10 1002@er 4433
10 1002@er 4433
DOI: 10.1002/er.4433
REVIEW PAPER
1
State Key Laboratory of Automotive
Summary
Simulation and Control, Jilin University,
Changchun 130025, China Progress in battery technology accelerates the transition of battery manage-
2
College of Automotive Engineering, Jilin ment system (BMS) from a mere monitoring unit to a multifunction integrated
University, Changchun 130025, China one. It is necessary to establish a battery model for the implementation of
Correspondence BMS's effective control. With more comprehensive and faster battery model,
Qing Gao, State Key Laboratory of it would be accurate and effective to reflect the behavior of the battery level
Automotive Simulation and Control, Jilin
to the vehicle. On this basis, to ensure battery safety, power, and durability,
University, Changchun 130025, China.
Email: [email protected]. some key technologies based on the model are advanced, such as battery state
estimation, energy equalization, thermal management, and fault diagnosis.
Funding information
Double Ten Special Project, Grant/Award
Besides, the communication of interactions between BMS and vehicle control-
Number: 17SS022; High‐tech Industry lers, motor controllers, etc is an essential consideration for optimizing
Special Project, Grant/Award Number: driving and improving vehicle performance. As concluded, a synergistic and
2016C022; National Natural Science
Foundation of China (NSFC) Key Pro-
collaborative BMS is the foundation for green‐energy vehicles to be intelligent,
gram, Grant/Award Number: U1864213 electric, networked, and shared. Thus, this paper reviews the research and
development (R&D) of multiphysics model simulation and multifunction inte-
grated BMS technology. In addition, summary of the relevant research and
state‐of‐the‐art technology is dedicated to improving the synergy and coordina-
tion of BMS and to promote the innovation and optimization of new energy
vehicle technology.
KEYWORDS
battery management system, battery modeling, functional application, system integration
Nomenclature: AET, average execution time; AUKF, adaptive unscented Kalman filter; BMS, battery management system; BTMS, battery thermal
management system; CAN, controller area network; CC‐CV, constant current‐constant voltage; CFD, computational fluid dynamics; DCE,
dissipative cell equalization; DC/DC, direct current to direct current; DOD, depth of discharge; ECM, equivalent circuit model; FEA, finite element
analysis; EKF, extend Kalman filter; EMS, energy management strategy; EPS, electronic power steering; EV, electric vehicles; ERDE, remaining
discharge energy; FLC, fuzzy logic control; GPS, global positioning system; HEV, hybrid electric vehicles; HPPC, hybrid pulse power characteristic;
ITS, intelligent transport system; LiCoO2, lithium cobalt oxide; LIB, lithium‐ion battery; LiFePO4, lithium iron phosphate; LiMnO4, lithium
manganese oxide; MCU, motor control unit; NCA, nickel‐cobalt‐alumina; NCM, nickel‐cobalt‐manganese; P2D, pseudo two dimensional; PDU,
power distribution unit; PRA, power relay assembly; R&D, research and development; RMSE, root‐mean‐square error; OCV, open circuit voltage;
OEMs, original equipment manufacturers; PCM, phase change material; PDEs, partial differential equations; PF, particle filter; MAE, mean
absolute error; NAS, sodium‐sulfur; NEs, nonlinear equations; RC, resistance and capacitance; SBMs, smart battery modules; SEI, solid electrolyte
interphase; SOC, state of charge; SOE, state of energy; SOF, state of function; SOH, state of health; SOP, state of power; SP, single particle; UDF,
user‐defined function; UKF, unscented Kalman filter; VCU, vehicle control unit; ZEBRA, sodium/nickel chloride
Int J Energy Res. 2019;2–33. wileyonlinelibrary.com/journal/er © 2019 John Wiley & Sons, Ltd. 1
2 SHEN AND GAO
model to battery temperature estimation to analogize the system requirements. Existing models for the field of
thermal simulation system of electricity. That is, when EVs can be divided into two categories: electrochemical
the heat source is activated, the current is converted into model and equivalent circuit model.
heat flow, causing the temperature to rise. The current is Electrochemical models, starting from internal reac-
used to represent the heat flow, the voltage is the temper- tion mechanism of battery, establish a series of electrode
ature, the resistance is the heat transfer resistance, and and electrolyte kinetic partial differential equations
the capacitance is the heat capacity. With this hypothesis, (PDEs). It can accurately predict the macroscopic physi-
the material thermodynamic properties of the battery can cal quantities (such as voltage and current) of batteries;
be converted into equivalent electrical parameters. A meanwhile, it can also stimulate the distribution of
model based on the analogy principle for LIBs was pre- microscopic physical quantities (such as electrolyte
sented, as shown in Figure 1. The heat balance equation overpotential, electrode current density, and solid‐state/
was established to predict the core and surface tempera- liquid‐phase lithium‐ion concentration). Such kind of
ture of the battery according to the law of electricity. model is accurate, but with high calculation cost. It is
And convection phenomenon between the battery surface worth noting that the electrochemical models are suitable
and surroundings was also considered. Meanwhile, for battery optimal design and safety analysis and can
Forgez et al29 further simplified the dual‐state equivalent also be applied to the battery management technology
circuit thermal model. The correctness of the internal after proper simplification.
temperature estimation of the model is verified by current The battery is usually stacked or wound by a multi-
pulse experiment and full charge and discharge experi- layer structure (micron‐sized electrode sheets,
ment, and it is within 1.5°C. This approach is simple centimeter‐size body), and the large size span makes it
enough to be applied in the BMS for EVs. The mathemat- difficult to build a high‐quality model when simulating
ical equations and diagrams for the above models are the actual battery structure. Therefore, when establishing
shown in Table 1. a three‐dimensional model, the average volume method
is generally adopted, that is, the average behavior of a cer-
tain volume is taken as the overall battery characteristics
2.2 | Electrical modeling for calculation. The US NREL30-32 presented a general
multiscale LIB modeling framework. It input parameters
The electrical property model can either respond to the (potential φ, temperature T, etc.) in the high dimension
macroscopic electrical parameters of batteries, save test into the low dimension in the form of the field, and the
time and cost, or characterize the particle domain param- parameters (current i, heat generation q, etc.) in the low
eters in the microstructure to analyze battery perfor- dimension were entered into the high dimension as a vol-
mances for meeting different levels of management ume source. The particle mechanism model and the
FIGURE 1 Equivalent electrical representation of the thermal model for the battery28 [Colour figure can be viewed at wileyonlinelibrary.
com]
SHEN AND GAO 5
2
Two‐dimensional model ∂T ∂ T k r ∂T ∂2 T
ρc ¼ kr 2 þ þ kz 2 þ q
∂t ∂r r ∂r ∂z
Three‐dimensional model ∂T 1∂ ∂T k z ∂2 T ∂2 T
ρc ¼ kr r þ 2 2 þ kz 2 þ q
∂t r ∂r ∂r r ∂θ ∂z
electrode model were packaged separately, which simpli- the battery size dimension, it is not a two‐dimensional
fied the calculation and update of the model. model in the strict sense. For the convenience of identifi-
Generally speaking, there is a repetition of a plurality cation, it is called a pseudo‐two‐dimensional (P2D)
of identical structures (sandwich structure) inside the bat- model, as shown in Figure 2. The model can directly sim-
tery, so it is unrealistic and unnecessary to establish a ulate the internal microscopic information of the battery
multilayer model to simulate the overall performance of (such as particle concentration distribution and current
the battery. To achieve a certain simplification, Newman potential distribution) and evaluate the material perfor-
et al33-36 assumed that the current density on the elec- mance of the battery quickly, which is difficult to
trode was equal, and the three line segments respectively complete for the traditional experimental methods. And
represented the positive electrode, separator, and nega- the control equations are given in Table 2.
tive electrode. Of course, there was a dimension on the This marks an establishment of a relatively fast and
cell size. At the same time, the model used Fick law of complete scientific system for evaluating battery perfor-
diffusion to idealize the battery active material into mance from a material perspective. Therefore, the P2D
uniform spherical particles to describe the embedding model has gained wide attention and application since
and disembedding of li‐ions in the solid phase material. its birth. The model study shifts from single‐phase
Since Fick's law was solved only in the radial direction (lithium manganese oxide [LMO]37-39 and lithium cobalt
of particles, it meant that there was a radial dimension. oxide [LCO]40,41) to multiphase materials, (lithium iron
However, due to the smaller radial dimension relative to phosphate [LFP],42-44 nickel‐cobalt‐manganese [NCM],45
and nickel‐cobalt‐alumina[NCA]46,47). What is more,
when Newman et al established the P2D model, a set of
BAND program derive from the finite difference method
was proposed to settle the coupled PDEs. Then the end-
less simplified algorithms have been introduced into the
calculation, including the finite element method,45,47
finite difference method,48 lattice Boltzmann.49,50 Other
FIGURE 2 The schematic diagram of pseudo‐two‐dimensional than using mathematical method to reduce or reconstruct
(P2D) model [Colour figure can be viewed at wileyonlinelibrary. the PDEs, there is also a method of approximating some
com] physical and chemical processes inside the battery, for
6 SHEN AND GAO
example, the single‐particle (SP) model38,51 where the battery dynamic behavior more accurately. And
battery electrode is regarded as a material particle for multiorder Thevenin equivalent circuit model was
calculation. applied to a 47.8‐kW LMO battery,56,57 as shown in figure
The equivalent circuit model (ECM) refers to the use (c). Moreover, many people proposed some extended
of circuit elements such as constant voltage source model for different situations on the basis of Thevenin
(indicating open circuit voltage), resistance (indicating model. Among them, the PNGV battery test manual
the difficulty of electron and ion movement), and RC net- added a series capacitor based on it to describe the perfor-
work (indicating the polarization inside the battery) to mance of batteries under high‐power pulse condition,68,69
capture the I‐V characteristics and transient behavior as shown in figure (d). For the battery composed of
of the battery. This model provides a good trade‐off LiFePO4, the response has a short‐time and long‐term
between the characterization of the external dynamic characteristics. Tsinghua University put forward the
behavior of the battery and the insight into internal or GNL model and split the parallel RC circuit into two on
microscopic behavior. And ECMs are generally divided the basis of the PNGV model, as shown in figure (e).
into two types: the ECM in the time domain and in the The entire circuit includes a series resistor and two RC
frequency domain. branches to consider the ohmic internal resistance, the
The time‐domain ECM establishes a circuit through electrochemical polarization internal resistance, and the
capacitance, inductance, resistor, and other circuit concentration difference polarization internal resistance,
elements to simulate the external characteristics like the respectively.70 Min and Rincon‐Mora61 also introduced
battery terminal voltage and current. The model is widely an ECM based on the predecessors. The left part was a
used in electric vehicle management system for its few capacitor and a current source, inherited from the Rint
parameters and easy identification.52 The time‐domain model, modeled the capacity, SOC, and runtime of the
ECMs are presented in Table 3. The simplest time‐ battery. The right part was similar to the GNL model,
domain ECM is a structure, in which a resistor is con- which was used to simulate the battery transient
nected in series with a voltage source. It is designed to response, as shown in figure (f). The model combined
describe the open circuit voltage of batteries, also known characteristics and advantages of the aforementioned
as the Rint model shown in figure (a).65 This model is model to meet the accuracy requirements for battery
easily parameterized and integrated into battery perfor- runtime, steady‐state characteristics and transient
mance simulation.66 However, owing to the simplified response analysis. These improved models can be called
form, the results react too quickly to capture the dynam- equivalent circuit models based on the Thevenin model.
ics that occur inside the battery, such as charge transfer. Besides, some researchers have proposed the dynamic
To further improve the model accuracy is to add a paral- equivalent resistance electrical model that used only one
lel RC network in the circuit of a single resistance model, variable resistor to describe the battery electrical charac-
also called the Thevenin equivalent circuit model,67 as teristics.71,72 It mainly gives a reasonable method for the
shown in figure (b). This model can reflect the polariza- steady‐state and transient battery modeling in the form
tion between electrode and electrolyte and describe the of internal resistance as a function of current and DOD
SHEN AND GAO 7
Model Model
Model Structure Expression Type Variables Refs.
Improved model
U bat ¼ U Eo − U CT − U W Analytic SOC, T Dai et al63 and
−I⋅RE function Greenleaf
RE is the electrolyte and electrode et al64
resistance, RW is the linear ohmic
characteristics, RCT is the
charge transfer, and CDLelectrochemical
(g) Impedance‐based model62
double
layer effect.
8 SHEN AND GAO
and has obtained satisfactory verification results in Na‐ in parameters extraction, which restricts its application
beta family batteries. in battery state monitoring and management to some
The frequency‐domain ECM also uses the same com- extent.74
ponents to construct a circuit from the time‐domain Dynamic representation of electrical characteristics of
ECM. The difference is the principle of the constructed the battery model depends largely on the expression type
circuit, making the response of sinusoidal excitation in a and variables selection. For instance, temperature, SOC,
certain frequency range coincide with the measured elec- and charge and discharge rate, involving in model param-
trochemical impedance spectrum of the battery. And the eterization, will have a great impact on model accuracy.
idea is a simulation of battery impedance spectrum, not Table 3 also lists some literatures that use the ECM to
a description of battery terminal voltage and current. reflect the electrical characteristics of battery from the
The relevant instrument measures the potential across a aspects of model structure, expression type, and variable
battery by applying small AC currants over a wide range selection.
of frequencies, and then a Nyquist plot is drew to show
the complex impedance of the battery over the entire
frequency range, as shown in Figure 3.73 These features
2.3 | Multiphysics modeling
can be divided into three regions over the frequency
The individual thermal or electrical properties are not
range. The mass transport (ie, diffusion effect) in the
sufficient to characterize all the properties of batteries.
low‐frequency region from millihertz to hertz is similar
As a closed organic system, it is necessary to combine var-
to the linear ohmic characteristics. There is a semicircle
ious physical characteristics with a more comprehensive
in the middle of hertz to kilohertz, similar to the RC
vision for battery modeling.
parallel circuit, which represents the charge transfer
phenomenon at the electrode. The high frequency
ranging from kilohertz to megahertz reveals the 2.3.1 | The coupling of thermal and elec-
conductance effect, which is similar to the inductor trical characteristics
characteristics. A frequency‐domain ECM can be made
on the basis of this plot, as shown in figure (g). The model The amount of heat, acting as the joint, directly affects
more specifically abstracts the electrochemical reactions the thermodynamic properties of the battery like the rate
occurring in the battery and maps the physical meanings of temperature changes. Conversely, the battery tempera-
to the circuit components to make the components more ture also affects the size of battery parameters, such as
practical. More comprehensive, meanwhile, there are resistances, thereby changing the battery voltage charac-
also shortcomings such as large calculation and difficulty teristics. In general, the higher the temperature, the
smaller the internal resistance and the lower the battery throughout the entire transformation from normal run-
voltage at a relatively load current. In order to fully reveal ning to thermal runaway. Results demonstrated that the
this coupling relationship and accurately simulate the model was helpful to predict the potential occurrence of
dynamic characteristics of batteries, the development of thermal runaway and assist the BMS. As for the construc-
a thermal and electric coupling model has a significant tion of pack model, a three‐dimensional thermal model
scientific and engineering application value. was built in Sun et al84 for better understanding the ther-
Electrochemical‐thermal coupled model, as one of the mal behavior of batteries under various operations. The
coupling forms, usually uses the electrochemical model approach comprised a pack‐level CFD model and an
as the electrical characteristic model and couples a thermal electro‐thermal cell‐level model, which are in three
model based on the heat equations at the same time. There- dimensions, as well a one‐dimensional battery network
fore, the model is all described by PDEs, which can reveal model. Thereby, it is possible to quickly predict the char-
battery voltage and temperature response characteristics acteristic parameters of the battery, such as nonuniform
very accurately. The studies on the thermo‐electric heat generation rate, temperature distribution, and varia-
coupling characteristics of batteries are shown in Table 4. tions. The flow diagram of the calculation process is
In addition, there is the electro‐thermal coupled shown in Figure 4.
model adopts ECMs as the electrical characteristic model
and couples a thermal model to simulate the electro‐
thermal response of LIBs. This kind of model is relatively 2.3.2 | The coupling of thermo‐electric
simple and easy to promote on real vehicles. Miranda and and aging characteristics
Hong81 established the coupling model of Thevenin
equivalent circuit model and thermal model for high‐ The battery aging, that is, capacity/power reduction,
power LiFePO4 batteries under normal temperature and internal resistance increasing, voltage drop, and self‐
achieved the estimation of the relative error in average discharge is inevitable. And it degrades the battery perfor-
temperature and voltage as 1% and 5%. In order to extend mance and life. Through tracking of aging phenomenon,
the temperature ranges of the model usage, especially for the prediction of the remaining life and health manage-
the low‐temperature condition, Jiang et al82 developed an ment of batteries can be completed. Therefore, the devel-
electro‐thermal coupled model with lower computation opment of coupled models that consider aging is critical
based on the frequency‐domain ECM. The novel model to assessing and improving the life of LIBs for EVs.
yielded a promising candidate for developing the fast Like all electrochemical cells, LIBs consist of an
charging and internal heating strategy and stimulating anode, a cathode, an electrolyte, and a separator. In the
the power batteries in cold weather. Besides, Ping et al83 charge and discharge cycle, lithium metal embedded in
established a complete electro‐thermal model that the carbon material is ionized and travels among the elec-
described variations in heat, voltage, and current trolyte, the cathode material, and the anode material
through the porous medium to release or accept elec- The data analysis pointed out that a degradation
trons. From the microscopic point of view, the main fac- mechanism, such as cracking of the SEI film, would take
tors affecting the aging degradation of LIBs are metal an essential role in the driving cycles. However, the
deposition, formation of passivation film, crack propaga- degradation occurring at anode was not considered at
tion, and dissolution of active material in the electrode.85 the above work, Kupper and Bessler87 proposed a model
The porosity modification mechanism caused by the framework, allowing the flexible multiphase electro-
growth of the solid electrolyte interphase (SEI) film at chemistry approach to declare reactions of SEI formation
the negative electrode was added to the electro‐thermal at the anode. Besides, it also integrated a 0D model of the
model to develop the theoretical relationship between void volume to describe gas concentration and pressure
the battery capacity and performance attenuation in variation when the aging happened. Ganesan et al88 also
Prada et al.86 The aging model covered the effects of dif- selected a single typical model and scaled it through
ferent battery impedance changes, such as the SEI film special factors to gain the response of battery pack and
resistance and the electrolyte mass transport resistance, discussed the effect of negative electrode changes on the
as shown in the following formula: pack‐level aging.
It can be seen that the microscopic factors affecting
the battery aging are diverse and intricate, and the effect
RT RT δSEI
RSC ¼ Rpct þ Rnct þ RSEI ¼ þ þ ; (2) of various mechanism interactions even more so. From a
Fi0;p Sp Fi0;n Sn κSEI Sn
macro perspective, battery aging can be divided into two
parts: calendar aging and cycle aging. The significance
where Sp = 3εs, pδpA/Rs, p and Sn = 3εs, nδnA/Rs, n are of cycle aging is needless to say. For calendar aging, since
the electro‐active surface areas of the positive and nega- 90% to 95% of the life of vehicles is in parking, it is also an
tive electrodes, respectively, and CLOSS to be expressed important factor in battery aging.89 In general, over-
as a function of the RSC increase as follows: charge, overdischarge, high or low temperature, high
SOC during storage, and high DOD would lead to a
Qz;init − Qz ðtÞ certain degree of capacity or power reduction, and these
CLOSS ðt Þ ¼ 100 ×
Qz;init degradations are also macroscopic representations of
2FρSEI κSEI Sn 2 several chemical and mechanical processes at the micro-
¼ 100 × ΔRSC : (3)
M SEI Qs;init scopic level. Therefore, a coupling model constructed by
SHEN AND GAO 11
parameterizing different stress factors in combination electrode and the accumulation of mechanical stress in
with an electro‐thermal coupling model was born. the battery are caused by the continuous extraction and
Wang et al90 collected a large‐span temperature, DOD insertion of lithium‐ions. When stress is accumulated to
and C‐rates cycle test data of 2.2 Ah, 26650 cylindrical a certain extent, the electrode may be broken,
cells and summarized a general battery cycle life model which reduces the durability of batteries. Therefore, it is
as follows: necessary to add mechanical stress analysis for LIB
modeling.
−31700 þ 370:3 × C − rate The different components of LIB have different
Qloss ¼ B⋅ exp ðAhÞ0:55 ; (4)
RT the mechanical characteristics. For the example of
qualitative analysis, the current collector has anisotropy,
where B is the preexponent factor and Ah is the
strain hardening, ductile fracture, and rate‐dependent
Ah‐throughput. Also lots of efforts have been made to
mechanical behaviors. And the separator is orthotropic,
understand the impact of different stress factors on
elasto‐viscoplastic, and temperature dependent.99 The
battery aging; Table 5 lists some of the research status.
mechanical behavior of a battery cell is not just the sum
of the contributions of each component. Instead, it is
2.3.3 | The coupling of thermo‐electric the result of the mechanical interaction among various
and mechanical characteristics components. Golmon et al100 proposed a multiscale
modeling approach for studying electrochemical and
Except for electrochemical performance, the battery mechanical interaction phenomena at macroscopic and
mechanical properties have gradually attracted people's microscopic scales. The electrochemical porous electrode
attention, especially for manufacturing process. During models presented by Newman et al were extended to
the charging/discharging process, the volume change of the macroscopic elastic deformations. The Butler‐Volmer
equation was used to explain the interface surface condi-
tions and pressures of the composite cathode matrix at
TABLE 5 Key elements of presented battery aging models
microscale. And the mesoscale was introduced into the
Type of aggregate model to relate microscopic and macroscopic
Aging Stress Factors mechanical effects. Sauerteig et al,101 likewise, applied a
Considered Considered Model Output Ref.
coupled 2D electrochemical‐mechanical model of LIB to
Cycle aging C‐rate, Capacity loss Shen et al91 study the volume change caused by intercalation and
Temperature, aging of electrodes. The calculation approach took into
SOC, Ah‐ consider the electrode expansion, stress generation, the
throughput
compression of electrodes and separator, and finally the
Initial capacity, Internal Anseán
lithium‐ion transport. However, these approaches ignore
SOC, resistance et al92
Temperature the effects of thermal fields. Valentin et al102 discussed
C‐rate, Capacity loss Omar et al93 thermal expansion leading to the mechanical stresses. A
Temperature, and internal thermo‐mechanical model was established to predict the
DOD resistance thermal gradient and stress along the cell, especially at
Calendar Temperature, SOC Capacity loss Grolleau the material interfaces. And the stress level at the
aging et al94 anode/copper and cathode/aluminum interfaces is shown
Calendar Temperature, SOC Capacity loss Ecker et al95 to be stronger in LFP/graphite cells. Actually, the charge
and cycle and internal and discharge cycles of the battery contained coupling
aging resistance problems of electrochemical, mechanical, and thermal
C‐rate, Capacity loss Prada et al86 aspect, and whether thermal or stress field, each of them
Temperature, and internal had a great effect on the electrochemical reaction. Duan
SOC, resistance
et al103 developed a similar multiphysical coupled model
Temperature, Capacity loss Schmalstieg
of the battery to describe the electrochemical properties,
DOD, , voltage, and internal et al96
Ah‐throughput resistance thermal and stress status under different operations. In
Ah‐throughput, Remaining Onori97 addition to the conservation of charge, electrochemical
Temperature, capacity kinetics, mass conservation, and energy balance in the
DOD well‐known thermoelectric coupling model, mechanical
Ah‐throughput, Remaining Serrao conservation of the electrodes was also established. It
Temperature, capacity et al98 also considered the effects of a common mechanical
SOC, C‐rate
strain and two other eigenstrains. The stress state of
12 SHEN AND GAO
electrodes was obtained by the solid mechanical estimation, energy equalization, thermal management,
equations as follows: and fault diagnosis.
εij ¼ εme
ij þ εij
ei T
þ εijei c ; (4)
3.1 | State estimation
1
where εme
ij ¼ ð1 þ νÞσ ij − νσ kk δij , εeiT
ij ¼ αΔTδ ij ,
E BMS needs to monitor the key data, such as battery current
1 and voltage, to estimate the state of batteries. This is the
ij ¼ ΔcΩδij .
and εeic
3 premise and basis for the implementation of other man-
Further, for the dynamic behaviors estimation and
agement algorithms. Battery state estimation plays a core
control, Oh et al104 exploited a novel model for LIBs
role in the BMS. It mainly includes battery temperature,
under actual vehicle operations, such as US06 duty cycle.
SOC, SOH, SOP/SOF, and SOE, wherein the temperature
The multiphysics model was mainly consisted of the
estimation can be referred to the thermal modeling chap-
following parts: an electro‐thermal mode for estimation
ter, other parameters are mutually influenced by the tem-
of the temperature and SOC of the battery, a swelling
perature parameters. For the relationship between
model for calculation the value of battery swelling, and
various state estimations, see Figure 6.
a force estimator for figuring out the acting force of the
The role of SOC in electric vehicles is similar to that of
variation of battery volume. In summary, the diagram of
fuel gauges in traditional internal combustion engines.70
the multiphysical coupling model is shown in Figure 5.
SOH characterizes battery's ability to store energy relative
Electrical models are able to predict load voltage in
to a new battery.105 SOP indicates the ability of the
response to the working conditions; thermal models are
battery to withstand the charge and discharge power.
able to forecast real‐time temperature in response to
Some literatures are also called SOF, or peak power.106
battery heat generation; aging models are able to dope
Compared with the above state estimation, there is less
out capacity or power loss in response to the different
concern about SOE. It is a new concept proposed by
stresses; and mechanical models are able to predict
academia in recent years, which represents the ratio of
structure stress in response to the internal and external
the battery current remaining energy to the nominal total
pressure shock. According to what the model is intended
energy.107 These parameters has a direct effect on the bat-
to describe, a battery cell/pack model is composed of one
tery life, the dynamic performance, and mileage range of
or more coupled models.
vehicles. However, the state value cannot be measured
directly; it can only be estimated indirectly using the bat-
3 | MODEL ‐BASED BMS tery model through terminal voltage, current, internal
A PP L I C A T IO N resistance, and other battery parameters.
The content of model‐based SOC estimation method
The first step is to choose appropriate battery model and incorporates of two main parts: application of battery
algorithm for realizing the corresponding function of models and appropriate algorithm. The battery model is
BMS. On the basis of this, this chapter briefly reviews used to calculate the voltage, current and temperature,
the development of BMS from the aspects of state and the estimation algorithm evaluates the SOC.108 At
FIGURE 5 Electro‐thermal‐aging‐
mechanical model coupling [Colour figure
can be viewed at wileyonlinelibrary.com]
SHEN AND GAO 13
FIGURE 6 Battery state estimation algorithm framework [Colour figure can be viewed at wileyonlinelibrary.com]
present, there are two kinds of electrical battery models mechanism model from the nature of LIBs reaction. An
used in SOC estimation, namely, electrochemical model electrochemical model has been developed to estimate
and ECM. Bizeray et al109 used the orthogonal collocation the power fade of LIBs in Ramadass et al.112,113 It uses
method solve the DAEs of the P2D model, and a modified an empirical formula to correct the growing rule of battery
extend Kalman filter (EKF) was used to estimate the
model. It is obvious that the method can rapidly recover
the model states from the wrong initial conditions while
maintaining high precision. In addition, based on the
second‐order ECM, Peng et al110 combined the noise sta-
tistical estimator and the model parameter regulator to
estimate the series‐connected battery pack SOC using
adaptive unscented Kalman filter (AUKF). At the same
time, some mixed techniques, such as simple corrections
and weighting, have also been proposed to avoid the
defects of using a single estimation method. Li et al111
implemented the high‐precision and low‐runtime online
SOC estimation by utilizing the two algorithms according
to the running time. When the initial error was large,
the particle filter algorithm was adopted to decrease the
convergence time. Or else the unscented Kalman filter
algorithm was applied to gain on the actual battery SOC
with low‐computational cost. Figure 7 shows the
SOC estimation errors of EKF, UKF, PF, and the
combined method and the performance comparison of
the four algorithms. The figure shows that the combined
method displayed a good accuracy and trade‐off among
MAE, RMSE, and AET.
The method of SOH estimation based on the battery
model is either from the perspective of internal parameters
such as the aging mechanism, or from the external param-
eters such as the load conditions. Combined with the bat- FIGURE 7 A, Comparison of state of charge (SOC) errors with
tery aging model, it is predicted by two kinds of the most an initial value of 100%. B, Comparison of SOC errors with a 10%
common evaluation indexes: capacity loss and resistance initial value111 [Colour figure can be viewed at wileyonlinelibrary.
com]
increase. One of them is to create a degradation
14 SHEN AND GAO
SEI resistance and then estimates the SOH. It not only By definition, the key to SOE estimation is to deter-
gives the discharge voltage characteristics of batteries but mine the current remaining discharge energy (ERDE).
also reflects the influence of SOH and discharge current The ERDE refers to the energy that the battery can provide
on capacity losses. The estimation method has a high pre- from the current state to the full discharge under certain
diction accuracy, a clear physical meaning, and a wide operating conditions. And the ERDE depends on battery
adaptability. However, the estimation process has a high terminal voltage, future conditions, and many other fac-
complexity and a great dependence on the model, which tors. Liu et al119,120 proposed an energy prediction
makes the monitoring algorithm difficult to implement approach for the dynamic driving condition based on
on low‐cost microcontrollers. Therefore, another SOH esti- the valid control algorithm. On this basis, the variation
mation method based on the circuit model has drawn of the future battery state and model parameters were
attention. The major idea is to use the optimal evaluation coupled and predicted in the ERDE prediction process.
techniques, such as least squares method, and to combine Specifically, the method further predicted the voltage var-
the measurable state signals to identify parameters related iation of the future discharge process, and the cumulative
to battery SOH. A novel approach deduced from ECM was energy was obtained by the first‐order ECM. During the
proposed in Remmlinger et al.114 The method utilized the prediction process, the model parameters was modified
internal resistance change as a judgment and combined according to the current measurement values, and the
the specific signal interval occurring in hybrid vehicle bat- prediction results of the terminal voltage sequence and
tery operation to realize the estimation of SOH. Dong the ERDE was updated. Moreover, as an example research
et al115 used the electrolyte impedance and charge transfer of the embedded BMS, Wang et al121,122 presented the
impedance to establish a capacity degradation model and ERDE prediction method on the basis of the μC/OS‐II real
to estimate the SOH and combined with support vector time operating system. And a model for SOE estimation
machine‐particle filter to identify the model parameters. was presented based on a first‐order ECM and Bayesian
Shui et al116 also proposed the evaluation of battery SOH learning technique. See Table 6 for more information on
based on the principles and the relationship among battery model applications in state estimation.
state parameters and mechanical characteristics like stack Meanwhile, the data‐driven method, that is, neither
stress. considering the battery actual reaction nor requiring the
At present, SOF/SOP estimation generally acquires accurate mode construction but paying more attention
the maximum charge and discharge current according to the relationship between input excitation and target
to the battery model, considering the current, SOC, response, is proposed, promoted, and popularized along
and terminal voltage constraints of the battery, thereby with the development of artificial intelligence. On the
obtaining the maximum charge and discharge power basis of some test data of the battery, the connection with
and the SOF/SOP. Plett117 proposed two methods to the state parameters is established to make prediction. It
estimate discharge and charge power that incorporate mainly includes neuro‐fuzzy approaches, SVM, regres-
voltage, SOC, and current of the battery: one was the sion technique, and other machine learning methods.
hybrid pulse power characteristic (HPPC) method; it Further analysis are as follows, such as artificial neural
used the open circuit voltage and internal resistance in network (AN),134 fuzzy neural network (FNN),135 support
the current state to estimate the instantaneous battery vector machine (SVM),136 relevant vector machine
SOP, and the other method based on SOC was obtained (RVM),137 autoregressive model (AR),138 and Gaussian
the limit current value by the maximum and minimum PROCESS REGRESSION (GPR).139 However, such algo-
SOC limits, thereby calculating the battery power state rithms rely on a large amount of experimental data for
over a period of time. And the method can accurately parameter integration to obtain better accuracy, resulting
predict the pack‐level available power by using an in long training time and low generalization ability. In
appropriate cell model and SOC information. Zhang addition, such research is mostly concentrated on single
et al118 also gave a method for estimating SOP from cell, and the prediction of the battery pack as a whole is
the battery cutoff voltage. It generally used a more accu- less, and correspondingly, the amount of data and algo-
rate dynamic battery model (ECM, combined model, rithm costs will also increase.
etc) to establish the state space equation of the battery
terminal voltage, SOC, current, and other parameters.
Then, the linearization was performed. The following 3.2 | Energy Equalization
solution was similar to the HPPC method. Finally, the
battery peak power in the current state was calculated The electric vehicle power batteries usually obtain high
through the maximum current under limit of cutoff voltage in series and high capacity in parallel. However,
voltage. due to internal reasons (the inconsistency of the physical
SHEN AND GAO 15
volume in manufacturing process) and external causes Compared with the voltage‐based equalization strat-
(temperature difference of the whole package, energy egy, the state of batteries can be better reflected by SOC.
imbalance caused by battery charge/discharge), the Owing to LiFePo4, battery has a relatively flat relation-
long‐term cycle will lead to a decrease in battery capacity ship between SOC and OCV; the SOC can be evaluated
and life without the equalization management. The on the basis of the tracking of OCV. Thus, Zheng
essence of the equalization is the redistribution of energy et al148 used the mean difference method to estimate the
among the cells. It includes the circuit topology and strat- consistency of the battery SOC by the first‐order equiva-
egy and complement each other. Topology is mainly lent circuit model. Besides, Zhang et al149 also used this
divided into dissipative type, such as resistance equaliza- mapping relation as a basis for battery equalization and
tion,140 and nondissipative type, such as capacitive equal- calculated the energy utilization ratio of batteries. Fur-
ization.141 In addition, there are equalization structures ther, the Thevenin ECM and the EKF algorithm were
with inductors and transformers.142,143 An excellent employed for SOC estimation of the battery in Ma
topology can achieve fewer components, more reliable et al.150 The two‐stage bidirectional equalization circuit
structure, and easier control. And the quality of the and the fuzzy logic control (FLC) were designed to
equalization strategy directly affects its efficiency. Equal- achieve the equalization between battery cells in the bat-
ization strategies fall into three aspects: voltage, SOC, tery pack. The diagram of the related method is shown in
and capacity equalization strategies. In the process of Figure 8. The proposed FLC algorithm was compared
R&D and production, the establishment of a battery with the traditional mean difference method to verify
model is fundamental and critical for reducing costs, the superiority of the developed one.
avoiding measurement errors of voltage and realizing Again, researchers have proposed an equalization
online acquisition of SOC and capacity.144 strategy on the basis of the total capacity, rechargeable
The early equalization strategy is mainly proposed for capacity, or releasable capacity, whose goal is to maxi-
lead‐acid battery. Since the voltage characteristic curve of mize the available capacity of the battery. Zheng
the lead‐acid battery has an obvious correspondence with et al151,152 built a first‐order ECM in SIMULINK and ver-
the remaining power,145 the correspondence relationship ified the effectiveness of the dissipative cell equalization
was used to judge the degree of the battery imbalance, (DCE) strategy with remaining charging capacity (RCC)
and the consistency of the final battery voltage was used as the online estimation target. Furthermore, according
as a criterion for equalization. So this method is simply to the battery voltage curve, a fuzzy logic DCE algorithm
referred to as voltage‐based equalization. Previous litera- was used to reduce the battery pack capacity deviation
tures141,146,147 used voltage as the judgment standard. effectively. In contrast, an active equalization approach
The measurable voltage, simple control algorithm, and on the basis of the available capacity of the battery was
low hardware requirements make this method be widely proposed to in Cui et al,153 which was derived from the
used in engineering. However, due to the existence of state space equation established by the second‐order
measurement error and hysteresis characteristics, it is dif- ECM. And a feedback balancing circuit was selected to
ficult to achieve accurate equalization control according modify the topology structure. The results showed that
to the voltage. And when voltage equalization is achieved the proposed equalization strategy had more excellent
in a single aspect, the other parameters of the battery are performance in improving the capacity of battery pack
still biased. than the other balancing benchmark methods. Moreover,
16 SHEN AND GAO
FIGURE 8 Diagram of the two‐stage equalization method based on fuzzy logic control (FLC) for battery packs150 [Colour figure can be
viewed at wileyonlinelibrary.com]
Diao et al154 presented a special active battery cell equal- temperature.156 Yang et al157 investigated the effects of
ization technique based on the maximum residual avail- radial spacing between batteries and gas flux on the ther-
able capacity, in which the change of internal resistance mal performance of the axial‐flow air cooling structure.
and capacity of a single cell in the battery pack was inte- Through the numerical simulation based on the P2D
grated by the Thevenin battery model. The DC/DC trans- model, the increase of the radial spacing made a better
former equalization structure was verified by analyzing temperature uniformity and a smaller average tempera-
the experimental results in energy utilization efficiency. ture rise of battery pack, but the space efficiency was
reduced. The liquid cooling is a relatively efficient and
compact, using water, oil, or coolant as the heat transfer
3.3 | Thermal management medium and the jackets or pipes on the bottom or side
of batteries to remove the heat. A two‐dimensional fully
Temperature is an essential parameter affecting battery coupled electrochemical‐thermal model for two different
performance. The methods of changing battery electrolyte cell designs (8 and 20 Ah) was simulated with both air
formulation or developing new positive and negative and liquid surface cooling in Bandhauer et al.158 Despite
materials cannot balance the high‐ or low‐temperature the liquid cooling significantly reduced peak temperature
performance, and the difficulties are serious for battery across the battery, it imposed the difference in tempera-
packs. Therefore, analysis of the heat generation mecha- ture. And as the cell size increased, liquid cooling exhib-
nism and temperature characteristics is of great signifi- ited an increased temperature gradient. Since liquid
cance for improving battery performance and safety. cooling is difficult to ensure the battery uniformity,
The battery model is not only to meet the detection PCM cooling has been proposed to improve the relative
demand of any temperature point but also to avoid the performance. Lazrak et al159 exploited 1D and 3D model-
problem of delay in temperature transfer during actual ling to analyze the effect of PCM thermo‐physical proper-
measurement and to facilitate the efficiency of BTMS. ties and define an improved design with PCM integration
The BTMSs have various structures and types, and the in battery packs, respectively. Although the conventional
common cooling methods are shown in Figure 9. PCM cooling can reduce the rise of temperature, the heat
The air cooling is simple in structure, low in cost, and absorbed by PCM cannot be effectively diffused to the
easy to install, which is widely used in electric vehicles.155 surroundings. Therefore, researchers have proposed a
For example, the Toyota Prius hybrid vehicle used a forced convection system in combination with PCM to
parallel air passage to adjust the battery system eliminate heat accumulation,160 or used composite phase
SHEN AND GAO 17
FIGURE 9 Common battery cooling methods and their pros and cons [Colour figure can be viewed at wileyonlinelibrary.com]
change materials to increase the PCM thermal conductiv- It is universally acknowledged that the heating mode
ity.161 What is more, the heat pipe BTMS is another com- of battery pack can be divided into external heating and
pact, light, and high‐efficiency alternative.162,163 Because internal heating. The former uses an external electric
the mechanism and process of two phase flow in heat heating devices, such as positive temperature coefficient
pipe are complex to model,164,165 studies are primarily (PTC) heater, to heat the battery pack.173 And the heat
based on experiment. Zou et al166 developed an integrated transfer mode used is the same as the above‐mentioned
thermal management structure that incorporates a heat cooling structure. The heat transfer medium can be air
pipe type BTMS with an air‐conditioning system to fulfill or liquid. Due to the existence of heat exchange with
the comprehensive heat domination for EVs. Notably, the external environment, some of the heat will be lost
some researchers have also proposed new BTMSs, such to the air and also may lead to the uneven temperature
as jet cooling167 and boiling cooling.168 More importantly, of batteries. The latter uses internal resistance heat by
due to insufficient vertical temperature gradient control the pulse current, which the temperature increase is
caused by external cooling strategies at high heat genera- faster and the consistency is better. Zhu et al174 indicated
tion, the internal cooling strategies were investigated to that except for the amplitude and frequency of current,
mitigate battery heat problems.169,170 Bandhauer et al171 the wave shapes also had an effect on the heating effi-
utilized a passive liquid‐vapor phase change heat ciency as well. For example, the sinusoidal current heated
removal inside micro‐channels embedded into the cell the battery from −24°C to 7.79°C, while the rectangular
to demonstrate the possible performance improvement pulse waveform was heated from −24°C to 25.6°C at the
based on a 3D electrochemical‐thermal model. Figure 10 same condition in their investigation. All of these
shows the maximum temperature rise and difference methods consume energy to heat the battery, thereby
for the internal cooling simulations as compared with sacrificing battery capacity.
the traditional air and liquid cooling reports in
Bandhauer et al.158 Based on the three‐dimensional ther-
mal swelling model with coupled thermo‐mechanical, Oh 3.4 | Fault diagnosis
and Epureanu172 indicated the elevated core temperature
and uneven temperature distributions play a vital role in If state estimation is the basis for other functions, then
the performance of the battery pack. This model is security is the common and most basic goal for all. Gen-
beneficial to the design thermal management of battery erally, the evolution mechanism of LIB safety is divided
packs, as well as the development of stress‐strain sensors into two cases. One is the reduction in reliability caused
and the optimal configuration. by self‐aging. As mentioned earlier, this is a slow process
18 SHEN AND GAO
FIGURE 10 Comparison of internal, air, and liquid cooling strategies at different compactness factors: A, maximum temperature; B,
maximum171 [Colour figure can be viewed at wileyonlinelibrary.com]
of change for the LIB aging mechanism. The other is a from the diagnostic object. Ouyang et al176 used the same
sudden failure of LIBs. With regard to technologies to method to analyze the short‐circuit fault in the battery. A
enhance battery safety, most of the safety techniques in recursive least square algorithm based on the mean
the former are related to the production of battery manu- difference model (MDM) deriving from ECM, which
facture. The latter is created by some unexpected events, consisted of the average and difference of a cell voltage
even a safety accident. The BMS is required to promptly and resistance, was employed. The algorithm first
warn of the failure that has occurred or will occur and estimated the basic parameters of the MDM, and then
give a corresponding response according to the severity calculated the characteristic values, like the voltage
(terminating battery charging or discharging, limiting differential and the fluctuation function of internal resis-
battery power or reporting alarm, etc). The LIB tance, and finally made short‐circuit diagnosis according
safety mutation mechanism mainly caused by external to the magnitude of fluctuation. For the LIBs, current
mechanical trigger (such as vibration, extrusion) and and voltage can only reflect the external characteristics,
environmental trigger (such as high temperature, high and the dynamics characteristics need to be described
humidity), causing short circuit of the battery, forming by internal state variables such as SOC and SOE. The
an electrical trigger (such as internal or external short diagnosis of these parameters can only be represented
circuit), which leads to a thermal trigger (such as by modeling, and see Section 3.1.
overheating) even thermal runway. Gradually, researchers found that the battery internal
According to the signal collected by BMS, the main resistance is sensitive to the battery health state or fault
faults of power system are as follows: voltage fault, cur- state, so some fault diagnosis methods based on resis-
rent fault, temperature fault, SOX fault, insulation fault, tance value have been born. Wang et al177 quantitatively
short‐circuit fault, and the like. These critical functions estimated the insulation resistances at anode and
rely deeply on measurements of embedded current and cathode, and troubleshooting was performed by the
voltage sensors. However, sensors may experience various change of insulation resistance value. Zhang et al178
forms of failures due to production defects, prolonged focused on the parallel‐connected battery group (PCBG)
exposure to wretched conditions, and external shocks. and used the PCBG resistance as a standard to identify
Liu and He175 proposed a valid model‐based fault PCBG faults and their causes. For an online aging incon-
diagnostic scheme to determine if there was current or sistency fault and a loose contact fault, the fault can be
voltage sensor issue. The EKF was applied to calculate detected by distinguishing the difference of the single
battery terminal voltage based on ECM, and the carrying resistance among PCBGs. In terms of the reasons of
fault signals were obtained by comparing the observed the problem, it was implemented by discriminated the
voltage with the evaluated. It also pointed out the con- changes in the PCBG resistance.
ventional method of the model‐based battery fault diag- Apart from the resistance, Feng et al179 extended the
nosis, which was to obtain residual signals and process diagnostic parameters and proposed a novel diagnosis
fault information by the difference between the model's approach for online internal short‐circuit detection. The
prior information and the measurement information method converted the battery voltage and temperature
SHEN AND GAO 19
into the inherent state (SOC) and parameter (ohmic resis- small error compared with the actual. The method did
tance), respectively, reflecting the incompatible capacity not identify state parameters of the battery during the
and heat loss. Kong et al180 also detected the short diag- diagnosis process and can be simply and credibly assem-
nosis according to the RCC variations between batteries. bled into the actual BMS. Unlike the usual fault diagnosis
The RCC of each cell can be obtained by the CC‐VC con- approaches, the fault severity was evaluated based on the
version, then the leakage current was obtained by the size of short‐circuit resistance. From another perspective,
change of RCC after each cycle, and it would be further Zhu et al181 developed a detailed finite element model to
turned into the short‐circuit resistance. The experimental cover the geometry and mechanical properties of almost
devices and results are depicted in Figure 11. We can see all components of a cell. Through the accurate analysis
that the normal and short‐circuit cell were distinguished of mechanical behavior, it found that a short circuit
obviously. The short‐circuit resistances varied little with occurred at a displacement of 4 mm during axial loading.
time, and the estimated average resistances had very In addition, Tsutsui et al182 further refined the failure
mechanism and pointed out that the mechanical defor-
mation alone could not predict battery failure well, and
both SOC and deformation need to be considered. At
low SOC, the electrical performance failure of the battery
was closely related to voltage drop, and it stood alone
against the external deformation stress. However, at high
SOC, a premature voltage drop was born, attributing to
the swelling phenomenon inside the battery and the ten-
dency of the anode and cathode contact.
4 | R &D OF BM S F U NCT I O NA L I T Y
AND I NTEGRATION IN VEHICLES
TABLE 7 Summary of the representative BMS Compared with the above system, the BMS system devel-
Manufacturers BMS Functions
oped by Korea Ajou University and Institute for
Advanced Engineering196 has fully considered the control
Mentzer Electronie GmbH and BADICOACH System and protection of charging/discharged, the calculation
Wemer Retzlatf in ●First vehicle–experiment
and display of SOC, thermal management, communica-
Germany183 ●Voltage, temperature and
current measurement of 20
tion with the PC and the motor controller, etc, as shown
batteries in Figure 12.
●Control of charging current of Based on the existing BMS techniques, there are more
charger and more studies focusing on the smart battery modules
●Single cell equalization (SBMs) to promote the development of a generalized
Tesla Motors184-187 ●Monitoring and Management design method. That is, a microcontroller is installed in
of 7104 Lithium Batteries a battery module and integrated with relevant circuits
●Acquisition and estimation of and then packaged them as a whole. A plurality of
voltage, current, SOC, and SBMs are connected to a main control module, and other
insulation signals
auxiliary devices are added to constitute a SBMs‐based
●Thermal management and
management system. Hong Kong University of Science
safety protection system
●Low cost passive equalization and Technology197 discussed the development of an orig-
inal BMS platform consisting of multiple local manage-
Bosch Rexroth Group188-191 ●Data stratified acquisition
●Radio network remote
ment units for power supply, voltage and current
transmission signal detection, and central management unit as an interface
●Invalid or depleted battery between internal BMS network and external components.
isolation system It can provide a full management to a pack with up to 16
●Startup or initialization batteries. And the military electric vehicle BMS developed
judgment by American Micron Corporation adopts this prototype
Axeon UK Ltd ●Transferring information to and Hnatczuk et al's.198
the host On the basis of the basic functions of BMS above,
●Data recording Chatzakis et al199 provided additional functions, a fault‐
●Diagnosis and prediction
tolerant capability and battery protection, with the same
●Error and alarm functions
structure, and Figure 13 shows a block diagram of this
AeroVironment SmartGuard System typical BMS topology. Zhu200 proposed an intelligent
●Distributed mode of collection
BMS with an updated system that inherited the functions
parameters
●Automatic overcharge
of the traditional BMS. This BMS was capable of storing
monitoring and analyzing the measurement data in order to detect
●Battery history and archiving battery failures and improve the battery safety by shorten-
●Provide information about the ing the measurement and communication time intervals.
worst cell Carkhuff et al201 applied multifrequency impedance mea-
Toyota Motor Corporation192- ●Suppress battery imbalance surement technology (1‐1000 Hz) to the BMS. Except for
194
●Judgment of battery the conventional voltage, temperature, and internal
maintenance and replacement impedance monitors, it can track faults associated with
needs anode, cathode, and electrolyte to identify battery mis-
matches and emerging faults. And real‐time monitoring
of changes in each battery was acted, including
charging/discharging, as well as at rest. Further, through
on the key technologies of on‐board BMS. Table 7 lists a physics‐based battery model, Prada et al202 studied the
some of the more representative R&D results. BMS specifications law that can be generalized to
Then again, some scientific institutions have also different lithium‐ion chemistries batteries. The model
made corresponding explorations. The University of can not only effectively implement the BMS traditional
Toledo195 presented a typical battery system. This partic- functions, including battery limitations in terms of
ular version included an electronic control unit (ECU) potential, current, temperature, and aging mechanism,
that monitored the battery pack real‐time situation and but also indicate the charge and discharge allowable cur-
assured the data collection, processing, and transmission. rent limit at different temperatures under safety and the
And an equalizer (EQU) balanced the charge levels of the SOC estimation for a given pulse duration according to
battery segments and controlled an onboard charger. vehicle operation.
SHEN AND GAO 21
FIGURE 12 Schematic structure of battery management system (BMS)196 [Colour figure can be viewed at wileyonlinelibrary.com]
FIGURE 13 Block diagram of a typical battery management system (BMS) topology199 [Colour figure can be viewed at wileyonlinelibrary.
com]
4.2 | Multicontroller interaction the supervision of the power source level. Externally,
BMS provides operating status of power batteries for the
Internally, BMS takes battery modules as the control whole vehicle and works in conjunction with other on‐
object to ensure their order and safety. It only realizes board controllers to ensure the optimization and
22 SHEN AND GAO
improvement of energy control management for vehicles. liquid thermal management system. And the cascade
This is a nonnegligible link in the development of estab- cooling was used to ensure the battery thermal safety.
lishing a complete BMS. For example, when the battery is in an overheated
The most used energy control management method state, the temperature curve of the test battery (18650)
for EVs in engineering is based on the stability of motor, from normal state to superheated state is as shown in
engine (HEVs), and other components, according to the Figure 14. Under adiabatic conditions, the battery initial
driver's acceleration and braking requirements, vehicle temperature was 25°C, and the temperature reached a
and battery status, etc to switch the power system maximum of 125°C at 4000 seconds. The side reaction
working mode. A vehicle power management system starts from 60°C and as it continues, the battery
was provided to minimize the number of components temperature changes from a proportional increase to
for the parallel connection of sub battery packs through an exponential one. When refrigerant was used to spray
integrating a power relay assembly (PRA) with a power the battery pack at 60°C, the temperature rising is effec-
distribution unit (PDU) by HYUNDAI Motor Co, Ltd.203 tively suppressed.
The integrated battery pack included sub‐relays placed Despite the rational construction of vehicle energy
in the sub‐battery packs, a sub‐BMS that controlled the management framework, the control strategy is also
sub relays, and a main BMS for managing the whole important to improve the energy‐saving level of the
power of the sub‐battery packs. The PDU included a electrification vehicles. The above control method for
PRA for selectively connecting voltages inputted from realizing the related functions is widely used in engineer-
the integrated battery pack with an electric load of a vehi- ing practice because it is effective, simple, and easy to
cle. Wang204 also disclosed a parallel charging and power implement. However, they cannot optimize the system
supply system for EVs, composed of multiple power operation and cannot fully utilize the energy‐saving
system and an energy storage system, to increase the trav- potential of EVs and HEVs. Therefore, intelligence
eling mileage of electric vehicles. The BMS was used for automobiles have become another important trend in
monitoring the voltage and the current of battery unit the development of EV industry. In recent years, due to
and realizing hybrid control on battery unit with a con- the great progress in technologies such as machine vision
version module. The interaction mode among MCU, and deep learning, the development of advanced assistant
VCU, and BMS was the same as the traditional form. driving and autonomous, or “self‐driving,” vehicle tech-
Unlike pure electric vehicle energy control management nologies has been promoted. At present, there are many
research, hybrid electric vehicles mostly focus on researches on vehicle environment perception,211,212
selecting and switching control strategies for pure electric intelligent driving, and interaction,213,214 but there are
mode, hybrid mode, engine working mode, and feedback few studies on applying intelligent technology to vehicle
braking mode. Combined with the user's requirements, energy‐saving control. Other than considering the fuel
BYD Company Ltd205 presented a control system based economy of the vehicle, Montazeri‐Gh et al215 also con-
on battery SOC as an automatic conversion standard. As sidered the impact of the control strategy on the vehicle's
for the technique whether the hybrid vehicle should tran-
sition between the EV mode or HEV mode, Kia Motors
Corporation206 checked the driver's requisite torque cal-
culated by monitoring the accelerator position sensor,
the gear position sensor, the determined engine on map
value, and the hypothetical map value.
In addition to the conventional power transmission
control, the battery pre‐charge communication,207 power
up and down of the whole vehicle,208 and so on are insep-
arable from the coordination of various controllers. Up to
present, the team has explored the battery modeling and
its application in battery thermal management, and the
communication and control between the heat pump sys-
tem and BTMS by BMS and VCU.209,210 On the basis of
conventional battery modeling, the SEI decomposition
in superheated state was considered, and the battery
model from normal to overheated under adiabatic condi-
tion was established. The based‐refrigerant cooling and FIGURE 14 Battery temperature curve [Colour figure can be
emergency jet cooling system was added to the common viewed at wileyonlinelibrary.com]
SHEN AND GAO 23
emission performance: According to the engine critical optimization to obtain an optimized EMS. Gong et al219
control line and the battery SOC, the working mode exploited ITS and neural networks to predict the trend
was divided into two steps. Firstly, the fuel consumption, of future vehicle speeds and then used dynamic program-
hydrocarbon, carbon monoxide, and nitrogen oxide emis- ming algorithms for energy optimization and power allo-
sions were normalized as the optimization target, then cation. Moreover, learning‐based energy management
genetic algorithm was used for optimization, and the strategies from recorded historical or driving data have
optimized control strategy was improved in fuel economy also been developed.220,221 The internet of vehicles can
and emission performance. Meanwhile, particle swarm transmit the vehicle and traffic information back to the
optimization (PSO),216 DIRECT algorithms,217 etc were cloud platform and then use the technologies such as
also used to optimize or adjust the relevant parameters cloud computing to learn and optimize EMS. Take HEV
of energy management strategy (EMS). Further, intelli- as an instance, Figure 15 discloses the key procedures of
gent information provided by global positioning system EMS in the vehicle control system and gives example of
(GPS)/intelligent transport system (ITS) also plays an future speed prediction. Obviously, whether learning
important role in energy management. Kim et al218 used from historical data or predictive information, these
GPS to predict future driving conditions and then used EMSs still require more precise control models and expert
dynamic programming algorithms for rolling experience. The development of these intelligent
FIGURE 16 Diagram of battery management system (BMS) from multiphysics modeling to multifunction application and integration
[Colour figure can be viewed at wileyonlinelibrary.com]
technologies has certain enlightening significance for the following guidance from the battery model to BMS
research of electric vehicles energy management. function application and integration.
Lithium‐ion power battery and its control technology Battery is a combination of electrochemistry science,
are either the key or the bottleneck of EV progress. Power materials science, thermal science, and mechanical sci-
battery is the core of energy output, and the control tech- ence. Regarding it as a multiphysics field is necessary
nology is integrated in the BMS. A set of vehicle control and an inevitable trend. There are several key issues
development process on BMS from multiphysics model- and challenges in the future construction of coupled
ing to multifunction application and integration is shown models for EVs and HEVs:
in Figure 16.
1. It improves the accuracy of battery lumped thermal
models. By referring to the internal mechanism to
5 | TASKS A ND CHALLENGES IN explain battery thermal phenomenon, the lumped
T H E FU T U R E model is modified and optimized, and the simple
and accurate online algorithm is integrated into the
As a link between power source and vehicle, state‐of‐the‐ BMS to identify and manage the battery internal
art algorithms and control approaches about BMS are and surface temperature.
developed and used in EVs in order to promote the 2. It is the organic combination of the circuit model and
innovation and development of new energy vehicle the mechanism model in battery electrical model.
techniques. Nevertheless, there is still a long way for The relationship between the equivalent components
BMS to go,3 and the user suspicion of the reliability of or fitting parameters and electrochemical parameters
BMS needs to be addressed through future research is established to obtain an electrical model that can
caused by the gap between laboratory tests and actual not only reflect the internal chemical characteristics
demands. In view of the synergistic improvement of but also retain the certain ability of fast and dynamic
BMS under complex conditions, this paper proposes the tracking.
SHEN AND GAO 25
3. It is the development of parameters of battery aging complex energy storage systems is a significant topic
model. By increasing other performance parameters for future research.
(such as overvoltage and heating rate) except for 4. A good trade‐off between BMS versatility and com-
capacity loss or internal resistance increase, the sta- plexity. The increasing requirements of luxury func-
tistics of the effect of complete parameters on aging tions, such as environment control and intelligent
are gradually realized. driving, create more obstacles for factories to develop
4. The mechanical model should be added to the cou- a BMS that enable to make system more appropriate
pling model in the form of mechanical while dealing with additional features.
internal/external stress or internal gas pressure equa- 5. BMS manufacturing standards. With the increasing
tion, so as to facilitate the establishment of a univer- demand of diversification, intelligence, and high‐
sal, modular model to switch the form for different end, a lot of manufacturers provide a BMS with
application conditions and battery material types. diverse specifications that enormously limit the
5. The adaptive model should be developed to update or industrial production and application of products.
modify itself and to realize more accurate on‐line Manufacturing standards are urgent to be established
model parameter identification and vehicle control. to develop a BMS with comprehensive functions,
6. The above problems are not only the situation faced anti‐interference, low‐energy, high integration for
by the single cell but also the battery pack needs to expanding cascade, and generality for promotion.
solve. Meantime, the random variability of the bat- 6. As a complex power machine, the electric vehicles
tery, the electric topology, the battery thermal man- need BMS to interact with VCU, MCU, and other
agement, etc should be taken into consideration. control units in real time. In this process, applying
The system model is combined with the aging propa- intelligent algorithms to the energy management of
gation dynamics to establish a battery system model electric vehicles is also an effective way to improve
on the basis of the performance and state parameter the energy utilization rate.
evaluation of individual cells.
Despite the upgrade of software technology, there is
The growing demand for EVs, user‐friendly functions, also lots of progress room for improving the hardware.
safety‐restricted design, wireless communication and etc The sensor layout is reasonable, the cost is low, and
are enormous innovations that offer a great deal of the overall detection balance is good; the sensor type
growth opportunities in this organic system, while there is complete, and the ultrasonic pulse diagnoses the
are several key issues and challenges in the process: internal electrochemical abnormality. What is more,
when the software algorithm is more difficult to sim-
1. In terms of traditional functions, the state estimation plify and the historical data storage is huge, the sensor
as the basic function should pay more attention to the based on the internet cloud computing is used to realize
accurate estimation under a wide range, multiple the remote data transmission, which greatly improves
temperature condition to meet the demand of full the hardware simplification of BMS. We can not only
operating mode. design EMSs based on intelligent algorithms but also
2. In order to achieve the improvement of charge and use advanced intelligent traffic information such
discharge efficiency, meanwhile, it is necessary to as GPS/ITS to predict road traffic information for a
take into account of minimizing the damage to the period of time in the future, thereby predicting the vehi-
battery itself during the process in equalization tech- cle speed, acceleration and deceleration behavior, and
nology. And the simplification of the equalization so on.
topology, the consideration of multiparameters algo- In recent years, autonomous driving technology is
rithm are necessary to avoid the overcharge and also rapidly developing, and many emerging automobile
overdischarge of batteries. enterprises generally develop autonomous driving sys-
3. Prediction and location of fault diagnosis. In the tems based on the EV platforms. The combination of
early period of the failure of the system, many fea- autonomous driving technology with the electrification
tures are not reflected. If the fault prediction of technology is bound to deal with the issue of coordinated
energy storage system can be realized by the weak control between the autonomous driving system and the
characteristics in the early stage, the fault of the sys- EV system. Determining how to analyze their coupling
tem can be detected as soon as possible. At the same relationship, how to build an integrated model of intelli-
time, battery packs consist of dozens or even hun- gent EVs, and how to carry out multisystem integrated
dreds of cells in series and parallel. Determining control of intelligent EVs, these problems are urgently
how to quickly locate faults and isolate them in needed for intelligent EVs, especially for self‐driving EVs.
26 SHEN AND GAO
Finally, the research and technology mentioned is algorithm. Meanwhile, the model built by the influence
mainly for LIB (traditional LIB). There are still many of aging phenomenon and mechanical stress is a more
efforts on new high‐energy density systems, like solid‐ comprehensive and realistic consideration of batteries
state LIB with high safety, replacing current organic elec- and is also a requirement for the development of the bat-
trolytes and separators,222 high‐temperature NAS battery, tery modeling technology in the future.
ZEBRA battery with low cost and long life, lithium‐sulfur Furthermore, this paper, on this basis, has deepened
battery with friendly environment,223 and price and the application and development of BMS. It involves the
metal‐air battery without charging.224 Among them, the acquisition of unmeasurable state parameters, the
core technology of high‐temperature NAS batteries is expansion of the equalization index except voltage for
ceramic preparation and high‐temperature insulation. It optimal battery status, the avoidance of temperature
is widely used in the infrastructure construction of transfer delay for timely thermal management, and the
large‐scale storage,225 stable power grid, and emergency improvement of diagnostic accuracy for vehicle safety.
energy supply. At present, the NAS battery produced by Among them, the battery state estimation is the basis
Japan NGK Corporation has a relatively complete for the operation of the other functions of BMS, and
management system. It can realize continuous remote the accuracy of prediction results will directly affect
monitoring and 3‐year thorough inspection, reaching the normal implementation of the management system.
unattended and fully automated state.226 ZEBRA battery, Meanwhile, SOC or capacity as an equalization standard
also with a high‐temperature system, is used in automo- for engineering, reasonable coupling of advanced battery
bile. It is a fully enclosed system that includes packaging thermal management system with other systems, such
and essential BMS, providing an interface to VCU.227 The as air‐conditioning and motor thermal management sys-
industrialization of the remaining battery systems has tem, as well as location, isolation or alarm after fault
had some application obstacles at present. The solid‐state determination still need to continue to explore. Besides,
LIB mainly depends on the breakthrough of material the appropriate selection of model and algorithms
technology, ie, the mature preparation technology of solid should be reflected in accordance with the relevant
electrolyte membranes. The key to the development of conditions.
ZEBRA battery is the solution for low conductivity and Last but not the least, this paper has reviewed the
volume change of sulfur, and the “shuttle” of lithium development of the multifunctional integrated battery
sulphide. Most metal‐air battery is the issue of electrode management system, combining with other on‐board
corrosion and self‐discharge. The research of energy controllers and intelligent technology, to form a complete
storage equipment has never been interrupted, and idea from multiphysics modeling simulation to multi-
commercialization and industrialization will be gradually function integrated technology. The higher the sophisti-
realized through continuous in‐depth research and opti- cated functional requirements, the greater the
mization design. computational burden. Consequently, a generalized
development rule or manufacturing standard about BMS
is waiting to be solved. It puts forward several reasonable
6 | CONCLUSION suggestions to realize the synergetic efficiency of the BMS
under the diversified and intricate conditions and to pro-
There are a multitude of researches and technologies in mote the innovation and development of new energy
the field of BMS range from the simplest monitoring to vehicles from electrification to intelligence.
a complex controller. Consequently, a large number of
papers on this topic have been published in the art, and
A C KN O WL ED G EME N T S
some of them are analyzed in this review.
First and foremost, this paper has summarized The authors gratefully acknowledge the financial fund of
techniques of battery modeling from a multiphysics the National Natural Science Foundation of China
perspective. Among them, the thermal model is mostly (NSFC) Key Program (No. U1864213). This research is
coupled with the electrical model for modeling. When also supported by the financial fund of the industry
coupled with the equivalent circuit model, it is mostly innovation from Jilin Province Development & Reform
used in the electric vehicle management system, while Commission (High‐tech Industry Special Project No.
with the electrochemical model, it is common in the 2016C022) and the Science and Technology Key Project
internal characteristics research of the batteries. from Changchun Municipal Administration of Science
Advances in improving and reducing electrochemical &Technology (Double Ten Special Project no. 17SS022).
models will certainly be a strong candidate for further Last but not the least, special thanks to Dr Yan Wang
increasing the accuracy while ensuring a simple and Dr Tianshi Zhang for their careful teaching and help.
SHEN AND GAO 27
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