XII-NEET : 2023-24

The Leader In Chemistry ..... Chemistry- Test No.: 29

• Chemical Bonding•
Date Time No. Of MCQs Marks

RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *
10/03/2024 60 mins. 50 180 (+4, –1)
6. Carbon atoms in C2(CN)4 are:
“Stethoscope is the only jewellery 1) sp hybridized
that can’t be earned by money. 2) sp2 hybridized
It can only be earned by 3) sp and sp2 hybridized
Passion and Hard-work”
4) sp, sp2 and sp3 hybridized
7. In which of the following case lst bond is
stronger than 2nd one.
SECTION : A 1) s – s, px – px(x is bonding axis)
2) py – py, px – px (z is bonding axis)
1. BeCl2 + 2Cl– 
 [BeCl4]–2
3) py – py, pz – pz (z is bonding axis)
The total number of vacant orbitals present on
central atom in [BeCl4]–2 is: 4) py – py, pz – pz(y is bonding axis)
1) Two 2) Three 8. Statement - I : NCl3 exists but NCl5 does not.
3) Four 4) Zero Statement - II : PCl3 and PCl5 both exist.
2. Match the Column
Column I Column II 1) Both Statement I and Statement II are correct
a. AlF3 i. Hypovalent 2) Both Statement I and Statement II are
b. AlCl3 ii. Hypervalent incorrect
c. SF6 iii. Complete octet 3) Statement I is correct but Statement II is
d. PBr3 incorrect
1) a-iii, b-iii, c-ii, d-i 2) a-i, b-iii, c-ii, d-i
4) Statement I is incorrect but Statement II is
3) a-iii, b-i, c-ii, d-iii 4) a-ii, b-i, c-iii, d-ii
correct
3. The central atom in IF 7 has seven pairs of
valence electrons. The shape of the molecule 9. The hybridisation of nitrogen in NO2+, NO3–
as per VSEPR theory is and NH4+ are respectively
1) Trigonal bipyramid 1) sp, sp3, and sp2 2) sp, sp2, and sp3
2) Hexagonal pyramid 3) sp2, sp and sp3 4) sp2, sp3 and sp
3) Pentagonal bipyramid
10. Which of the following is steam volatile
4) Square bipyramid
4. In OF2 molecule, the total number of bond 1) Phenol 2) o - Nitrophenol
pairs and lone pairs of electrons are 3) m - Nitrophenol 4) p - Nitrophenol
respectively
11. In the anion HCOO–
the two carbon – oxygen
1) 2, 6 2) 2, 8 bonds are found to be of equal length. What is
3) 2, 10 4) 2, 9 the reason for it ?
5. Which of the following gives rise to formation
1) Electronic orbitals of carbon atom are
of bond.
hybridised.
2) The C=O bond is weaker than the C–O
1) 2) bond
3) The anion HCOO – has two resonating
structures
4) The anion is obtained by removal of a proton
3) 4) None of these. from the acid molecule.

Prof. Motegaonkar S. R. [Link]. Che. Gold Medalist, SET/NET--JRF, GATE, BARC,TIFR Qualified 1
12. Statement I : Two p orbitals overlap with each 19. Statement I : OF2 and SF2 both exist.
other along internuclear axis, this is known as Statement II : OF4, OF6, SF4 and SF6 all these
lateral overlapping. molecules do not exist.
Statement II : Maximum electron density of s- 1) Both Statement I and Statement II are correct

RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *RCC * *
orbital lie on x-axis.
2) Both Statement I and Statement II are
1) Both Statement I and Statement II are correct incorrect
2) Both Statement I and Statement II are 3) Statement I is correct but Statement II is
incorrect incorrect
3) Statement I is correct but Statement II is 4) Statement I is incorrect but Statement II is
incorrect correct
4) Statement I is incorrect but Statement II is 20. Which of the following species contains equal
correct number of - and - bonds ?
13. Assertion(A) : A bonding molecular orbital is 1) HCO3– 2) XeO4
more stable than antibonding molecular orbital. 3) (CN)2 4) CH2(CN)2
Reason(R) : In bonding orbital, repulsion
21. The shape of the species I3– will be :
between nuclei is very less and tends to hold
the nuclei together, while in antibonding 1) Trigonal 2) Pyramidal
orbitals, natural repulsion of electrons takes 3) Linear 4) Angular
place. 22. Which molecules is T-shped?
1) Both (A) and (R) are correct and (R) is the 1) BeF2 2) BCl3
correct explanation of (A)
3) NH3 4) ClF3
2) Both (A) and (R) are correct but (R) is not the
correct explanation of (A) 23. The pair having similar geometry is
3) (A) is correct but (R) is not correct 1) BF3, NH3 2) BF3, SO3
4) (A) is not correct but (R) is correct 3) BeF2, H2O 4) BCl3, PCl3
14. Weakest bonds is :- 24. Which of the following is an example of super
1) H – F 2) H – Cl octet molecule?
3) H – Br 4) H – I 1) ClF3 2) PCl5
15. Which of the following has maximum number 3) IF7 4) All the three
of lone pairs associated with Xe?
25. Consider the molecules CH4, NH3 and H2O.
1) XeO3 2) XeF4 Which of the given statements is FALSE ?
3) XeF6 4) XeF2 1) The H–O–H bond angle in H2O is smaller
16. Which of the following is odd electron than the H–N–H bond angle in NH3
molecule? 2) The H–C–H bond angle in CH4 is larger than
1) N2O 2) ClO3 the H–N–H bond angle in NH3
3) CO2 4) SO2 3) The H–C–H bond angle in CH4, the H–N–H
17. The species having bond angles of 120° is _____. bond angle in NH3, and the H–O–H bond
1) PH3 2) ClF3 angle in H2O are all greater than 90°
3) NCl3 4) BCl3 4) The H–O–H bond angle in H2O is larger than
the H–C–H bond angle in CH4
18. Match the following.
26. Consider the following species :
Column I Column II
CN+, CN–, NO, CN
i. BCl3 a. sp3
Which one of these will have the highest bond
ii. BrCl3 b. sp3d2
order ?
iii. NH4+ c. sp3d
1) NO 2) CN–
2– 2
iv. [SbCl5] d. sp
3) CN+ 4) CN
1) i-d, ii-c, iii-a, iv-b 2) i-a, ii-b, iii-c, iv-d
3) i-d, ii-b, iii-a, iv-c 4) i-b, ii-d, iii-c, iv-a

Prof. Motegaonkar S. R. [Link]. Che. Gold Medalist, SET/NET--JRF, GATE, BARC,TIFR Qualified 2
27. Statement I : HCN contains total 4 covalent 34. Match the following.
bonds. Column I Column II
Statement II : HNC contains three covalent i. KCN a. Ionic bond
bonds and one coordinate bond. ii. CsCl b. Covalent bond

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1) Both Statement I and Statement II are correct iii. CH3Cl c. Both ionic and
2) Both Statement I and Statement II are covalent bond
incorrect iv. H3O+ d. Both co-ordinate
3) Statement I is correct but Statement II is bond & covalent bond
incorrect
1) i-a, ii-b, iii-c, iv-d 2) i-c, ii-a, iii-b, iv-d
4) Statement I is incorrect but Statement II is
3) i-d, ii-a, iii-c, iv-b 4) i-b, ii-a, iii-d, iv-c
correct
35. Which of the following is NOT matched
28. Which of the following covalent molecule is correctly ?
an exception to octet rule? 1) NH3–Polar molecule with polar bonds
1) BeCl2 2) CO2 2) CH4 –non-polar molecule with non-polar
3) H2O 4) CH4 bonds
29. Which of the following molecule is 3) CHCl3–polar molecule with polar bonds
theoretically not possible? 4) H2S – non-polar molecule with polar bonds
1) SF4 2) OF2 SECTION : B
36. Which of the following orbital overlap is NOT
3) OF4 4) O2F2
possible according to VBT ?
30. The compound which contains both ionic and
covalent bonds is
1) CH4 2) H2O 1) 2)
3) KCN 4) KCl
31. The structure of XeOF4 is
3) 4)
1) tetrahedral
2) square pyramidal
37. In which case  bond will form
3) squre planar 1) px – py (bonding axis z)
4) octahedral 2) py – py (bonding axis y)
32. Correct statement regarding molecules SF4, CF4 3) py – pz (bonding axis y)
and XeF4 are 4) pz – pz (bonding axis x)
1) 2, 0 and 1 lone pair of central atom 38. Hybridisation of CH3+ and CH 3 are
respectively 1) sp and sp2 respectively
2) 1, 0 and 1 lone pair of central atom 2) sp2 and sp2 respectively
respectively 3) sp2 and sp3 respectively
3) 0, 0 and 2 lone pair of central atom 4) sp3 and sp3 respectiveley
respectively 39. H3O+, NH4+, BCl3, AlH4–, NCl3,
4) 1, 0 and 2 lone pair of central atom BeH2, BeH4–2, NH3 , NO3–, O3
The total number of molecules having
respectively
coordinate bond
33. Which of the following compounds contain(s)
1) Two 2) Four
no covalent bond(s) ?
3) Five 4) Six
KCl, PH3, O2, B2H6, H2SO4
40. BCl3, BeCl2, NH3, H2O,
1) KCl, B2H6, PH3 2) KCl, H2SO4 AlBr3, AlH3, PCl5, SiF4
3) KCl 4) KCl, B2H6 How many of these molecules can behave as
lewis acid ?
1) Two 2) Four
3) Six 4) Eight

Prof. Motegaonkar S. R. [Link]. Che. Gold Medalist, SET/NET--JRF, GATE, BARC,TIFR Qualified 3
41. Column-I Column-II 44. Assertion (A) : Carbon molecule [C 2 ] is
INA-(x-axis) Type of bond diamagnetic.
Reason (R) : No unpaired electron is present in
a. d xy + d xy i. P-P C2 molecule.

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1) Both (A) and (R) are correct and (R) is the
b. d xy + py ii. d-d correct explanation of (A)
c. s + px iii.  2) Both (A) and (R) are correct but (R) is not the
correct explanation of (A)
d. Pz + Pz iv. d-p
3) (A) is correct but (R) is not correct
1) a-ii, b-iv, c-iii, d-i 2) a-ii, b-iii, c-i, d-iv
4) (A) is not correct but (R) is correct
3) a-i, b-iv, c-ii, d-iii 4) a-iii, b-iv, c-i, d-ii
45. Among the following ions, the p  d 
42. Find the correct match between the molecule overlap could be present in
and its molecular orbital diagram.
1) NO3 2) PO43
i. H2 a.
3) CO32 4) NO2
46. For which of the following molecule
significant   0 ?
ii. H2– b. Cl CN OH SH

A) B) C) D)

iii. He2 c. Cl CN OH SH
1) A and B 2) Only C
3) C and D 4) Only A
47. On the basis of VSEPR theory, find the
INCORRECT combination.
iv. Li2 d.
Shape of Bond Lone Example
molecule pairs () pairs
1) V-shape 2 1 SO 2
1) i-b, ii-c, iii-d, iv-a 2) i-c, ii-a, iii-b, iv-d
2) Trigonal 3 1 NCl 3
3) i-c, ii-d, iii-a, iv-b 4) i-b, ii-d, iii-a, iv-c pyramidal
43. Which of the following combination of atomic 3) See-saw 4 1 SF 4
orbitals are NOT suitable for the formation of 4) Square 5 1 SF 6
molecular orbitals ? pyramidal
48. Statement I : AlF3 is a hypovalent molecule.
i.
Statement II : AlF3 is an ionic compound
1) Both Statement I and Statement II are correct
2) Both Statement I and Statement II are
ii. iii. incorrect
3) Statement I is correct but Statement II is incorrect
4) Statement I is incorrect but Statement II is correct
49. The structure of XeO3F2 is
1) tetrahedral 2) trigonal bipyramidal
iv. v. 3) squre planar 4) octahedral
50. According to V.B.T which is correct about CH4
1) All the four C – H bonds are different
2) All the four C – H bonds are identical
1) i and v 2) ii, iii and v 3) Two C – H bonds are different from the other
3) i and iv 4) iii, iv, v two C – H bonds
4) One C – H bond is different than rest of the
three C – H bonds

Prof. Motegaonkar S. R. [Link]. Che. Gold Medalist, SET/NET--JRF, GATE, BARC,TIFR Qualified 4