Page 1/8

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: Aqua-clean
· Article number: 140211001
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
Cleaning and disinfection product for water and liquid feed systems.
· Application of the substance / the mixture
Cleaning and disinfection product for water and liquid feed systems.
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Kanters Special Products BV
De Stater 32
NL-5737 RV LIESHOUT
THE NETHERLANDS
Tel.: +31 (0) 499 425 600
Fax: +31 (0) 499 425 610
E-mail: info@[Link]
· Further information obtainable from: Product safety department.
· 1.4 Emergency telephone number:
+31 (0)499 425 600

In case of an emergency:
National Poison Information Centre.
Tel.: +31 (0)30 274 88 88.
(Restricted to inform professionals in case of acute poisoning.)

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS03 flame over circle

Ox. Liq. 2 H272 May intensify fire; oxidiser.

GHS05 corrosion

Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

STOT SE 3 H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R22: Harmful if swallowed.

Xi; Irritant
R37/38-41: Irritating to respiratory system and skin. Risk of serious damage to eyes.
(Contd. on page 2)
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 Page 2/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 1)

O; Oxidising
R8: Contact with combustible material may cause fire.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS03 GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labelling:
hydrogen peroxide solution
· Hazard statements
H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P221 Take any precaution to avoid mixing with combustibles.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
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 Page 3/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 2)
· Dangerous components:
CAS: 7722-84-1 hydrogen peroxide solution 25-50%
EINECS: 231-765-0 C R35; Xn R20/22; O R8
R5
Ox. Liq. 1, H271; Skin Corr. 1A, H314; Acute Tox. 4, H302;
Acute Tox. 4, H332
· Additional information: For the wording of the listed risk phrases refer to section 16.

* SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.

* SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Not required.
· 6.2 Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
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(Contd. on page 4)

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 Page 4/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 3)

* SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility:
Store away from reducing agents.
Store away from flammable substances.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s)
This product should only be used as a cleaning and disinfection product for water and liquid feed systems.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
7722-84-1 hydrogen peroxide solution
WEL Short-term value: 2.8 mg/m³, 2 ppm
Long-term value: 1.4 mg/m³, 1 ppm
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
(Contd. on page 5)
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 Page 5/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 4)
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

· Body protection:
Protective work clothing
Use protective suit.

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Colourless
· Odour: Pungent
· Odour threshold: Not determined.
· pH-value at 20 °C: > 1.5
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 114 °C
· Flash point: Not applicable.
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Not determined.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1.19 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Fully miscible.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
(Contd. on page 6)
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 Page 6/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 5)

· Solvent content:
Water: 50.0 %
· 9.2 Other information No further relevant information available.

* SECTION 10: Stability and reactivity

· 10.1 Reactivity Stabil under normal conditions.
· 10.2 Chemical stability Stabil under normal conditions.
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions Reacts with reducing agents.
· 10.4 Conditions to avoid High temperatures.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: Oxygen

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Strong irritant with the danger of severe eye injury.
· Sensitisation: No sensitising effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
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 Page 7/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 6)

· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

* SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN2014
· 14.2 UN proper shipping name
· ADR 2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTION
· IMDG HYDROGEN PEROXIDE, AQUEOUS SOLUTION,
MARINE POLLUTANT
· IATA HYDROGEN PEROXIDE, AQUEOUS SOLUTION
· 14.3 Transport hazard class(es)
· ADR, IATA

· Class 5.1 Oxidising substances.

· Label 5.1+8
· IMDG

· Class 5.1 Oxidising substances.

· Label 5.1+8
· 14.4 Packing group
· ADR, IMDG, IATA II
· 14.5 Environmental hazards:
· Marine pollutant: Yes
Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Oxidising substances.
· Danger code (Kemler): 58
· EMS Number: F-H,S-Q
· Segregation groups Peroxides
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code E
(Contd. on page 8)
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 Page 8/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.03.2015 Version number 4 Revision: 04.03.2015

Trade name: Aqua-clean

(Contd. of page 7)

· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· UN "Model Regulation": UN 20 14 , H YD R O GE N P E R O X I DE , A QU E O US
SOLUTION, 5.1 (8), II

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H271 May cause fire or explosion; strong oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
R20/22 Harmful by inhalation and if swallowed.
R35 Causes severe burns.
R5 Heating may cause an explosion.
R8 Contact with combustible material may cause fire.
· Department issuing MSDS: Product safety department.
· Contact: Mr. Derksen
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
Ox. Liq. 1: Oxidising Liquids, Hazard Category 1
Ox. Liq. 2: Oxidising Liquids, Hazard Category 2
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· * Data compared to the previous version altered.
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