STATION

When not anchoring on arrival, an Island Energy Services Mooring Master will board arriving
vessels.
For vessels arriving, take aboard Mooring Team at latitude 21° 14.55' N and longitude 158° 04' W.

X. LIABILITY

The services of the Mooring Master are provided upon the express understanding and condition that,
while aboard for the purpose of assisting such vessel, the Mooring Master becomes for such purposes
the servant of the owners and/or charterers of the vessel. Island Energy Services shall not be
responsible or liable for any damage or injury resulting from the advice and assistance given by such
Mooring Master or from his acts while aboard the assisted vessel.
 XI. HOURS OF OPERATION

Mooring operations are conducted during daylight hours only, weather permitting. Unmooring
operations can be conducted at any time, day or night.

XII. ANCHORING

Vessels engaged in foreign trade and U.S. vessels engaged in coastwise trade must be under the
direction and control of a First Class Pilot when operating within waters in the vicinity of the Barbers
Pt. offshore pipeline terminals. The area now includes all waters bounded by a line connecting the
following points:

21°17´47"N 158°06´23"W
21°14´49"N 158°06´23"W
21°14´49"N 158°03´10"W
21°15´26"N 158°00´57"W
21°18´18"N 158°01´49"W

Vessels wishing to anchor, while awaiting berth, should consult with their agent. Island Energy
Services will advise their agent as to the berthing schedule and prospects for anchoring.

XIII. BALLAST

Shore facilities may be available for handling either dirty or clean ballast at this terminal.

XIV. BERTHING PROCEDURES

Figure 4 illustrates the basic berthing procedure for the mooring. The detailed procedure is modified
to fit conditions of the berth, wind, current, sea state, vessel size/loading, limitations of vessel's
mooring gear, and other factors as recognized with the advice of the Mooring Master. In general,
the following procedure is followed for typical berthing.

• Vessel approaches the mooring on a due north heading, passing approximately 800 feet east of No.
6 mooring buoy.

• Starboard anchor is let go at Point A and 9 to 9½ shots of chain are payed out on the run, starboard
chain is then held.

• When starboard chain fetches up leading aft, port anchor is dropped at Point B and stern is worked
into berth as the starboard chain is held and the port chain is payed out to approximately 8 shots
and the lines are run to the mooring buoys. Then both chains are adjusted as necessary to position
the vessel properly in the berth.

• Wind and current will largely govern usage of tug assistance and which mooring lines are run out
first.
 XV. DEPARTURE FROM BERTH (Also refer to Appendix I, #16-#20 & Safety Sec. 6, III)

• The procedure for leaving the berth is conventional for such moorings and includes the following
steps:

• Hose is disconnected, blinded and lowered to the sea bottom.

• Tug assistance is required for all departing laden ships. Adverse weather may require, for vessel
safety, that a laden ship depart the berth before tug assistance can be obtained.

• Lines to buoys are slacked by the vessel's crew then released at the buoy by the line boat crew.

• Anchors are heaved in one at a time and the port anchor is normally heaved in first.

• Mooring Master leaves the vessel after it is underway and well clear of the moorings.
SECTION 4. OPERATIONS AT MOORING

I. MINIMUM PERSONNEL ON DUTY DURING TRANSFER OPERATIONS

Vessel: Minimum personnel on duty during transfer operations are vessel's Person in Charge
(Master or Licensed Deck Officer), the Mooring Master or Mooring Master Assistant, and the
vessels on watch crew.

Shore: Minimum shore personnel on duty during transfer operations are the Area 2 Shift
Team Leader, Head Operator, Control Operator and two (2) Area Operators.

II. RESPONSIBILITY

The Master is responsible for his vessel at all times. The Mooring Master will advise the Master
with respect to the connecting of the cargo transfer hoses, valve operation, loading and
discharge pressures and temperatures, and product transfer hazards, but will not direct transfer
operations except as necessary to protect the Terminal facilities. Manipulation of the ship's
valves and the hose valve is the direct responsibility of the ship's personnel. Neither Island
Energy Services nor their personnel shall be responsible for any loss, damage, or injury
accruing in consequence of any assistance, instructions, or advice given or tendered.

III. MOORING MASTER ROLE

In accordance with CFR 33, part 155-810, Tank Vessel Security, vessels in Island Energy
Services mooring are manned 24 hours a day and the duty of a security watchman is not
required.

A Mooring Master is required to be aboard at all times during the transfer of products to or
from a vessel in the berth. While the vessel's master remains solely responsible for all ship's
operations, the Island Energy Services Mooring Master has the local knowledge necessary for
the conduct of safe operation of the vessel in the berth and will assist in coordinating transfer
operations and maintain radio communications with the shore facility. An English speaking
member of the crew shall be stationed at the radio to provide continued communications.

Before transfer operations are begun, the Mooring Master verifies that sea suction valves are
closed and lashed, that overboard discharge lines connected to the cargo system are blocked
off and that manifolds not in use are kept blanked. If cargo is to be discharged, he will verify
that loading drops are checked to see that they are securely closed. The Mooring Master's
advice should be sought before any mooring lines or anchors are in any way adjusted.

The Mooring Master will assist the vessel's Master in conferring with shore personnel to
verify transfer instructions prior to and during the movement of any product, including
anticipated stops or other changes which affect transfer rates such as stripping operations,
crude oil washing (COW), switching pumps or manifolds to prevent equipment damage or
other mishaps.

The Mooring Master will also follow transfer operations and help compare vessel and shore
volumes. If unaccountable differences occur, cargo operations must cease until the differences
are reconciled. During emergencies, he coordinates vessel and shore operations on behalf of
 the vessel and keeps all parties informed as to the nature and status of the emergency.

In the event of an oil spill, the Mooring Master will assist the Master of the vessel in notifying
the U.S. Coast Guard of the type and extent of the spill and in initiating emergency oil spill
corrective action in conjunction with terminal personnel. (See Appendix I for Mooring Master
Duties).

IIIA. MOORING MASTER ASSISTANT ROLE

A Mooring Master Assistant (MMA) will board with the Mooring Master as an additional
representative of the Terminal to discuss and observe safety, pollution prevention, and oil spill
cleanup response. The MMA shall assist the Mooring Master, observe cargo operations to see
that all regulations are followed, and may relieve during cargo transfer as the Terminal Person
in Charge. (See Appendix I for MMA duties).

IV. ON SHORE PERSONNEL DUTIES

Due to the type of operation of Island Energy Services marine lines, there is no personnel
shelter on shore where the line exits the ocean.

Shore facilities involved in transfers of products to or from vessels in the mooring area are
controlled and monitored in the Refinery Central Control Building. These activities are
supervised by the Area II Shift Team Leader. He is assisted by a Head Operator, Control
Operator and two Operators. The Central Control Building is the oil movement
communications center. Consequently, it is manned at all times whether or not a vessel is in
the mooring area.

There is a minimum of two people on duty in the Blending and Shipping area whenever
transfers to or from a vessel are in progress. In the event of an emergency, all Blending and
Shipping personnel are radio equipped and can be contacted immediately if their assistance is
required.

Under normal circumstances, the Control Operator is stationed in the Central Control Building
and is responsible to monitor and direct all oil movements to and from ships as well as other
oil movements within the Refinery tank field. He maintains radio communication at all times
with vessel and onshore personnel who are directly involved in marine transfer operations. The
Control Operator reviews transfer instructions prior to the start of any oil movements to or from
a vessel and confirms these instructions with personnel aboard the vessel. If revisions are
necessary, he enters such revisions on the copy of transfer instructions maintained in this
Central Control Building. He directs the activities of onshore tank field personnel and arranges
for tank gauging, pump operation, tank switching, alignment of pipeline systems and other
operations required to comply with the transfer instructions. He gives notice to all personnel
involved with marine transfers prior to any changes in operations or starting or stopping
transfers. The Control Operator closely monitors oil movements to and from vessels and
compares shore volumes with ship volumes. In the event of an emergency, he maintains radio
contact with the vessel and takes action as requested by the Mooring Master and/or the Shift
Team Leader. He keeps the Shift Team Leader advised of the status of transfer operations and
notifies him immediately if any emergency occurs. If the Control Operator must leave his
 station for any reason, he arranges to be relieved by personnel qualified to perform his duties.

An Operator assists the Head Operator during transfers to and from vessels. He, under the
direction of the Head Operator and/or the Shift Team Leader, performs tank, pump, pipeline,
and other field activities. He maintains radio communications with the Central Control Building
and arranges for qualified personnel to relieve him if he has to leave the tank field area.

Additional personnel are assigned by the Head Operator or Shift Team Leader as required to
assist with field operations. The Shift Team Leader oversees transfer operations and makes
changes in procedures and/or personnel as required. He also stays in radio contact with the
Central Control Building at all times during transfers involving vessels.

In accordance with paragraphs 154.710(a) of the Federal Register 33CFR, the designated
"person in charge" is the Shift Team Leader of the Blending & Shipping area.

V. VESSEL PERSONNEL REQUIREMENTS

Any vessel engaged in the transfer of products must keep sufficient officers and crew aboard
at all times to safely disconnect hoses and shift the vessel to anchor if warranted by an
emergency situation.

VI. CARGO TRANSFER INSTRUCTIONS AND DECLARATION OF INSPECTION

(DOI)

Transfers of products to or from vessels in the berth will be prescheduled and documented in
the form of transfer instructions (referred to as "Cargo Orders" by Refinery employees). The
instruction form provides for the following information to be recorded:

1) Name of Vessel
2) Estimated time and date of arrival of the Vessel
3) Approximate size and type of cargo
4) Instructions regarding continuous radio communications, recording of temperatures and
pressures and recording pumping data
5) Ordered steps for transferring oil including volumes, origins and destinations
6) Loading port data when available
7) Product laboratory analyses.

Prior to transferring to or from a vessel, these orders will be transmitted to all parties concerned.
They will be reviewed and revised as necessary. Once the vessel has connected to the marine
systems, these transfer instructions will be reviewed via radio by personnel stationed in the
Control Room and aboard the vessel, including the Mooring Master. Any additional revisions
will be made at that time and agreed to before transfer operations are begun. After the transfer
instructions have been finalized, transfer operations will be started when all parties confirm that
systems are ready to transfer and receive products.

If revisions in the transfer instructions are required while transfer operations are in progress,
personnel in the Central Control Building will discuss the proposed revisions with the vessel,
 including the Mooring Master. When both sides agree on the revisions, each will make the
required changes on his copy of the transfer instructions (DOI).

VII. TRANSFER RATES, PRESSURE AND TEMPERATURE LIMITS

Discharge rates from vessels over the submarine systems vary with the temperature, gravity
and viscosity of the product handled, the pressure at the ship's rail, the location of the shore
receiving tank and the height of oil in the receiving tank.

Vessels discharging products over the submarine system should discharge at maximum rates
consistent with maximum temperature and pressure limits. Discharge rates are acceptable up
to 26,000 BPH of light crudes on the 30-inch system.

The maximum temperature limits for stocks transferred over the submarine systems are:

180oF for crude and heavy fuel oils

125oF for diesel and light fuel oils

The maximum pressure limit is 150 psig at the ship's rail (see Appendix XI for calculation of
maximum allowable pressure).

VIII. VOLUME CHECKING

Shore tank gages will be taken every two hours on the "even" hour and exchanged with the
vessel to check total observed volumes. Vessel officers should initiate the call as soon as
possible after taking gages. If the difference is excessive, the transfer will be shut down and
still gages will be checked on both the vessel and the shore tanks. Pumping will not be
resumed until the difference has been reconciled.

IX. TRANSFER SYSTEMS PRESSURE PROTECTION

The submarine systems, including the marine hoses, are designed to operate safely at pressures
above the maximum pressures that the vessel's pumps can normally achieve. The onshore
loading pump system is equipped with a pressure relief valve that is set to relieve at 240 psig
which is below the maximum allowable working pressure of the marine systems. The relief
valve was installed to comply with Title 33 CFR, Part 126.15, Section 7.(y).

Both marine pipeline systems are protected by low pressure alarms. In the event either of these
alarms sounds during transfer operations, the transfer pumps will be immediately shut down
until the cause of the low pressure has been determined. Transfers will not resume until the
situation has been evaluated and a decision has been made that it is safe to do so.

X. LIFTING AND CONNECTING HOSES

After the vessel has been securely moored in the berth, the Mooring Master will advise the
crew in the lifting and connecting of the cargo hoses following the general procedure set forth
below:

• Hose is pressurized to 80-100 psig (and remains so until hung off at rail).
• Ship's crew hangs off submarine hose at the rail with the chain attached to the hose. The
end of the hose lowered to the deck in a smooth curve.
• At the Mooring Captain's discretion, a bounce dive to check the hose position and insure the
hose is not kinked may be done.

• The hose is depressurized.

• Ship's crew unbolts and removes blind flange from the end of the hose string. The hose is
lifted to the vessel's riser after the flange is removed. The hose is connected directly to the
vessel's riser (Figure 6). (Top of roll bar should not be higher than lower lip of manifold
flange(s).)

XI. PRESSURE TESTS OF SUBMARINE HOSES

All submarine hoses associated with all berths of the Terminal are annually removed and
subjected to hydrostatic pressure tests and vacuum leak checks. In addition, a pressure pack is
made by the shore facility prior to commencing any transfer. The pressure pack (80#-100#) is
put on with the lines full and the hose lying on the bottom.

XII. START/STOP NOTICE TO SHORE AND SHIPBOARD PERSONNEL

During the transfer, radio communications will be maintained and advance notice given to shore
and shipboard personnel ten minutes prior to stopping or starting transfers. Any variations in
operations which will affect the transfer rate will be transmitted to other personnel involved via
radio to keep all parties informed of impending changes. These variations may include stripping
tanks, switching vessel compartments or shore tankage, crude oil washing, the starting or
shutting down of any pump and changes in manifolding. This communication will assist in
preventing mishaps and equipment damage. Personnel in the Central Control Building, the
vessel's officers, and the Mooring Master aboard the vessel will closely follow volumes of
products transferred.

If any differences occur which cannot be reconciled, the transfer will be stopped and not
resumed until the cause of such differences has been determined and evaluated. Keep in mind
that ship gauges may not be accurate due to the rolling action of the sea.

XIII. PROCEDURE FOR DISCHARGING

Cargo is discharged to the refinery using the ship's pumps to transfer the product ashore. All
shipboard cargo transfer action is taken by ship's crew in consultation with the Mooring Master.
The sequence of operations for each transfer is controlled by facility personnel in the pumping
station control room ashore in accordance with the cargo transfer instructions.

It is important that the vessel maintain the product at the specified temperature and pressure at
the ship's rail as indicated in Section 4-VI.

It is essential that the discharging sequence be carefully planned so that stripping and/or
collecting of tank bottoms is going on during the discharge ashore. When discharging high
 pour cargo, vessel shall not stop transfer for periods of more than 45 minutes. Mooring Master
will consult with the Master on the plans to assure that maximum practicable discharge rates
will be attained consistent with ship's safety. Vessel should complete discharge with Main
Cargo Pump and avoid stripping with positive displacement pumps that may cause the hose to
float. When cargo transfer is completed with high pour cargo, the terminal may require the
vessel to conduct a diesel Line Displacement using a main cargo pump. The vessel must
pump the diesel at a minimum rate of 6,000 bbl. per hour. After the main cargo pump trips,
stripping of the last tank and deck line is by stripping pump, via MARPOL line to
manifold. The ship must only pump liquid, however, and not pump any gas which can
cause the hose to float after returning it to sea.

XIV. PROCEDURE FOR LOADING

Loading of a vessel consists of pumping the product from the shore pumping station under the
control of facility personnel in the control room. In each step of the loading operation the vessel
will be told by the shore facility precisely how many barrels of product to take aboard. The
ship's crew, with the Mooring Master's assistance, will advise the shore station when that
quantity is reached. Facility personnel in the control room will close valves and stop pumps as
appropriate to stop loading. IMPORTANT: DO NOT UNDER ANY CIRCUMSTANCES
CLOSE SHIP'S VALVES OR SUBMARINE HOSE VALVE AGAINST FLOW! Upon
completion of all loading operations the shore facility personnel will advise the vessel to close
the hose valve.

The particular sequence of operations for each transfer is controlled by the facility personnel
in the control room ashore. These operations follow the detailed procedure prepared by the
Refinery Short Range Planner. See Section 4-V.

XV. COMPLETION OF TRANSFERS

At the completion of transfers, the butterfly valves on the end of the marine hoses must be
closed securely and blanked before the hoses are returned to the ocean floor.

After hoses are blanked off, shore pressurizes hoses again until they are secured on the bottom.

At the Mooring Master's discretion, a bounce dive may be done to check the hose position and
insure the hose is not kinked. Onshore facilities, such as pumps and valves, are checked at the
completion of transfers to insure they are shut down or blocked.

Volumes transferred will be verified by the Control Operator with the vessel and the Mooring
Master prior to departure of the vessel. The vessel or Mooring Master must notify the control
operator when the vessel is underway and clear of berth.

XVI. EMERGENCY SHUTDOWN SYSTEMS

The onshore pump used for transferring products to a vessel in the berth has a remote shutdown
switch located in the control house. If, during transfer to a vessel, an emergency occurs that
requires the loading pump to be shut down, shipboard personnel shall immediately contact the
control via radio. Upon receiving the request to shut down the loading pump, the Control
Operator stationed at the radio will actuate the pump stop switch. The Control Operator may
also close motor operated valves at the Refinery plot limit on the 30" and 20" marine lines.
 These valves, when activated will close completely in 25 seconds.

Additionally, each crude tank involved in transfers to or from vessels is equipped with remote
operated electrically driven valves on both the tank suction and discharge systems. In an
emergency these valves can be closed quickly. Each valve also has a manual closing system so
that it can be closed even if a power failure were to occur during or as a result of the emergency.

Once the transfer pumps are shut down and the tank's valves are blocked in, the vacuum pump
system can be activated using P-2006 for the 30" line. This pump will not pull vacuum on the
20" Mo-Gas Marine Line. Pulling suction on the 20" marine line can be accomplished by using
either P-2089 or P-2096. Manifolding these pumps will allow you to pull suction on the 20"
marine line and discharge Mo-Gas into Tank 109.

XVII. POWER AVAILABILITY AND MACHINERY

Any vessel in the mooring or in the vicinity of the moorings shall keep its engineering plant on
standby with full power available within 30 minutes to the main engine and steering gear.
Power to the anchor windlasses, deck winches, and the ship’s whistle will be available at all
times. Tension winches shall be kept on manual brake. No repairs to the engineering plant
are permitted in the moorings if such repairs impair or limit the ship's power availability in any
way. When fast in the mooring, the ship's propeller shall not be turned except by use of jacking
gear, until the hose is returned to sea, when the engine may be kicked ahead & astern.

XVIII. DISPLAY OF CODE FLAG “B” AND ANCHOR SIGNALS

During all discharging, loading, ballasting or deballasting operations the International Code Flag
"B" and a black anchor ball shall be displayed during daylight hours, and proper anchor lights
shall be displayed during darkness. These lights should be of a character such as to be visible
at a distance of at least 1 mile and show an unbroken white light all around the horizon.

XIX. BALLASTING/DEBALLASTING WHILE DISCHARGING/LOADING

While in the berth, vessels shall maintain by cargo or segregated ballast (or a combination of)
a minimum of 30% of DWT at all times. If ballast water is to be loaded in cargo tanks,
double valve segregation is required. Masters of double hull/double bottom vessels must
certify that there is a written cargo and ballast transfer plan covering the ship’s duration in
the mooring. The Master must also certify that the ship’s loading or discharge plan contains
provisions to ensure that positive vessel stability will be maintained at all times.

XX. UNAUTHORIZED CRAFT ALONGSIDE

No craft may come alongside a ship in a berth of the terminal without the prior approval of the
Mooring Master. The presence of an unauthorized craft alongside a ship will render the vessel
unacceptable. It is the duty of the ship's personnel to keep the sides of the vessel clear of all
unauthorized craft.
XXI. VISITORS TO THE SHIP

Visitors to the ship are strictly prohibited while the vessel is in the moorings, except as
specifically authorized by the ship's Master after consultation with the Mooring Master.
SECTION 5. - COMMUNICATIONS

I. RADIO COMMUNICATIONS

Communications between a vessel in the mooring area and the onshore facilities are made via
VHF radio. The radios normally used for ship-to-shore communications operate on a special
frequency (Mooring talk group channel 4A). In addition, all the portable radios in B & S area
have the Mooring talk group channels. The onshore base station is located at the Central Control
Building. The base station is attended at all times and is normally operated by the Blending
and Shipping Control Operator. Shift Team Leader and the two Blending and Shipping
Operators are also fully qualified to use all ship-to-shore radios. The Shift Team Leader and
the Operators carry portable radios on a different frequency and are linked to the Head Operator
via a second base station.

The Mooring Master carries a portable radio which operates on the Mooring talk group channel
4A aboard all vessels in the mooring area to assist the vessel Master in ship-to- shore
communications. The ship's name is used as a call sign when being contacted from the shore
station. A second portable radio is operated by an English speaking deck officer on watch. If it
becomes necessary for the deck officer to leave the radio, an English speaking member of the
crew shall be stationed at the radio to maintain communications.

All radio communications are made in accordance with FCC regulations.

In the event of a failure of the Mooring talk group system, there is an on-shore maritime mobile
stations which can be used for ship-to-shore communications. It operates on VHF channels 16
and 10. The station is in the Central Control Building. The Mooring Master will also take a
portable radio which operates on the alternate frequency with him aboard each ship. The ship's
VHF radio is also capable of reaching these stations. The Central Control Building call sign is
KBP 359.

All portable radios are certified to be "intrinsically safe" and are so embossed on the
manufacturer's equipment label.

II. LANGUAGE

The official language of the terminal is English. The ship shall provide at all times personnel
capable of communicating in English with the Mooring Master and between the ship and
terminal personnel ashore. An English-speaking member of the vessel's crew shall be stationed
at all times at the radio provided for communications between the ship and terminal personnel
ashore.
SECTION 6. - SAFETY

I. PERSONNEL SAFETY EQUIPMENT

Personnel safety equipment will be adequate, readily available, and clearly identified. The ship
shall ensure that life ring buoys are kept available in the vicinity of the pilot ladder and the
ladder will be kept at a proper height for safe boarding on and off. All personnel are to embark
or disembark utilizing a properly rigged Pilot ladder or combination ‘Pilot/Accommodation’
ladder. An accommodation ladder alone will not be used.

II. FIRE FIGHTING EQUIPMENT

Firefighting equipment shall be in readiness throughout the vessel. Fire hoses with nozzles
will be laid out for immediate use on the cargo deck. There are no fixed platforms at the Island
Energy Services mooring.

III. MINIMUM PERSONNEL ABOARD

The vessel shall provide sufficient personnel to moor, connect hoses, and conduct cargo
operations safely. It shall retain sufficient personnel aboard (where shore leave is permitted) to
disconnect hoses and unmoor vessel in the case of bad weather or other emergency.

Not less than one deck officer shall be on watch either at the control room or on deck. He shall
have at least two crew members on deck, alert and available at all times. One of the two crew
members shall be in sight of the cargo hoses and the ship's manifold at all times. No person
under the influence of alcohol, marijuana, or any drug is to be allowed on deck.

IV. ILLUMINATION OF VESSEL

The vessel shall be illuminated as a minimum in accordance with existing U.S. Coast Guard
regulations, providing, however, that the vessel have sufficient illumination of all spaces and
working areas associated with transfer and mooring operations. This shall include all ladders
and passageways between key operating stations, such as the pump room and ship's manifold.

In addition, vessels transferring cargo during darkness will illuminate the sea area around the
vessel. Illumination is required in order that any oil on the surface of the sea may be detected
readily so that appropriate action may be taken in a timely manner. The vessel will also display
anchor lights for a vessel for her class while at anchor awaiting berth or while in the mooring.
 V. DANGEROUS GAS HAZARDS

The transfer of any product which may contain dangerous concentrations of toxic gas, such as
crudes containing hydrogen sulfide, must be undertaken only with appropriate personnel safety
precautions. The same precautions must be taken when loading tanks which have previously
held product containing such dangerous gas.

VI. SMOKING/ALCOHOL POLICY

The ship's Master in consultation with the Mooring Master shall designate smoking areas. No
smoking will be permitted on deck while in the moorings. Smoking may be prohibited entirely
at times by the Mooring Master. Cigarette butts must be disposed of in appropriate containers
and shall not be thrown overboard or through portholes at any time. The ship’s Master shall be
advised of the Island Energy Services Alcohol Policy as per Appendix III.

VII. RADIOS AND ELECTRICAL EQUIPMENT ON DECK

No radio (including portable transistor radios) or electrical tool or appliance shall be used on
deck unless certified for use in hazardous petroleum areas, and then only with approval of the
Mooring Master.

VIII. TANK HATCHES AND ULLAGE PLUGS

Tank hatches and ullage plugs shall be kept closed at all times except when gauging, thieving,
or sampling and then only with the approval of the Mooring Master.

IX. DOORS, PORTHOLES AND VENTILATORS

Doors and portholes facing the main decks shall be closed and remain closed. Ventilators shall
be kept in proper trim to minimize fire and explosion hazard.

X. FIREBOATS

A fireboat may be available, but only from Honolulu harbor. Because of the distance to the
harbor, this fireboat would be called upon only in the event that the ship's equipment cannot
control a fire.

XI. CRUDE WASHING

Crude washing should be undertaken only with concurrence of Mooring Master. The Shore
Control Operator shall be notified also. See Appendix X for details.
XII. INERT GAS SYSTEMS

Normally a vessel fitted with an inert gas system (IGS) will not be permitted to carry on cargo
operations unless the inert gas system is in good order and in operation. When an IGS equipped
vessel arrives with the system inoperative, the vessel will not be berthed until the IGS is
repaired and/or put in operation. If the IGS breaks down after the vessel has berthed, all cargo
operations will be stopped and the terminal may elect to take the vessel off the berth unless the
IGS is repaired in a reasonable time. See Appendix X for details regarding IGS operation.

All time lost because of the IGS being inoperative and/or out of order will be for vessel
account.

XIII. SUSPENSION OF OFF LOADING DURING HOSTILE MOORING CONDITIONS

Responsibility

Suspension of offloading during hostile mooring conditions is a judgment call by the ship's
master, on the advice of the Mooring Master.

Ship Characteristics

The characteristics of a ship's equipment and crew are important factors when considering
suspension of mooring operations. Good handling ships are equipped with efficient anchor
windlasses and mooring winches and synthetic ropes. They are also capable of loading
segregated ballast during discharge to maintain at least 30% of the vessels D.W.T. and their
crews are experienced and familiar with the off shore mooring.

General Guidelines for Suspending Operation

When a ship is in our seven point mooring, the main consideration is the safety of the pipeline
transfer hoses and every action taken is based on preserving its integrity and avoiding a
pollution incident.
Parameters in Mooring Analysis for Stopping Cargo Operations and Vacating Berth

When weather conditions are at or near the allowable limits, the best indicator is often observing
the buoys. If buoys do not submerge, the combined forces are normally within safe limits.

Stop Cargo and Vacate Berth:

- any winds other than S'ly quadrant (SE to SW) with sustained winds of 30+ kts
- seas and/or swells causing buoys to submerge
- currents causing buoys to submerge

For S'ly quadrant (SE to SW) winds:

- stop cargo operation with sustained winds 15+ kts
- drop hose and vacate berth with sustained winds 18-20+ kts

The decision to suspend operations or depart the mooring is to be made by the ship's Master
on the advice of the Mooring Master.

Consideration must be given to the fact that the Barbers Point mooring site is located in a
completely open sea environment and is exposed to extreme elements of wind, waves, currents
and heavy ocean swells.
SECTION 7. WATER POLLUTION CONTROL

I. OIL SPILL CONTAINMENT EQUIPMENT

In accordance with U.S. Coast Guard Regulations, a fixed container or enclosed deck area must
be provided under or around each oil loading manifold and each oil transfer connecting area. A
means of draining or removing spilled oil from each container or enclosed deck area must also
be provided. Any such enclosed deck area must have means of closing each scupper or drain.

II. SPILL AVOIDANCE INSPECTION

With the help of the Mooring Master, the Master will ensure that sea suction valves are
securely closed and lashed prior to starting any cargo transfer operations. Overboard
discharge lines connected to the cargo system are also to be checked to ensure that they are
effectively blocked off. Manifolds not in use will be kept blanked. If cargo is to be discharged,
all loading drops are to be securely closed. All deck scuppers are to be kept effectively
plugged and drip pans or appropriate enclosed deck areas are to be placed under manifold
hose connections. Deck hose is to be properly supported.

III. OIL-TIGHT SHIP

A vessel will be subject to rejection if inspection by the Mooring Master shows the ship not to
be oil-tight. Should a leak develop while the vessel is berthed at the Terminal, every effort shall
be made to stop that leak as quickly as possible. As a minimum this shall consist of using all
ship's pumps to transfer oil from the leaking tank or tanks. Divers for emergency hull repairs in
the moorings may be arranged for by the vessel's agent with the prior concurrence of the
Mooring Master.

IV. RESPONSIBILITY FOR OIL DISCHARGES OR SPILL

If a vessel discharges or spills oil in the vicinity of the Terminal, the Terminal operators shall
have the right to take any action that may be necessary to clean up the contaminated area. This
area includes not only the sea area involved, but the shore, vessels, and any structure or property
located in or upon the sea or on the shore. Island Energy Services shall have the right to settle
any claims of third parties arising from such contamination. All costs and expenses incurred
by the Company in the course of the cleanup or claims settlement shall be borne by the
vessel or by those owning the vessel at the time of the said contamination. Island Energy
Services shall be entitled to reimbursement by said owners for any such costs and expenses.

In the event of such a contamination, the ship's Master will have been expected to
acknowledge the responsibility by signing and delivering to Island Energy Services a copy
of the form shown in Appendix II.
V. DRIP, DISCHARGE, AND SPILL CONTAINMENT AND COLLECTION

The Terminal maintains a comprehensive Oil Spill Contingency Plan. The plan provides for
bringing all required, available personnel and equipment into action to stop, contain, and
collect any oil spilled into the sea.

IMPORTANT: IN THE EVENT OF AN OIL SPILL, ANY VESSEL IN THE

MOORINGS AUTOMATICALLY BECOMES PART OF THE CLEANUP
OPERATION. Any vessel calling on the Terminal should be prepared to make all of its
facilities available to assist in the containment and collection of any spill associated with the
Terminal.

VI. OIL SPILL CONTINGENCY PLANS

The procedures to be followed in the event of an oil spill in open waters such as the mooring
area are highly dependent on conditions existing at the time of the spill. Many factors must be
evaluated in order for the proper action to be taken to contain and/or clean up the spill.
Examples are the size, location and extent of the spill, wind, weather, ocean current and general
sea conditions, the time of day, the type of oil spilled, etc. Therefore, the following procedures
serve only as a guide for oil spill control, containment and cleanup and variations may be made
at the discretion of the individual directing oil spill operations.

A. OIL SPILLS ON THE DECK OF A VESSEL

If an oil spill occurs on the deck of a vessel, the vessel's officers, with the counsel of
the Mooring Master, will provide guidance to vessel's crew in the containment and
cleanup of the oil. They will immediately locate the source of the oil and prevent
further spillage. Oil spillage into the water must be avoided if at all possible. Should
any oil spill on deck, all cargo transfer operations will be shut down immediately and
will not resume until the spill has been satisfactorily cleaned up and authorization is
received from the U. S. Coast Guard Captain of the Port to resume operations. If oil
reaches the water, the procedures below under Paragraph B will be followed.

B. OIL SPILLS IN THE MOORING AREA WATERS

Oil spills may originate in the mooring area waters from a vessel, the marine hose
system or the submarine pipelines. The Mooring Master will assist vessel's crew in
surveillance of the mooring area for oil spillage from any source. If an oil spill occurs
and oil enters the water, the Mooring Master will assist vessel's crew in locating the
source of the spill and taking whatever action necessary to reduce or prevent
additional leakage. When the cause of the oil spill has been located and corrected,
the vessel then initiates cleanup and containment procedures applicable to existing
conditions. The vessel will also ensure that the oil spill is reported to the
U. S. Coast Guard and will keep shore personnel advised of the status of the spill.
The vessel must advise the Refinery via radio of onshore activities required to reduce
or eliminate oil spillage (i.e., shutting down the transfer pump, closing valves,
requesting materials, requesting boom, requesting clean-up personnel, etc.).
1. Vessel Leaks

If a vessel develops a hull leak, the deck officer will transfer the contents of the
leaking compartment to another of the vessel's compartments, if possible. If an oil spill
results from vessel's discharge system the deck officer will have the system shut down
immediately.

2. Marine Hose Failure

Procedures for controlling oil spills resulting from failure of marine hoses will vary
depending on circumstances but, in general, the following actions will be taken:

a) The deck officer will have oil transfer operations immediately stopped and
blocked in. If the transfer is to the vessel, he contacts the control house via radio
to request the onshore loading pump be shut down and tanks blocked in via the
remote control system. If the transfer is from the vessel, he has the vessel's pump
stopped and the shore puts a vacuum on hose.

b) The deck officer will request Refinery personnel via radio to take suction on
the appropriate system with the onshore emergency evacuation pump. This
should cause sea water to be sucked into the hose at the point of leakage and
prevent further spillage.

c) The Mooring Master may direct the line boat to kink the hose by folding it back
on itself. This would minimize further spillage.

d) The U. S. Coast Guard is notified of the oil spill situation.

e) Divers are called out to install a special slip blind to isolate the leaking hose
section.

f) A new hose section is readied and a boat takes it to the mooring area.

g) Divers lower the new hose into the desired underwater location and the hose
string is straightened.

h) The defective hose section is disconnected underwater leaving the special slip
blind in place and the new hose section is attached.

i) When the new hose section has been bolted up loosely, the special slip blind is
removed by the divers and the flange bolts tightened securely.
 3. Submarine Pipeline Failure

Procedures for controlling oil spills which occur as a result of a leak in a submarine
pipeline are similar to those employed with failure of marine hoses (items A-D above).
If a submarine pipeline leak occurs that is relatively small, temporary repairs may be
made by installation of wooden or steel plugs. If the pipeline leak is the result of a
major rupture, permanent repairs would be more difficult to make and would take
much longer, possibly several days. A temporary clamp would be installed until such
repairs were complete and an underwater tent may be required to be installed over the
leak to permit leaking oil to be gathered and pumped to a boat or barge above.

C. USCG AREA CONTINGENCY PLAN

The Coast Guard has prepared the Hawaii Area Contingency Plan covering the existing
local facilities. These action plans are response actions recommended by the Coast Guard
for any oil spill. This plan is available at the Hawaii Oil Spill Response Center.

D. SPILL CLEANUP

Spill cleanup will be handled in accordance with the Hawaii Refinery Oil Spill Response
Plan. This manual is available to all persons responsible for oil transfer via the offshore
mooring. The Marine Safety Office also maintains a copy. This manual details reporting,
containment, and response plans for all types of oil spills.

E. CONTAINMENT EQUIPMENT

The area of the refinery where the marine pipelines emerge above ground is protected by
dikes which are designed to adequately impound any oil leakage from valve packings, flange
leaks or pipeline leaks.

The Refinery is a member of CLEAN ISLANDS COUNCIL OIL SPILL COOPERATIVE

(CIC). Should an onshore or offshore oil spill occur, the Refinery has access to all the CIC
equipment. A complete list of CIC equipment is listed in Appendix VI.

The oil spill response vessel "Clean Islands" is available to assist in the event of an
offshore oil spill. This vessel is 130 feet long and is equipped with expanding booms,
sorbents, a Walosep skimmer and other equipment required to quickly contain and clean
up an offshore spill.

A complete list of oil spill equipment aboard the O.S.R.V. is listed in Appendix VI.

Various lengths of oil spill containment boom, as required by OPA 90, shall be available
at the mooring aboard the line boat. The spill boom shall be ready for immediate
deployment and the vessel and crew may be requested to assist in containing any oil spill
incidents occurring.
SECTION 8. TRAINING PROGRAMS

Each Island Energy Services employee assigned to handle operations involving transfers of
products to or from vessels in the mooring area has had adequate training to qualify him for
such responsibilities. Operators receive approximately two weeks of detailed training in Blending
and Shipping operations by a qualified operator under the guidance of the Shift Team Leader
prior to being assigned to one of the Blending and Shipping Operator positions. Such training
includes observation of operator functions and activities, plus first hand performance under the
direction of the Operator conducting the training. In addition, each Operator goes through
extensive on and off the job training programs directly applicable to this position. Satisfactory
completion of these programs is verified by written and oral examinations. Each operator’s
individual training records are on file at the Central Control Building for review by the U.S. Coast
Guard.

Each Head Operator is trained in the Operator positions as well as the Head Operator position
before he is assigned Head Operator responsibilities. He has previously qualified in Operator
level jobs before he is trained as a Head Operator. He also is put through an on-the-job training
program designed specifically for this position. Satisfactory completion of the program is verified
by written and oral examinations.

Shift Team Leaders have had operation experience before being selected to train in these
positions. Each must be familiar with the responsibilities of all subordinate functions and
receives training in each according to his knowledge and experience. Supervisor training is
provided by Operators, Head Operators and other Shift Team Leaders as necessary to qualify
him for the responsibilities of this assignment.

Island Energy requires all Mooring Masters to have a broad maritime background, primarily
on oil tankers, and possess an Unlimited Masters License issued by the U.S. Coast Guard.
Mooring Masters undergo thorough training in all aspects of the mooring and terminal
operations. Mooring Master trainees will complete all requirements to achieve Mooring
Master Assistant as the first level of training. Mooring Master trainees will also be required
to obtain endorsements on their U.S. Coast License of First Class Pilot for the Island Energy
Conventional Buoy Mooring (formerly Chevron Offshore mooring and approaches) and
Tankerman (P.I.C.). Upon completion of all training they are issued a letter or certificate of
Mooring Master in Charge by Island Energy. In accordance with CFR 33 part 154.710,
Person in Charge must have had at least 48 hours of experience in transfer operation at a
facility of operations.

The Person in Charge should be aware and knowledgeable of the following:

1. The hazards of each product to be transferred.

2. The rules in CFR 33, part 154.710 and part 156.
3. The facility operating procedures as described in the Operations Terminal Manual.
4. Vessel transfer and control systems.
5. Local discharge reporting procedures.
6. The facility's contingency plan for discharge reporting and containment.
SECTION 9. – DESCRIPTION OF CARGO HANDLED (SDS)

The IES Barbers Point Marine Terminal transfers products between the terminal and the refinery over 20” and
30” diameter lines.

The 30” diameter marine line handles the transferring of crude oil, fuel oil, diesel fuel No. 2, and vacuum gas
oil.

The 20” diameter marine line handles the transferring of gasoline, gasoline components, naphtha, and diesel.

Safety Data Sheets (SDS) for the following products transferred at the Barbers Point Marine Terminal follow:
• Crude Oil
• Chevron Fuel Oil 6
• Vacuum Gas Oils (VGO)
• Gasoline (Generic) and components
• Naphtha
• Diesel Fuel No. 2

Island Energy Services is in the process of creating Safety Data Sheets (SDS) to replace the Chevron SDS sheets
in this section. Island Energy Services will provide its new SDS sheets the next time the Barbers Point Marine
Terminal Manual is revised.
Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Crude Oil
Product Use: Refinery feed stock
Product Number(s): CPS294605, CPS294607, CPS294609, CPS294611, CPS294613, CPS294615,
CPS294617, CPS294619, CPS294623, CPS294629, CPS294635, CPS294637, CPS294639, CPS294647,
CPS296000, CPS296251, CPS296252, CPS296253, CPS296254, CPS296277, CPS296926, CPS296927,
CPS296935, CPS296936, CPS296938, CPS296945, CPS296946, CPS296999, CPS297556, CPS301455
Synonyms: Sour Crude, Heavy Crude, Petroleum, Sweet Crude
Company Identification
Chevron Products Company
Environment & Safety
P. O. Box 1635, 1301 McKinney
Houston, TX 77251
United States of America

Transportation Emergency Response

CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
MSDS Requests: (510) 242-7131

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable liquid: Category 2. Aspiration toxicant: Category 1. Carcinogen: Category

1B. Eye irritation: Category 2A. Target organ toxicant (repeated exposure): Category 2. Target organ
toxicant (central nervous system): Category 3. Chronic aquatic toxicant: Category 2.

Signal Word: Danger

Physical Hazards: Highly flammable liquid and vapor.

Health Hazards: May be fatal if swallowed and enters airways. May cause cancer. Causes serious eye
irritation. May cause drowsiness or dizziness.

Environmental Hazards: Toxic to aquatic life with long lasting effects.

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Revision Number: 19 1 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
Target Organs: May cause damage to organs (Blood/Blood Forming Organs, Liver, Spleen, Thymus)
through prolonged or repeated exposure.

PRECAUTIONARY STATEMENTS:
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking.
Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use explosion-proof
electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing
dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective
gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.
Wash thoroughly after handling. Avoid release to the environment.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Take off
immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. IF
SWALLOWED: Immediately call a poison center or doctor/physician. Do NOT induce vomiting. Call a
poison center or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. IF
exposed or concerned: Get medical advice/attention. In case of fire: Use media specified in the SDS to
extinguish. Collect spillage.
Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

HAZARDS NOT OTHERWISE CLASSIFIED: May release highly toxic and flammable hydrogen sulfide
gas (H2S).

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Crude oil 8002-05-9 100 %wt/wt
Xylene 1330-20-7 < 5 %wt/wt
Toluene 108-88-3 < 3 %wt/wt
Hexane 110-54-3 < 2 %wt/wt
Benzene 71-43-2 < 1 %wt/wt
Ethylbenzene 100-41-4 < 1 %wt/wt
Hydrogen sulfide 7783-06-4 > 0.002 %wt/wt

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye: Flush eyes with water immediately while holding the eyelids open. Remove contact lenses, if worn,
after initial flushing, and continue flushing for at least 15 minutes. Get medical attention if irritation persists.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical
attention if any symptoms develop. To remove the material from skin, use soap and water. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by
mouth to an unconscious person.
Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention if breathing difficulties continue. If exposure to hydrogen
_____________________________________________________________________

Revision Number: 19 2 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
sulfide (H2S) gas is possible during an emergency, wear an approved, positive pressure air-supplying
respirator. Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get immediate medical attention.

Most important symptoms and effects, both acute and delayed

IMMEDIATE SYMPTOMS AND HEALTH EFFECTS
Eye: Contact with the eyes causes irritation. Symptoms may include pain, tearing, reddening, swelling and
impaired vision.
Skin: Skin contact may cause drying or defatting of the skin. Contact with the skin is not expected to cause
an allergic skin response. Symptoms may include pain, itching, discoloration, swelling, and blistering. Not
expected to be harmful to internal organs if absorbed through the skin.
Ingestion: Because of its low viscosity, this material can directly enter the lungs, if swallowed, or if
subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death.
Inhalation: The vapor or fumes from this material may cause respiratory irritation. Symptoms of
respiratory irritation may include coughing and difficulty breathing. Excessive or prolonged breathing of this
material may cause central nervous system effects. Central nervous system effects may include
headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness,
confusion, or disorientation. At extreme exposures, central nervous system effects may include respiratory
depression, tremors or convulsions, loss of consciousness, coma or death. Hydrogen sulfide has a strong
rotten-egg odor. However, with continued exposure and at high levels, H2S may deaden a person's sense
of smell. If the rotten egg odor is no longer noticeable, it may not necessarily mean that exposure has
stopped. At low levels, hydrogen sulfide causes irritation of the eyes, nose, and throat. Moderate levels
can cause headache, dizziness, nausea, and vomiting, as well as coughing and difficulty breathing. Higher
levels can cause shock, convulsions, coma, and death. After a serious exposure, symptoms usually begin
immediately.

The U.S. National Institute for Occupational Safety and Health (NIOSH) considers air concentrations of
hydrogen sulfide gas greater than 100 ppm to be Immediately Dangerous to Life and Health (IDLH).

DELAYED OR OTHER SYMPTOMS AND HEALTH EFFECTS: Prolonged or repeated exposure to this
material can cause cancer. Contains material that may cause damage to the following organ(s) following
repeated skin contact based on animal data: Liver Blood/Blood Forming Organs spleen Thymus Risk
depends on duration and level of exposure. See Section 11 for additional information.

Indication of any immediate medical attention and special treatment needed

Note to Physicians: Administration of 100% oxygen and supportive care is the preferred treatment for
poisoning by hydrogen sulfide gas. For additional information on H2S, see Chevron MSDS No. 301.
Ingestion of this product or subsequent vomiting may result in aspiration of light hydrocarbon liquid, which
may cause pneumonitis.

SECTION 5 FIRE FIGHTING MEASURES

See Section 7 for proper handling and storage.

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Do not use water spray or a direct stream of water.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire
space without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion. Combustion may form oxides of: Sulfur,
Nitrogen.

_____________________________________________________________________

Revision Number: 19 3 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
 SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area with combustible gas
indicator. If this material is released into a work area, evacuate the area immediately. Persons entering the
contaminated area to correct the problem or to determine whether it is safe to resume normal activities
must comply with all instructions in the Exposure Controls/PersonalProtection section.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated
materials in disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities as appropriate or required.

SECTION 7 HANDLING AND STORAGE

Precautionary Measures: Do not get in eyes, on skin, or on clothing. This material presents a fire hazard.
Liquid quickly evaporates and forms vapor (fumes) which can catch fire and burn with explosive violence.
Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding
equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises above
-10C (15F). Do not get in eyes. Do not taste or swallow. Do not breathe vapor or fumes. Wash
thoroughly after handling.
General Storage Information:DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE
AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.
Unusual Handling Hazards: Toxic quantities of hydrogen sulfide (H2S) may be present in storage tanks
and bulk transport vessels which contain or have contained this material. Persons opening or entering
these compartments should first determine if H2S is present. See Exposure Controls/Personal Protection
-Section 8. Do not attempt rescue of a person over exposed to H2S without wearing approved supplied-air
or self-contained breathing equipment. If there is a potential for exceeding one-half the occupational
exposure standard, monitoring of hydrogen sulfide levels is required. Since the sense of smell cannot be
relied upon to detect the presence of H2S, the concentration should be measured by the use of fixed or
portable devices.
General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,
sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use
appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106,
'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended
Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003,
'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

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Revision Number: 19 4 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and
other substances in the work place when designing engineering controls and selecting personal protective
equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful
levels of this material, the personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the equipment since protection is usually
provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below the recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: Wear protective equipment to prevent eye contact. Selection of protective equipment
may include safety glasses, chemical goggles, face shields, or a combination depending on the work
operations conducted.
Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may
include gloves, apron, boots, and complete facial protection depending on operations conducted.
Suggested materials for protective gloves include: Polyvinyl Alcohol (PVA) (Note: Avoid contact with water.
PVA deteriorates in water.), Viton.
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational
exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an
approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator
for Organic Vapors.
Determine if airborne concentrations are below the occupational exposure limit for hydrogen sulfide. If not,
wear an approved positive pressure air-supplying respirator. For more information on hydrogen sulfide, see
Chevron MSDS No. 301. Refer to the OSHA Benzene Standard to determine what type of respirator is
required based on exposure levels.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation

Crude oil Not -- -- -- --
Applicable
Hydrogen sulfide ACGIH 10 ppm 15 ppm -- --
(weight) (weight)
Hydrogen sulfide CVX 5 ppm 15 ppm -- --
Hydrogen sulfide OSHA Z-2 -- -- 20 ppm --
(weight)
Xylene ACGIH 100 ppm 150 ppm -- A4
(weight) (weight)
Xylene OSHA Z-1 435 mg/m3 -- -- --
Toluene ACGIH 50 ppm -- -- Skin A4
(weight)
Toluene OSHA Z-2 200 ppm -- 300 ppm --
(weight) (weight)
Hexane ACGIH 50 ppm -- -- Skin
(weight)
Hexane OSHA Z-1 1800 mg/m3 -- -- --
Benzene ACGIH .5 ppm 2.5 ppm -- Skin A1
(weight) (weight) Skin
Benzene CVX 1 ppm 5 ppm -- --
(weight) (weight)

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Revision Number: 19 5 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
Benzene OSHA SRS 1 ppm 5 ppm -- --
(weight) (weight)
Benzene OSHA Z-2 10 ppm -- 25 ppm --
(weight) (weight)
Ethylbenzene ACGIH 20 ppm 125 ppm -- A3
(weight) (weight)
Ethylbenzene OSHA Z-1 435 mg/m3 -- -- --
Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Amber to Black

Physical State: Viscous liquid
Odor: Mild to pungent sulfurous odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: 0 - 14 psia
Vapor Density (Air = 1): >1
Initial Boiling Point: 37.8°C (100°F) - >815.6°C (1500°F)
Solubility: Soluble in hydrocarbon solvents; insoluble in water.
Freezing Point: Not Applicable
Specific Gravity: 0.75 - 1.04
Viscosity: <0.9 cSt - >20000 cSt @ 40°C (104°F)
Decomposition temperature: No Data Available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available
Flashpoint: < 15 °C - 93 °C (< 59 °F - 199 °F)
Autoignition: 280 °C (536 °F)
Flammability (Explosive) Limits (% by volume in air): Lower: 1.4 Upper: 7.6

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Conditions to Avoid: Avoid contact with heat, light, catalysts, halogens or any other chemicals.
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product
components.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product
components.

_____________________________________________________________________

Revision Number: 19 6 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product
components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components.

Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
components.

Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.
Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Contains
benzene, which has been classified as a carcinogen by the National Toxicology Program (NTP) and a
Group 1 carcinogen (carcinogenic to humans) by the International Agency for Research on Cancer (IARC).

Contains ethylbenzene which has been classified as a Group 2B carcinogen (possibly carcinogenic to
humans) by the International Agency for Research on Cancer (IARC).

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
components or a similar material.
Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:

The International Agency for Research on Cancer (IARC) reviewed the carcinogenic potential of crude oil
in 1989 and concluded that there was limited evidence for the carcinogenicity of crude oil in animals and
inadequate evidence for the carcinogenicity of crude oil in humans. The basis for the findings for animals
are results from studies in which crudes applied to the skin of lab animals showed benign and malignant
skin tumors in some studies, but not in others.

This product contains n-hexane.

TARGET ORGAN TOXICITY: Prolonged or repeated ingestion, skin contact or breathing of vapors of
n-hexane has been shown to cause peripheral neuropathy. Recovery ranges from no recovery to complete
recovery depending upon the severity of the nerve damage. Exposure to 1000 ppm n-hexane for 18 hr/day
for 61 days has been shown to cause testicular damage in rats. However, when rats were exposed to
higher concentrations for shorter daily periods (10,000 ppm for 6 h/day, 5 days/wk for 13 weeks), no
testicular lesions were seen.
CARCINOGENICITY: Chronic exposure to commercial hexane (52% n-hexane) at a concentration of
9000ppm was not carcinogenic to rats or to male mice, but did result in an increased incidence of liver
tumors in female mice. No carcinogenic effects were observed in female mice exposed to 900 or 3000 ppm
hexane or in male mice. The relevance for humans of these hexane-induced mouse liver tumors is
questionable.
GENETIC TOXICITY: n-Hexane caused chromosome aberrations in bone marrow of rats, but was negative
in the AMES and mouse lymphoma tests.

This product may contain significant amounts of Polynuclear Aromatic Hydrocarbons (PAH's) which have
been shown to cause skin cancer after prolonged and frequent contact with the skin of test animals. Brief
or intermittent skin contact with this product is not expected to have serious effects if it is washed from the
skin. While skin cancer is unlikely to occur in human beings following use of this product, skin contact and
breathing, of mists, vapors or dusts should be reduced to a minimum.

_____________________________________________________________________

Revision Number: 19 7 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
This product contains toluene.
GENERAL TOXICITY: The primary effects of exposure to toluene in animals and humans are on the
central nervous system. Solvent abusers, who typically inhale high concentrations (thousands of ppm) for
brief periods of time, in addition to experiencing respiratory tract irritation, often suffer permanent central
nervous system effects that include tremors, staggered gait, impaired speech, hearing and vision loss, and
changes in brain tissue. Death in some solvent abusers has been attributed to cardiac arrhythmias, which
appear to be have been triggered by epinephrine acting on solvent sensitized cardiac tissue. Although liver
and kidney effects have been seen in some solvent abusers, results of animal testing with toluene do not
support these as primary target organs.
HEARING: Humans who were occupationally exposed to concentrations of toluene as low as 100 ppm for
long periods of time have experienced hearing deficits. Hearing loss, as demonstrated using behavioral and
electrophysiological testing as well as by observation of structural damage to cochlear hair cells, occurred
in experimental animals exposed to toluene. It also appears that toluene exposure and noise may interact
to produce hearing deficits.
COLOR VISION: In a single study of workers exposed to toluene at levels under 50 ppm, small decreases
in the ability to discriminate colors in the blue-yellow range have been reported for female workers. This
effect, which should be investigated further, is very subtle and would not likely have been noticed by the
people tested.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: Toluene may also cause mental and/or growth
retardation in the children of female solvent abusers who directly inhale toluene (usually at thousands of
ppm) when they are pregnant. Toluene caused growth retardation in rats and rabbits when administered at
doses that were toxic to the mothers. In rats, concentrations of up to 5000 ppm did not cause birth defects.
No effects were observed in the offspring at doses that did not intoxicate the pregnant animals. The
exposure level at which no effects were seen (No Observed Effect Level, NOEL) is 750 ppm in the rat and
500 ppm in the rabbit.

This product contains xylene.

ACUTE TOXICITY: The primary effects of exposure to xylene in animals and humans are on the central
nervous system. In addition,in some individuals, xylene exposure can sensitize cardiac tissue to
epinephrine which may precipitate fatal ventricular fibrillation. DEVELOPMENTAL TOXICITY: Xylene has
been reported to cause developmental toxicity in rats and mice exposed by inhalation during pregnancy.
The effects noted consisted of delayed development and minor skeletal variations. In addition, when
pregnant mice were exposed by ingestion to a level that killed nearly one-third of the test group, lethality
(resorptions) and malformations (primarily cleft palate) occurred. Since xylene can cross the placenta, it
may be appropriate to prevent exposure during pregnancy. GENETIC TOXICITY/CARCINOGENICITY:
Xylene was not genotoxic in several mutagenicity testing assays including the Ames test. In a cancer study
sponsored by the National Toxicology Program (NTP),technical grade xylene gave no evidence of
carcinogenicity in rats or mice dosed daily for two years. HEARING: Mixed xylenes have been shown to
cause measurable hearing loss in rats exposed to 800 ppm in the air for 14 hours per day for six weeks.
Exposure to 1450 ppm xylene for 8 hours caused hearing loss while exposure to 1700 ppm for 4 hours did
[Link] no information is available for lower concentrations, other chemicals that cause hearing loss in
rats at relatively high concentrations do not cause hearing loss in rats at low concentrations. Worker
exposure to xylenes at the permissible exposure limit (100 ppm, time-weighted average) is not expected to
cause hearing loss.

This product contains benzene.

GENETIC TOXICITY/CANCER: Repeated or prolonged breathing of benzene vapor has been associated
with the development of chromosomal damage in experimental animals and various blood diseases in
humans ranging from aplastic anemia to leukemia (a form of cancer). All of these diseases can be fatal. In
some individuals, benzene exposure can sensitize cardiac tissue to epinephrine which may precipitate fatal
ventricular fibrillation.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: No birth defects have been shown to occur in pregnant
laboratory animals exposed to doses not toxic to the mother. However, some evidence of fetal toxicity such
as delayed physical development has been seen at such levels. The available information on the effects of
benzene on human pregnancies is inadequate but it has been established that benzene can cross the

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human placenta.
OCCUPATIONAL: The OSHA Benzene Standard (29 CFR 1910.1028) contains detailed requirements for
training, exposure monitoring, respiratory protection and medical surveillance triggered by the exposure
level. Refer to the OSHA Standard before using this product.

GENETIC TOXICITY: Ethylbenzene tested negative in the bacterial mutation test, Chinese Hamster Ovary
(CHO) cell in vitro assay, sister chromatid exchange assay and an unscheduled DNA synthesis assay.
Conflicting results have been reported for the mouse lymphoma cell assay. Increased micronuclei were
reported in an in vitro Syrian hamster embryo cell assay; however, two in vivo micronuclei studies in mice
were negative. In Syrian hamster embryo cells in vitro, cell transformation was observed at 7 days of
incubation but not at 24 hours. Based on these results, ethylbenzene is not expected to be mutagenic or
clastogenic. CARCINOGENICITY: In studies conducted by the National Toxicology Program, rats and mice
were exposed to ethylbenzene at 25, 250 and 750 ppm for six hours per day, five days per week for 103
weeks. In rats exposed to 750 ppm, the incidence of kidney tubule hyperplasia and tumors was increased.
Testicular tumors develop spontaneously in nearly all rats if allowed to complete their natural life span; in
this study, the development of these tumors appeared to be enhanced in male rats exposed to 750 ppm. In
mice, the incidences of lung tumors in males and liver tumors in females exposed to 750 ppm were
increased as compared to control mice but were within the range of incidences observed historically in
control mice. Other liver effects were observed in male mice exposed to 250 and 750 ppm. The incidences
of hyperplasia were increased in the pituitary gland in female mice at 250 and 750 ppm and in the thyroid in
male and female mice at 750 ppm.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is expected to be toxic to aquatic organisms and may cause long-term adverse effects in the
aquatic environment. The product has not been tested. The statement has been derived from the
properties of the individual components.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is not expected to be readily biodegradable. The product has not been tested. The statement
has been derived from the properties of the individual components.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

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Due to the potential variability in the physical and chemical properties of naturally occurring hydrocarbon
materials, transport classifications should be evaluated at the time of shipment on a cargo specific basis,
if possible. The guidance provided below is given for convenience only, without any warranty or
guarantee of any kind, and is accepted and used at the recipient’s sole risk:
The DG Transport Packing group (PG) is a function of the Initial Boiling Point (IBP) and Flash Point,
Pensky-Martens, Closed Cup (PM CC) of the material:
· PG I if the IBP </=35 deg C (95 deg F);
· PG II if the IBP > 35 deg C (95 deg F) with a FP is below 23 deg C (73 deg F); or
· PG III if the IBP > 35 deg C (95 deg F) with a FP >/= 23 deg C (73 deg F) but </= 60 deg C (140 deg
F)
· For US DOT jurisdictions only, liquids with a Flash Point (PM CC) > 60 deg C (140 deg F) but < 93
deg C (200 deg F) may be derogated to be Hazard Class, COMBUSTIBLE LIQUID. Disclosure as
Toxic to the Aquatic Environment (marine pollutant) is optional.
· For International jurisdictions, liquid petroleum crude oils outside the regulated Flash Point
ranges are UN3082 Environmentally Hazardous Substances when classified Toxic to the Aquatic
Environment (e.g., Acute 1, Chronic 1, and/or Chronic 2 Aquatic Toxics per IMO/IMDG , ADR,
UNMR Chapters 2.9).

Petroleum crude oils NOT containing or NOT potentially generating hydrogen sulfide in sufficient
concentrations to pose an inhalation hazard in head space vapors may be consigned under the
following:

US DOT
Shipping Description: UN1267, PETROLEUM CRUDE OIL, 3, PG I, II, or III
· UN number: UN1267
· UN proper shipping name: PETROLEUM CRUDE OIL
· Transport hazard class(es): 3
· Packing group: I, II, or III
· Environmental hazards: Disclosure of Acute 1, Chronic 1 and/or Chronic 2 Aquatic Toxics as an
environmentally hazardous/marine pollutant (MP) is optional.
· Special precautions for user: See Special Provisions in the 49 CFR HMR

ADR/RID:
Shipping Description: UN1267 PETROLEUM CRUDE OIL, 3, PG I, II, or III ADR CODE F1, MARINE
POLLUTANT/ENVIRONMENTALLY HAZARDOUS SUBSTANCE
· UN number: UN1267
· UN proper shipping name: PETROLEUM CRUDE OIL
· Transport hazard class(es): 3
· Packing group: I, II, or III
· Environmental hazards: Acute 1, Chronic 1 and/or Chronic 2 Aquatic Toxics are environmentally
hazardous/marine pollutant (MP) for Transport
· Special precautions for user: See Special Provisions in the ADR/RID code

ICAO/IATA:
Shipping Description: UN1267, PETROLEUM CRUDE OIL, 3, PG I, II, or III
· UN number: UN1267
· UN proper shipping name: PETROLEUM CRUDE OIL
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Revision Date: OCTOBER 02, 2014 SDS : 2493
 · Transport hazard class(es): 3
· Packing group: I, II, or III
· Environmental hazards: Acute 1, Chronic 1 and/or Chronic 2 Aquatic Toxics are environmentally
hazardous/marine pollutants (MP) for transport. Environmentally hazardous/Marine Pollutant
disclosure is not required if the material has another transport Hazard Class 1 -8.
· Special precautions for user: See all Special Provisions in ICAO Technical Instructions or the IATA
DGR

IMO/IMDG:
Shipping Description: UN1267, PETROLEUM CRUDE OIL, 3, PG I, II, or III, (FLASH POINT SEE SECTION 5 OR
9), MARINE POLLUTANT
· UN number: UN1267
· UN proper shipping name: PETROLEUM CRUDE OIL
· Transport hazard class(es): 3
· Packing group: I, II, or III
· Flash Point: See appropriate MSDS Section for Flash Point, Pensky-Martens, Closed Cup
· Environmental hazards: Acute 1, Chronic 1 and/or Chronic 2 Aquatic Toxics are environmentally
hazardous/marine pollutants (MP) for Transport
· Special precautions for user: See all Special Provisions in the IMO/IMDG
· Bulk marine cargoes of petroleum are carried under the IBC Code as MARPOL ANNEX I.

TC Shipping Description: SEE IMO/IMDG SHIPPING DESCRIPTION OR REFERENCE BILL OF LADING

Petroleum Crude Oils containing or known to generate hydrogen sulfide in sufficient concentrations to
pose an inhalation hazard in head space vapors must be consigned under UN3494 in all international
jurisdictions. Consignor/offerors should be aware that flammable liquids meeting the criteria of two or
more transport hazards might best be described by alternative shipping names, e.g. UN1992,
FLAMMABLE LIQUIDS, TOXIC, N.O.S. or UN2924, FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.:

Note: In US DOT DG/HazMat jurisdictions, a bulk packaging of crude oil that emits hydrogen sulfide in
sufficient concentration that vapors evolved may present an inhalation hazard must be marked as
specified in 49 CFR 172.327. Bulk packagings used to transport of such hydrogen sulfide generating
petroleum crude oils must include a marking, label, tag, or sign to warn of the H2S hazard. A warning on
the shipping papers in association with the Proper Shipping Description (PSD) is also advised. For
example: WARNING - HYDROGEN SULFIDE INHALATION HAZARD or POTENTIAL HYDROGEN SULFIDE
INHALATION HAZARD

US DOT (Use of UN3494 is not mandated, but permitted.)

Shipping Description: For crude oils not expected to have, but could have, an H2S Inhalation Hazard –
UN1267, PETROLEUM CRUDE OIL, 3, PG I, II, or III Optional note: (POTENTIAL HYDROGEN SULFIDE
INHALATION HAZARD) or

Shipping Description: For crude oils known to have a potential H2S Inhalation Hazard (e.g., meets the
regulatory criteria of a Toxic for transport) - UN3494, PETROLEUM SOUR CRUDE OIL, FLAMMABLE,
TOXIC, 3 (6.1), PG I, II, or III (WARNING - HYDROGEN SULFIDE INHALATION HAZARD) SEE 49 CFR 172.327
AND 172.102, SPECIAL PROVISION 357
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Revision Date: OCTOBER 02, 2014 SDS : 2493
 · UN number: UN3494
· UN proper shipping name: PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC
· Transport hazard class(es): 3(6.1)
· Packing group: I, II, or III
· Environmental hazards: Disclosure of Acute 1, Chronic 1 and/or Chronic 2 Aquatic Toxics as
environmentally hazardous/marine pollutants is optional.
· Special precautions for user: See all Special Provisions in the 49 CFR HMR. Please note 49 CFR 173.327 and
172.102, Special Provision 357

ADR/RID
Shipping Description: UN3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC, 3 (6.1), PG I, II, or III ADR CODE
FT1 MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS (WARNING - HYDROGEN SULPHIDE INHALATION
HAZARD) SEE ADR CHAPTER 3.3, SPECIAL PROVISION 343
· UN number: UN3494
· UN proper shipping name: PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC
· Transport hazard class(es): 3(6.1)
· Packing group: I, II, or III
· Environmental hazards: Acute 1, Chronic 1 and/or Chronic 2 Aquatic Toxics are environmentally
hazardous/marine pollutants (MP) for Transport
· Special precautions for user: See all Special Provisions in the ADR/RID code. Please note ADR CHAPTER 3.3,
Special Provision 343

ICAO/IATA – Air transport of Hydrogen Sulfide bearing materials is not recommended. Please consult with your
qualified Dangerous Goods Safety Advisor.

IMO/IMDG
Shipping Description: UN3494, PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC, 3 (6.1), PG I, II, or III, (FLASH
POINT SEE SECTION 5 or 9), MARINE POLLUTANT (WARNING - HYDROGEN SULPHIDE INHALATION HAZARD) SEE
IMDG CHAPTER 3.3, SPECIAL PROVISION 343
· UN number: UN3494
· UN proper shipping name: PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC
· Transport hazard class(es): 3(6.1)
· Packing group: I, II, or III
· Flash Point: See MSDS Section 5 or 9 for Flash Point
· Environmental hazards: Acute 1, Chronic 1 and /or Chronic 2 Aquatic Toxics are environmentally
hazardous/marine pollutants (MP) for Transport
· Special precautions for user: See all Special Provisions in the IMO/IMDG. Please note IMDG CHAPTER 3.3,
Special Provision 343
· Bulk marine cargoes of petroleum are carried under the IBC Code as MARPOL ANNEX I
·
TC Shipping Description: SEE IMO/IMDG SHIPPING DESCRIPTION OR REFERENCE BILL OF LADING

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
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Revision Date: OCTOBER 02, 2014 SDS : 2493
 5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

The following components of this material are found on the regulatory lists indicated.
Benzene 01-1, 02, 03, 04, 05, 06, 07
Crude oil 03, 05, 06, 07
Ethylbenzene 01-2B, 03, 04, 05, 06, 07
Hexane 03, 05, 06, 07
Hydrogen sulfide 05, 06, 07
Toluene 03, 04, 05, 06, 07
Xylene 03, 05, 06, 07

CERCLA REPORTABLE QUANTITIES(RQ)/EPCRA 302 THRESHOLD PLANNING QUANTITIES(TPQ):

Component Component RQ Component TPQ Product RQ
Benzene 10 lbs None 1010 lbs
Hydrogen sulfide 100 lbs None 101 lbs

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS (Philippines),
TSCA (United States).

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 3 Flammability: 3 Reactivity: 0

HMIS RATINGS: Health: 3* Flammability: 3 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16
Revision Date: OCTOBER 02, 2014

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration

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Revision Number: 19 13 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our
control and with which we may be unfamiliar and since data made available subsequent to the
date hereof may suggest modifications of the information, we do not assume any responsibility
for the results of its use. This information is furnished upon condition that the person receiving
it shall make his own determination of the suitability of the material for his particular purpose.

_____________________________________________________________________

Revision Number: 19 14 of 14 Crude Oil

Revision Date: OCTOBER 02, 2014 SDS : 2493
Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Fuel Oil 6 2.0S

Product Use: Fuel
Product Number(s): 285653
Synonyms: Bunker Fuel Oil (BFO), High Sulfur Fuel Oil (HSFO)
Company Identification
Chevron Products Company
6001 Bollinger Canyon Road
San Ramon, CA 94583
United States of America

Transportation Emergency Response

CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
Product Information: [Link]

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable liquid: Category 4. Carcinogen: Category 1B. Target organ toxicant
(repeated exposure): Category 2. Reproductive toxicant (developmental): Category 2. Acute inhalation
toxicant: Category 4. Acute aquatic toxicant: Category 1. Chronic aquatic toxicant: Category 1.

Signal Word: Danger

Physical Hazards: Combustible liquid.

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1 of 10 Fuel Oil 6 2.0S

Revision Number: 10
SDS : 1410
Revision Date: FEBRUARY 29, 2016
Health Hazards: May cause cancer. Suspected of damaging the unborn child. Harmful if inhaled.

Target Organs: May cause damage to organs (Blood/Blood Forming Organs, Liver, Thymus) through
prolonged or repeated exposure.

Environmental Hazards: Very toxic to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS:
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. Do not
breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective
gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.
Avoid release to the environment.
Response: IF exposed or concerned: Get medical advice/attention. IF INHALED: Remove person to
fresh air and keep comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. In
case of fire: Use media specified in the SDS to extinguish. Collect spillage.
Storage: Store in a well-ventilated place. Keep cool. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

HAZARDS NOT OTHERWISE CLASSIFIED: Heating may release highly toxic and flammable hydrogen
sulfide (H2S). Do not attempt rescue without supplied-air respiratory protection.

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Heavy Fuel Oil, No. 6 68553-00-4 100 %weight
Total sulfur Mixture 2 %weight
Clarified oils, catalytic cracked 64741-62-4 < 1 %weight

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water. If heated material should splash into eyes, flush eyes immediately with fresh water
for 15 minutes while holding the eyelids open. Remove contact lenses, if worn. Get immediate medical
attention.
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if
contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and

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SDS : 1410
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shoes or thoroughly clean before reuse. If the hot material gets on skin, quickly cool in water. See a
doctor for extensive burns. Do not try to peel the solidified material from the skin, or use solvents or
thinners to dissolve it. The use of vegetable oil or mineral oil is recommended for removal of this material
from the skin.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get
medical advice.
Inhalation: If exposure to hydrogen sulfide (H2S) gas is possible during an emergency, wear an approved,
positive pressure air-supplying respirator. Move the exposed person to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention.

Most important symptoms and effects, both acute and delayed

IMMEDIATE HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation. If this material is heated, thermal burns
may result from eye contact.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin
is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if
absorbed through the skin. If this material is heated, thermal burns may result from skin contact.
Ingestion: Not expected to be harmful if swallowed.
Inhalation: May be harmful if inhaled. Hydrogen sulfide has a strong rotten-egg odor. However, with
continued exposure and at high levels, H2S may deaden a person's sense of smell. If the rotten egg odor
is no longer noticeable, it may not necessarily mean that exposure has stopped. At low levels, hydrogen
sulfide causes irritation of the eyes, nose, and throat. Moderate levels can cause headache, dizziness,
nausea, and vomiting, as well as coughing and difficulty breathing. Higher levels can cause shock,
convulsions, coma, and death. After a serious exposure, symptoms usually begin immediately.

The U.S. National Institute for Occupational Safety and Health (NIOSH) considers air concentrations of
hydrogen sulfide gas greater than 100 ppm to be Immediately Dangerous to Life and Health (IDLH).

DELAYED OR OTHER HEALTH EFFECTS:

Reproduction and Birth Defects: Absorption of this material through the skin may cause harm to the
unborn child based on animal data.
Cancer: Prolonged or repeated exposure to this material may cause cancer.
Target Organs: Repeated exposure to this material may cause damage to the following organ(s):Liver
Blood/Blood Forming Organs Thymus Risk depends on duration and level of exposure. See Section 11
for additional information.

Indication of any immediate medical attention and special treatment needed

Note to Physicians: Administration of 100% oxygen and supportive care is the preferred treatment for
poisoning by hydrogen sulfide gas. For additional information on H2S, see Chevron MSDS No. 301.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Unusual Fire Hazards: See Section 7 for proper handling and storage.
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SDS : 1410
Revision Date: FEBRUARY 29, 2016
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space
without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion. Combustion may form oxides of: Sulfur.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area with combustible gas
indicator.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated
materials in disposable containers and dispose of in a manner consistent with applicable regulations. If
heated material is spilled, allow it to cool before proceeding with disposal methods.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with
explosive force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights,
welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises
above 29C (85F).
Do not get in eyes, on skin, or on clothing. Avoid contact of heated material with eyes, skin, and clothing.
Do not breathe vapor or fumes. Do not breathe gas. Wash thoroughly after handling.
Unusual Handling Hazards: Toxic quantities of hydrogen sulfide (H2S) may be present in storage tanks
and bulk transport vessels which contain or have contained this material. Persons opening or entering
these compartments should first determine if H2S is present. See Exposure Controls/Personal Protection
-Section 8. Do not attempt rescue of a person over exposed to H2S without wearing approved supplied-air
or self-contained breathing equipment. If there is a potential for exceeding one-half the occupational
exposure standard, monitoring of hydrogen sulfide levels is required. Since the sense of smell cannot be
relied upon to detect the presence of H2S, the concentration should be measured by the use of fixed or
portable devices.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,

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be sufficient. Review all operations which have the potential of generating and accumulating an
electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank
cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and
use appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE
AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities,
and other substances in the work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material, the personal protective equipment listed below is recommended. The user
should read and understand all instructions and limitations supplied with the equipment since protection is
usually provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use in a well-ventilated area.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice. If this material is heated, wear chemical goggles
or safety glasses or a face shield.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select
protective clothing depending on operations conducted, physical requirements and other substances in the
workplace. Suggested materials for protective gloves include: Nitrile Rubber, Silver Shield, Viton. If this
material is heated, wear insulated clothing to prevent skin contact if engineering controls or work practices
are not adequate to prevent skin contact.
Respiratory Protection:
If material is heated and emits hydrogen sulfide, determine if airborne concentrations are below the
occupational exposure limit for hydrogen sulfide. If not, wear an approved positive pressure air-supplying
respirator. For more information on hydrogen sulfide, see Chevron MSDS No. 301. When used as a fuel,
this material can produce carbon monoxide in the exhaust. Determine if airborne concentrations are below
the occupational exposure limit for carbon monoxide. If not, wear an approved positive-pressure
air-supplying respirator.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.
_____________________________________________________________________

5 of 10 Fuel Oil 6 2.0S

Revision Number: 10
SDS : 1410
Revision Date: FEBRUARY 29, 2016
Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation

Heavy Fuel Oil, No. 6 Not Applicable -- -- -- --

Total sulfur Not Applicable -- -- -- --
Clarified oils, catalytic cracked Not Applicable -- -- -- --
No applicable occupational exposure limits exist for this material or its components.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Black
Physical State: Liquid
Odor: No data available
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: No data available
Vapor Density (Air = 1): No data available
Initial Boiling Point: 37.8°C (100°F) - 198.9°C (390°F)
Solubility: No data available
Freezing Point: No data available
Specific Gravity: 1.03 @ 15.6°C (60.1°F)
Density: No data available
Viscosity: 380 cSt @ 50°C (122°F) (Min)
Coefficient of Therm. Expansion / °F: No data available
Decomposition temperature: No data available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available

Flashpoint: (Pensky-Martens Closed Cup) 66 °C (150 °F)

Autoignition: No data available
Flammability (Explosive) Limits (% by volume in air): Lower: No data available Upper: No data
available

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
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Revision Number: 10
SDS : 1410
Revision Date: FEBRUARY 29, 2016
handling conditions of temperature and pressure.
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: Hydrogen Sulfide (Elevated temperatures)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for similar
materials.

Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for similar materials.

Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials.

Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar
materials.

Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials.

Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
components.
Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.

Carcinogenicity: Refer to ADDITIONAL TOXICOLOGY INFORMATION below.

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components
or a similar material.

Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:

This material contains the high-boiling fraction of catalytically cracked oils. The International Agency for
Research on Cancer (IARC) in Monograph 33 (1984) and Supplement 7 (1987) included these oils in their
definition of Untreated and Mildly-Treated Oils. IARC considers these oils to be Group 1, or human,
carcinogens.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is expected to be very toxic to aquatic organisms and may cause long-term adverse effects in
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Revision Number: 10
SDS : 1410
Revision Date: FEBRUARY 29, 2016
the aquatic environment.
The product has not been tested. The statement has been derived from the properties of the individual
components.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is not expected to be readily biodegradable. The product has not been tested. The statement
has been derived from products of a similar structure and composition.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

DOT Shipping Description: For packages with a Flash Point (PM Closed Cup) >/= 23 deg C but </= 60
deg C:
UN1202, GAS OIL, 3, III; OPTIONAL DISCLOSURE: UN1202, GAS OIL, 3, III,
MARINE POLLUTANT (FUEL OIL); NOTE: POTENTIAL HYDROGEN SULFIDE
INHALATION HAZARD
Optional disclosure per 49 CFR when Flash Point (PM Closed Cup) > 38 deg
C < 93 deg C per 49 173.150 (f):
UN1202, GAS OIL, COMBUSTIBLE LIQUID, III; NON-BULK PACKAGES ARE EXEMPTED FROM THE
PROVISIONS OF 49 CFR IN USA JURISDICTIONS; NOTE: POTENTIAL HYDROGEN SULFIDE
INHALATION HAZARD
Optional disclosure as a GHS Environmental Hazard/Marine Pollutant when
Flash Point (Closed Cup) > 60 deg C:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(FUEL OIL), 9, III,
MARINE POLLUTANT (FUEL OIL); NOTE: POTENTIAL HYDROGEN SULFIDE
INHALATION HAZARD

IMO/IMDG Shipping Description: For packages with a Flash Point (PM Closed Cup) >/= 23 deg C but </=
60 deg C: UN1202, GAS OIL, 3, III, FLASH POINT SEE SECTION 5 OR 9, MARINE POLLUTANT

_____________________________________________________________________

8 of 10 Fuel Oil 6 2.0S

Revision Number: 10
SDS : 1410
Revision Date: FEBRUARY 29, 2016
(FUEL OIL); OPTIONAL DISCLOSURE: UN1268, PETROLEUM DISTILLATES, N.O.S. (FUEL OIL), 3, III,
FLASH POINT SEE SECTION 5 OR 9, MARINE POLLUTANT (FUEL OIL); NOTE: POTENTIAL
HYDROGEN SULPHIDE INHALATION HAZARD For packages with a Flash Point (PM Closed Cup) > 60
deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, N.O.S. (FUEL OIL), 9, III, MARINE
POLLUTANT (FUEL OIL); NOTE: POTENTIAL HYDROGEN SULPHIDE INHALATION HAZARD

ICAO/IATA Shipping Description: For packages with a Flash Point (PM Closed Cup) >/= 23 deg C, </= 60
deg C: UN1202, GAS OIL, 3, III; NOTE: POTENTIAL HYDROGEN SULPHIDE INHALATION HAZARD
For packages with a Flash Point (PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, N.O.S. (FUEL OIL), 9, III, MARINE POLLUTANT (FUEL OIL); NOTE:
POTENTIAL HYDROGEN SULPHIDE INHALATION HAZARD

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

The following components of this material are found on the regulatory lists indicated.
Clarified oils, catalytic cracked 01-1, 01-2B, 04

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS (Philippines),
TSCA (United States).

SECTION 16 OTHER INFORMATION

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9 of 10 Fuel Oil 6 2.0S

Revision Number: 10
SDS : 1410
Revision Date: FEBRUARY 29, 2016
NFPA RATINGS: Health: 2 Flammability: 2 Reactivity: 0

HMIS RATINGS: Health: 1* Flammability: 2 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16
Revision Date: FEBRUARY 29, 2016

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct as of
the date hereof. Since this information may be applied under conditions beyond our control and with
which we may be unfamiliar and since data made available subsequent to the date hereof may
suggest modifications of the information, we do not assume any responsibility for the results of its use.
This information is furnished upon condition that the person receiving it shall make his own
determination of the suitability of the material for his particular purpose.

_____________________________________________________________________

10 of 10 Fuel Oil 6 2.0S

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SDS : 1410
Revision Date: FEBRUARY 29, 2016
Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Vacuum Gas Oils (VGO)

Product Use: Refinery feed stock
Product Number(s): 276649, 276806
Company Identification
Chevron Products Company
6001 Bollinger Canyon Road
San Ramon, CA 94583
United States of America

Transportation Emergency Response

CHEMTREC: (800) 424-9300 or (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
Product Information: [Link]

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable liquid: Category 4. Carcinogen: Category 1B. Target organ toxicant
(repeated exposure): Category 2. Reproductive toxicant (developmental): Category 2. Acute inhalation
toxicant: Category 4. Acute aquatic toxicant: Category 1. Chronic aquatic toxicant: Category 1.

Signal Word: Danger

Physical Hazards: Combustible liquid.

Health Hazards: May cause cancer. Suspected of damaging the unborn child. Harmful if inhaled.

Target Organs: May cause damage to organs (Blood/Blood Forming Organs, Liver, Thymus) through
prolonged or repeated exposure.

_____________________________________________________________________

Revision Number: 7 1 of 9 Vacuum Gas Oils (VGO)

Revision Date: SEPTEMBER 21, 2015 SDS : 7705
Environmental Hazards: Very toxic to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS:
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. Do not
breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective
gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.
Avoid release to the environment.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell. In case of fire: Use media specified in the SDS to extinguish.
Collect spillage.
Storage: Store in a well-ventilated place. Keep cool. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

HAZARDS NOT OTHERWISE CLASSIFIED: May release highly toxic and flammable hydrogen sulfide
gas (H2S).

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Distillates, vacuum 70592-78-8 0 - 100 %weight
Distillates, light vacuum 70592-77-7 0 - 100 %weight

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical
attention if any symptoms develop. To remove the material from skin, use soap and water. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get
medical advice.
Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention if breathing difficulties continue. If exposure to hydrogen
sulfide (H2S) gas is possible during an emergency, wear an approved, positive pressure air-supplying
respirator. Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get immediate medical attention.

Most important symptoms and effects, both acute and delayed

IMMEDIATE HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Skin contact may cause drying or defatting of the skin. Symptoms may include pain, itching,
discoloration, swelling, and blistering. Contact with the skin is not expected to cause an allergic skin
response. Not expected to be harmful to internal organs if absorbed through the skin.
Ingestion: Not expected to be harmful if swallowed.

_____________________________________________________________________

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Revision Date: SEPTEMBER 21, 2015 SDS : 7705
Inhalation: May be harmful if inhaled. Hydrogen sulfide has a strong rotten-egg odor. However, with
continued exposure and at high levels, H2S may deaden a person's sense of smell. If the rotten egg odor
is no longer noticeable, it may not necessarily mean that exposure has stopped. At low levels, hydrogen
sulfide causes irritation of the eyes, nose, and throat. Moderate levels can cause headache, dizziness,
nausea, and vomiting, as well as coughing and difficulty breathing. Higher levels can cause shock,
convulsions, coma, and death. After a serious exposure, symptoms usually begin immediately.

The U.S. National Institute for Occupational Safety and Health (NIOSH) considers air concentrations of
hydrogen sulfide gas greater than 100 ppm to be Immediately Dangerous to Life and Health (IDLH).

DELAYED OR OTHER HEALTH EFFECTS:

Reproduction and Birth Defects: This material may cause harm to the unborn child.
Cancer: Prolonged or repeated exposure to this material may cause cancer.
Target Organs: Repeated exposure to this material may cause damage to the following organ(s) based
on animal data:Liver Blood/Blood Forming Organs Thymus Risk depends on duration and level of
exposure. See Section 11 for additional information.

Indication of any immediate medical attention and special treatment needed

Note to Physicians: Administration of 100% oxygen and supportive care is the preferred treatment for
poisoning by hydrogen sulfide gas. For additional information on H2S, see Chevron MSDS No. 301.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

Unusual Fire Hazards: See Section 7 for proper handling and storage.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire
space without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion. Combustion may form oxides of: Sulfur,
Nitrogen.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area with combustible gas
indicator. If this material is released into a work area, evacuate the area immediately. Persons entering the
contaminated area to correct the problem or to determine whether it is safe to resume normal activities
must comply with all instructions in the Exposure Controls/PersonalProtection section.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated
materials in disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.

_____________________________________________________________________

Revision Number: 7 3 of 9 Vacuum Gas Oils (VGO)

Revision Date: SEPTEMBER 21, 2015 SDS : 7705
 SECTION 7 HANDLING AND STORAGE

General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with
explosive force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights,
welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises
above 29C (85F).
Do not get in eyes, on skin, or on clothing. Do not breathe vapor or fumes. Wash thoroughly after
handling.
Unusual Handling Hazards: Toxic quantities of hydrogen sulfide (H2S) may be present in storage tanks
and bulk transport vessels which contain or have contained this material. Persons opening or entering
these compartments should first determine if H2S is present. See Exposure Controls/Personal Protection
-Section 8. Do not attempt rescue of a person over exposed to H2S without wearing approved supplied-air
or self-contained breathing equipment. If there is a potential for exceeding one-half the occupational
exposure standard, monitoring of hydrogen sulfide levels is required. Since the sense of smell cannot be
relied upon to detect the presence of H2S, the concentration should be measured by the use of fixed or
portable devices.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,
sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use
appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces .
USE AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and
other substances in the work place when designing engineering controls and selecting personal protective
equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful
levels of this material, the personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the equipment since protection is usually
provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
If user operations generate airborne material, use process enclosures, local exhaust ventilation, or other
engineering controls to control exposure.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may
_____________________________________________________________________

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Revision Date: SEPTEMBER 21, 2015 SDS : 7705
include gloves, apron, boots, and complete facial protection depending on operations conducted.
Suggested materials for protective gloves include: Chlorinated Polyethylene (or Chlorosulfonated
Polyethylene), Nitrile Rubber, Polyurethane, Viton.
Respiratory Protection: If exposure to harmful levels of airborne material may occur when working with
this material, wear an approved respirator that provides protection, such as: Air-Purifying Respirator for
Organic Vapors.
Determine if airborne concentrations are below the occupational exposure limit for hydrogen sulfide. If not,
wear an approved positive pressure air-supplying respirator. For more information on hydrogen sulfide, see
Chevron MSDS No. 301.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation

Distillates, vacuum Not -- -- -- --

Applicable
Distillates, light vacuum Not -- -- -- --
Applicable
No applicable occupational exposure limits exist for this material or its components.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Amber to Black

Physical State: Viscous liquid
Odor: Mild to pungent sulfurous odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: No data available
Vapor Density (Air = 1): Not Applicable
Initial Boiling Point: 148.9°C (300°F)
Solubility: Soluble in hydrocarbon solvents; insoluble in water.
Melting Point: No data available
Specific Gravity: 0.8 - 0.9 @ 15.6°C (60.1°F)
Viscosity: >20 cSt @ 40°C (104°F)
Evaporation Rate: No data available
Decomposition temperature: No data available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available

Flashpoint: (Pensky-Martens Closed Cup) > 61 °C (> 141 °F)

Autoignition: 338 °C (640 °F)
Flammability (Explosive) Limits (% by volume in air): Lower: 0.5 Upper: 5

SECTION 10 STABILITY AND REACTIVITY

_____________________________________________________________________

Revision Number: 7 5 of 9 Vacuum Gas Oils (VGO)

Revision Date: SEPTEMBER 21, 2015 SDS : 7705
Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Conditions to Avoid: No data available.
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for similar
materials.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for similar materials.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar
materials.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
components.
Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.

Carcinogenicity: The hazard evaluation is based on data for components or a similar material.

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
components or a similar material.

Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:

This product may contain significant amounts of Polynuclear Aromatic Hydrocarbons (PAH's) which have
been shown to cause skin cancer after prolonged and frequent contact with the skin of test animals. Brief
or intermittent skin contact with this product is not expected to have serious effects if it is washed from the
skin. While skin cancer is unlikely to occur in human beings following use of this product, skin contact and
breathing, of mists, vapors or dusts should be reduced to a minimum.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is expected to be very toxic to aquatic organisms and may cause long-term adverse effects in

_____________________________________________________________________

Revision Number: 7 6 of 9 Vacuum Gas Oils (VGO)

Revision Date: SEPTEMBER 21, 2015 SDS : 7705
the aquatic environment.
The product has not been tested. The statement has been derived from products of a similar structure and
composition.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is not expected to be readily biodegradable. The product has not been tested. The statement
has been derived from products of a similar structure and composition.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

DOT Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point (PM
Closed Cup) >/= 23 deg but </= 60 deg C: UN1268, PETROLEUM DISTILLATES, 3, III; OPTIONAL
DISCLOSURE: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, MARINE POLLUTANT
(PETROLEUM DISTILLATES) Optional disclosure per 49 CFR when Flash Point (PM Closed Cup) > 38
deg C < 93 deg C per 49 173.150 (f): UN1268, PETROLEUM DISTILLATES, N.O.S., COMBUSTIBLE
LIQUID, III; NON-BULK PACKAGES ARE EXEMPTED FROM THE PROVISIONS OF 49CFR IN USA
JURISDICTIONS Optional disclosure as a GHS Environmental Hazard/Marine Pollutant when Flash
Point (Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.(PETROLEUM DISTILLATES), 9, III, MARINE POLLUTANT (PETROLEUM DISTILLATES)

IMO/IMDG Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point
(PM Closed Cup) >/= 23 deg C, </= 60 deg C: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, FLASH
POINT SEE SECTION 5 OR 9, MARINE POLLUTANT (PETROLEUM DISTILLATES) For packages with
a Flash Point (PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (PETROLEUM DISTILLATES), 9, III, MARINE POLLUTANT (PETROLEUM
DISTILLATES)

ICAO/IATA Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point
(PM Closed Cup) >/= 23 deg C, </= 60 deg C: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III For
packages with a Flash Point (PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (PETROLEUM DISTILLATES), 9, III, MARINE POLLUTANT
(PETROLEUM DISTILLATES)

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

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Revision Number: 7 7 of 9 Vacuum Gas Oils (VGO)

Revision Date: SEPTEMBER 21, 2015 SDS : 7705
SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), KECI (Korea), TSCA (United States).

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 3 Flammability: 2 Reactivity: 0

HMIS RATINGS: Health: 3* Flammability: 2 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 14
Revision Date: SEPTEMBER 21, 2015

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration

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Revision Number: 7 8 of 9 Vacuum Gas Oils (VGO)

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Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our
control and with which we may be unfamiliar and since data made available subsequent to the
date hereof may suggest modifications of the information, we do not assume any responsibility
for the results of its use. This information is furnished upon condition that the person receiving
it shall make his own determination of the suitability of the material for his particular purpose.

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Revision Number: 7 9 of 9 Vacuum Gas Oils (VGO)

Revision Date: SEPTEMBER 21, 2015 SDS : 7705
Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

GASOLINE (GENERIC)
Product Use: Fuel
Product Number(s): 204147, 204148, 204149, 204150, 204151, 204152, 204156, 204157, 204158,
204159, 204160, 204161, 204180, 204181, 204182, 204472, 204473, 204474, 204475, 204476, 204477,
204490, 204491, 204492, 204493, 204494, 204495, 204756, 204757, 204758, 204759, 204760, 204761,
205000, 205001, 205002, 210000, 240000, NN2914
Company Identification
Chevron Products Company
6001 Bollinger Canyon Rd., T3325/B10
San Ramon, CA 94583
United States of America

Transportation Emergency Response

CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
Product Information: (800) 582-3835
SDS Requests: (800) 414-6737

SPECIAL NOTES: This MSDS applies to: all motor gasoline.

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable liquid: Category 1. Aspiration toxicant: Category 1. Carcinogen: Category

1A. Target organ toxicant (repeated exposure): Category 1. Eye irritation: Category 2A. Germ Cell
Mutagen: Category 1B. Skin irritation: Category 2. Reproductive toxicant (developmental): Category 2.
Target organ toxicant (central nervous system): Category 3. Acute aquatic toxicant: Category 2. Chronic
aquatic toxicant: Category 2.

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Signal Word: Danger

Physical Hazards: Extremely flammable liquid and vapor.

Health Hazards: May be fatal if swallowed and enters airways. May cause genetic defects. May cause
cancer. Causes skin irritation. Causes serious eye irritation. Suspected of damaging the unborn child.
May cause drowsiness or dizziness.

Target Organs: Causes damage to organs (Blood/Blood Forming Organs) through prolonged or repeated
exposure.

Environmental Hazards: Toxic to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS:
General: Keep out of reach of children. Read label before use.
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking.
Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use explosion-proof
electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid
breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear
protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as
required. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid
release to the environment.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of
soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and
wash it before reuse. IF ON SKIN (or hair): Take off immediately all contaminated clothing and wash it
before reuse. Rinse skin with water/shower. IF SWALLOWED: Immediately call a poison center or
doctor/physician. Do NOT induce vomiting. Call a poison center or doctor/physician if you feel unwell. Get
medical advice/attention if you feel unwell. IF exposed or concerned: Get medical advice/attention. In
case of fire: Use media specified in the SDS to extinguish. Specific treatment (see Notes to Physician on
this label). Collect spillage.
Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable

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 SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Gasoline 86290-81-5 100 %vol/vol
Toluene (methylbenzene) 108-88-3 1 - 35 %vol/vol
Xylene (contains o-, m-, & p- xylene isomers in 1330-20-7 1 - 15 %vol/vol
varying amounts)
Pentane, 2,2,4-trimethyl- (Isooctane) 540-84-1 1 - 13 %vol/vol
Butane 106-97-8 1 - 12 %vol/vol
Ethanol 64-17-5 0 - 10 %vol/vol
Benzene 71-43-2 0.1 - 4.9 %vol/vol
Hexane 110-54-3 1 - 5 %vol/vol
Heptane 142-82-5 1 - 4 %vol/vol
Ethyl benzene 100-41-4 0.1 - 3 %vol/vol
Cyclohexane 110-82-7 1 - 3 %vol/vol
Naphthalene 91-20-3 0.1 - 2 %vol/vol
Methylcyclohexane 108-87-2 1 - 2 %vol/vol

Motor gasoline is considered a mixture by EPA under the Toxic Substances Control Act (TSCA). The
refinery streams used to blend motor gasoline are all on the TSCA Chemical Substances Inventory. The
appropriate CAS number for refinery blended motor gasoline is 86290-81-5. The product specifications of
motor gasoline sold in your area will depend on applicable Federal and State regulations.

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye: Flush eyes with water immediately while holding the eyelids open. Remove contact lenses, if worn,
after initial flushing, and continue flushing for at least 15 minutes. Get immediate medical attention.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical
attention if any symptoms develop. To remove the material from skin, use soap and water. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by
mouth to an unconscious person.
Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention if breathing difficulties continue or if any other symptoms
develop.

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Most important symptoms and effects, both acute and delayed
IMMEDIATE HEALTH EFFECTS
Eye: Contact with the eyes causes severe irritation. Symptoms may include pain, tearing, reddening,
swelling and impaired vision.
Skin: Contact with the skin causes irritation. Skin contact may cause drying or defatting of the skin.
Contact with the skin is not expected to cause an allergic skin response. Symptoms may include pain,
itching, discoloration, swelling, and blistering.
Ingestion: Highly toxic; may be fatal if swallowed. Because of its low viscosity, this material can directly
enter the lungs, if swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and
can cause severe injury or death. May be irritating to mouth, throat, and stomach. Symptoms may include
pain, nausea, vomiting, and diarrhea.
Inhalation: Excessive or prolonged breathing of this material may cause central nervous system effects.
Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of
coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures, central
nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness,
coma or death.

DELAYED OR OTHER HEALTH EFFECTS:

Reproduction and Birth Defects: Contains material that may cause harm to the unborn child if inhaled
above the recommended exposure limit.
Cancer: Prolonged or repeated exposure to this material may cause cancer. Gasoline has been classified
as a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for Research on
Cancer (IARC).

Whole gasoline exhaust has been classified as a Group 2B carcinogen (possibly carcinogenic to humans)
by the International Agency for Research on Cancer (IARC).

Contains benzene, which has been classified as a carcinogen by the National Toxicology Program (NTP)
and a Group 1 carcinogen (carcinogenic to humans) by the International Agency for Research on Cancer
(IARC).
Contains naphthalene, which has been classified as a Group 2B carcinogen (possibly carcinogenic to
humans) by the International Agency for Research on Cancer (IARC). Contains ethylbenzene which has
been classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency
for Research on Cancer (IARC).

Genetic Toxicity: Contains material that may cause heritable genetic damage based on animal data.
Target Organs: Contains material that may cause damage to the following organ(s) following repeated
inhalation at concentrations above the recommended exposure limit:Blood/Blood Forming Organs Risk
depends on duration and level of exposure. See Section 11 for additional information.

Indication of any immediate medical attention and special treatment needed

Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light
hydrocarbon liquid, which may cause pneumonitis.

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 SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Unusual Fire Hazards: See Section 7 for proper handling and storage.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space
without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area with combustible gas
indicator.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated
materials in disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Precautionary Measures: This product presents an extreme fire hazard. Liquid very quickly evaporates,
even at low temperatures, and forms vapor (fumes) which can catch fire and burn with explosive violence.
Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding
equipment, and electrical motors and switches. Never siphon gasoline by mouth.
Do not store in open or unlabeled containers. READ AND OBSERVE ALL PRECAUTIONS ON
PRODUCT LABEL. Do not get in eyes, on skin, or on clothing. Do not get in eyes. Do not taste or
swallow. Do not breathe vapor or fumes. Wash thoroughly after handling. Keep out of the reach of
children.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an
electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank

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cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and
use appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE
AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities,
and other substances in the work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material, the personal protective equipment listed below is recommended. The user
should read and understand all instructions and limitations supplied with the equipment since protection is
usually provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below the recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: Wear protective equipment to prevent eye contact. Selection of protective equipment
may include safety glasses, chemical goggles, face shields, or a combination depending on the work
operations conducted.
Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may
include gloves, apron, boots, and complete facial protection depending on operations conducted.
Suggested materials for protective gloves include: Chlorinated Polyethylene (or Chlorosulfonated
Polyethylene), Nitrile Rubber, Polyurethane, Viton.
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational
exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an
approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator
for Organic Vapors.
When used as a fuel, this material can produce carbon monoxide in the exhaust. Determine if airborne
concentrations are below the occupational exposure limit for carbon monoxide. If not, wear an approved
positive-pressure air-supplying respirator.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

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Component Agency TWA STEL Ceiling Notation

Gasoline ACGIH 300 ppm 500 ppm -- A3

(weight) (weight)
Toluene (methylbenzene) ACGIH 20 ppm -- -- --
(weight)
Toluene (methylbenzene) OSHA Z-2 200 ppm -- 300 ppm --
(weight) (weight)
Xylene (contains o-, m-, & p- xylene ACGIH 100 ppm 150 ppm -- --
isomers in varying amounts) (weight) (weight)
Xylene (contains o-, m-, & p- xylene OSHA Z-1 435 mg/m3 -- -- --
isomers in varying amounts)
Pentane, 2,2,4-trimethyl- OSHA Z-1 2350 mg/m3 -- -- --
(Isooctane)
Pentane, 2,2,4-trimethyl- ACGIH 300 ppm -- -- --
(Isooctane) (weight)
Butane ACGIH -- 1000 ppm -- --
(weight)
Ethanol ACGIH 1000 ppm -- -- A4 A3
(weight)
Ethanol OSHA Z-1 1900 mg/m3 -- -- --
Benzene ACGIH .5 ppm 2.5 ppm -- Skin A1
(weight) (weight) Skin
Benzene OSHA SRS 1 ppm 5 ppm -- --
(weight) (weight)
Benzene OSHA Z-2 10 ppm -- 25 ppm --
(weight) (weight)
Benzene CVX 1 ppm 5 ppm -- --
(weight) (weight)
Hexane ACGIH 50 ppm -- -- Skin
(weight)
Hexane OSHA Z-1 1800 mg/m3 -- -- --
Heptane ACGIH 400 ppm 500 ppm -- --
(weight) (weight)
Heptane OSHA Z-1 2000 mg/m3 -- -- --
Ethyl benzene ACGIH 20 ppm 125 ppm -- A3
(weight) (weight)
Ethyl benzene OSHA Z-1 435 mg/m3 -- -- --
Cyclohexane ACGIH 100 ppm -- -- --
(weight)
Cyclohexane OSHA Z-1 1050 mg/m3 -- -- --

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Naphthalene ACGIH 10 ppm 15 ppm -- Skin
(weight) (weight)
Naphthalene OSHA Z-1 50 mg/m3 -- -- --
Methylcyclohexane ACGIH 400 ppm -- -- --
(weight)
Methylcyclohexane OSHA Z-1 2000 mg/m3 -- -- --
Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Colorless to yellow

Physical State: Liquid
Odor: Petroleum odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: 5 psi - 15 psi (Typical) @ 37.8 °C (100 °F)
Vapor Density (Air = 1): 3 - 4 (Typical)
Initial Boiling Point: 27.2°C (81°F) - 204.4°C (400°F) (Typical)
Solubility: Insoluble in water; miscible with most organic solvents.
Freezing Point: Not Applicable
Melting Point: Not Applicable
Specific Gravity: 0.70 g/ml - 0.80 g/ml @ 15.6°C (60.1°F) (Typical)
Viscosity: <1 SUS @ 37.8°C (100°F)
Evaporation Rate: No data available
Decomposition temperature: No data available
Octanol/Water Partition Coefficient: 2 - 7

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available

Flashpoint: (Tagliabue Closed Cup ASTM D56) < -45 °C (< -49 °F)
Autoignition: > 280 °C (> 536 °F)
Flammability (Explosive) Limits (% by volume in air): Lower: 1.4 Upper: 7.6

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: None known (None expected)
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Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product
components.

Skin Corrosion/Irritation: For a 4-hour exposure, the Primary Irritation Index (PII) in rabbits is: 4.8/8.0.

Skin Sensitization: This material did not cause skin sensitization reactions in a Buehler guinea pig test.

Acute Dermal Toxicity: LD50: >3.75 g/kg (rabbit).

Acute Oral Toxicity: LD50: >5 ml/kg (rat).

Acute Inhalation Toxicity: 4 hour(s) LD50: >20000 mg/m3 (rat).

Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.

Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Gasoline
has been classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the International
Agency for Research on Cancer (IARC).

Whole gasoline exhaust has been classified as a Group 2B carcinogen (possibly carcinogenic to humans)
by the International Agency for Research on Cancer (IARC).

Contains benzene, which has been classified as a carcinogen by the National Toxicology Program (NTP)
and a Group 1 carcinogen (carcinogenic to humans) by the International Agency for Research on Cancer
(IARC).
Contains naphthalene, which has been classified as a Group 2B carcinogen (possibly carcinogenic to
humans) by the International Agency for Research on Cancer (IARC). Contains ethylbenzene which has
been classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency
for Research on Cancer (IARC).

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for components
or a similar material.

Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:

This product contains naphthalene.
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GENERAL TOXICITY: Exposure to naphthalene has been reported to cause methemoglobinemia and/or
hemolytic anemia, especially in humans deficient in the enzyme glucose-6-phosphate dehydrogenase.
Laboratory animals given repeated oral doses of naphthalene have developed cataracts.
REPRODUCTIVE TOXICITY AND BIRTH DEFECTS: Naphthalene did not cause birth defects when
administered orally to rabbits, rats, and mice during pregnancy, but slightly reduced litter size in mice at
dose levels that were lethal to the pregnant females. Naphthalene has been reported to cross the human
placenta. GENETIC TOXICITY: Naphthalene caused chromosome aberrations and sister chromatid
exchanges in Chinese hamster ovary cells, but was not a mutagen in several other in-vitro
[Link]: In a study conducted by the National Toxicology Program (NTP), mice exposed
to 10 or 30 ppm of naphthalene by inhalation daily for two years had chronic inflammation of the nose and
lungs and increased incidences of metaplasia in those tissues. The incidence of benign lung tumors
(alveolar/bronchiolar adenomas) was significantly increased in the high-dose female group but not in the
male groups. In another two-year inhalation study conducted by NTP, exposure of rats to 10, 30, and 60
ppm naphthalene caused increases in the incidences of a variety of nonneoplastic lesions in the nose.
Increases in nasal tumors were seen in both sexes, including olfactory neuroblastomas in females at 60
ppm and adenomas of the respiratory epithelium in males at all exposure levels. The relevance of these
effects to humans has not been established. No carcinogenic effect was reported in a 2-year feeding
study in rats receiving naphthalene at 41 mg/kg/day.

This product contains cyclohexane.

Cyclohexane primarily affects the central nervous systems of laboratory animals and humans. Acute or
prolonged inhalation of cyclohexane at levels below the recommended exposure limits does not result in
toxic effects while acute exposures to levels above these recommended limits can cause reversible central
nervous system depression. Prolonged exposures of laboratory animals to high levels (up to low
thousands of parts per million) have also caused reversible effects which included hyperactivity, diminished
response to stimuli, and adaptive liver changes while very high levels (high thousands of parts per million)
were fatal. No developmental effects were seen in rats or rabbits following exposures of up to 7000 ppm
cyclohexane. No reproductive effects occurred in rats, although postnatal pup growth was reduced at 7000
ppm in a similar manner as observed in the parental animals. Cyclohexane has not been shown to be
mutagenic in several in vitro and in vivo assays and has not produced tumors in several dermal application
long-term bioassays. Based on these results and the lack of any mutagenic or genotoxic metabolites,
cyclohexane is not expected to be mutagenic or genotoxic. Following dermal exposure, cyclohexane is
rapidly absorbed, metabolized,and excreted.

This product contains butane.

An atmospheric concentration of 100,000 ppm (10%) butane is not noticeably irritating to the eyes, nose or
respiratory tract, but will produce slight dizziness in a few minutes of exposure. No chronic systemic effect
has been reported from occupational exposure.

This product contains benzene.

GENETIC TOXICITY/CANCER: Repeated or prolonged breathing of benzene vapor has been associated
with the development of chromosomal damage in experimental animals and various blood diseases in
humans ranging from aplastic anemia to leukemia (a form of cancer). All of these diseases can be fatal. In
some individuals, benzene exposure can sensitize cardiac tissue to epinephrine which may precipitate fatal
ventricular fibrillation.

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REPRODUCTIVE/DEVELOPMENTAL TOXICITY: No birth defects have been shown to occur in pregnant
laboratory animals exposed to doses not toxic to the mother. However, some evidence of fetal toxicity such
as delayed physical development has been seen at such levels. The available information on the effects of
benzene on human pregnancies is inadequate but it has been established that benzene can cross the
human placenta.
OCCUPATIONAL: The OSHA Benzene Standard (29 CFR 1910.1028) contains detailed requirements for
training, exposure monitoring, respiratory protection and medical surveillance triggered by the exposure
level. Refer to the OSHA Standard before using this product.

This product contains n-hexane.

TARGET ORGAN TOXICITY: Prolonged or repeated ingestion, skin contact or breathing of vapors of
n-hexane has been shown to cause peripheral neuropathy. Recovery ranges from no recovery to complete
recovery depending upon the severity of the nerve damage. Exposure to 1000 ppm n-hexane for 18 hr/day
for 61 days has been shown to cause testicular damage in rats. However, when rats were exposed to
higher concentrations for shorter daily periods (10,000 ppm for 6 h/day, 5 days/wk for 13 weeks), no
testicular lesions were seen.
CARCINOGENICITY: Chronic exposure to commercial hexane (52% n-hexane) at a concentration of
9000ppm was not carcinogenic to rats or to male mice, but did result in an increased incidence of liver
tumors in female mice. No carcinogenic effects were observed in female mice exposed to 900 or 3000 ppm
hexane or in male mice. The relevance for humans of these hexane-induced mouse liver tumors is
questionable.
GENETIC TOXICITY: n-Hexane caused chromosome aberrations in bone marrow of rats, but was negative
in the AMES and mouse lymphoma tests.

This product contains ethanol (ethyl alcohol).

Chronic ingestion of ethanol can damage the liver, nervous system and heart. Chronic heavy consumption
of alcoholic beverages has been associated with an increased risk of cancer. Ingestion of ethanol during
pregnancy can cause human birth defects such as fetal alcohol syndrome. Gasolines are highly volatile
and can produce significant concentrations of vapor at ambient temperatures. Gasoline vapor is heavier
than air and at high concentrations may accumulate in confined spaces to present both safety and health
hazards. When vapor exposures are low, or short duration and infrequent, such as during refueling and
tanker loading/unloading, neither total hydrocarbon nor components such as benzene are likely to result in
any adverse health effects. In situations such as accidents or spills where exposure to gasoline vapor is
potentially high, attention should be paid to potential toxic effects of specific components. Information
about specific components in gasoline can be found in Sections 2/3, 8 and 15 of this MSDS. More detailed
information on the health hazards of specific gasoline components can be obtained calling the Chevron
Emergency Information Center (see Section 1 for phone numbers).
Pathological misuse of solvents and gasoline, involving repeated and prolonged exposure to high
concentrations of vapor is a significant exposure on which there are many reports in the medical literature.
As with other solvents, persistent abuse involving repeated and prolonged exposures to high
concentrations of vapor has been reported to result in central nervous system damage and eventually,
death. In a study in which ten human volunteers were exposed for 30 minutes to approximately 200, 500 or
1000 ppm concentrations of gasoline vapor, irritation of the eyes was the only significant effect observed,
based on both subjective and objective assessments.
Lifetime inhalation of wholly vaporized unleaded gasoline at 2056 ppm has caused increased liver tumors

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in female mice and kidney cancer in male rats. In their 1988 review of carcinogenic risk from gasoline, The
International Agency for Research on Cancer (IARC) noted that, because published epidemiology studies
did not include any exposure data, only occupations where gasoline exposure may have occurred were
reviewed. These included gasoline service station attendants and automobile mechanics. IARC also
noted that there was no opportunity to separate effects of combustion products from those of gasoline itself.
Although IARC allocated gasoline a final overall classification of Group 2B, i.e. possibly carcinogenic to
humans, this was based on limited evidence in experimental animals plus supporting evidence including
the presence in gasoline of benzene. The actual evidence for carcinogenicity in humans was considered
inadequate.
MUTAGENICITY: Gasoline was not mutagenic, with or without activation, in the Ames assay (Salmonella
typhimurium), Saccharamyces cerevisesae, or mouse lymphoma assays. In addition, point mutations were
not induced in human lymphocytes. Gasoline was not mutagenic when tested in the mouse dominant lethal
assay. Administration of gasoline to rats did not cause chomosomal aberrations in their bone marrow cells.
EPIDEMIOLOGY: To explore the health effects of workers potentially exposed to gasoline vapors in the
marketing and distribution sectors of the petroleum industry, the American Petroleum Institute sponsored a
cohort mortality study (Publication 4555), a nested case-control study (Publication 4551), and an exposure
assessment study (Publication 4552). Histories of exposure to gasoline were reconstructed for cohort of
more than 18,000 employees from four companies for the time period between 1946 and 1985. The results
of the cohort mortality study indicated that there was no increased mortality from either kidney cancer or
leukemia among marketing and marine distribution employees who were exposed to gasoline in the
petroleum industry, when compared to the general population. More importantly, based on internal
comparisons, there was no association between mortality from kidney cancer or leukemia and various
indices of gasoline exposure. In particular, neither duration of employment, duration of exposure, age at
first exposure, year of first exposure, job category, cumulative exposure, frequency of peak exposure, nor
average intensity of exposure had any effect on kidney cancer or leukemia mortality. The results of the
nested case-control study confirmed the findings of the original cohort study. That is, exposure to gasoline
at the levels experienced by this cohort of distribution workers is not a significant risk factor for leukemia
(all cell types), acute myeloid leukemia, kidney cancer or multiple myeloma.

This product contains ethylbenzene.

BIRTH DEFECTS AND REPRODUCTION: Ethylbenzene is not expected to cause birth defects or other
developmental effects based on well-conducted studies in rabbits and rats sponsored by NIOSH. Other
studies in rats and mice which reported urinary tract malformations have many deficiencies and have
limited usefulness in evaluating human risk. Reproductive effects are not expected based on a NIOSH
study of fertility, and lack of effects observed for sperm counts and motility, estrous cycle and pathology of
reproductive organs following repeated exposures. HEARING: Statistically significant losses in outer hair
cells (OHCs) were observed in rats exposed to >=200 ppm ethylbenzene, 6 hours/day, 6 days/week for 13
weeks, after an 8-week recovery period. Following longer exposure, inner hair cells losses were also
observed in rats exposed to >= 600 ppm ethylbenzene, but only occasionally in rats exposed to 400 ppm.
The Lowest Observed Adverse Effect Level in rats (LOAEL) was 200 ppm for losses of OHCs. Guinea pigs
exposed to ethylbenzene at 2,500 ppm, 6 hours/day for 5 days did not show auditory deficits or losses in
OHCs. The concentration of ethylbenzene used in the JP-8 study was approximately 10 ppm. GENETIC
TOXICITY: Ethylbenzene tested negative in the bacterial mutation test, Chinese Hamster Ovary (CHO) cell
in vitro assay, sister chromatid exchange assay and an unscheduled DNA synthesis assay. Conflicting
results have been reported for the mouse lymphoma cell assay. Increased micronuclei were reported in an

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in vitro Syrian hamster embryo cell assay; however, two in vivo micronuclei studies in mice were negative.
In Syrian hamster embryo cells in vitro, cell transformation was observed at 7 days of incubation but not at
24 hours. Based on these results, ethylbenzene is not expected to be mutagenic or clastogenic.
CARCINOGENICITY: In studies conducted by the National Toxicology Program, rats and mice were
exposed to ethylbenzene at 25, 250 and 750 ppm for six hours per day, five days per week for 103 weeks.
In rats exposed to 750 ppm, the incidence of kidney tubule hyperplasia and tumors was increased.
Testicular tumors develop spontaneously in nearly all rats if allowed to complete their natural life span; in
this study, the development of these tumors appeared to be enhanced in male rats exposed to 750 ppm. In
mice, the incidences of lung tumors in males and liver tumors in females exposed to 750 ppm were
increased as compared to control mice but were within the range of incidences observed historically in
control mice. Other liver effects were observed in male mice exposed to 250 and 750 ppm. The incidences
of hyperplasia were increased in the pituitary gland in female mice at 250 and 750 ppm and in the thyroid in
male and female mice at 750 ppm.

This product contains toluene.

GENERAL TOXICITY: The primary effects of exposure to toluene in animals and humans are on the
central nervous system. Solvent abusers, who typically inhale high concentrations (thousands of ppm) for
brief periods of time, in addition to experiencing respiratory tract irritation, often suffer permanent central
nervous system effects that include tremors, staggered gait, impaired speech, hearing and vision loss, and
changes in brain tissue. Death in some solvent abusers has been attributed to cardiac arrhythmias, which
appear to be have been triggered by epinephrine acting on solvent sensitized cardiac tissue. Although liver
and kidney effects have been seen in some solvent abusers, results of animal testing with toluene do not
support these as primary target organs.
HEARING: Humans who were occupationally exposed to concentrations of toluene as low as 100 ppm for
long periods of time have experienced hearing deficits. Hearing loss, as demonstrated using behavioral
and electrophysiological testing as well as by observation of structural damage to cochlear hair cells,
occurred in experimental animals exposed to toluene. It also appears that toluene exposure and noise may
interact to produce hearing deficits.
COLOR VISION: In a single study of workers exposed to toluene at levels under 50 ppm, small decreases
in the ability to discriminate colors in the blue-yellow range have been reported for female workers. This
effect, which should be investigated further, is very subtle and would not likely have been noticed by the
people tested.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: Toluene may also cause mental and/or growth
retardation in the children of female solvent abusers who directly inhale toluene (usually at thousands of
ppm) when they are pregnant. Toluene caused growth retardation in rats and rabbits when administered at
doses that were toxic to the mothers. In rats, concentrations of up to 5000 ppm did not cause birth defects.
No effects were observed in the offspring at doses that did not intoxicate the pregnant animals. The
exposure level at which no effects were seen (No Observed Effect Level, NOEL) is 750 ppm in the rat and
500 ppm in the rabbit.

This product contains xylene.

ACUTE TOXICITY: The primary effects of exposure to xylene in animals and humans are on the central
nervous system. In addition,in some individuals, xylene exposure can sensitize cardiac tissue to
epinephrine which may precipitate fatal ventricular fibrillation. DEVELOPMENTAL TOXICITY: Xylene has
been reported to cause developmental toxicity in rats and mice exposed by inhalation during pregnancy.

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The effects noted consisted of delayed development and minor skeletal variations. In addition, when
pregnant mice were exposed by ingestion to a level that killed nearly one-third of the test group, lethality
(resorptions) and malformations (primarily cleft palate) occurred. Since xylene can cross the placenta, it
may be appropriate to prevent exposure during pregnancy. GENETIC TOXICITY/CARCINOGENICITY:
Xylene was not genotoxic in several mutagenicity testing assays including the Ames test. In a cancer study
sponsored by the National Toxicology Program (NTP),technical grade xylene gave no evidence of
carcinogenicity in rats or mice dosed daily for two years. HEARING: Mixed xylenes have been shown to
cause measurable hearing loss in rats exposed to 800 ppm in the air for 14 hours per day for six weeks.
Exposure to 1450 ppm xylene for 8 hours caused hearing loss while exposure to 1700 ppm for 4 hours did
not. Although no information is available for lower concentrations, other chemicals that cause hearing loss
in rats at relatively high concentrations do not cause hearing loss in rats at low concentrations. Worker
exposure to xylenes at the permissible exposure limit (100 ppm, time-weighted average) is not expected to
cause hearing loss.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is expected to be toxic to aquatic organisms and may cause long-term adverse effects in the
aquatic environment.

96 hour(s) LC50: 2.7 mg/l (Oncorhynchus mykiss)

96 hour(s) LC50: 1.8 mg/l (Mysidopsis bahia)
96 hour(s) LC50: 8.3 mg/l (Cyprinodon variegatus)
48 hour(s) LC50: 3.0 mg/l (Daphnia magna)

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is expected to be readily biodegradable. Following spillage, the more volatile components of
gasoline will be rapidly lost, with concurrent dissolution of these and other constituents into the water.
Factors such as local environmental conditions (temperature, wind, mixing or wave action, soil type, etc),
photo-oxidation, biodegradation and adsorption onto suspended sediments, can contribute to the
weathering of spilled gasoline.

The aqueous solubility of non-oxygenated unleaded gasoline, based on analysis of benzene, toluene,
ethylbenzene+xylenes and naphthalene, is reported to be 112 mg/l. Solubility data on individual gasoline
constituents also available.

POTENTIAL TO BIOACCUMULATE
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Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: 2 - 7

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations. Check
governmental regulations and local authorities for approved disposal of this material.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

DOT Shipping Description: UN1203, GASOLINE, 3, II; OPTIONAL DISCLOSURE: UN1203, GASOLINE,
3, II, MARINE POLLUTANT (GASOLINE)

IMO/IMDG Shipping Description: UN1203, GASOLINE, 3, II, FLASH POINT SEE SECTION 5 OR 9,
MARINE POLLUTANT (GASOLINE)

ICAO/IATA Shipping Description: UN1203, GASOLINE, 3, II

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

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The following components of this material are found on the regulatory lists indicated.
Cyclohexane 05, 06, 07
Heptane 05, 06, 07
Methylcyclohexane 05, 06, 07
Pentane, 2,2,4-trimethyl- (Isooctane) 05, 06, 07
Naphthalene 01-2B, 02, 04, 05, 06, 07
Xylene (contains o-, m-, & p- xylene isomers in 03, 05, 06, 07
varying amounts)
Benzene 01-1, 02, 03, 04, 05, 06, 07
Butane 05, 06, 07
Ethanol 01-1, 02, 04, 05, 07
Hexane 05, 06, 07
Gasoline 01-2B, 07
Ethyl benzene 01-2B, 03, 04, 05, 07
Toluene (methylbenzene) 04, 05, 07

CERCLA REPORTABLE QUANTITIES(RQ)/EPCRA 302 THRESHOLD PLANNING QUANTITIES(TPQ):

Component Component RQ Component TPQ Product RQ

Benzene 10 lbs None 186 lbs
Cyclohexane 1000 lbs None 34188 lbs
Ethyl benzene 1000 lbs None 34964 lbs
Hexane 5000 lbs None 129149 lbs
Naphthalene 100 lbs None 4000 lbs
Pentane, 2,2,4-trimethyl- (Isooctane) 1000 lbs None 6270 lbs
Toluene (methylbenzene) 1000 lbs None 2627 lbs
Xylene (contains o-, m-, & p- xylene 100 lbs None 649 lbs
isomers in varying amounts)

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS (Philippines),
TSCA (United States).

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 1 Flammability: 4 Reactivity: 0

HMIS RATINGS: Health: 2* Flammability: 4 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
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recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1,16
Revision Date: JANUARY 07, 2016

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct as of
the date hereof. Since this information may be applied under conditions beyond our control and with
which we may be unfamiliar and since data made available subsequent to the date hereof may
suggest modifications of the information, we do not assume any responsibility for the results of its use.
This information is furnished upon condition that the person receiving it shall make his own
determination of the suitability of the material for his particular purpose.

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Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Naphtha
Product Use: Chemical Feedstock, Fuel
Product Number(s): CPS203019, CPS212980
Synonyms: Naphtha, Petroleum, Straight Run Naphtha, Whole Straight Run
Company Identification
Chevron Products Company
6001 Bollinger Canyon Road
San Ramon, CA 94583
United States of America

Transportation Emergency Response

CHEMTREC: (800) 424-9300 or (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
Product Information: [Link]

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable liquid: Category 1. Aspiration toxicant: Category 1. Carcinogen: Category

1A. Target organ toxicant (repeated exposure): Category 1. Germ Cell Mutagen: Category 1B. Skin
irritation: Category 2. Target organ toxicant (central nervous system): Category 3. Acute aquatic toxicant:
Category 2. Chronic aquatic toxicant: Category 2.

Signal Word: Danger

Physical Hazards: Extremely flammable liquid and vapor.

Health Hazards: May be fatal if swallowed and enters airways. May cause genetic defects. May cause
cancer. Causes skin irritation. May cause drowsiness or dizziness.

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Target Organs: Causes damage to organs (Auditory System, Blood/Blood Forming Organs) through
prolonged or repeated exposure.

Environmental Hazards: Toxic to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS:
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking.
Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use explosion-proof
electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Use only
outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face
protection. Use personal protective equipment as required. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Avoid release to the environment.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN:
Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. IF ON SKIN (or hair): Take off immediately all
contaminated clothing and wash it before reuse. Rinse skin with water/shower. IF SWALLOWED:
Immediately call a poison center or doctor/physician. Do NOT induce vomiting. IF exposed or concerned:
Get medical advice/attention. In case of fire: Use media specified in the SDS to extinguish. Specific
treatment (see Notes to Physician on this label). Collect spillage.
Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Naphtha, straight run full-range 64741-42-0 100 %weight
Toluene (methylbenzene) 108-88-3 1 - 6 %weight
Benzene 71-43-2 0.1 - 5 %weight
Xylene (contains o-, m-, & p- xylene isomers in 1330-20-7 1 - 4 %weight
varying amounts)

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical
attention if any symptoms develop. To remove the material from skin, use soap and water. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by
mouth to an unconscious person.

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Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention if breathing difficulties continue or if any other symptoms
develop.

Most important symptoms and effects, both acute and delayed

IMMEDIATE HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin causes irritation. Skin contact may cause drying or defatting of the skin.
Symptoms may include pain, itching, discoloration, swelling, and blistering. Contact with the skin is not
expected to cause an allergic skin response.
Ingestion: Highly toxic; may be fatal if swallowed. Because of its low viscosity, this material can directly
enter the lungs, if swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and
can cause severe injury or death. May be irritating to mouth, throat, and stomach. Symptoms may include
pain, nausea, vomiting, and diarrhea.
Inhalation: Excessive or prolonged breathing of this material may cause central nervous system effects.
Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of
coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures, central
nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness,
coma or death.

DELAYED OR OTHER HEALTH EFFECTS:

Cancer: Prolonged or repeated exposure to this material may cause cancer. Contains benzene, which
has been classified as a carcinogen by the National Toxicology Program (NTP) and a Group 1 carcinogen
(carcinogenic to humans) by the International Agency for Research on Cancer (IARC).

Genetic Toxicity: Contains material that may cause heritable genetic damage based on animal data.
Target Organs: Contains material that may cause damage to the following organ(s) following repeated
inhalation at concentrations above the recommended exposure limit:Blood/Blood Forming Organs Auditory
System Risk depends on duration and level of exposure. See Section 11 for additional information.

Indication of any immediate medical attention and special treatment needed

Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light
hydrocarbon liquid, which may cause pneumonitis.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

Unusual Fire Hazards: See Section 7 for proper handling and storage.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire
space without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area with combustible gas
indicator.
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Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated
materials in disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Precautionary Measures: This material presents a fire hazard. Liquid quickly evaporates and forms vapor
(fumes) which can catch fire and burn with explosive violence. Invisible vapor spreads easily and can be
set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches.
Fire hazard is greater as liquid temperature rises above -10C (15F). Do not get in eyes, on skin, or on
clothing. Do not taste or swallow. Do not breathe vapor or fumes. Wash thoroughly after handling.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,
sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use
appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces .
USE AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and
other substances in the work place when designing engineering controls and selecting personal protective
equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful
levels of this material, the personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the equipment since protection is usually
provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below the recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
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Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may
include gloves, apron, boots, and complete facial protection depending on operations conducted.
Suggested materials for protective gloves include: Chlorinated Polyethylene (or Chlorosulfonated
Polyethylene), Nitrile Rubber, Polyurethane, Viton.
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational
exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an
approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator
for Organic Vapors.

Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation

Naphtha, straight run full-range Not -- -- -- --

Applicable
Toluene (methylbenzene) ACGIH 50 ppm -- -- Skin A4
(weight)
Toluene (methylbenzene) OSHA Z-2 200 ppm -- 300 ppm --
(weight) (weight)
Benzene ACGIH .5 ppm 2.5 ppm -- Skin A1
(weight) (weight) Skin
Benzene OSHA SRS 1 ppm 5 ppm -- --
(weight) (weight)
Benzene OSHA Z-2 10 ppm -- 25 ppm --
(weight) (weight)
Benzene CVX 1 ppm 5 ppm -- --
(weight) (weight)
Xylene (contains o-, m-, & p- xylene ACGIH 100 ppm 150 ppm -- A4
isomers in varying amounts) (weight) (weight)
Xylene (contains o-, m-, & p- xylene OSHA Z-1 435 mg/m3 -- -- --
isomers in varying amounts)
Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Yellow
Physical State: Liquid
Odor: Hydrocarbon odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: 3.37 - 11.5
Vapor Density (Air = 1): 2.8 (Estimated)
Initial Boiling Point: -3.9°C (25°F) - 162.8°C (325°F)
Solubility: Insoluble in water.
Freezing Point: Not Applicable
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Specific Gravity: 0.7 - 0.75 @ 15.6°C (60.1°F)
Density: 43.5 - 46.5 lbs/ft3 H20=1
Decomposition temperature: No data available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available

Flashpoint: < -7 °C (< 20 °F) (Estimated)

Autoignition: 498 °C (928 °F)
Flammability (Explosive) Limits (% by volume in air): Lower: 1.2 Upper: 7.8

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Conditions to Avoid: Avoid contact with heat, sparks, fire and oxidizing agents
Incompatibility With Other Materials: Not applicable
Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for similar
materials.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for similar materials.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar
materials.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar
materials.
Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.

Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Contains
benzene, which has been classified as a carcinogen by the National Toxicology Program (NTP) and a
Group 1 carcinogen (carcinogenic to humans) by the International Agency for Research on Cancer (IARC).

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
_____________________________________________________________________

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components or a similar material.

Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:

This product contains toluene.
GENERAL TOXICITY: The primary effects of exposure to toluene in animals and humans are on the
central nervous system. Solvent abusers, who typically inhale high concentrations (thousands of ppm) for
brief periods of time, in addition to experiencing respiratory tract irritation, often suffer permanent central
nervous system effects that include tremors, staggered gait, impaired speech, hearing and vision loss, and
changes in brain tissue. Death in some solvent abusers has been attributed to cardiac arrhythmias, which
appear to be have been triggered by epinephrine acting on solvent sensitized cardiac tissue. Although liver
and kidney effects have been seen in some solvent abusers, results of animal testing with toluene do not
support these as primary target organs.
HEARING: Humans who were occupationally exposed to concentrations of toluene as low as 100 ppm for
long periods of time have experienced hearing deficits. Hearing loss, as demonstrated using behavioral and
electrophysiological testing as well as by observation of structural damage to cochlear hair cells, occurred
in experimental animals exposed to toluene. It also appears that toluene exposure and noise may interact
to produce hearing deficits.
COLOR VISION: In a single study of workers exposed to toluene at levels under 50 ppm, small decreases
in the ability to discriminate colors in the blue-yellow range have been reported for female workers. This
effect, which should be investigated further, is very subtle and would not likely have been noticed by the
people tested.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: Toluene may also cause mental and/or growth
retardation in the children of female solvent abusers who directly inhale toluene (usually at thousands of
ppm) when they are pregnant. Toluene caused growth retardation in rats and rabbits when administered at
doses that were toxic to the mothers. In rats, concentrations of up to 5000 ppm did not cause birth defects.
No effects were observed in the offspring at doses that did not intoxicate the pregnant animals. The
exposure level at which no effects were seen (No Observed Effect Level, NOEL) is 750 ppm in the rat and
500 ppm in the rabbit.

This product contains xylene.

ACUTE TOXICITY: The primary effects of exposure to xylene in animals and humans are on the central
nervous system. In addition,in some individuals, xylene exposure can sensitize cardiac tissue to
epinephrine which may precipitate fatal ventricular fibrillation. DEVELOPMENTAL TOXICITY: Xylene has
been reported to cause developmental toxicity in rats and mice exposed by inhalation during pregnancy.
The effects noted consisted of delayed development and minor skeletal variations. In addition, when
pregnant mice were exposed by ingestion to a level that killed nearly one-third of the test group, lethality
(resorptions) and malformations (primarily cleft palate) occurred. Since xylene can cross the placenta, it
may be appropriate to prevent exposure during pregnancy. GENETIC TOXICITY/CARCINOGENICITY:
Xylene was not genotoxic in several mutagenicity testing assays including the Ames test. In a cancer study
sponsored by the National Toxicology Program (NTP),technical grade xylene gave no evidence of
carcinogenicity in rats or mice dosed daily for two years. HEARING: Mixed xylenes have been shown to
cause measurable hearing loss in rats exposed to 800 ppm in the air for 14 hours per day for six weeks.
Exposure to 1450 ppm xylene for 8 hours caused hearing loss while exposure to 1700 ppm for 4 hours did
not. Although no information is available for lower concentrations, other chemicals that cause hearing loss
in rats at relatively high concentrations do not cause hearing loss in rats at low concentrations. Worker
exposure to xylenes at the permissible exposure limit (100 ppm, time-weighted average) is not expected to
cause hearing loss.

This product contains benzene.

GENETIC TOXICITY/CANCER: Repeated or prolonged breathing of benzene vapor has been associated

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with the development of chromosomal damage in experimental animals and various blood diseases in
humans ranging from aplastic anemia to leukemia (a form of cancer). All of these diseases can be fatal. In
some individuals, benzene exposure can sensitize cardiac tissue to epinephrine which may precipitate fatal
ventricular fibrillation.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: No birth defects have been shown to occur in pregnant
laboratory animals exposed to doses not toxic to the mother. However, some evidence of fetal toxicity such
as delayed physical development has been seen at such levels. The available information on the effects of
benzene on human pregnancies is inadequate but it has been established that benzene can cross the
human placenta.
OCCUPATIONAL: The OSHA Benzene Standard (29 CFR 1910.1028) contains detailed requirements for
training, exposure monitoring, respiratory protection and medical surveillance triggered by the exposure
level. Refer to the OSHA Standard before using this product.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is expected to be toxic to aquatic organisms and may cause long-term adverse effects in the
aquatic environment.
The product has not been tested. The statement has been derived from the properties of the individual
components.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is not expected to be readily biodegradable. The biodegradability of this material is based on
an evaluation of data for the components or a similar material.
The product has not been tested. The statement has been derived from products of a similar structure and
composition.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

DOT Shipping Description: UN1268, PETROLEUM DISTILLATES, N.O.S. (NAPHTHA), 3, I, MARINE

POLLUTANT (NAPHTHA)

IMO/IMDG Shipping Description: UN1268, PETROLEUM DISTILLATES, N.O.S. (NAPHTHA), 3, I,

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FLASH POINT SEE SECTION 5 OR 9, MARINE POLLUTANT (NAPHTHA)

ICAO/IATA Shipping Description: UN1268, PETROLEUM DISTILLATES, N.O.S. (NAPHTHA), 3, I

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

Toluene (methylbenzene) 03, 04, 05, 06, 07

Benzene 01-1, 02, 03, 04, 05, 06, 07
Xylene (contains o-, m-, & p- xylene isomers in 03, 05, 06, 07
varying amounts)

CERCLA REPORTABLE QUANTITIES(RQ)/EPCRA 302 THRESHOLD PLANNING QUANTITIES(TPQ):

Component Component RQ Component TPQ Product RQ
Benzene 10 lbs None 200 lbs
Toluene (methylbenzene) 1000 lbs None 16667 lbs
Xylene (contains o-, m-, & p- xylene 100 lbs None 2500 lbs
isomers in varying amounts)

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS (Philippines),
TSCA (United States).

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 1 Flammability: 3 Reactivity: 0

HMIS RATINGS: Health: 2* Flammability: 3 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index

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recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16
Revision Date: MAY 14, 2015

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our
control and with which we may be unfamiliar and since data made available subsequent to the
date hereof may suggest modifications of the information, we do not assume any responsibility
for the results of its use. This information is furnished upon condition that the person receiving
it shall make his own determination of the suitability of the material for his particular purpose.

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Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

DIESEL FUEL No. 2

Product Use: Fuel [See Section 16 for Additional Product Numbers]
Synonyms: 15 S Diesel Fuel 2, Alternative Low Aromatic Diesel (ALAD), Calco LS Diesel 2, CALCO
ULS C-B0-B5 DF2, CALCO ULS C-B0-B5 DF2 DYED, CALCO ULS C-B2 DF2, CALCO ULS C-B2 DF2
DYED, CALCO ULS C-B5 DF2, CALCO ULS C-B5 DF2 DYED, Calco ULS DF2, Calco ULS Diesel 2,
CALCO ULS S-B0-B5 DF2 DYED, Calco ULS S-B5 DF2, Calco ULS S-B5 DF2 DYED, CALCO ULS TC-B1
DF2, CALCO ULS TC-B1 DF2 DYED, CALCO ULS TC-B2 DF2, CALCO ULS TC-B2 DF2 DYED, CALCO
ULS TC-B3 DF2, CALCO ULS TC-B3 DF2 DYED, CALCO ULS TC-B4 DF2, CALCO ULS TC-B4 DF2
DYED, CALCO ULS TC-B5 DF2, CALCO ULS TC-B5 DF2 DYED, CALCO ULS TX-B1 DF2, CALCO ULS
TX-B1 DF2 DYED, CALCO ULS TX-B2 DF2, CALCO ULS TX-B2 DF2 DYED, CALCO ULS TX-B3 DF2,
CALCO ULS TX-B3 DF2 DYED, CALCO ULS TX-B4 DF2, CALCO ULS TX-B4 DF2 DYED, CALCO ULS
TX-B5 DF2, CALCO ULS TX-B5 DF2 DYED, Chevron LS Diesel 2, Chevron ULS Diesel 2, CT ULS
C-B0-B5 DF2, CT ULS C-B0-B5 DF2 DYED, CT ULS C-B2 DF2, CT ULS C-B5 DF2, CT ULS S-B0-B5 DF2
DYED, CT ULS S-B5 DF2, CT ULS S-B5 DF2 DYED, CT ULS S-BO-B5 DF2, CT ULS SPECIAL DF2
DYED, CT ULS TC-B1 DF2, CT ULS TC-B2 DF2, CT ULS TC-B3 DF2, CT ULS TC-B4 DF2, CT ULS
TC-B5 DF2, CT ULS TX-B1 DF2, CT ULS TX-B2 DF2, CT ULS TX-B3 DF2, CT ULS TX-B4 DF2, CT ULS
TX-B5 DF2, Diesel Fuel Oil, Diesel Grade No. 2, Diesel No. 2-D S15, Diesel No. 2-D S500, Diesel No. 2-D
S5000, Distillates, straight run, Gas Oil, HS Diesel 2, HS Heating Fuel 2, Light Diesel Oil Grade No. 2-D, LS
Diesel 2, LS Heating Fuel 2, Marine Diesel, RR Diesel Fuel, Texaco Diesel, Texaco Diesel No. 2, ULS
C-B0-B5 DF2, ULS C-B0-B5 DF2 DYED, ULS C-B2 DF2, ULS C-B2 DF2 DYED, ULS C-B5 DF2, ULS C-B5
DF2 DYED, ULS S-B0-B5 DF2 DYED, ULS S-B5 DF2, ULS S-BO-B5 DF2, ULS TC-B1 DF2, ULS TC-B1
DF2 DYED, ULS TC-B2 DF2, ULS TC-B2 DF2 DYED, ULS TC-B3 DF2, ULS TC-B3 DF2 DYED, ULS
TC-B4 DF2, ULS TC-B4 DF2 DYED, ULS TC-B5 DF2, ULS TC-B5 DF2 DYED, ULS TX-B1 DF2, ULS
TX-B1 DF2 DYED, ULS TX-B3 DF2, ULS TX-B3 DF2 DYED, ULS TX-B4 DF2, ULS TX-B4 DF2 DYED,
ULS TX-B5 DF2, ULS TX-B5 DF2 DYED, Ultra Low Sulfur Diesel 2
Company Identification
Chevron Products Company
Marketing, MSDS Coordinator
6001 Bollinger Canyon Road
San Ramon, CA 94583
United States of America

Transportation Emergency Response

CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
MSDS Requests: [Link]
Technical Information: (510) 242-5357
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SPECIAL NOTES: This MSDS covers all Chevron, Texaco and Calco CARB & non-CARB Diesel No. 2
Fuels. The sulfur content is less than 0.5% (mass). Red dye is added to non-taxable fuel. (MSDS 6894)
SPECIAL NOTES: This MSDS covers all Chevron and Calco CARB Low Sulfur Diesel No. 2 Fuels. Red
dye is added to non-taxable fuel. (MSDS 7098)

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable liquid: Category 3. Aspiration toxicant: Category 1. Skin irritation:

Category 2. Carcinogen: Category 2. Target organ toxicant (central nervous system): Category 3. Acute
aquatic toxicant: Category 2. Chronic aquatic toxicant: Category 2.

Signal Word: Danger

Physical Hazards: Flammable liquid and vapor.

Health Hazards: May be fatal if swallowed and enters airways. Causes skin irritation. Suspected of
causing cancer. May cause drowsiness or dizziness.

Environmental Hazards: Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

PRECAUTIONARY STATEMENTS:
General: Keep out of reach of children. Read label before use.
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat/sparks/open flames/hot surfaces. -- No smoking.
Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use explosion-proof
electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only
outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face
protection. Use personal protective equipment as required. Wash thoroughly after handling. Avoid release
to the environment.
Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN:
Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. IF ON SKIN (or hair): Take off immediately all
contaminated clothing and wash it before reuse. Rinse skin with water/shower. IF SWALLOWED:
Immediately call a poison center or doctor/physician. Do NOT induce vomiting. Call a poison center or
doctor/physician if you feel unwell. IF exposed or concerned: Get medical advice/attention. In case of fire:
Use media specified in the SDS to extinguish. Specific treatment (see Notes to Physician on this label).
Collect spillage.
Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.

HAZARDS NOT OTHERWISE CLASSIFIED: Not Applicable

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 SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Diesel Fuel No. 2 68476-34-6 95 - 100 %volume
Fatty Acid Methyl Esters (FAME) Mixture 0 - 5 %volume
ALKANES,C10-C20-BRANCHED AND LINEAR 928771-01-1 0 - 5 %volume
Total sulfur Mixture 0 - 0.5 %volume
Naphthalene 91-20-3 0.02 - 0.2 %volume

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical
attention if any symptoms develop. To remove the material from skin, use soap and water. Discard
contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by
mouth to an unconscious person.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air,
move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.
Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention if breathing difficulties continue or if any other symptoms develop.

Most important symptoms and effects, both acute and delayed

IMMEDIATE HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin causes irritation. Contact with the skin is not expected to cause an allergic skin
response. Symptoms may include pain, itching, discoloration, swelling, and blistering.
Ingestion: Because of its low viscosity, this material can directly enter the lungs, if swallowed, or if
subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or death.
May be irritating to mouth, throat, and stomach. Symptoms may include pain, nausea, vomiting, and
diarrhea.
Inhalation: Excessive or prolonged breathing of this material may cause central nervous system effects.
Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of
coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures, central
nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness,
coma or death. The vapor or fumes from this material may cause respiratory irritation. Mists of this
material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and
difficulty breathing.

DELAYED OR OTHER HEALTH EFFECTS:

Cancer: Whole diesel engine exhaust has been classified as a Group 2A carcinogen (probably
carcinogenic to humans) by the International Agency for Research on Cancer (IARC). Prolonged or
repeated exposure to this material may cause cancer. Contains naphthalene, which has been classified as
a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for Research on

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Cancer (IARC). Risk depends on duration and level of exposure. See Section 11 for additional
information.

Indication of any immediate medical attention and special treatment needed

Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light
hydrocarbon liquid, which may cause pneumonitis.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

Unusual Fire Hazards: See Section 7 for proper handling and storage.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire
space without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this
material is released into the work area, evacuate the area immediately. Monitor area with combustible gas
indicator.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean non-sparking tools to
collect absorbed material. Where feasible and appropriate, remove contaminated soil. Place contaminated
materials in disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with
explosive force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights,
welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises
above 29C (85F).
Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Do not breathe vapor or fumes. Do
not breathe mist. Wash thoroughly after handling. Keep out of the reach of children.
Unusual Handling Hazards: WARNING! Do not use as portable heater or appliance fuel. Toxic fumes
may accumulate and cause death. Slow heat generation may occur with oil-soaked rags, spent filter aids
and spent absorbent material and may cause spontaneous combustion if stored near combustibles and not
handled properly. Store biodiesel soaked rags, filter aids, and spill absorbent material in approved safety
disposal containers and dispose of properly. Biodiesel soaked rags may be washed with soap and water
and allowed to dry in well ventilated area.

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Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,
sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use
appropriate mitigating procedures.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces .
USE AND STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and
other substances in the work place when designing engineering controls and selecting personal protective
equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful
levels of this material, the personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the equipment since protection is usually
provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below the recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may
include gloves, apron, boots, and complete facial protection depending on operations conducted.
Suggested materials for protective gloves include: Chlorinated Polyethylene (or Chlorosulfonated
Polyethylene), Nitrile Rubber, Polyurethane, Viton.
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational
exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an
approved respirator that provides adequate protection from this material, such as: Air-Purifying Respirator
for Organic Vapors.
When used as a fuel, this material can produce carbon monoxide in the exhaust. Determine if airborne
concentrations are below the occupational exposure limit for carbon monoxide. If not, wear an approved
positive-pressure air-supplying respirator.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation

Diesel Fuel No. 2 ACGIH 100 mg/m3 -- -- Skin A3

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 total
hydrocarbon
Diesel Fuel No. 2 CVX -- 1000 mg/m3 -- --
ALKANES,C10-C20-BRANCHED Not -- -- -- --
AND LINEAR Applicable
Fatty Acid Methyl Esters (FAME) Not -- -- -- --
Applicable
Total sulfur Not -- -- -- --
Applicable
Naphthalene ACGIH 10 ppm 15 ppm -- Skin
(weight) (weight)
Naphthalene OSHA Z-1 50 mg/m3 -- -- --
Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Varies depending on specification

Physical State: Liquid
Odor: Petroleum odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: 0.04 kPa (Approximate) @ 40 °C (104 °F)
Vapor Density (Air = 1): >1
Initial Boiling Point: 175.6°C (348°F) - 370°C (698°F)
Solubility: Soluble in hydrocarbons; insoluble in water
Freezing Point: Not Applicable
Melting Point: Not Applicable
Specific Gravity: 0.8 - 0.88 @ 15.6°C (60.1°F) (Typical)
Viscosity: 1.9 cSt - 4.1 cSt @ 40°C (104°F)
Decomposition temperature: No Data Available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available

Flashpoint: (Pensky-Martens Closed Cup) 52 °C (125 °F) Minimum

Autoignition: 257 °C (494 °F)
Flammability (Explosive) Limits (% by volume in air): Lower: 0.6 Upper: 4.7

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Conditions to Avoid: Avoid contact with heat, sparks, fire and oxidizing agents
Incompatibility With Other Materials: Not applicable

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Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for similar
materials.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for similar materials.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar
materials.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar
materials.
Acute Toxicity Estimate: Not Determined

Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.

Carcinogenicity: The hazard evaluation is based on data for components or a similar material. Whole
diesel engine exhaust has been classified as a Group 2A carcinogen (probably carcinogenic to humans) by
the International Agency for Research on Cancer (IARC). Contains naphthalene, which has been
classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for
Research on Cancer (IARC).

Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
components or a similar material.

Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:

The National Institute of Occupational Safety and Health (NIOSH) has recommended that whole diesel
exhaust be regarded as potentially causing cancer. This recommendation was based on test results
showing increased lung cancer in laboratory animals exposed to whole diesel exhaust.

This product contains naphthalene. GENERAL TOXICITY: Exposure to naphthalene has been reported to
cause methemoglobinemia and/or hemolytic anemia, especially in humans deficient in the enzyme
glucose-6-phosphate dehydrogenase. Laboratory animals given repeated oral doses of naphthalene have
developed cataracts. REPRODUCTIVE TOXICITY AND BIRTH DEFECTS: Naphthalene did not cause
birth defects when administered orally to rabbits, rats, and mice during pregnancy, but slightly reduced litter
size in mice at dose levels that were lethal to the pregnant females. Naphthalene has been reported to
cross the human placenta. GENETIC TOXICITY: Naphthalene caused chromosome aberrations and sister
chromatid exchanges in Chinese hamster ovary cells, but was not a mutagen in several other in-vitro
[Link]: In a study conducted by the National Toxicology Program (NTP), mice exposed
to 10 or 30 ppm of naphthalene by inhalation daily for two years had chronic inflammation of the nose and
lungs and increased incidences of metaplasia in those tissues. The incidence of benign lung tumors

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(alveolar/bronchiolar adenomas) was significantly increased in the high-dose female group but not in the
male groups. In another two-year inhalation study conducted by NTP, exposure of rats to 10, 30, and 60
ppm naphthalene caused increases in the incidences of a variety of nonneoplastic lesions in the nose.
Increases in nasal tumors were seen in both sexes, including olfactory neuroblastomas in females at 60
ppm and adenomas of the respiratory epithelium in males at all exposure levels. The relevance of these
effects to humans has not been established. No carcinogenic effect was reported in a 2-year feeding study
in rats receiving naphthalene at 41 mg/kg/day.

This product contains gas oils.

CONCAWE (product dossier 95/107) has summarized current health, safety and environmental data
available for a number of gas oils, typically hydrodesulfurized middle distillates, CAS 64742-80-9,
straight-run middle distillates, CAS 64741-44-2, and/or light cat-cracked distillate CAS 64741-59-9.
CARCINOGENICITY: All materials tested have caused the development of skin tumors in mice, but all
featured severe skin irritation and sometimes a long latency period before tumors developed. Straight-run
and cracked gas oil samples were studied to determine the influence of dermal irritation on the
carcinogenic activity of middle distillates. At non-irritant doses the straight-run gas oil was not carcinogenic,
but at irritant doses, weak activity was demonstrated. Cracked gas oils, when diluted with mineral oil,
demonstrated carcinogenic activity irrespective of the occurrence of skin irritation. Gas oils were tested on
male mice to study tumor initiating/promoting activity. The results demonstrated that while a straight-run
gas oil sample was neither an initiator or promotor, a blend of straight-run and FCC stock was both a tumor
initiator and a promoter.
GENOTOXICITY: Hydrotreated & hydrodesulfurized gas oils range in activity from inactive to weakly
positive in in-vitro bacterial mutagenicity assays. Mouse lymphoma assays on straight-run gas oils without
subsequent hydrodesulphurization gave positive results in the presence of S9 metabolic activation. In-vivo
bone marrow cytogenetics and sister chromatic exchange assay exhibited no activity for straight-run
components with or without hydrodesulphurization. Thermally or catalytically cracked gas oils tested with
in-vitro bacterial mutagenicity assays in the presence of S9 metabolic activation were shown to be
mutagenic. In-vitro sister chromatic exchange assays on cracked gas oil gave equivocal results both with
and without S9 metabolic activation. In-vivo bone marrow cytogenetics assay was inactive for two cracked
gas oil samples. Three hydrocracked gas oils were tested with in-vitro bacterial mutagenicity assays with
S9, and one of the three gave positive results. Twelve distillate fuel samples were tested with in-vitro
bacterial mutagenicity assays & with S9 metabolic activation and showed negative to weakly positive
results. In one series, activity was shown to be related to the PCA content of samples tested. Two in-vivo
studies were also conducted. A mouse dominant lethal assay was negative for a sample of diesel fuel. In
the other study, 9 samples of No 2 heating oil containing 50% cracked stocks caused a slight increase in
the number of chromosomal aberrations in bone marrow cytogenetics assays. DEVELOPMENTAL
TOXICITY: Diesel fuel vapor did not cause fetotoxic or teratogenic effects when pregnant rats were
exposed on days 6-15 of pregnancy. Gas oils were applied to the skin of pregnant rats daily on days 0-19
of gestation. All but one (coker light gas oil) caused fetotoxicity (increased resorptions, reduced litter
weight, reduced litter size) at dose levels that were also maternally toxic.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
A series of studies on the acute toxicity of 4 diesel fuel samples were conducted by one laboratory using
water accommodated fractions. The range of effective (EC50) or lethal concentrations (LC50) expressed
as loading rates were: This material is expected to be toxic to aquatic organisms and may cause long-term
adverse effects in the aquatic environment.
The product has not been tested. The statement has been derived from products of a similar structure and
composition.

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MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY

This material is not expected to be readily biodegradable. On release to the environment the lighter
components of diesel fuel will generally evaporate but depending on local environmental conditions
(temperature, wind, mixing or wave action, soil type, etc.) the remainder may become dispersed in the
water column or absorbed to soil or sediment. Diesel fuel would not be expected to be readily
biodegradable. In a modified Strum test (OECD method 301B) approximately 40% biodegradation was
recorded over 28 days. However, it has been shown that most hydrocarbon components of diesel fuel are
degraded in soil in the presence of oxygen. Under anaerobic conditions, such as in anoxic sediments,
rates of biodegradation are negligible.
The product has not been tested. The statement has been derived from products of a similar structure and
composition.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

DOT Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point (PM
Closed Cup) >/= 23 deg C but </= 60 deg C: UN1202, GAS OIL, 3, III; OPTIONAL DISCLOSURE:
UN1202, GAS OIL, 3, III, MARINE POLLUTANT (DIESEL FUEL) Optional disclosure per 49 CFR when
Flash Point (PM Closed Cup) > 38 deg C < 93 deg C per 49 173.150 (f): UN1202, GAS OIL,
COMBUSTIBLE LIQUID, III; NON-BULK PACKAGES ARE NOT REGULATED IN USA JURISDICTIONS
Optional disclosure as a GHS Environmental Hazard/Marine Pollutant when Flash Point (Closed Cup) >
60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(DIESEL FUEL),
9, III, MARINE POLLUTANT (DIESEL FUEL)

IMO/IMDG Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point
(PM Closed Cup) >/= 23 deg C, </= 60 deg C: UN1202, GAS OIL, 3, III, FLASH POINT SEE SECTION 5
OR 9, MARINE POLLUTANT (DIESEL FUEL); OPTIONAL DISCLOSURE: UN1268, PETROLEUM
DISTILLATES, N.O.S. (DIESEL FUEL), 3, III, FLASH POINT SEE SECTION 5 OR 9, MARINE
POLLUTANT (DIESEL FUEL) For packages with a Flash Point (PM Closed Cup) > 60 deg C: UN3082,
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (DIESEL FUEL), 9, III, MARINE
POLLUTANT (DIESEL FUEL)

ICAO/IATA Shipping Description: For packages with an Initial Boiling Point > 35 deg C and a Flash Point
(PM Closed Cup) >/= 23 deg C, </= 60 deg C: UN1202, GAS OIL, 3, III For packages with a Flash Point
(PM Closed Cup) > 60 deg C: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (DIESEL FUEL), 9, III, MARINE POLLUTANT (DIESEL FUEL)

_____________________________________________________________________

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Revision Date: FEBRUARY 03, 2015 SDS : 6894
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

The following components of this material are found on the regulatory lists indicated.
Diesel Fuel No. 2 07
Naphthalene 01-2B, 02, 03, 04, 05, 06, 07

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United
States).

NEW JERSEY RTK CLASSIFICATION:

Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to
be identified as follows: DIESEL FUEL

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 1 Flammability: 2 Reactivity: 0

HMIS RATINGS: Health: 2* Flammability: 2 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

Additional Product Number(s): CPS 203408, CPS 270059, CPS203410, CPS203413, CPS203417,
CPS203431, CPS203436, CPS203437, CPS203441, CPS203443, CPS203447, CPS203449, CPS203450,
CPS220122, CPS225114, CPS225115, CPS225150, CPS266176, CPS270000, CPS270005, CPS270030,
CPS270031, CPS270032, CPS270033, CPS270034, CPS270040, CPS270041, CPS270042, CPS270043,
CPS270044, CPS270045, CPS270046, CPS270047, CPS270048, CPS270049, CPS270050, CPS270051,
CPS270052, CPS270053, CPS270054, CPS270058, CPS270060, CPS270062, CPS270063, CPS270064,
_____________________________________________________________________

Revision Number: 23 10 of 11 DIESEL FUEL No. 2

Revision Date: FEBRUARY 03, 2015 SDS : 6894
CPS270065, CPS270068, CPS270069, CPS270070, CPS270081, CPS270082, CPS270083, CPS270084,
CPS270085, CPS270086, CPS270087, CPS270088, CPS270089, CPS270090, CPS270091, CPS270094,
CPS270095, CPS270096, CPS270100, CPS270101, CPS270102, CPS270103, CPS270104, CPS270105,
CPS270106, CPS270107, CPS270108, CPS270109, CPS270110, CPS270111, CPS270112, CPS270113,
CPS270114, CPS270115, CPS270116, CPS270117, CPS270118, CPS270119, CPS270120, CPS270121,
CPS270122, CPS270123, CPS270124, CPS271006, CPS272006, CPS272007, CPS272008, CPS272009,
CPS272010, CPS272011, CPS272012, CPS272013, CPS272093, CPS272102, CPS272126, CPS272129,
CPS272130, CPS272131, CPS272152, CPS272185, CPS272190, CPS272195, CPS272593, CPS272601,
CPS272602, CPS272693, CPS272793, CPS273003, CPS273030, CPS273053, CPS275000
REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16
Revision Date: FEBRUARY 03, 2015

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our
control and with which we may be unfamiliar and since data made available subsequent to the
date hereof may suggest modifications of the information, we do not assume any responsibility
for the results of its use. This information is furnished upon condition that the person receiving
it shall make his own determination of the suitability of the material for his particular purpose.

_____________________________________________________________________

Revision Number: 23 11 of 11 DIESEL FUEL No. 2

Revision Date: FEBRUARY 03, 2015 SDS : 6894
SECTION 10. - SUMMARY OF APPLICABLE LAWS & REGULATIONS

The following laws and regulations contain oil pollution provisions applicable to petroleum facilities.

Refuse Act of 1889, USC 407

Prohibits discharge of refuse matter of any kind or description from foreign or domestic ship or
waterfront facility in U. S. Navigable Waters (USNW) tributaries if refuse floats or washes into
USNW, or on banks in likely to be washed into USNW. Penalties of $500.00 to $2,500.00, 30 days to
1 year imprisonment, or both may be assessed and vessels are liable in "IN REM" for penalties.

Oil Pollution Act of 1961, USC 1001-1015

Prohibits any discharge or escape of oil or oily mixture from a seagoing vessel of U. S. Registry or any
nationality except from tankers under 150 gross tons, other vessels under 500 gross tons, ships engaged
in the Whaling industry, and Naval ships auxiliaries. It prohibits such discharge in a zone measured
from the base line from which the territorial sea is established, which generally extends 50 miles to
sea. Modifications to this Act are published in the Notification to Mariners. Penalties of
$500.00 to $2,500.00 or imprisonment of one year or both may be assessed. Any ship other than one
owned and operated by the United States is liable "IN REM" for penalties. Licenses may be revoked
or suspended under this Act. It also requires an oil slick record book to be kept by tankers and vessels
using oil fuels and must include entries relative to certain discharges or escapes of oil. Persons failing
to keep proper records may be fined $500.00 to $2,500.00 and persons making false entry in these
records can be fined $500.00 to $2,500.00 and imprisoned for six months or both.

Water Quality Improvement Act Amendments of 1972, PL 92-500

Prohibits discharges of oil into the water in harmful quantities. Such discharges include those which
violate applicable water quality standards in USNW or cause a film or sheen upon adjoining shorelines
or cause a sludge or emulsion to be deposited beneath the surface of the water or upon adjoining
shorelines. This Act applies in USNW, adjoining shorelines and the contiguous zone. Failing to report
prohibited discharges may result in penalties of up to $5,000.00 or imprisonment up to one year or
both. Fines up to $5,000.00 may be assessed for discharges. Cleanup costs up to
$14,000,000.00 or $100.00 per gross ton are sanctioned for discharges from offshore or shore side
facilities. Also, fines up to $5,000.00 may be assessed for violating any part of the regulations.

U. S. Coast Guard Regulations, 46 CFR

Requires merchant marine officers and seamen to have additional knowledge of oil pollution and of
laws, regulations, and procedures to prevent oil pollution, and requires pollution prevention equipment
for vessel certification.
Ports and Waterways Safety Act of 1972, PL 92-340

Requires all vessels, regardless of tonnage size, which are documented under the laws of the United
States or enter USNW and have on board liquid cargo in bulk which is inflammable or combustible or
oil of any kind or form to have a certificate of inspection issued by the U. S. Coast Guard that the
vessel is in compliance with the rules and regulations for protection of the marine environment.

All vessels shall have on board shipping document indicating the kinds, grades, and approximate
quantities of cargo on board. Fines up to $10,000.00 may be assessed for violations. Penalties of
$5,000.00 to $50,000.00 and/or imprisonment up to five years may be imposed for willful violations.
Exceptions are public vessels other than those engaged in commercial service.

Regulations for Control of Pollution by Oil and Hazardous Substances, Discharge Removal, 33
CF 153

Includes required procedures for notification of spills and cleanup operations.

Oil Prevention Regulations for Marine Oil Transfer Facilities, 33 CRF 154

Includes design and construction requirements, equipment requirements, as well as procedures for
inspections and operations.

Oil Prevention Regulations for Vessels, 33 CFR 155

Includes design and construction criteria for oil segregation and oil prevention equipment aboard
vessels. Includes requirements for meeting MARPOL 73/78. These regulations also address
administrative matters such as personnel, oil transfer books and operational procedures.

Regulations for Oil and Hazardous Material transfer Operations, 33 CFR 156

Covers primarily administrative matter of oil transfer such as notification, person in charge definition
and inspection forms.

Regulations for Reception Facilities for Oil, Noxious Liquid Substances, and Garbage, 33 CFR
158

This section includes the MARPOL 73/78 requirements for reception facilities that accept garbage
and oil slops from tank vessels. Covers both operational and administrative requirements.

The Oil Pollution Act of 1990

Requires vessels and facilities to have detailed spill response plans for several levels of spills. This
regulation defines most probable spill size, maximum most probable and worst case discharges for the
specific vessel or terminal configuration. The United States Coast Guard has jurisdiction over vessels
and any marine transportation related facility. The Environmental Protection Agency also has joint
jurisdiction over the Refinery as a facility that could cause substantial harm to the environment.
Environmental Protection Agency, 40 CFR Part 112

Water Programs; Oil Pollution Prevention; Non-Transportation Related Onshore and Offshore
Facilities.

Establishes requirements for Spill Prevention Control and Countermeasure Plans (SPCC Plans) to
prevent spills of oil by non-transportation related onshore and offshore facilities into the navigable
waters of the United States.

Department of Health, State of Hawaii, Chapter 37, Water Pollution Control

Limits discharge of any substance in state water which might cause pollution.

Department of Health, State of Hawaii, Chapter 37A, Water Quality Standards

Establishes water quality standards for all Hawaiian waters.

Department of Transportation, State of Hawaii, Water Transportation Facility Division, Rules and
Regulations and Tariff #14, Section 3430

Prohibits the littering or pollution of water.

 APPENDICES

I. Mooring Master's/Mooring Master Assistant’s Duties and Responsibilities

II. Marine Terminal Checklist, Certificate of Responsibility & Declaration of Inspection

III. Alcohol Policy & Alcohol Observation Procedures

IV. Federal Pollution Actions Plans

V. Clean Islands Council Equipage and Material Resources

VI. Summary of Minimum Line Requirements

VII. Summary of Emergency Plans and Procedures for Hurricanes/Tropical Storms

VIII. Over the Rail Pressure Calculations

IX. Marine Hose Change & Inspection Checklist (includes: Diver Preparation Materials
Checklist, Submarine Hose Changeout Material Checklist & Submarine Hose Checklist

X. Marine Terminal Inert Gas System (IGS) and Crude Oil Washing Operations (COW)
Checklist

XI. Barbers Point Mooring: Hose Operation Checklist

XII. Island Energy Services Pre-Mooring/Unmooring Checkoff List

 APPENDIX I

MOORING MASTER’S DUTIES AND RESPONSIBILITIES AT MARINE TERMINAL

1. Boards arriving vessel outside of the mooring, together with the Mooring Master Assistant who
assists the Mooring Master in the following duties:

2. Evaluates vessel’s equipment (anchors, mooring lines, cargo booms, deck winches, fairleads, bitts,
cargo systems, etc.).

3. Ensures that all necessary preparations for mooring have been made (both anchors clear and ready
to drop, mooring lines properly placed, port cargo boom topped up, steam on deck mooring
winches, wrenches, snatch blocks, handy billys, stoppers, etc., laid out and ready).

4. Describes the planned course of action to moor the ship to the Master and deck officers who will
be involved.

5. Advises the Master as to maneuvering the vessel into the mooring area.

6. Advises the Master as to dropping of anchors and running of lines to the mooring buoys.

7. Directs the actions of tugs and line boat during mooring operations.

8. Advises the Master as to directing the adjustment of the anchor chains and mooring lines so that
the vessel is properly positioned in the berth.

9. Advises the Master and Deck Officer as to the lifting and connecting of the cargo hose.

10. Provides the vessel with radios, drain valve, gaskets and hose handling equipment as necessary.

11. Acts as liaison between ship and shore in coordinating preparations for cargo handling operations
by radio or deck telephone.

12. Assists the Master in ensuring that all sea suction and overboard discharge valves are closed and
lashed.

13. Checks to be sure that scupper plugs are in place and oil tight.

14. Counsels vessel personnel on details of cargo handling during the loading or discharging
operations.

15. Assists Master in enforcing government and company operating and safety regulations.

16. Advises the Master and deck officers as to the adjustment of anchor chains and/or mooring lines
during the cargo handling operation to keep the vessel properly positioned in the berth during
changes in draft or weather conditions.

17. Keeps himself currently informed of any impending weather changes bymeans of broadcast
reports and by observing local conditions.
18. Advises the Master as to additional lines to be put out when changing weather conditions indicate
such action to be necessary.

19. Assists the Master in making the decision as to whether or not cargo handling operations can
safely continue when weather conditions worsen.

20. Advises the Master and deck officers as to the disconnecting and lowering of the submarine hose
when cargo activities have been completed, or when weather conditions indicate that the berth
should be vacated.

21. Advises the Master as to the taking in of mooring lines and heaving up of anchors.

22. Controls the actions of tugs and line boat while unmooring.

23. Advises the Master as to piloting the vessel safely clear of the moorings.

24. Prepares and submits a log of his activities while on the vessel.

25. Acts as “On Scene Commander” for cleanup operations for oil spilled in/on the water.

NOTE: Some of the regulations referred to in #15 above are:

1. Vessel properly positioned and securely moored.

2. Scupper plugs in place and oil tight and drip pans in place under cargo hose connections.

3. Spool above hose valve drained before blank flange removed.

4. Hose connections properly made up. No leaks in the system.

5. Pressure gauge installed.

6. Portable radio working properly.

7. Adequate number of qualified personnel available at all times.

8. Frequent surveillance of the water around the vessel for evidence of oil.

9. Submarine hose illuminated at night to detect possible leaks.

10. Close communication between ship and shore facility to control cargo handling.

11. Anchor ball and “BRAVO” flag displayed by day, and anchor lights displayed at night.

12. Cargo handling area properly illuminated at night.

13. Weather doors and ports on main decks kept closed and checked frequently.

14. “No smoking” regulations enforced.

 MOORING MASTER ASSISTANT’S DUTIES
AT MARINE TERMINAL

1. Upon boarding the vessel, carries out the following responsibilities under the direction of
the Mooring Master:

A. Evaluates vessel's equipment (anchors, mooring lines, cargo booms, deck winches,
fairleads, bits, etc.) and ensure readiness and suitability of vessels for berthing.

B. Verifies that all necessary preparations for mooring have been made (anchors clear
and ready to drop, mooring lines properly placed, all necessary hose handling
equipment onboard and ready for use).

C. Provide overview and direction of the mooring operation to the vessel's officers in
charge of the bow and deck "details".

D. Monitors actions of vessel personnel and takes appropriate corrective measures with
regard to safety, discipline, performance, and operation of vessel systems.

E. Monitors the vessel's approach to the designated berth and counsels with the
Mooring Master on progress.

F. Oversees the dropping of anchors and running of lines to the mooring buoys to
properly moor and position the vessel in the berth.

G. Oversees vessel and line boat personnel during line handling activities.

2. On a relief basis with the Mooring Master, serves as the Terminal Representative and
pollution prevention officer onboard the vessel. Coordinates and directs cargo handling
operations:

A. Acts as liaison between ship and shore in coordinating preparations for cargo
handling operations.

B. Supervises the lifting of the cargo hose and ensures that it is properly secured at the
deck edge and connected to vessel's risers.

C. Confirm that all sea suction and overboard discharge valves are closed, lashed, and
sealed, and that scupper plugs are in place.

D. Counsels and advises vessel officers on details of cargo handling during loading or
unloading operations and on ballasting requirements and precautions necessary to
protect the environment.

E. Prior to start of cargo transfer, coordinates the pressure test of hoses and submarine
system. Notifies terminal and Island Energy Services management offices of any
deficiencies found.
 F. Directs the adjustment of anchor chains and/or mooring lines and for placement of
additional mooring lines during changes in draft or weather conditions.

G. Has the responsibility and authority to shut down a vessel cargo transfer operation
in the event of an actual or perceived unsatisfactory condition or procedure that may
lead to a spill or put the vessel or terminal in an unsafe situation.

H. Enforces all government and Company operating and safety regulations.

I. Notifies Mooring Master of all problems including cargo transfer rates, deck
equipment deficiencies, and mooring problems. In event of oil spill or sighting,
assists the Mooring Master who acts as on-scene commander in charge of cleanup
until relieved by Terminal Cleanup Response Team. When required by Mooring
Master, prepares written reports of all problems and incidents to appropriate
Island Energy Services management.

J. Coordinates with U. S. Coast Guard, Government officials, vessel agents, and harbor
authorities as required for the proper fulfillment of job duties.

3. Upon conclusion of the transfer operation and at the direction of the Mooring Master:

A. Oversees the disconnecting and lowering of submarine hose.

B. Oversees vessel and line boat personnel during the taking in of mooring lines and
raising up of anchors.

C. Monitors the vessel's departure from the berth and counsels with the Mooring Master
on progress.

4. As directed by the Port Captain:

A. Inspects third party vessels per Island Energy Services inspection procedures and
as directed by Mooring Master.

B. Visits the terminal and terminal supervisors to keep himself up-to-date on terminal
operations.

C. Assists in out port functions as assigned by the Port Captain or Island Energy
Services management.
 APPENDIX II

BARBERS POINT MARINE TERMINAL

BARBERS POINT, HAWAII
DATE:

TO MASTER OF :

In addition to your own safety regulations and those of the U.S. Coast Guard, please observe the Terminal’s safety regulations listed in the attached “Declaration of
Inspection” - while your vessel is moored at the Barbers Point Marine Terminal. Also, your ship is expected to be in compliance with the United States Coast Guard
Pollution Regulations. You will be given a copy of our Terminal manual which covers these and other regulations in more detail.

A Mooring Master and Mooring Master Assistant will meet you on arrival. As the representatives of the Terminal, they will discuss with you matters of safety, pollution
prevention and oil spill cleanup response. They will also observe cargo operations to see that all regulations are followed. If they find that any regulations are not being
followed in any way, they are empowered to halt cargo operations and, if necessary, require the vessel to leave the berth. At all times and under all conditions you, as
Master, are solely responsible for the safe and proper mooring of the vessel, connecting or disconnecting of hoses, transfer of cargo, gauging of the ship’s tanks,
ballasting, compliance with Terminal and U.S. Coast Guard regulations. The Mooring Master and Mooring Master Assistant are at all time servants of the vessel.

Before cargo operations start, the Mooring Master will discuss the Declaration of Inspection with you, your Chief Engineer, and the Vessel Person in Charge. The Mooring
Master or Mooring Master Assistant will also inspect the vessel to make sure that all the necessary safety precautions have been taken. You, your Chief Engineer and the
Vessel Person in Charge will sign the Declaration - along with the Terminal representatives, to show that you understand and agree to the precautions to be taken.

Also, at the change of each shift, have your Duty Officer review the Declaration and sign it to show that he, too, understands and agrees to the precautions.

We appreciate your cooperation in these matters.

Capt. Kurt Jacobson Mr. Mark Hepburn

Port Captain Logistics Manager
Barbers Point Marine Terminal Island Energy Services
Island Energy Services

I acknowledge and agree to the above.

Master’s Signature
FROM: TO:
Island Energy Services (VESSEL)
Barbers Pt., HI (VESSEL PIC)
Barbers Point Marine Terminal (DATE)

I hereby certify that the above-named vessel is in compliance of the U.S.C.G. Pollution
Regulations, namely 33 CFR Sub-Chapter O, amendments to 46 CFR, Sub-chapter D,
and/or have obtained the necessary waivers.

CERTIFICATE OF FINANCIAL RESPONSIBILITY

CONDITION OF USE - - OIL SPILL CLEANUP

A) Vessel PIC warrants that the vessel is an ITOPF MEMBER1, or has a

certificate or responsibility equal to ITOPF MEMBERSHIP.

B) Any dispute between VESSEL PIC and Terminal Operator as to the

reasonableness of the measures undertaken and/or expenditure for oil clean up
incurred by Terminal Operator hereunder, shall be referred to arbitration
before the American Arbitration Association in San Francisco pursuant to its
rules.

C) The provisions are not in derogation of such other rights as Terminal Operator
may have or may otherwise have or acquire by law or any international
convention.

VESSEL PIC:
Signature

Date
 DECLARATION OF INSPECTION

BARBERS POINT MARINE TERMINAL VESSEL FLAG

DATE TRANSFER COMMENCED

The following items have been visually inspected and meet the requirements of the Code VPIC TPIC 33 CFR
NO. of Federal Regulations INITIAL INITIAL REFERENCE COMMENTS

1. Vessel moorings - strength and length. Vessel is properly spotted. Mooring lines are 156.120 (a)
strong enough to hold and of sufficient length to adjust to expected conditions. Lines
will be properly tended. Tension winches are on manual brake.
2. Transfer hoses/loading arms - length. Oil transfer hoses are long enough to allow the 156.120 (b)
vessel to move to the limits of its moorings without placing strain on the hose or oil
transfer piping system.
3. Hose support - each hose is supported to prevent kinking or other damage to the hose 156.120 (c)
and strain on its coupling. Hoses will be supported with double slings, bridle or saddle
(no single sling).
4. Respective transfer system alignment - each part of the oil transfer system is aligned to 156.120 (d)
allow the flow of oil.
5. Respective transfer system - unused components blanked off. Each part of the oil 156.120 (e)
transfer system not necessary for the transfer operation is securely blanked or shut off.
6. Respective unused hoses, manifolds blanked off, the end of each hose or manifold that is 156.120 (f)
not connected for the transfer of oil is blanked off using adequate gaskets and at least 4
bolts, or an approved blanking device.
7. Transfer system attached to fixed connection - vessel and terminal. The transfer 156.120 (g)
system shall be connected to a fixed piping system.
8. Vessel overboard discharges, sea suctions - valves shut and sealed. Each overboard 156.120 (h)
discharge or sea suction valve that is connected to the vessel’s oil transfer or cargo tank XXXXX
system is sealed or lashed in the closed position. The seals will not be broken except in XXXXX
the presence of the Mooring Master or in case of an emergency. Ballasting while
handling cargo is prohibited except in cases where a separate clean ballast system is
available and the operation is approved by the Mooring Master.
9. Transfer hose - condition - vessel and terminal. Each oil transfer hose has no 156.120 (i)
unrepaired loose covers, kinks, bulges, soft spots, or any other defect which would permit
the discharge of oil through the hose material and no gouges, cuts, or slashes that
penetrate the first layer of hose reinforcement.
10. Transfer hose markings - each hose must be marked with the words “oil service” and 154.500
the maximum allowable working pressure. 154.510
 The following items have been visually inspected and meet the requirements of the Code VPIC TPIC 33 CFR
NO. of Federal Regulations INITIAL INITIAL REFERENCE COMMENTS

11. Transfer connections - properly made - use suitable material in joints and couplings to 156.120 (k)
ensure a leak-free seal, and must be made with the proper size bolts in every hole. The 156.130
bolts and nuts must be tightened uniformly to distribute the load.
12. Monitoring devices (if any) - in operation any monitoring devised required are installed XXXXX 156.120 (l)
and operating properly. XXXXX
13. Terminal small discharge containment in place XXXXX 156.120 (m)
14. Vessel discharge containment in place and drained - the vessel must have a 156.120 (n)
containment system under or around each manifold, connection, vessel fuel tank vent,
and overflow and fill pipe which complies with Coast Guard Regulations, and
periodically drained to provide the required capacity.
15. Drains and scuppers - properly closed - drains in the discharge containment system 156.120 (o)
must be closed, and each scupper is plugged.
16. Connections - leak free- all connections in the oil transfer system are leak free. 156.120 (p)
Connections and pressure gauges shall be monitored to check for leaks and to ensure that
the maximum working pressure is not exceeded.
17. Communications – tested and working. Communication between the ship and the terminal 156.120 (q)
will be tested and proved functional prior to start of transfer and ensure that continuous two- 154.560
way voice communication between the person in charge of the vessel transfer operation and the
person in charge of the facility transfer operation is operational and functional throughout
transfer operations.
18. Terminal/vessel emergency shutdown operable - the emergency means of shutdown is 156.120 (r)
in position and operable.
19. TPIC - meets qualification requirements XXXXX 154.710
20. VPIC - meets qualification requirements XXXXX 155.710
21. TPIC and VPIC will be at site of transfer operation and immediately available to the oil 156.120 (t)(1)
transfer personnel.
22. TPIC and VPIC have in their possession a copy of the facility operations manual and 156.120 (t)(2)
vessel oil transfer procedures respectively.
23. Transfer conducted in accordance with Terminal/Vessel transfer procedures 156.120 (t)(3)
156.120 (u)(2)
24. Terminal persons/vessels crew required for transfer are on duty - the VPIC of cargo 156.120 (u)(1)
transfer will have at least two assistants at all times; one to maintain watch in the riser
are, the other to assist.
25. At least one person is at the site of the transfer operation who fluently speaks the language or 156.120 (v)
languages spoken by both persons in charge. That language will be English.
 The following items have been visually inspected and meet the requirements of the Code VPIC TPIC 33 CFR
NO. of Federal Regulations INITIAL INITIAL REFERENCE COMMENTS

26a. The person in charge of oil transfer operations on the transferring vessel or facility and 156.120 (w)
the person in charge of oil transfer operations on the receiving vessel or facility have held
a conference, to ensure that each person in charge understands the following details of the
transfer operations:
b. Quantity, type of stocks and temperature 156.120 (w)(1)
c. The sequence of transfer operations. 156.120 (w)(2)
d. The initial, maximum and topping off rates. 156.120 (w)(3)
e. Name/title and location of each person participating in the transfer operation. 156.120 (w)(4)
f. Detail of transferring and receiving systems, including the number and speed of ship’s 156.120 (w)(5)
pumps and shore booster pumps to be used.
g. Critical stages of the transfer operations. 156.120 (w)(6)
h. Federal, State and Local rules that apply to the transfer of oil. 156.120 (w)(7)
i.. Signals for standby, slowdown and stop transfer operation shall be conducted by UHF 156.120(w)(12)
walkie-talkie, VHF, or telephone.
j. Emergency Procedures: 156.120 (w)(8)
All cargo transfer shall be immediately shutdown if any of the following occurs:
a. A severe electrical storm
b. A fire on the vessel, at the wharf or in the vicinity of either.
c. Sufficient competent personnel are not present during cargo handling or a language
barrier develops between the vessel and facility.
d. If a break occurs in the transfer system, cargo is leaking at the joints or connections
at a rate exceeding the capacity of the containment system, or if a spill occurs.
e. If a serious vapor condition develops aboard or around the vessel or facility.
k. Discharge Containment Procedures: 156.120 (w)(9)
The vessel must have a containment system under or around each manifold, connection,
vessel fuel tank vent, and overflow and fill pipe which complies with Coast Guard
regulations. A vessel that does not have a common tank vent system must have
containment under each tank vent.
NO. The following items have been visually inspected and meet the requirements of the Code VPIC TPIC 33 CFR
of Federal Regulations INITIAL INITIAL REFERENCE COMMENTS

26l. Discharge Reporting Procedures and Requirements: 156.120(w)(10)

It is the vessel masters’ responsibility to prevent any oil, ballast, or bilge water from
being pumped or spilled overboard. In the event of a spill the Terminal will take steps to
contain and clean up any oil from the surface of the water immediately. The Master’s
signature on this form constitutes authorization for the Terminal to clean up any oil
spilled by the vessel at the vessel owner’s expense.
Frequent inspections will be made of the submarine hose and water surrounding the
vessel to check for leakage of oil. At night, these areas will be adequately illuminated by
floodlights. All oil spills, regardless of the amount, will be reported immediately to the
Mooring Master. The Terminal will be promptly notified by the Mooring Master and
will handle notification of government authorities and Island Energy Services officials.
The master is still responsible to notify all proper authorities for his owner.
m. Watch or shift arrangement, posted per vessel. 156.120(w)(11)
n. Transfer Shutdown Procedures: 156.120(w)(12)
The Person-in-Charge shall speak fluent English. If not possible, a person who speaks
fluent English shall be stationed near the shutdown button or valve and shall maintain
continuous communication with the terminal and vessel Person-in-Charge. A radio
(walkie-talkie) will be provided by the terminal and must always be in possession of the
Person-in-Charge.
The Person-in-Charge shall remain in the vicinity of the transfer operation and be
available to the oil transfer personnel to supervise connections, disconnections, topping
off and emergency shutdowns, if needed. Terminal and vessel Person-In-Charge will
indicate and acknowledge to each other that they are ready 10, 5 & 1 minute(s) prior to
any starting, stopping or changing of any transfer operations.
27. The person in charge of oil transfer operation on the transferring vessel or facility and the 156.120 (x)
person in charge of oil transfer operations on the receiving vessel or facility agree to
begin the transfer operation.
28. Transfer operation between sunset and sunrise on a barge or vessel must have fixed 156.120 (y),(z)
lighting that adequately illuminates each transfer connection point and the work area on
the barge or vessel. The pilot ladder is properly secured and lighted.
Life ring buoy will be available in the vicinity of the pilot ladder and the ladder will be
kept at a proper height for safe boarding on and off.
NO. The following items have been visually inspected and meet the requirements of the Code VPIC TPIC 33 CFR
of Federal Regulations INITIAL INITIAL REFERENCE COMMENTS

29. INERT GAS SYSTEM XXXXX XXXXX

a. Initial and maximum transfer rates confirmed. Manual valves correctly positioned.
b. Maximum and minimum operating pressures confirmed.
c. Alarms tested within previous 24 hours. XXXXX 156.120
(aa)(7)(i)
d. Automatic shutdown system tested within previous 24 hours. XXXXX 156.120
(aa)(7)(i)
e. Oxygen and gas analyzers tested with span gas within previous 24 hours. XXXXX
f. Verify the Inert Gas System is operating properly and if inerted, the oxygen content in the
vessel’s cargo tank is at or below 8%.
30. Firefighting equipment in readiness - Sufficient serviceable fire equipment with
suitable nozzles shall be attached to the fire main and shall be ready for instant use. Fire
hoses are uncoiled and laid out for use. There shall be adequate water pressure to supply
at least 50 lbs. of pressure at each nozzle.
31. Spill containment equipment in readiness 156.120 (m)
32. All vessel cargo and personnel compartment openings will be closed during transfer, XXXXX
except when required to be temporarily opened. XXXXX
33. Pressure relief valves and cargo vents shall be fitted with Coast Guard approved flame
screens. Flame screens shall be of proper size and in good condition. Vent piping shall XXXXX
be sound and free of leaks. Gauge ports and ullage plugs are closed and will be kept XXXXX
closed. Tank tops are closed, and will not be opened except when gas free.
34. No unauthorized craft alongside.
35. Entry to pumprooms, bilges and ventilation precautions will be observed. XXXXX
36. Boiler fire inspection complete by the senior deck officer and whether in his judgment boiler XXXXX 46CFR35.3530
fires may be maintained with reasonable safety during the cargo transfer operation. b
37. Warning signals/signs visible. The vessel shall have a red flag. Warning signs on the XXXXX 46CFR35.35-
gangway and radio room are in place. XXXXX 30 b
38. No smoking will be allowed on the ship’s weather deck at any time. No smoking will be XXXXX 46CFR35.35-
allowed on board except in places approved by the Master, and signs are posted. XXXXX 30 b
NO. The following items have been visually inspected and meet the requirements of the Code of Federal Regulations VPIC TPIC
INITIAL INITIAL

39. Tank vessel able to move within 30 minutes and will be maintained in trim and engine condition to permit same. The crew aboard at all times
will be maintained at sufficient size to disconnect hoses, unmoor and get the vessel away from the berth. Steam, electrical or hydraulic
systems will be maintained at all times on vessel’s anchor windlass and deck winches. (Yes) (No) ?
40. The vessel shall maintain 30% of its summer dead weight tonnage at all time while in the berth.
41. When handling a high pour cargo, as specified by the terminal, a maximum shutdown time of 45 minutes is permitted. The vessel
should resume discharge, initiate a water flush or be prepared to load cargo, as determined by the terminal, within this 45 minute
time period.
42. Intoxicated and disorderly persons shall not be permitted aboard the vessel. It shall be the responsibility of the VPIC to ascertain whether
vessel personnel are intoxicated and disorderly.
43. The vessel must have a closed loading and gauging system with operational individual tank level indicating equipment. All gauging, thieving,
or sampling must be conducted with a gas tight ullage measurement system.
44. When fast in the mooring, ship’s propeller will not be turned except by use of jacking gear. Clearance to turn the propeller for departure will
be given by the Mooring Master after the transfer hose is returned to the sea.
45. No repairs or maintenance will be done and no fires lighted without prior approval from the Mooring Master. Power or manual spark
producing devices shall not be operated on weather decks, in pumprooms, in cargo or fuel tanks or in compartments which may accumulate
vapors. No welding is permitted while on the mooring.
46. Cargo decks of the vessel shall remain free of dirty rags, rubbish, debris and loose tools. Excess hydrocarbon leakage in pumproom bilges
shall not be permitted.
47. No garbage or any other waste material will be thrown overboard.
48. Electrical equipment shall be approved for the hazardous area it is used in. All electrical installations in the pumproom shall be either
explosion-proof and/or intrinsically safe except when handling only Grade E cargo. All wiring in hazardous areas shall be in good condition.
Electrical cables to portable equipment shall be disconnected unless certified for use in hazardous areas.
49. The main transmitting antennae shall be switched off and grounded.
50. The Mooring Master shall satisfy himself that the vessel is operating under a valid Coast Guard certificate of inspection in the case of a United
States flag vessel or documentation indicating the results of the latest Coast Guard inspection of the vessel in the case of a foreign flag vessel.
51. The Vessel Person-in-Charge shall provide assurance that all equipment and procedural deficiencies noted by the Coast Guard have been or
are being corrected in the manner prescribed.
52. The Terminal Person-in-Charge shall have the cargo information card or papers for each cargo being handled immediately available.
53. Launch schedules will be arranged with the Mooring Master and agent with regard to weather conditions and launch availability.
54. The Terminal may elect to place an observer aboard your vessel. He will be in no way responsible for any phase of vessel’s operation.
55. The VPIC will compare gross barrels with “Island Energy Services Refinery Control” every two hours on the even hour by radio.
The vessel is to embark/disembark personnel utilizing a pilot ladder or a pilot-accommodation combination ladder. The
56. accommodation ladder may only be used alone under special circumstances, with calm conditions, and Mooring Master and launch
Operator approval.
THE UNDERSIGNED PERSONS IN CHARGE AGREE TO CONDUCT THE TRANSFERS IN ACCORDANCE WITH THE PROCEDURES SET FORTH IN
THE TERMINAL OPERATIONS MANUAL OR VESSEL OPERATING PROCEDURES, AS APPROPRIATE.

We have completed our inspection and all items are understood. Cargo transfer is ready to proceed.

Master

Chief Engineer

Mooring Master

Mooring Master Assistant

Chief Officer

Transfer Commenced Transfer Completed

date/time date/time
 ENDORSEMENT OF CHANGE OF WATCH OR SHIFT

I have read the Declaration above, and I find that all conditions remain satisfactory. I have tested the
communications system and advised the other unit of the change in personnel. (155.820)

VESSEL TERMINAL
NATURE/TITLE DATE/TIME SIGNATURE/TITLE DATE/TIME
 Appendix III

ISLAND ENERGY SERVICES

OFFSHORE MORRING ALCOHOL POLICY
& ALCOHOL OBSERVATION PROCEDURES

The policy for seamen joining vessels by launch in the mooring or at anchor, who appear / act
impaired by consumption of alcohol is described below. This is necessary to ensure the safety of all
involved.

When a person reports to a launch to join a vessel, the launch Captain, Security Officer or TNC
Agent observes the individual for signs of impairment. If an individual appears impaired, the launch
Captain will delay the scheduled launch run and contact the Mooring Master or Port Captain. The
Mooring Master or Port Captain will contact a certified testing service and promptly arrange to meet
and test the individual at the launch site. Should the test prove negative (under 0.04% blood alcohol
content) the individual will be permitted to proceed to the vessel. If the test is positive (at or above
0.04% blood alcohol content) the individual will be escorted to and checked into a local hotel. Any
individual appearing impaired, that refuses to submit to alcohol testing by a certified testing service
will be considered the same as testing positive for alcohol. This policy will be enforced without
exception and no individual who tests positive will be transported to a vessel. The Master
Agent/Charter of the vessel the individual is assigned will be advised and will be responsible for the
hotel costs. If the individual is an IES employee, the Mooring Master or Port Captain will notify the
IES Logistics Manager of the situation.

The contract launch service must agree to assist IES in enforcing this policy.

A copy of this policy will be provided to visiting Masters for posting.

 APPENDIX IV
FEDERAL POLLUTION ACTION PLANS

The current Hawaii Area Contingency Plan is on file at Clean Islands Council Spill Response Center.
 APPENDIX V
OSRO Classifications

OSRO Classification: Section 580 – Hawaii Area Contingency Plan Rev. 6.2 (2015)
CIC Equipment List by Location
OSRV Clean Islands Equipment List
Location Equipment Type Description Quantity Units
OSRV BOOM BOAT 10 FT. AVON BOOM TENDER 1 EACH
OSRV INFLATABLE OCEAN BOOM HYDE/RO-BOOM "J-SHAPE" 1200 FEET
FOSS/HI SPRINT OCEAN BOOM "J-
OSRV INFLATABLE OCEAN BOOM SHAPE" 850 FEET
OSRV INFLATABLE OCEAN BOOM EFC 76" OCEAN BOOM "U" SHAPES 160 FEET
OSRV MISCELLANEOUS EXPANDI ROTO PACK TURN TABLE 1 EACH
OSRV OCEAN BOOM EXPANDI ROTO-PACK 600 FEET
OSRV OCEAN BOOM EXPANDI ROTO-PACK 650 FEET
OSRV PACKAGE PPE BOAT PACKAGE - 4 PERSON 6 SETS
OSRV POWER PACK LISTER HYDRAULIC POWER PACK 1 EACH
OSRV POWER PACK POWER PACK CONTROL TABLE 1 EACH
OSRV POWER PACK POWER PACK CONTROL TABLE 1 EACH
AMERICAN MARINE HYDRAULIC
OSRV POWER PACK POWER PACK 1 EACH
OSRV SKIMMER GT 185 OCEAN SKIMMER 1963 DeratedBBLS/day
OSRV SKIMMER GT 185 OCEAN SKIMMER 1963 DeratedBBLS/day
OSRV VEHICLE SILVERADO RESPONSE P/U TRUCK 1 EACH
OSRV VEHICLE FORD RESPONSE VAN 1 EACH

Spill Center Equipment List

Location Equipment Type Description Quantity Units
SPILL CENTER API SEPARATOR VERSITEK API SEPARATOR 1 EACH
SPILL CENTER API SEPARATOR VERSITEK API SEPARATOR 1 EACH
ZONE CONTROL/DECON PACKAGE
SPILL CENTER BEACH TRAILER TRAILER 1 EACH
SPILL CENTER BOAT TRAILER DILLY BOAT TRAILER 1 EACH
SPILL CENTER BOAT TRAILER PACIFIC BOAT TRAILER 1 EACH
SPILL CENTER BOAT TRAILER SPECTRUM SHOPBUILT TRAILER 1 EACH
SPILL CENTER BOAT TRAILER SHORELINE BOAT TRAILER 1 EACH
SPILL CENTER BOAT TRAILER EASY LOADER TRAILER 1 EACH
SPILL CENTER BOAT TRAILER CALKINS BOAT TRAILER 1 EACH
SPILL CENTER BOAT TRAILER FOOTHILL BOAT TRAILER 1 EACH
SPILL CENTER BOOM BOAT 17 FT. BOOM BOAT WITH O/B 1 EACH
SPILL CENTER BOOM BOAT 17' McKEE W/ 140HP O/B 1 EACH
 15 FT. FIBERGLASS UNDER PIER
SPILL CENTER BOOM BOAT BOAT 1 EACH
SPILL CENTER BOOM BOAT 13.5 FT BOSTON WHALER WITH O/B 1 EACH
SPECTRUM TRAILER W/ 1000' ACME
SPILL CENTER BOOM TRAILER BOOM 1000 FEET
SPILL CENTER BOOM TRAILER ACME TRAILER 0 FEET
SPECTRUM TRAILER W/ 1000' ACME
SPILL CENTER BOOM TRAILER BOOM 1000 FEET
TRAILER WITH 2 DISPERSANT
SPILL CENTER DISPERSANT TRAILER BUCKET SYSTEMS 1 EACH
OIL STOP 42" AUTO BOOM "J"
SPILL CENTER INFLATABLE OCEAN BOOM SHAPE PACK 600 FEET
SPILL CENTER MISCELLANEOUS COMMS CART 1 EACH
KARCHER STEAM PRESSURE
SPILL CENTER MISCELLANEOUS WASHER 1 EACH
SPILL CENTER MISCELLANEOUS 3KW ONAN GENERATOR (DIESEL) 1 EACH
DR POWERWAGON/POWERED
SPILL CENTER MISCELLANEOUS WAGON 1 EACH
5.5K NORTHSTAR/HONDA
SPILL CENTER MISCELLANEOUS GENERATOR 1 EACH
75KW CUMMINS/KOHLER
SPILL CENTER MISCELLANEOUS GENERATOR (DSL) 1 EACH
SPILL CENTER OCEAN BOOM EXPANDI ROTO-PACK 750 FEET
SPILL CENTER OCEAN BOOM EXPANDI ROTO-PACK 400 FEET
SPILL CENTER OCEAN BOOM EXPANDI ROTO-PACK 800 FEET
SPILL CENTER OCEAN BOOM 43 INCH TROIL BOOM 500 FEET
SPILL CENTER PACKAGE FOSS 25'X50 LARGE DECON POOL 1 EACH
BEACH TOOL/FLAT SHOVEL
SPILL CENTER PACKAGE PACKAGE 5 EACH
BEACH TOOL/FLAT SHOVEL
SPILL CENTER PACKAGE PACKAGE 5 EACH
LARGE HEAT STRESS SHADE
SPILL CENTER PACKAGE STATION 1 EACH
BEACH TOOL/FLAT SHOVEL
SPILL CENTER PACKAGE PACKAGE 5 EACH
MULTI PERSON HAND WASHING
SPILL CENTER PACKAGE BASIN 1 EACH
SPILL CENTER PACKAGE PPE OVERPACK - 50 PERSON 75 SETS
SPILL CENTER PACKAGE PPE OVERPACK - 50 PERSON 75 SETS
SPILL CENTER PACKAGE LARGE WORKVEST PACK 50 SETS 50 SETS
BEACH TOOL/FLAT SHOVEL
SPILL CENTER PACKAGE PACKAGE 5 EACH
SPILL CENTER PACKAGE PPE OVERPACK - 50 PERSON 75 SETS
SPILL CENTER PACKAGE PPE OVERPACK - 50 PERSON 75 SETS
SPILL CENTER PACKAGE LARGE WORKVEST PACK 50 SETS 50 SETS
LARGE PERSONNEL ZONE
SPILL CENTER PACKAGE CONTROL STATION 1 EACH
LARGE PERSONNEL ZONE
SPILL CENTER PACKAGE CONTROL STATION 1 EACH
LARGE PERSONNEL ZONE
SPILL CENTER PACKAGE CONTROL STATION 1 EACH
LARGE HEAT STRESS SHADE
SPILL CENTER PACKAGE STATION 1 EACH
HELICOPTER COMMUNICATIONS
SPILL CENTER PACKAGE PACKAGE 1 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
LIGHTSTAND TRAILER W/ ONAN
SPILL CENTER PACKAGE GEN. 1 EACH
SPILL CENTER PACKAGE FLUOROMETER KIT (NRDA) 1 EACH
SPILL CENTER PACKAGE PPE HAT PACK W/ 30 HATS 30 EACH
SPILL CENTER PACKAGE PPE HAT PACK W/ 30 HATS 30 EACH
SPILL CENTER PACKAGE HOTEL ZONE CONTROL PACKAGE 1 EACH
SPILL CENTER PACKAGE HOTEL ZONE CONTROL PACKAGE 1 EACH
SPILL CENTER PACKAGE HOTEL ZONE CONTROL PACKAGE 1 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
SPILL CENTER PACKAGE BIRD WASH WATER UNIT 1 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
SPILL CENTER PACKAGE HARBOR BOOM LIGHTING SYSTEMS 1 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
BEACH TOOL/TARBALL FORK
SPILL CENTER PACKAGE PACKAGE 5 EACH
BEACH TOOL/TARBALL FORK
SPILL CENTER PACKAGE PACKAGE 5 EACH
BEACH TOOL/TARBALL FORK
SPILL CENTER PACKAGE PACKAGE 5 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
SPILL CENTER PACKAGE SMALL DECON STATION 1 EACH
SPILL CENTER PACKAGE BEACH TOOL/SHRAKE PACKAGE 5 EACH
BEACH TOOL/FLAT SHOVEL
SPILL CENTER PACKAGE PACKAGE 5 EACH
SPILL CENTER PACKAGE SMALL DECON STATION 1 EACH
ASI 16TSO HYDRAULIC POWER
SPILL CENTER POWER PACK PACK 1 EACH
 ASI 16TSO HYDRAULIC POWER
SPILL CENTER POWER PACK PACK 1 EACH
SPILL CENTER POWER PACK POWER PACK CONTROL TABLE 1 EACH
SPILL CENTER POWER PACK POWER PACK CONTROL TABLE 1 EACH
2" DOUBLE DIAPHRAGM PUMP W/
SPILL CENTER PUMP 25' HOSE 133 DeratedBBLS/day
DIESEL AMERICA CENTRIFICAL
SPILL CENTER PUMP PUMP DeratedBBLS/day
3" DOUBLE DIAPHRAGM
SPILL CENTER PUMP PNEUMATIC PUMP 1371 DeratedBBLS/day
ACME FLOATING WASHDOWN
SPILL CENTER PUMP PUMP 1 EACH
ACME FLOATING CIRCULATION
SPILL CENTER PUMP PUMP 1 EACH
SPILL CENTER PUMP DOP 250 PUMP PACKAGE 15408 BBLS/day
SPILL CENTER PUMP HONDA CENTRIFICAL PUMP 1508 DeratedBBLS/day
2" DOUBLE DIAPHRAGM PUMP W/
SPILL CENTER PUMP 25' HOSE 133 DeratedBBLS/day
SPILL CENTER PUMP DOP 160 PUMP PACKAGE 4680 BBLS/day
2" DOUBLE DIAPHRAGM PUMP W/
SPILL CENTER PUMP 25' HOSE 133 DeratedBBLS/day
SPILL CENTER PUMP DIESEL POWERED PHP 754 DeratedBBLS/day
SPILL CENTER PUMP DIESEL POWERED PHP 754 DeratedBBLS/day
SPILL CENTER PUMP DIESEL POWERED PHP 754 DeratedBBLS/day
SPILL CENTER PUMP DIESEL POWERED PHP 754 DeratedBBLS/day
SPILL CENTER PUMP DOP 160 PUMP PACKAGE 4680 BBLS/day
SPILL CENTER PUMP 2" GAS DIAPHRAGM PUMP 228 DeratedBBLS/day
10 FT. UNDER PIER SKIFF WITH
SPILL CENTER SKIFF OARS 1 EACH
SPILL CENTER SKIMMER SKIM PACK MODEL 4200 754 DeratedBBLS/day
SPILL CENTER SKIMMER SKIM PACK MODEL 4200 754 DeratedBBLS/day
SPILL CENTER SKIMMER SLICKBAR SLURP WIER 54 DeratedBBLS/day
SPILL CENTER SKIMMER MINI WALOSEP 301 DeratedBBLS/day
SPILL CENTER SKIMMER GT 185 OCEAN SKIMMER 1963 DeratedBBLS/day
SPILL CENTER SKIMMER OIL MOP OMI 11-9D 240 70%DeratedBBLS/day
SPILL CENTER SKIMMER OIL MOP OMI 1-4D 129 90%DeratedBBLS/day
SPILL CENTER SKIMMER LORI 4 BRUSH SIDE MOUNTED 7321 84%DeratedBBLS/day
SPILL CENTER SKIMMER KAISER AG OELA MODEL 3 754 DeratedBBLS/day
SPILL CENTER SKIMMER KAISER AG OELA MODEL 3 754 DeratedBBLS/day
SPILL CENTER SKIMMER SKIM PACK MODEL 4200 754 DeratedBBLS/day
SPILL CENTER STORAGE SYSTEMS 1,321 GALLON RO-TANK - TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS 2400 GALLON FAST TANK 1 EACH
SPILL CENTER STORAGE SYSTEMS CANFLEX TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS CANFLEX TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS CANFLEX TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS 2500 GALLON QUICKTANK W/ HOOD 1 EACH
SPILL CENTER STORAGE SYSTEMS 2400 GALLON FAST TANK 1 EACH
SPILL CENTER STORAGE SYSTEMS 2400 GALLON FAST TANK 1 EACH
SPILL CENTER STORAGE SYSTEMS 1,321 GALLON RO-TANK - TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS 2400 GALLON FAST TANK 1 EACH
20,000 GALLON STORAGE
SPILL CENTER STORAGE SYSTEMS BLADDERS 1 EACH
20,000 GALLON STORAGE
SPILL CENTER STORAGE SYSTEMS BLADDERS 1 EACH
20,000 GALLON STORAGE
SPILL CENTER STORAGE SYSTEMS BLADDERS 1 EACH
20,000 GALLON STORAGE
SPILL CENTER STORAGE SYSTEMS BLADDERS 1 EACH
20,000 GALLON STORAGE
SPILL CENTER STORAGE SYSTEMS BLADDERS 1 EACH
SPILL CENTER STORAGE SYSTEMS 1,321 GALLON RO-TANK - TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS 1,321 GALLON RO-TANK - TSB 1 EACH
SPILL CENTER STORAGE SYSTEMS 2400 GALLON FAST TANK 1 EACH
SPILL CENTER VEHICLE DODGE DURANGO 1 EACH
SPILL CENTER VEHICLE FORD F350 STAKE TRUCK 1 EACH

Barber's Pt. Equipment List

Location Equipment Type Description Quantity Units
BARBER'S
PT. API SEPARATOR VERSITEK API SEPARATOR 1 EACH
BARBER'S 21 FT. BOSTON WHALER WITH TWIN
PT. BOOM BOAT O/B'S 1 EACH
BARBER'S CONTAINER W/ 1000' HARBOR
PT. BOOM CONTAINER BOOM 1000 FEET
BARBER'S
PT. PACKAGE PPE BOAT PACKAGE - 4 PERSON 6 SETS
BARBER'S
PT. PACKAGE MEDIUM WORKVEST PACK 30 SETS 30 EACH
BARBER'S
PT. PACKAGE PPE SITE PACKAGE - 12 PERSON 18 SETS
BARBER'S
PT. PUMP DIESEL POWERED PHP 754 DeratedBBLS/day
BARBER'S 8 FT. UNDER PIER SKIFF WITH
PT. SKIFF PADDLES 1 EACH
BARBER'S
PT. SKIMMER SKIM PACK MODEL 4200 754 DeratedBBLS/day
BARBER'S SKIMMER KAISER AG OELA MODEL 3 754 DeratedBBLS/day
PT.
BARBER'S
PT. SORBENT SORBENT PADS 10 BALE
BARBER'S
PT. SORBENT 8" SORBENT BOOM 10 BALE
BARBER'S
PT. SORBENT SORBENT SWEEP 10 BALE
BARBER'S
PT. SORBENT VISCOUS SWEEP/DRAG NET 10 BALE
BARBER'S
PT. STORAGE SYSTEMS 2500 GALLON QUICKTANK W/ HOOD 1 EACH
BARBER'S
PT. STORAGE SYSTEMS 2400 GALLON FAST TANK 1 EACH
BARBER'S
PT. STORAGE SYSTEMS 2500 GALLON QUICKTANK W/ HOOD 1 EACH
 APPENDIX VI
SUMMARY OF MINIMUM LINE REQUIREMENTS

Lines are to meet breaking strength requirements as follows:

VESSEL BREAKING STRENGTH

SIZE
Wire Primary Rope Double-Up Rope
<30 110,000 lbs 130,000 lbs 165,000 lbs
or or or
49 Tons 58 Tons 75 Tons
30 - 49 130,000 lbs 165,000 lbs 165,000 lbs
or or or
59 Tons 75 Tons 75 Tons
50 - 99 150,000 lbs 188,888 lbs 165,000 lbs
or or or
67 Tons 84 Tons 75 Tons
100 - 149 165,000 lbs 210,000 lbs 165,000 lbs
or or or
75 Tons 95 Tons 75 Tons
< 150 220,000 lbs 270,000 lbs 165,000 lbs
or or or
100 Tons 122 Tons 75 Tons

All lines on the 6 winch drums are to be the same material. All other lines are to be of the same synthetic
material. The line on a 7th winch drum on the poop, if fitted, is to be of the same wire or synthetic material as
the rest of the lines.

Lines may include rope pendants up to 300 ft in length to meet the 1,000 ft requirement as long as the pendant
and connecting shackle meet the breaking strength requirements for rope per above. Rope pendants and
shackles can be rented from the terminals. When lowering rental lines back to the workboat, the vessel’s deck
crew will be advised by the Mooring Master Assistant, to safeguard the workboat crew. Island Energy Services
recommends making fast synthetic mooring lines as per the OCIMF booklet “Effective Mooring” or by
wrapping three round turns about both bitts, then figure eight for another three turns. Chafing gear is
recommended where synthetic lines pass through chocks. It is prohibited to apply grease to any synthetic line or
to chafing gear.

No synthetic ropes with elongation over 15% at full breaking strength will be accepted. Ropes are available on
a rental basis from the terminals. Pendants under 50 ft are not subject to this requirement.

Aramid fiber ropes (Kelvar, Spectra) may meet wire breaking strength requirements if manufacturer-provided
chafing sleeves are fitted.

Mooring stations for each of the 14 lines are to be equipped with dedicated full strength, properly located,
functioning fairheads (if used) and closed chocks. Each mooring station for ropes not on winches is, in addition,
to be equipped with dedicated, full strength, properly located, functioning double horn bitts and warping
winches. Warping heads on winches with wire drums are acceptable if properly located. Closed chocks are to
be suitably sized for easily passing pendant connecting shackles if used.

Constant tension winches must be braked by means of manual brake.

 APPENDIX VII
SUMMARY OF EMERGENCY PLANS AND PROCEDURES FOR HURRICANES/TROPICAL STORMS

Hours Before Arrival Refinery U.S. Weather REFINERY ACTION

of Sustained Gale Force Winds Alert Condition Service Alert
48 to 72 ----> White ----> Bulletins are being 1) The Refinery Disaster Response Team should be holding regular meetings
issued on NOAA and issuing bulletins to the field when updated information is available.
indicating the 2) Preparations for high winds outlined in Attachment VI should be started.
hurricane’s location 3) Double check emergency supplies.
and intensity 4) Test emergency generator.
5) Build level in Tk-353 (condensate).

24 to 30 ----> Yellow ----> Hurricane Watch 1) Civil Defense coordinator should be sent to Civil Defense Office.
2) Preparation for high winds should be complete.
3) Operations should review all plant shutdown procedures.
4) Switch to low pour point feed at the FCC and Crude Units.

10 to 12 ----> Orange ----> Hurricane Warning 1) Complete all steps above.

2) Shutdown and depressure all plants except the FCC, the Cooling Tower,
LPG Refrigeration, and two boilers.
3) Displace the black oil pipelines with low pour point product.
4) Pull FCC feed and dry circulate. Start to withdraw catalyst and depressure.
5) Open tank roof drains (except ones that leak) and block in tank impounding
basins. The B & S shift supervisor should be notified of any leaking roof
drains.
6) Preparations should be made to evacuate the refinery.

4 to 6 ----> Red Hurricane Warning 1) All employees, except volunteers to remain, must evacuate the refinery at
least 1 or 2 hours before the arrival of sustained gale force winds (by order
of Civil Defense).
2) Slump any catalyst remaining in the FCC unit.
3) Continue to depressure all plants.
4) Solicit volunteers to ride out the storm in the Administration Building. Be
sure they have checked with their immediate family and have adequate
supplies.
5) As the Refinery is evacuated, shut down all boilers, secure LPG
refrigeration, secure the Cooling Tower, and open all breakers at the main
substation.
 APPENDIX VIII
OVER THE RAIL PRESSURE CALCULATIONS

The pipeline was built to an ANSI rating of 150 psi which means that it has a working pressure of 275
psi at 100 degrees.

CONVERT FOR TEMPERATURE DIFFERENCE

Working pressure @ 100 degrees = 275 psi

Working pressure @ 180 degrees = 240 psi

Test pressure = 425 psi

INCLUDE TANKER STATIC HEAD PRESSURE

Including the tanker static head in feet and the depth of the ocean in feet, we have -

Ship static head = 60 feet

Ocean depth = 65 feet

125 Total feet of head

In converting this total head pressure (feet) to psi, we will use the specific gravity of our heaviest crude.

Santa Maria crude = 15 degrees API = .9659 specific gravity

CONVERSION:

Psi = Feet/Head * specific gravity/2.31

Psi = 125 * 1.0/2.31 = 54 psi

Round to 60 psi

240 psi
-60 psi
180 psi at the rail to equal 240 psi on the ocean bottom

VELOCITY LIMITATION

At a pumping rate of 25,000 barrels/hour the stock velocity is under 50 fps. The hoses used in this
terminal are all rated for 70 fps. This allows a maximum pumping rate of 37,000 barrels/hour.

NOTE: Maximum rate allowed by terminal is 26,000 BPH.

 APPENDIX IX
MARINE HOSE CHANGE & INSPECTION CHECKLIST

Purpose: This procedure describes the steps involved in safely inspecting and changing out the
20”/30” marine line hoses.

Preparation: 1. American Divers Inc. (A.D.I.) conducts diving operations according to their Operations
Procedures & Safe Practice Manual. All A.D.I. employees involved with change must
understand and comply with its procedures.

2. Crew to assemble at pier 14 and review equipment and material checklist. Depart for
mooring area.

3. A half hour short of mooring area notify Control “O” vacuum is needed on 20”/30” hose.

4. Position tug over work area. Meet with crew and divers regarding work schedule.

5. CONDUCT SAFETY MEETING BEFORE ANY WORK COMMENCES.

 WORK ITEM AREA
RESPONSIBLE COMPLETED
DATE TIME INITIAL
ONE MONTH PRIOR:

1. Check and prepare all required stock materials Reliability

and bolts for adequate quantity. See SK-22-
133 (23 items).
2. Check condition of flange insulation at plot Reliability
limit.
3. Notify Island Energy Services (IES) Port Captain Reliability
of the 30" line test and hose change out.
Coordinate with the Short Range planner and with
IES Port Captain to pick a tentative date for this
work to take place. Notify American Divers of the
date picked.
4. Contact Harbor Master and arrange space for Reliability
Hose Assembly and Disassembly.
5. Order flange insulation kit if necessary. Reliability
6. Insure that all of the required chains have been Reliability
repaired and are on site - ready to be
deployed.

TWO WEEKS PRIOR:

1. Check back with Harbor Master to Reliability

reconfirm reservation.
2. Sandblast and prepare spare hose pick-up Reliability
buoy for deployment during hose change out.
3. Gather together and give the Divers the materials Reliability
and equipment listed on SK-22-167.
4. Confirm with IES Port Captain of our intent to Process
hydro-test the 30" M/L and replace the CRUDE
submarine hose string.
5. Arrange with IES Port Captain to sample the Process
water they displace the 30" M/L with (at both
ends).

ONE WEEK PRIOR:

1. Calibrate two 0-600 psig gages, two 0-600 psig Reliability

chart recorders.
2. Calibrate two psv's set at 435 psig. These items Reliability
are to be to D.O.T. specifications.
3. Test the process of the P-2008 vacuum pump Process
one week prior to the hose change out.
 WORK ITEM AREA
RESPONSIBLE COMPLETED
DATE TIME INITIAL
ONE DAY PRIOR:

1. Deliver to Harbor the necessary hoses. Connect Reliability

the new Crude hose string together. Inspect
inside of hose for foreign object. Fill out Hose
checklist for each hose before bolting together.
The hoses should be connected into one string in
the series shown on drawing
22-HB-76 for hydro-testing.
2. Have a pump and the necessary firehose available Reliability
for charging seawater to the hoses. Seawater will
be the test medium. Use a high pressure hose for
doing the hydro-test. Install a calibrated 0-600
psig gauge and a relief valve set at 435 psig on
the test manifold.
Use a circular chart pressure recorder to record
the test. Sign the chart record with the names of
the persons conducting the test. Also, list the
date, test pressure and the serial numbers of the
hoses tested and affirmation of no leaks.
Reliability P/L Tech. To receive copies of the
charts.

THIS IS TO FULFILL USCG REGULATIONS

REQUIRING HYDRO-TESTS WITHIN 6
MONTHS OF USING HOSE IN A STRING.
3. Hydro-test the 13 hoses to 425 psig and hold for Reliability
15 minutes. Island Energy Services Inspector to
verify hydro- test.
4. American Divers to pick up new hose string, Reliability
butterfly valve assembly, pickup buoy and chains
and tie up hoses to barge

1. PROCESS is to secure the 30” MOV immediately Process

after the line has been flushed by the vessel in the
berth. Double-check the MOV manually to insure
that the valve is closed.
2. Hook up hoses from fire water system to end of Process
vacuum pump suction header. (Fire hydrant
located across from the berm on the road.)
3. Install a test manifold to the existing vacuum pump Process
suction header and attach a hi-pressure test hose
to the 4” valve.
4. Install the calibrated 0-600 psi gage and relief Process
valve set at 435 psi on the test manifold.
5. Connect the circular 24 hr chart recorder to the Process
vent on the M/L.
 WORK ITEM AREA
RESPONSIBLE COMPLETED
DATE TIME INITIAL
6. Open fire hydrant and displace vacuum manifold Process
to a Crude tank via the vacuum pump bypass
valve.
7. Open 4” discharge valve to vacuum pump on the Process
30” line on the makai side of the insulating flange.
Pull vacuum. Drain the 30” M/L to the oily sewer.
8. When water level is below the 4” nozzle, break the Process
flange on the makai side of the MOB and replace
spacer with blind. Follow all standard blinding
procedures as described in H-9900.
9. Refill 30” M/L with water. Process
10. PROCESS to pull vacuum on the 30” M/L until the Process
subhose string has been disconnected and the 30”
M/L blinded with a 16” boilermaker by American
Divers. PROCESS should hold and extra operator
to man the vacuum pump. PROCESS is to notify
AMERICAN DIVER when the vacuum is
maintained. American Diver is to notify
PROCESS when the 30”M/L is blinded.
11. OIL IS NOT TO BE DISCHARGED INTO Process
NAVIGABLE WATERS. Coordinate activities to
use the chain locker on the Divers work vessel as
an API separator to displace the oily/water out of
the hose string when floating the hose.
12. Blind off the 4” suction valve to the vacuum pump. Process
13. Hook up test pump to fire water system. Open fire Process
hydrant to hydro-test pump and open pump
discharge valve to the 30” M/L. Open vent valves
on the 30” M/L (at the 10 acre site and at the
refinery). When all air is removed, close all vents.
14. Raise pipeline pressure to 200 psig at a rate of Process
about 5 psig per minute. Stop and check all flange
connections for tightness.
15 After tightness inspection, raise test pressure to Process
225 psig at a rate of about 5 psig per minute.
Secure pumping and hold test pressure for 4
hours (make sure four hours of daylight remain).
16. An Island Energy Services Inspector shall Process
witness the start time and pressure, and the
completion time and pressure. The inspector
shall initial the circular chart. Copies shall be
given to the Reliability P/L Tech. P/L Tech. Will
initiate a letter to the Coast Guard with a copy of
the chart, stating that the hydro-test has been
17. American Divers will standby and inspect the Process
seaward end of the 30”M/L as needed during the
hydro-test.
 WORK ITEM AREA
RESPONSIBLE COMPLETED
DATE TIME INITIAL
18. If the line develops a leak, the leak shall be Process
located, line depressured and repaired. The
hydro-test procedure will then begin again with
item #14.
19. After the 30”M/L has successfully passed the Process
hydro-test, the line should be depressured slowly.

NOTE: The following procedures are contingent

on the successful hydro-test of the 30”M/L

1. On request of American Divers, PROCESS is to Process,

pull a vacuum on the 30”M/L. They are to Reliability
maintain the vacuum until the hose string has
been bolted up and the butterfly valve assembly
has been installed and blinded. PROCESS will
notify AMERICAN DIVER when the vacuum is
maintained. AMERICAN DIVER is to notify
PROCESS when the hose string and valve
assembly are bolted up and blinded.
2. The entire 30” line should be brought up to a Process,
pressure of 180 psig (Fire Waterline pressure) at Reliability
a rate of about 5 psig per minute. Hold until
tightness check is complete.
3. American Divers should then check subhose Process,
string for flange leaks Reliability
4. After the line is up to pressure and holding, Process,
American Divers can be given the OK to bring the Reliability
old 30” hose string and the butterfly assembly into
Harbor. American divers will coordinate with
Pipeline Analyst to remove the hoses from the
harbor.
5. The hoses will be taken apart and delivered to the Process,
back of the machine shop for vacuum test and Reliability
hydro-testing. The butterfly valve will be brought
to the machine shop for repair.
6. PROCESS shall verify tightness of the 30” M/L Process,
via the gage at the test pump. Reliability
7. Open the 1 1/2” vent valve on the 30” line on the Process,
makai side of the insulating flange. Drain the 30” Reliability
M/L to the water draw box at the plot limit via the
4” valve located on the 30” M/L just before it goes
underground. The water will drain through the
vacuum pump bypass.
8. Install 1 1/2” bull plug at the 10 acre site and Process,
chain lock valve. Reliability
9. Remove the 30” blind and replace it with the Process,
spacer. Refill the 30” M/L with water. Reliability
10. The entire 30” line should again be brought up to Process,
a pressure of 180 psig at a rate of about 5 psig Reliability
per minute. Hold until tightness on the spacer is
verified. Check bull plug at 10 acre site for leaks.
 WORK ITEM AREA
RESPONSIBLE COMPLETED
DATE TIME INITIAL
11. Remove all test equipment and clean up the work Process,
site. Reliability

POST HYDRO-TEST WORK:

NOTE: All of the following “Post Hydro-test” work

is to be done with 20 days of the hose string
change out.

1. Relocate the 4 spool pieces that were removed

from the old hose string.
2. The old hoses shall be vacuum tested to 30” and
hydro-tested to 425 psig. Those hoses which
inspection okays should be cleaned and repaired
as necessary. Then they should be transported
to the hose storage area and put on the hose
racks.
OTHER RELATED WORK:
1. Inspect the butterfly valve to ensure proper Machinist
operation. Replace the gaskets and seal if
required.
2. Obtain valve spool thickness data and document in Inspections/
the electronic inspection system.
Machinist
Ensure 1” Drain Bull Plug is in good condition and
properly secured.
Hydrotest valve spool.
Fill out attached Butterfly Valve Spool Checklist.
3. Inspect the chains that are brought in; document Inspections
condition and recommend changes.
4. Insure brass I.D. Tag, “MAWP 275#” is attached to Inspections/
butterfly valve per USCG Regulations. Machinist

ATTACHMENTS:
- 30” Marine Line Hydro-test Procedure

- Annual 20”/30” Marine Hose Change &

Inspection Checklist.

SK 22167 - Diver Preparation Materials Checklist

SK 221331 - Sub Hose Changeout Material

Checklist

22HB76 - Sub Hoses Fittings and Attachments

SK22161 - Sub Hose Valve Arrangement

Submarine Hose Check

Butterfly Valve Spool Checklist

 DIVER PREPARATION MATERIALS CHECKLIST

The following materials should be prepared and given to American Divers in preparation for the removal of the hose string
and hydro-testing of the marine pipeline.

All valves should be lubricated and checked. New bolts should be issued. Camloks on the Oil Leak Prevention Canister
should be examined and replaced as necessary. The condition of the Oil Leak Prevention Canister hoses should be
inspected and replaced if necessary.

ITEM LIST

1. 1 each 16” 150 lb. blind flange.

2. 1 each 16” 150 lb. asbestos gasket with tab for item number 1.
3. 1 each 12” 300 lb. hose and tow plate with two 2” valves and camlok connector for Oil
Leak Prevention Canister hose.
4. 1 each 12” 300 lb. red neoprene rubber gasket for item number 3.
5. 1 each 16” 150 lb. hose and two plate with 3/4” air “quick disconnect” hose connector.
6. 1 each 16” 150 lb. red neoprene rubber gasket for item number 5.
7. 16 each 1-1/8” x 6-1/2” long Teflon coated studs & nuts for 12” 300 lb. flange.
8. 32 each 1” 6-1/2” long Teflon coated studs & nuts for 16” 150 lb. flanges.
9. 80 feet 2” clear X green vinyl suction hose with camlok ends.
10. 1 each Repacked Oil Leak Prevention Canister (SK 22-168)
11. 1 each Refinery air hose Quick Release fitting x 3/4” NPT adaptor.

The above items are to be LOANED to American Divers prior to their use on the Marine Line shutdown. Upon completion
of the shutdown, these materials are to be returned to Island Energy Services for storage.
 SUBMARINE HOSE CHANGEOUT MATERIAL CHECKLIST

ITEM LIST

1. 2 each PSV’s set @ 435 psig

2. 1 each Air compressor, 6m cfm or more
3. 150 ft. Air hose, 1” with couplings
4. 2 each Spud wrench, 1-5/8”
6. 1 each Slugging wrench, 1-5/8”
7. 1 each Sledge hammer, 8 lb.
8. 1 coil Manila rope, 3/4” x 200 Ft.
9. 1 each Blind flange 16” x 150 lb. with 3/4” valve
10. 1 each Blind flange 16” x 150 lb. With handle and 2” valve
11. 12/7 each Gaskets w/tab, 16” x 150 lb.
12. 5 each Gaskets w/tab, 12” x 300 lb.
13. 4 each Gaskets w/tab, 12” x 150 lb.
14. 1 lot Dunnage lumber assorted sizes (2x4, 4x4, 4x6, x 6” long)
15. 4 each Nylon sling (preferred) or 1/2” cable slings x 10’ long
16. 5 each Galvanized shackles, 1/2”
17. 2 each Lifting equipment - Grove & JLG
18. 1 each Impact wrench & 1-5/8” socket
19. 192/112 Teflon coated studs & nuts, 1” dia. X 6-1/2” long
20. 54 each Teflon coated studs & nuts, 1-1/8 dia. X 6-1/2” long
21. 12 each Teflon coated studs & nuts, 1” dia. X 10” long
22 12 each Teflon coated studs & nuts, 1-1/2” dia. X 7-1/2” long for Hold Down Clamp
 SUBMARINE HOSE CHECKLIST

Purpose: Look inside of each hose for any foreign object before bolting up.

COMPLETED
DATE INITIAL

1. HOSE NO. 1 FREE OF FOREIGN OBJECT

2. HOSE NO 2 FREE OF FOREIGN OBJECT
3. HOSE NO 3 FREE OF FOREIGN OBJECT
4. HOSE NO 4 FREE OF FOREIGN OBJECT
5. HOSE NO 5 FREE OF FOREIGN OBJECT
6. HOSE NO 6 FREE OF FOREIGN OBJECT
7. HOSE NO 7 FREE OF FOREIGN OBJECT
8. HOSE NO 8 FREE OF FOREIGN OBJECT
9. HOSE NO 9 FREE OF FOREIGN OBJECT
10. HOSE NO 10 FREE OF FOREIGN OBJECT
11. HOSE NO 11 FREE OF FOREIGN OBJECT
12. HOSE NO 12 FREE OF FOREIGN OBJECT
13. HOSE NO 13 FREE OF FOREIGN OBJECT
 BUTTERFLY VALVE SPOOL CHECKLIST

Purpose: Ensure proper operation of Butterfly Valve and verify integrity of Valve Spool.

COMPLETED

DATE INITIAL

1. Inspect valve body, no excessive wear.

2. Replace gasket and seal as required.

3. 1” drain bull plug is in good condition and

secured properly.

4. Obtain valve spool thickness data and document

in the electronic inspection system.

5. Hydro test spool with valve closed, 300psig.

6. Hydro test spool with valve open, 425psig.

 APPENDIX X
IGS & COW CHECK LIST
Vessel Date
______________________________________________________________________________
Terminal

Check “Yes” Or “No” in appropriate block. Yes No

1. Vessel pre-arrival message has been fully and satisfactorily answered (attach copy) . . . . . . . . . . .
2. Vessel has valid IGS and Oil Pollution and COW Certificates . . . . . . . . . . . . . . . . . . . . . . . . . . .
3. If Number 1 above is “No”, have deficiencies been rectified . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4. All hatches, butterworth plates, and ullage holes are properly closed and gas tight . . . . . . . . . . .
5. Vessel is equipped with fixed tank cleaning machines in all tanks to be crude-washed . . . . . . . .
6. Tank cleaning machine entry points are properly closed and gas tight . . . . . . . . . . . . . . . . . . . . .
7. Crude-washing piping system is permanent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
8. All crude-washing pipelines are independent of vessel’s fire lines . . . . . . . . . . . . . . . . . . . . . . . .
9. Crude washing pipelines are independent of vessel’s sea water pump in the engine room . . . . . .
10. If answer to No. 9 above is “No”, is connection line to engine room blanked off . . . . . . . . . . . .
11. Main cargo pumps are fitted with overspeed trips . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
12. Main cargo pumps are fitted with remote emergency stops . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
13. Pressure gauges are installed on pump discharge lines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
14. Vessel is equipped with operational inert gas system . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
15. Vessel is equipped with oxygen analyzers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
How many fixed ___________________
How many portable _________________
16. Vessel is equipped with hydrocarbon analyzers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
How many ________________________
17. IGS is capable of delivering inert gas with an oxygen content of not more than 5% by volume
in the inert gas supply main to the cargo tanks. Cargo and slop tanks will be maintained
by 8% oxygen during operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
18. Vessel has written crude-washing procedures on board available for terminal review . . . . . . . . . .
19. Vessel procedures provide for the proper deployment of ship’s personnel, with constant
inspection of all systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20. Vessel is equipped with an internal communication station, walkie talkies,
or other communication system . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
21. Crude-washing supply to machines is controlled by throttling a valve on discharge line . . . . . . .

22. Person in charge of operation experienced in COW Name: ________________________________

Rank: ________________________________

23. Method of disposal of crude-washings - a) Recycle to suction side of main pumps and ashore ___________
b) To discharge side of main pumps and ashore ___________
c) To slop tank and/or cargo tank ___________

Vessel Representative’s signature Terminal Representative’s signature

___________________________ Rank _______________________

shall be the Master or Chief Officer
Note: Vessel shall not be approved to carry on cargo operation if the IGS is not operational. COW shall not be approved
if “No” is indicated for any of items number 2 through 8, or 10 through 21 of this list:

Vessel is acceptable for COW. Yes No

Vessel is acceptable for cargo operations. Yes No

Terminal Supervisor’s signature Time/Date

 APPENDIX XI
BARBERS POINT MOORING: HOSE OPERATION CHECKLIST

VESSEL NAME ____________________________

MOORING MASTER ____________________________

MOORING MASTER ASSISTANT ____________________________

Definitions: M/M = Mooring Master

MMA = Mooring Master Assistant
TPIC = Terminal Person In Charge
(Either Mooring Master or Mooring Master Assistant)
VPIP = Vessel Person in Charge (Ships Officer)

Note: TPIC (M/M or MMA) to be present at manifold area entire time of lifting, connecting, disconnecting,
and letting go the hose. Vessel’s deck officer and deck crew responsible for lifting, connecting,
disconnecting and letting go the hose only under advise of TPIC.

TPIC to initial each item as completed, prior to proceeding on to next operation.

CONNECTING HOSE Date

Vessel is in proper position in mooring for lifting hose & vessel’s deck officer and deck crew
stationed at manifold.

TPIC calls for and receives confirmation that hoses are pressurized prior to any movement by
line/assist tug; then instructs tug to bring hose buoy alongside ship.

After lifting hose, securing with hang off chain, TPIC to call for and receive confirmation hose is de-
pressured prior to removing blank from end of hose.

After hose connected: TPIC verifies gasket in place, bolts in every hole, hose properly supported,
and pressure gauge installed at manifold or between hose valve and manifold.

TPIC will open valve, notify terminal, and if:

A) Loading-request 100 psi to confirm tight connection
B) Discharging-connection visually observed upon start up.

DISCONNECTING HOSE Date

Hose string left with only low pour cargo or water flush.

Hose valve and ship’s manifold closed, shore blocked in (depressurized), then spool
between manifold and hose valve drained.

After disconnect and hose blanked off, wipe all oil off hose.

After hose is lifted by bale, request terminal pressurize and then inspect for any leakage.

After hoses repositioned on bottom, notify terminal to take pressure off the hose(s).
 APPENDIX XII

ISLAND ENERGY SERVICES

PRE-MOORING/UNMOORING CHECKOFF LIST

SHIP _____________________ DATE _____________________

The following items have been review for compliance with I.E.S. Barbers Point Marine Terminal
Requirements:

DESCRIPTION MOORING UNMOORING

1. Weather conditions satisfactory as per Marine Terminal Manual.

2. Mooring equipment and hose handling gear.

3. Master/Pilot conference conducted describing the vessel’s intended

track and speed and the use of assist tug(s) and line boat.

4. Mooring procedures and sequences discussed with vessel Master

and deck Officers.
5. Master verifies all required pre-arrival and pre-sailing tests made
and navigation equipment in good order.
6. Oil spill containment boom at the mooring, ready for immediate
deployment.
7. Assist tug(s) standing by.

8. Communications established aboard vessel, between assist tug(s)

and line boat.
9. Master has confirmed intentions regarding any high pour point
cargoes with the planned submarine line displacements or seawater
hose flushes.
10. Emergency hose flushes have been discussed and approved

11. Master confirms that all policies and procedures performed by the
vessel Officers and crew are approved by vessel Owners or
Operating Managers
12. If a loss of containment/petroleum spill occurs, the Mooring Master
will take charge of directing all on water response and recovery
operations. The vessel’s Master is still responsible for all spill
response on board and for making required notifications on behalf
of Owners.

______________________________
Mooring Master

______________________________
Mooring Master Assistant
 DRAWINGS

Figure 1 - Barber’s Point Mooring Area Chart

Figure 2 - Vessel Moored in Berth

Figure 3 - Submarine Pipelines System Drawing

Figure 4 - Basic Berthing Sequence

Figure 5 - Typical Mooring and Hose Connection Schematic

Figure 6 - Typical Over-the-Rail Hose Connection Direct to Vessel’s Riser

Figure 7 - Bathymetric Survey of Mooring

Figure 8 - Sub Hose Valve Arrangement & Ship Attachment

Figure 9 - Submarine Hoses Fittings & Attachments

Note: Several of these drawings are marked as Chevron. Island Energy Services, LCC
acquired Chevron’s former Hawaii assets in November 2016. These Chevron drawings
reflect the assets that Island Energy Services now owns and operates
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