Air Pollution Management Overview
Air Pollution Management Overview
Tribhuvan University
Kirtipur, Kathmandu, Nepal
Enna Mool
15 November, 2021
Unit 1. Management of Air Pollution
1.1 Introduction to air quality criteria: Exposure to air pollution, Evaluating
exposure-response relationships, Formulation of air quality criteria or
guidelines, Criteria for endpoints other than for carcinogenicity, Criteria for
carcinogenic end points, Ecological effects
• Specially designed for the welfare of both human health and environment
• Guaita, R., Pichiule, M., Maté, T., Linares, C., & Díaz, J. (2011). Short-term impact of particulate matter (PM2. 5) on respiratory
mortality in Madrid. International journal of environmental health research, 21(4), 260-274.
Particulate Matter
• Sources
➢ Combustion of wood and fossil fuels
➢ Construction and demolition activities
➢ Entrainment of road dust into the air
➢ Agricultural operations
➢ Industrial processes
➢ Forest fires
Carbon Monoxide (CO)
• Silent killer
• Toxic gas which is colorless, odorless and tasteless
• Sources
➢ Incomplete combustion of fossil fuels
• When inhaled, binds with haemoglobin
• Reduces the amount of oxygen transported in the blood stream to
critical organs like the heart and brain
Nitrogen Dioxide (NO2)
• Reddish-brown pungent irritating toxic gas
• Sources
➢ Incomplete combustion of fossil fuels
➢ Making of nitric acid, welding and using explosives, refining of petrol
and metals, commercial manufacturing, and food manufacturing
➢ React with other gases in the atmosphere to form nitric acid
Sulfur Dioxide (SO2)
• Colorless but nasty toxic gas
• Sources
➢ Incomplete combustion of fossil fuels or other materials that contain
sulfur
➢ Power plants, metals processing and smelting facilities
• It reacts easily with other substances to form harmful compounds
such as sulfuric acid and sulfate particles.
Ground Level Ozone (O3)
• Colorless and highly irritating gas that forms just above the earth's
surface (up to about 2 miles above ground)
Figure 4. Flow diagram illustrating the process by which the EPA administrator reviews and sets a new NAAQS.
CASAC refers to the Clean Air Scientific Advisory Committee. Diamonds are used to denote official actions by
the administrator. SOURCE: Greenbaum et al. 2001. Reprinted with permission from the American Journal of
Epidemiology; copyright 2001, Oxford Press.
Air Pollutants Concentration
• ppm: part per million
• pphm: part per hundred million
• ppb: part per billion
• ppt: part per trillion
Air Pollutants Concentration
• Particulate matter: mg/m3 or ug/m3
• Nitrogen dioxide, 1 ppb = 1.91 ug/m3
• Sulphur dioxide, 1 ppb = 2.66 ug/m3
• Ozone, 1 ppb = 2.0 ug/m3
• Carbon monoxide, 1 ppb = 1.16 ug/m3
• Benzene, 1 ppb = 3.24 ug/m3
Exercise
1. CO concentration is given as 90 mg/m3 at 90oC and 6 atm. Express this
concentration in parts per million (ppm). (Ans: 15.94)
2. The air quality for nitrogen dioxide in Delhi is 470 ug/m3 at 25oC and 1
atm of pressure. Find the concentration of NO2. (Ans: 0.2498)
3. The exhaust from a car contains 1.5% by volume of CO. Compute the
concentration of CO in mg/m3 at 25oC and 1 atm of pressure. (Ans: 1.717
*104)
4. For an SO2 emission of 22000 kg/day and an exhaust gas flow rate of 5.0
million m3/hr (after the scrubber) measured at 150oC and 1 atm of
pressure, calculate the concentration (ppm) of SO2 the exhaust gases.
(Ans: 99.42)
Exposure to Air Pollution
• Exposure, in a generic form, as the contact between an agent (e.g., a
pollutant) and a target (e.g., a human lung) (Zartarian et al., 1997)
• Exposure can exist without dose but not a dose without an exposure
• Zartarian, V. G., OTT, W. R., & Duan, N. (1997). A Quantitative Definition of Exposure and Related. Journal of Exposure Analysis
and Environmental Epidemiology, 7(4), 411-437.
Figure 4. Graphical representation of the exposure and dosage received by person i at
location (x,y,z) and time t~ to a pollutant in a carrier medium with concentration C(x,y,z,t,)
(Ott, 1982)
• Ott, W. R. (1982). Concepts of human exposure to air pollution. Environment International, 7(3), 179-196.
Exposure to Air Pollution
Figure 5. Air pollution system conceptualized continuum from source to human health
effects (Lioy, 1990; Smith, 1993; Lioy, 1999)
• Lioy, P.J. (1990) Assessing total human exposure to contaminants. Environ. Sci. Technol. 24, 938–945.
• Smith, K.R. (1993) Fuel combustion, air pollution exposure, and health: the situation in developing countries. Annu. Rev.
Energy Environ. 18, 529–566.
• Lioy, P.J. (1999) The 1998 ISEA Wesolowski Award lecture – exposure analysis: reflections on its growth and aspirations for its
future. J. Exposure Anal. Environ. Epidemiol. 9, 273–281.
Exposure to Air Pollution
• Personal air pollutant intake related to a series of environment-
human interaction processes, including human contacting with the air
pollutants, the concentration of the pollutants over space and time,
and the absorption of the pollutants by human body
• Weisel, C. P. (2002). Assessing exposure to air toxics relative to asthma. Environmental health perspectives, 110(suppl 4), 527-
537.
Exposure to Air Pollution
• But other routes are often involved. For example, suspended dust
may be inhaled, but settled dust may be ingested when it deposits on
food or semi volatile air pollutants may sorb to surfaces whereupon a
person’s skin, eyes, and nose come into contact with what was
previously an air pollutant
• Silverman, R. A., & Ito, K. (2010). Age-related association of fine particles and ozone with severe acute asthma in New York
City. Journal of Allergy and Clinical Immunology, 125(2), 367-373.
• Monn, C. (2001). Exposure assessment of air pollutants: a review on spatial heterogeneity and indoor/outdoor/personal
exposure to suspended particulate matter, nitrogen dioxide and ozone. Atmospheric environment, 35(1), 1-32.
People spend varying amounts of time
indoors and outdoors in numerous
locations. Each person has a unique
exposure profile due to varying airborne
concentrations of pollutants and time
spent in each microenvironment. In
addition, unique characteristics of the
person and activity, eg, breathing rate,
also change the amount of pollutant
absorbed, which leads to a unique dose of
the pollutant. In this case, the exposure (E)
equation includes the sum of all exposure
events (j), which are each the mean
concentration (C) integrated with respect
to time of the event j per exposure
duration (T) (Ozkaynak, 2009)
Figure 6. Various scales of air pollution that contribute to personal exposures (Ozkaynak, 2009)
• Ozkaynak, H. (2009). Case Study Applications of Human Exposure Models, in Eurotox 2009 Conference, WHO/IPCS CEC6
Exposure Assessment Course, Dresden, Germany.
Exposure Assessment
• A process of quantitatively characterizing the relationship between
the dose of an agent and the magnitude or incidence of an adverse
health effect
• Lioy, P.J. (1990) Assessing total human exposure to contaminants. Environ. Sci. Technol. 24, 938–945.
Exposure Assessment
• Quantitative or qualitative evaluation of that contact; it describes the
intensity, frequency, and duration of contact, and often evaluates the
rates at which the chemical crosses the boundary (chemical intake or
uptake rates), the route by which it crosses the boundary (exposure
route; e.g., dermal, oral, or respiratory), and the resulting amount of
the chemical that actually crosses the boundary (a dose) and the
amount absorbed (internal dose)
Exposure Assessment
• One of the four key components in health risk assessment
• Long-term effects
▪ Last for years or for an entire lifetime or even lead to person’s death
▪ Include illnesses like heart disease; lung cancer; respiratory diseases;
long-term damage to people’s nerves, brain, kidneys, liver; cause
birth defects
Effects from Exposure to Air Pollution
Pollutant Health Effects
Particulate Matter Aggravates respiratory illnesses; long-term exposure may cause increased incidence of
chronic conditions such as bronchitis; linked to heart disease; suppresses immune system;
cause cancer or other tissue damage
Carbon monoxide Reduces blood’s ability to transport oxygen; headache and fatigue at lower levels; mental
impairment or death at high levels
Nitrogen Dioxide Irritate respiratory tract; respiratory disease particularly asthma, heart disease; suppresses
immune system; cause cancer or other tissue damage
Sulfur Dioxide Irritate respiratory tract; long-term exposure may cause increased incidence of chronic
conditions such as bronchitis; linked to heart disease; suppresses immune system; cause
cancer or other tissue damage
Ground level ozone Irritate eyes; irritates respiratory tract; produces chest discomfort; aggravates respiratory
conditions such as asthma and chronic bronchitis
Lead Neurological; kidney; gastrointestinal; cardiovascular; reproductive; developmental effects;
immune system
Air pollution & cardiovascular injury:
Epidemiology, Toxicology, and Mechanisms
(Simkhovich et al., 2008)
• Simkhovich, B. Z., Kleinman, M. T., & Kloner, R. A. (2008). Air pollution and
cardiovascular injury: epidemiology, toxicology, and mechanisms. Journal
of the American College of Cardiology, 52(9), 719-726.
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of NOAEL/LOAEL
➢Criteria for selection of adverse effect
➢Criteria for selection of uncertainty factors
➢Criteria for selection of averaging times
➢Criteria for consideration of sensory effects
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of NOAEL/LOAEL
• While setting guidelines, the NOAEL must be the highest level of
exposure at which no adverse effects are detected
• It is difficult to be sure that this has been identified unless the level of
exposure at which adverse effects begin to appear has also been
defined
• The level of exposure of concern in terms of human health is more
easily related to the LOAEL, and this level was therefore used
whenever possible
No Observed Adverse Effect Level (NOAEL) – Highest dose at which there was not an observed toxic or adverse effect
Lowest Observed Adverse Effect Level (LOAEL) – Lowest dose at which there was an observed toxic or adverse effect
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of NOAEL/LOAEL
• There are several factors (species, sex, age, strain, development
status, group size, sensitivity of applied methods, selection of dose
levels) that can influence the magnitude of the observed values
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of adverse effect
• Definition of a distinction between adverse and non-adverse effects
poses considerable difficulties
• Adverse effect is “any effect resulting in functional impairment and/or
pathological lesions that may affect the performance of the whole
organism or which contributes to a reduced ability to respond to an
additional challenge”
• A significant degree of subjectivity and uncertainty remains
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of adverse effect
• To resolve this difficulty, the evidence ranked in three categories
▪ The first category comprises observations which were not used as a
basis for guideline values
▪ The second category is a lowest-observed-effect level (or no-
observed-effect level) that is supported by other scientific
information
▪ The third category comprises levels of exposure at which there is
clear evidence for substantial pathological changes and have a major
influence on the derivation of the guidelines
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of uncertainty factors
• A guideline derived from studies of effects on laboratory animals in
the absence of human studies generally requires the application of an
increased uncertainty factor
• Human may be more susceptible than laboratory animal species
• Negative data from human studies will tend to reduce the magnitude
of this uncertainty factor
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of uncertainty factors
• Scientific judgement about uncertainty factors should take into
account the biochemical toxicology of pollutants which includes the
types of metabolite formed, the variability in metabolism or response
in humans suggesting the existence of hypersusceptible groups, and
the likelihood that the compound or its metabolites will accumulate
in the body.
• Environmental Health Criteria No. 170 (1) was a valuable source of
information
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of uncertainty factors
• When the database is strong, expert judgement can be used to set a
guideline which indicates the low level of uncertainty
• If the database is weak, then a larger level of uncertainty will exist. At
this time, a standardized approach will be used. For this, application
of a substantial uncertainty factor will be involved
Criteria for endpoints other than for carcinogenicity
➢Criteria for selection of averaging times
• Toxicity is a complex function of the interaction between
concentration of a pollutant and duration of exposure
• The damaged can be caused by both short term exposures to high
concentration as well as by long-term exposures to low concentration
• The specified averaging times are based on effects on health
• Short-term averaging times are recommended if the short-term
exposures lead to adverse effects
• Long-term averaging period are recommended based on the
knowledge of the exposure-response relationship
Criteria for endpoints other than for carcinogenicity
➢Criteria for consideration of sensory effects
• Intensity, quality, acceptability, annoyance and their respective levels
considered for the evaluation of sensory effects
• Intensity, where the detection threshold level is defined as the lower
limit of the perceived intensity range (by convention the lowest
concentration that can be detected in 50% of the cases in which it is
present);
• Quality, where the recognition threshold level is defined as the lowest
concentration at which the sensory effect, such as odour, can be
recognized correctly in 50% of the cases; and
Criteria for endpoints other than for carcinogenicity
➢Criteria for consideration of sensory effects
• Acceptability and annoyance, where the nuisance threshold level is
defined as the concentration at which not more than a small
proportion of the population (less than 5%) experiences annoyance
for a small part of the time (less than 2%); since annoyance will be
influenced by a number of psychological and socioeconomic factors, a
nuisance threshold level cannot be defined on the basis of
concentration alone
• The problems of irritation (for example, of the skin) and headache
were also considered as possible problems of annoyance
Criteria for carcinogenic endpoints
• Cancer risk assessment basically involves qualitative assessment of
how likely it is that an agent is a human carcinogen, and a
quantitative assessment of the cancer risk that is likely to occur at
given levels and duration of exposure
➢Qualitative assessment of carcinogenicity
➢Quantitative assessment of carcinogenic potency
Criteria for carcinogenic endpoints
➢Qualitative assessment of carcinogenicity
• A substance is considered as a carcinogen based on the qualitative
evaluation of all available information on carcinogenicity, ensuring
that the association is unlikely to be due to chance alone
Criteria for carcinogenic endpoints
➢Qualitative assessment of carcinogenicity
• International Agency for Research on Cancer (IARC) have been applied
for the classification criteria
• Group 1: Proven human carcinogen
• Group 2A: Probably carcinogenic to humans
• Group 2B: Possibly carcinogenic to humans
• Group 3: Not classifiable as to its carcinogenicity to humans
• Group 4: Noncarcinogenic to humans
Criteria for carcinogenic endpoints
➢Quantitative assessment of carcinogenic potency
• It includes the extrapolation of risk from relatively high dose levels to
relatively low dose levels
• High dose levels are characteristic of animal experiments or
occupational exposures where cancer responses can be measured
• Low dose levels are concern with environmental protection where
such risks are too small to be measured directly, performed either by
animal studies or by epidemiological studies
Criteria for carcinogenic endpoints
➢Quantitative assessment of carcinogenic potency
• The risk associated with lifetime exposure to a certain concentration
of a carcinogen in the air has been estimated by linear extrapolation
• The carcinogenic potency can be expressed as the incremental unit
risk estimate
• The incremental unit risk estimate for an air pollutant is defined as
“the additional lifetime cancer risk occurring in a hypothetical
population in which all individuals are exposed continuously from
birth throughout their lifetimes to a concentration of 1 μg/m3 of the
agent in the air they breathe”
Ecological Effects
Hazardous Air Mercury, dioxins Direct toxic effects to Conservation of mercury and dioxins in
Pollutants (HAPs) animals. biogeochemical cycles and accumulation
in the food chain. Sublethal impacts.
Air Pollution Control Philosophies
• Air pollution control depends on four basic philosophies
1. Emission standards
2. Air quality standards
3. Emission taxes
4. Cost benefit standards
Air Pollution Control Philosophies
1. Emission standards
• Maximum possible or practical degree of emission control exists
• It varies between various classes of emitters however presumably can
be determined for each
• This philosophy considered as cleanest possible air
• The maximum emissions of different classes will keep the pollution
emission rate at lowest possibility and each class is required to limit
emissions to this maxima
Air Pollution Control Philosophies
2. Air quality standards
• A limit on the amount of a given pollutant in the air
• It is usually enshrined in national (or federal) law and are legally
binding
• It is considered to be the level of an air pollutant such as
concentration that is adopted by a regulatory authority as
enforceable
• The effect based level and the averaging time have to be specified in
the formulation of a standard
• Primary standards provide public health protection, including
protecting the health of "sensitive" populations such as asthmatics,
children, and the elderly
Air Pollution Control Philosophies
• Secondary standards provide public welfare protection, including
protection against decreased visibility and damage to animals, crops,
vegetation, and buildings
• AQS at the national level, a legislative framework usually provides the
basis for the evaluation and decision-making process
• Standards setting strongly depends on the type of risk management
strategy adopted
❖Identification and selection of pollutants to which the legislative
instrument will apply
Air Pollution Control Philosophies
❖The numeric value of the standards for the various pollutants,
applicable detection methods and monitoring methodology, etc.
should be published
❖Actions to be taken to implement the standard, considering emission
control measures and necessary
❖The departmental process for making decisions about the
appropriate standards
• AQS is incorporated in CAA
• AQS is a Zero-damage philosophy
• Review- NAAQS, criteria pollutants
Advantages and Disadvantages of Air Quality
Standards
• The cost-effectiveness is good but not excellent
• It has the advantages of concentrating pollution control investments
in the areas with the worst air pollution problems and also allows
lower pollution control costs in areas with less serious problems
• However, once a set of air quality standards is set in place, the
standards must be met everywhere even in areas people seldom or
never visit
Advantages and Disadvantages of Air Quality
Standards
• The flexibility is fair as the standards can be met by multiple ways
• Each national or local agency can formulate its best considered
regulations within limits
• Special cases and emergencies can be handled locally
Advantages and Disadvantages of Air Quality
Standards
• The evolutionary ability is fair as standards can be changed based on
new data.
• However, its expensive as well as time consuming
• For more detail,
Nevers, N. D. (1977). Air pollution control philosophies. Journal of the
Air Pollution Control Association, 27(3), 197-218.
Air Pollution Control Philosophies
3. Emission taxes
• This philosophy would tax each emitter of major pollutants based on
some published scale related to its emission rate
• Economic tool based on polluters pay principle
• The tax rate is arranged in the way that the major polluters would find
it economical to install pollution control equipment rather than
paying taxes
Air Pollution Control Philosophies
4. Cost benefit standards
• The cost of damage goes high while the cost of pollution control goes
low with the higher level of concentration of a pollutant permitted in
ambient air
• It reflects acceptance level of damage following the amount willing to
be spend to reduce the damage
Adoption of Standards/Guidelines
• The National Ambient Air Quality Standards (NAAQS), US EPA 2015
• Typical Levels of PM10 & CO in Developing Country Homes with WHO
& USEPA Guidelines
• WHO Air Quality Guideline, 2005 (Global Update)
– Interim Targets for Particulate Matter, Annual Mean
Concentration; WHO Interim Targets for Particulate Matter, 24 - Hour
Concentration; WHO Interim Targets for Ozone, 8 – Hour
Concentrations; WHO Interim Targets for Sulfur Dioxide
• WHO Guidelines for Indoor Air Quality: Selected Pollutants, 2010
Adoption of Standards/Guidelines
• Guidelines for Air Pollutants with Carcinogenic Health Endpoints
• Guidelines for Air Pollutants with Non - Carcinogenic Health
Endpoints
• Classification of Toxic Compounds
• EU Directives, Air Quality Standards (2008)
• All EPA Emission standards, 2016
• EURO Emission Standards (Euro VI)
Air Pollution Control Strategy
• It is a set of specific techniques and measures identified and
implemented to achieve reductions in air pollution to attain an air
quality standard or goal
• It helps to improve the air quality providing a framework that includes
following activities
➢Realistic but challenging objectives
➢Regulation and financial incentives to help achieve the objectives
➢Analysis of costs and benefits
➢Monitoring and research to increase our understanding
➢Information to raise public awareness
Air Pollution Control Strategy
Motives of Control Strategies includes
• Prudent use of natural resources without compromising promotion
and conservation of environmental components
• Healthier lifestyle
• Economic and social growth
Factors in Designing an Effective Air Quality Control Strategy
Environmental Engineering Economic
Ambient air quality Pollutant characteristics Capital cost, operating
conditions, relevant (such as abrasiveness, costs, equipment
meteorological reactivity and toxicity), maintenance, equipment
conditions, location of the gas stream lifetime, and
emissions source, noise characteristics, administrative, legal, and
levels, and any ancillary performance enforcement costs.
pollution from the control characteristics of the
system itself control system, and
adequate utilities (for
example, water for wet
scrubbers)
Air Pollution Control Strategy
Steps in Developing a Control Strategy
• Determine priority pollutants
• Identify measures to control sources of pollution
• Incorporate the control measures
• Public involvement
• Compliance and enforcement programs
Guidelines
• Recommendation or guidance on the protection of human beings or
receptors in the environment from the adverse effects of air
pollutants
Location: CDES
Accessed on November 17, 2021
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