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Chemical Kinetics DPP-1

01. Chemical Kinetics deals with

(a) reaction rate and mechanisms (b) Feasibility of the reaction
(c) Energy content of the reaction (d) All of these
02. The rate law for the single-step reaction 2A + B → 2C,is given by:
(a) rate= k[A].[B] (b) rate=k [A]2.[B] (c) rate=k[2A].[B] (d) rate=k [A]2.[B]º
03. Consider the reaction
N2(g)+3H2(g)→2NH3(g)
d[NH3 ] d[H2 ]
The equality relationship between and ‒ is
dt dt

04. The rate of reaction

(a) increases as the reaction proceeds (b) decreases as the reaction proceeds
(c) remains the same as the reaction proceeds (d) may decrease or increase as the reaction proceeds
05. The unit of rate of reaction is
(a) mol/dm3 (b) mol/pound (c) mol/dm3sec (d) mol/cm3
06. In the rate equation, when the conc. of reactants is unity then rate is equal to
(a) specific rate constant (b) average rate constant
(c) instantaneous rate constant (d) None of above
07. The rate of reaction between two specific time intervals is called
(a) instantaneous rate (b) average rate (c) specific rate (d) ordinary rate
08. At the beginning, the decrease in the conc. of reactants is
(a) slow (b) moderate (c) rapid (d) None of above
09. The average rate and instantaneous rate of a reaction are equal
(a) at the start (b) at the end
(c) in the middle (d) when two rate have time interval ∆𝑡 → 0
10. For a given chemical reaction 𝛾1A + 𝛾2B→ 𝛾3 C + 𝛾4D Concentration of C changes from 10 m mol dm-3
to 20 m mol dm-3 in 10 seconds. Rate of appearance of D is 1.5 times the rate of disappearance of B
which is twice the rate of disappearance A. The rate of appearance of D has been experimentally
determined to be 9 m mol dm-3 s-1. Therefore the rate of reaction is _____ m mol dm-3 s-1.
(a) 1 (b) 3 (c) 2 (d) 0
11. The rate of the reaction 2N2O5→4NO2+O2 can be written in three ways :
−d[N2 O5 ] d[NO2 ] d[O2 ]
= k[N2 O5] ; = k’[N2 O5] ; = k”[N2 O5]
dt dt dt
The relationship between k and k′ and between k and k″ are
(a) k' = 2k ; k' = k (b) k' = 2k ; k″=k / 2
(c) k' = 2k ; k″ = 2k (d) k' = k ; prime k″= k
12. The reaction between X and Y is first order with respect to X and zero order with respect to Y.

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 [𝑋] [𝑌] 𝐼𝑛𝑖𝑡𝑖𝑎𝑙 𝑟𝑎𝑡𝑒
Experiment
𝑚𝑜𝑙 𝐿−1 𝑚𝑜𝑙 𝐿−1 𝑚𝑜𝑙 𝐿−1 𝑚𝑖𝑛−1
I. 0.1 0.1 2 X 10-3
II. L 0.2 4 X 10-3
III. 0.4 0.4 M X 10-3
IV. 0.1 0.2 2 X 10-3
Examine the data of table and calculate ratio of numerical values of M and L. (Nearest inetger)
(a) 0.4,8,02 (b) 0.2,8,40 (c) 2,0.8,40 (d) 0.8,2,40
[Link] one of the following statements for the order of a reaction is incorrect?
(a) Order can be determined only experimentally.
(b) Order is not influenced by stoichiometric coefficient of the reactants.
(c) Order of reaction is sum of power to the concentration terms of reactants to express the rate of
reaction.
(d) Order of reaction is always whole number.
14. The rate of the reaction 2NO+Cl2 → 2NOCl is given by the rate equation rate = k [NO]2 [Cl2]
The value of the rate constant by:
(a) increasing the concentration of NO. (b) increasing the temperature.
(c) increasing the concentration of the Cl2 (d) doing all of the above
15. Units of rate constant of first and zero order reactions in terms of molarity M unit are respectively
(a) sec-1, Msec-1 (b) sec-1, M (c) Msec-1, sec-1 (d) M, sec-1.
16. A reaction involving two different reactants can never be
(a) bimolecular reaction (b) second order reaction
(c) first order reaction. (d) unimolecular reaction
17. 3A → B + C it would be a zero order reaction when
(a) the rate of reaction is proportional to square of concentration of A
(b) the rate of reaction remains same at any concentration of A
(c) the rate remains unchanged at any concentration of Band C
(d) the rate of reaction doubles if concentration of B is increased to double
18. For the following homogeneous reaction,
𝑘
A+B→C
the unit of rate constant is
(a) sec-1 (b) sec-1 mol L-1 (c) sec-1 mol-1 L (d) sec-2 mol L2
19. Velocity constant & of a reaction is affected by
(a) change in the concentration of the reactant (b) change of temperature
(c) change in the concentration of the product (d) None of the above
20. In the reaction 2A + B → A2B, if the concentration of A is doubled and that of B is halved, then the rate
of the reaction will:
(a) increase 2 times (b) increase 4 times (c) decrease 2 times (d) remain the same
21. The order of a reaction, with respect to one of the reacting component Y, is zero. It implies that:
(a) the reaction is going on at a constant rate
(b) the rate of reaction does not vary with temperature
(c) the reaction rate is independent of the concentration of Y
(d) the rate of formation of the activated complex is zero
22. The unit of rate constant for a zero order reaction is
(a) mol L-1 s-1 (b)L mol-1 s-1 (c) L mol-2 s-1 (d) s-1
23. The order of a reaction with rate equal to k [A]3/2[B]-1/2 is:
(a) 1 (b) - ½ (c) - 3/2 (d) 2
24. For the reaction,
𝐻+
CH3COCH3 + I2 → products
𝑑𝑥
The rate is governed by expression → products 𝑑𝑡 = k [acetone][H+]
(a) 1 (b) 0 (c) 3 (d) 2

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25. The rate constant for the reaction 2N2O5→ 4NO2 + O2 is 3.10 x 10-5 sec-1. If the rate is 2.4 x 10-5 mol
liter-1 sec-1 then the concentration of N2O5 (in mol litre-1) is:
(a) 0.04 (b) 0.8 (c)(0.07) (d) 14
26. The rate law for a reaction between the substances A and B is given by Rate = k [A]n [B]m On doubling
the concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of
the reaction will be as
1
(a) (m + n) (b) (n - m) (c) 2(n-m) (d)
2(𝑚+𝑛)
27. Which one of the following reactions is a true first order reaction?
(a) Alkaline hydrolysis of ethyl acetate
(b) Acid catalyst hydrolysis of ethyl acetate
(c) Decomposition of N2O
(d) Decomposition of gaseous ammonia on a hot platinum surface
28. What is order with respect to A, B, C, respectively
[A] [B] [C] rate (M/sec.)
0.2 0.1 0.02 8.08 x 10-3
0.1 0.2 0.02 2.01 x 10-3
0.1 1.8 0.18 6.03 x 10-3
0.2 0.1 0.08 6.464 x 10-2
(a) -1, 1, 3/2 (b) -1,1, 1/2 (c) 1,3/2, -1 (d) 1,-1, 3/2
29. The rate constant of a reaction is 3.00 × 103 L mol-1 sec-1.
The order of this reaction will be:
(a) 0 (b) 1 (c) 2 (d) 3
30. During the kinetic study of the reaction, 2A + B → C+D, following results were obtained:
Run [A] (mol L-1) [B] (mol L-1) Initial rate of formation of
D (mol L-1 mol-1)
I 0.1 0.1 6.0 x 10-3
II 0.3 0.2 7.2 x 10-2
III 0.3 0.4 2.88 x 10-1
IV 0.4 0.1 2.40 x 10-2
Based on the above data which one of the following is correct?
(a) rate = k [A]2 [B] (b) rate = k[A] [B] (c) rate=k[A]2[B]2 (d) rate =k[A] [B]2
31. Nitrogen monoxide, NO, reacts with hydrogen, H2, according to the following equation:
2NO(g) + 2H2(g) → N2(g) +2H2O(g)
If the mechanism for this reaction were,
2NO(g) + H2(g) → N2(g)+H2O2(g); slow
H2O2(g)+H2(g) → 2H2 O(g); fast
Which of the following rate laws would we expect to obtain experimentally?
(a) Rate= k[H2 O2 ][H2] (b) Rate = k[NO]2[H2]
(c) Rate = k[NO]2[H2]2 (d) Rate=k[NO][H2]
32. The initial rates of reaction 3A + 2B + C → Products, at different initial concentrations are given below:
Initial rate,
Initial rate, Ms1 [A]0,M [B]0,M [C]0,M
-3
5.0 x 10 0.010 0.005 0.010
5.0 x 10-3 0.010 0.005 0.015
-2
1.0 x 10 0.010 0.010 0.010
1.25 x 10-3 0.005 0.005 0.010
The order with respect to the reactants, A, B and C are respectively
(a) 3,2,0 (b) 3,2,1 (c) 2,2,0 (d) 2,1,0
33. The chemical reaction 2O3→ 3O2 proceeds as following :

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 𝐹𝑎𝑠𝑡 𝑆𝑙𝑜𝑤
O3 → O2 + O ; O + O3 → 2O2 the rate law expression should
(a) r = k[O3]2 (b) r = k[O3]2 [O2]-1 (c) r = k3[O3][O2]2 (d) r = [O3][O2]2
34. Consider a reaction aG + bH → Products. When concentration of both the reactants G and H is doubled,
The rate increases by eight times. However, when concentration of G is doubled keeping the
concentration of H fixed, the rate is doubled. The overall order of the reaction is
(a) 0 (b) 1 (c) 2 (d) 3
35. The plot that represents the zero order reaction is :

36. The plot of concentration of the reactant vs time for a reaction is a straight line with a negative slope. The
Reaction follows a rate equation
(a) zero order (b) first order (c) second order (d) third order
37. The half-life of a reaction is inversely proportional to the square of the initial concentration of the
reactant. Then the order of the reaction is
(a) 0 (b) 1 (c) 2 (d) 3
38. The rate equation for a reaction, N2O → N2 + 1/2O2 is Rate = k[N2O]0 = k. If the initial concentration of
the reactant is a mol L-1, the half-life period of the reaction is
𝑎 𝑎 𝑘
(a) 𝑡1 = (b) −𝑡1 = ka (c) 𝑡1 = (d) 𝑡1 =
2 2𝑘 2 2 𝑘 2 𝑎
39. A radioactive clement has a half life of 200 days, The percentage of original activity remaining after 83
days is _____.
(Given : antilog 0.125= 1.333, antilog 0.693 = 4.93)
(a) 100 (b) 83 (c) 75 (d) 200
40. The rate constant for a first order reaction whose half-life, is 480 seconds is :
(a) 2.88 x 10-3 sec-1 (b) 2.72 × 10-3sec-1 (c) 1.44 × 10-3sec-1 (d) 1.44 sec-1
41. Assuming l𝜇g of trace radioactive element X with a half life of 30 years is absorbed by a growing tree.
The amount of X remaining in the tree after 100 years is ______.
[Given : In 10 = 2.303; log 2 = 0.30]
(a) 10-3 𝜇g (b) 1× 10-1 𝜇g (c) 10-2 𝜇g (d) 0.1×10-1 𝜇g
42. Diazonium salt decomposes as
C6 H5N2+ CI- → C6 H5 CI + N2
At 0ºC, the evolution of N2 becomes two times faster when the initial concentration of the salt is
doubled. Therefore, it is
(a) a first order reaction (b) a second order reaction
(c) independent of the initial concentration of the salt (d) a zero order reaction
43. For the given first order reaction A → B the half life of the reaction is 0.3010 min. The ratio of the initial
concentration of reactant to the concentration of reactant at time 2.0 min will be equal to
(Nearest integer)
(a) 50 (b) 25 (c) 15 (d) 100
44. 2NO+2H2 → N2 + 2H2O
The above reaction has been studied at 800℃. The related data are given in the table below

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 Reaction Initisal Initisal Initial rate
serial pressure of pressure of ( −𝑑𝑝
) /(kPa/s)
Number H2 / kPa NO / kPa 𝑑𝑡
1 65.6 40.0 0.135
2 65.6 20.1 0.033
3 38.6 65.6 0.214
4 19.2 65.6 0.106
The order of the reaction with respect to NO is
(a) 2 (b) 0 (c) 1 (d) 3
45. The reaction A → B follows first order kinetics. The time taken for 0.8 mole of A to produce 0.6 mole of
B is 1 [Link] is the time taken for conversion of 0,9 mole of A to produce 0.675 mole of B?
(a) 2 hours (b) 1 hour (c) 0.5 hour (d) 0.25 hour
-14 -1
46. For a first order reaction A → B, the rate constant, k = 5.5 × 10 s . The time required for 67%
completion of reaction is x x 10-1 times the half life of reaction. The value of x is (Given : log 3=0.4771)
(a) 2 (b) 5 (c) 16 (d) 10
47. A reaction proceeds by first order, 75% of this reaction was completed in 32 min. The time required for
50%completion is
(a) 8 min (b) 16min (c) 20min (d) 24min
3
48. t 1⁄ can be taken as the time taken for the concentration of a reactant to drop to of its initial value. If
4 4
the rate constant for a first order reaction is k, the t 1⁄ can be written as
4
(a) 0.75/k (b) 0.69/k (c) 0.29/k (d) 0.10/k
[Link] the reaction, 2A + B → products. When concentration of B alone was doubled, the half-life did
not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of
rate constant for this reaction is
(a) s-1 (b) Lmol-1 s-1 (c) no unit (d) mol L-1 s-1
50. [A] → [B]
Reactant Product
If formation of compound [B] follows the first order of kinetics and after 70 minutes the concentration of
[A] was found to be half of its initial concentration. Then the rate constant of the reaction is x x 10-6 s-1.
The value of x is _____.
(a) 165 (b) 155 (c) 145 (d) 105
51. In a reaction A → Products, when start is made from 8.0 × 10-2 M of A, half-life is found to be 120
minute. For the initial concentration 4.0 x 10-2 M, the half-life of the reaction becomes 240 minute. The
order of the reaction is:
(a) zero (b) one (c) two (d) 05
52. For the decomposition of azomethane,
CH3 N2 CH3 (g) → CH3CH3(g) + N2 (g) a first order reaction, the variation in partial pressure with time at
at 600K is given as

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 The half life of the reaction is.
(a) 2× 10-5s (b) 2× 10-2s (c) 4× 10-2s (d) 2 × 10-2s
53. The half life for the decomposition of gaseous compound A is 240 s when the gaseous pressure was 500
Torr initially. When the pressure was 250 Torr, the half life was found to be 4.0 min, The order of the
reaction is
(a) 0 (b) 2 (c) ½ (d) 1
54. A substance 'A' decomposes by a first order reaction starting initially with [A] = 2.00 M and after 200
min, [A] becomes 0.15 M. For this reaction t 1⁄ is
2
(a) 53.72 min (b) 50.49 min (c) 48.45 min (d) 46.45 min
55. For the order reaction A → B, the rete constant, k = 5.5 x 10-1 s-1. The time required for 67% completion
of reaction is x x 10-1 time the half life of reaction. The value of x is ____.
(Given : log 3= 0,4771)
(a) 16 (b) 47 (c) 67 (d) 55
56. The bromination of acetone that occurs in acid solution is represented by this equation.
CH3COCH3 (aq) + Br2 (aq) → CH3COCH2 Br (aq) + H+ (aq) + Br- (aq)
These kinetic data were obtained for given reaction concentrations.

57. If the activation energy for the forward reaction is 150 kJ mol-1 and that of the reverse reaction is
260 kJ mol-1, what is the enthalpy change for the reaction ?
(a) 410 kJ mol-1 (b) -110kJ mol-1 (c) 110 kJ mol-1 (d) -410 kJ mol-1
1
58. For a reaction, given below is the graph of In k vs 𝑇 . The activation energy for the reaction is equal
to _____ cal mol-1.
(Given : R = 2 cal K-1 mol-1)

(a) 8 (b) 5 (c) 6 (d) 4

59. In a reversible reaction the energy of activation of the forward reaction is 50 kcal. The energy of
activation for the reverse reaction will be
(a) <50 kcal (b) either greater than or less than 50 kcal (c) 50 kcal (d) > 50 kcal
60. Which of the following statements best describes how a catalyst works?
(a) A catalyst changes the potential energies of the reactants and products.
(b) A catalyst decreases the temperature of the reaction which leads to a faster rate.
(c) A catalyst lowers the activation energy for the reaction by providing a different reaction mechanism.
(d) A catalyst destroys some of the reactants, which lowers the concentration of the reactants.

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61. For a first order reaction, the plot of log k against 1/T is a straight line. The slope of the line is equal to

62. In a zero-order reaction for every 10° rise of temperature, the rate is doubled. If the temperature is
increased from 10°C to 100°C, the rate of the reaction will become :
(a) 256times (b) 512 times (c) 64 times (d) 128 times
63. It has been found that for a chemical reaction with rise in temperature by 9K the rate constant gets
doubled. Assuming a reaction to be occurring at 300 K, the value of activation energy is found to be
______ kJ mol-1.
(Given In 10=2.3, R= 8.3 JK-1|mol-1, log 2 = 0.30)
(a) 23 (b) 83 (c) 60 (d) 59
64. A reaction having equal energies of activation for forward and reverse reaction has :
(a) ∆G = 0 (b) ∆H = 0 (c) ∆H = ∆G = ∆S = 0 (d) ∆S = 0
65. In an exothermic reaction if ∆H is the enthalpy then activation energy is
(a) more than ∆H (b) less than ∆H (c) equal to ΔH (d)none of the above
1
66. In the Arrhenius plot of' In k vs , a linear plot is obtained with a slope of-2 x 104 K. The energy of
T
activation of the reaction (in kJ mole-1) is (R value is 8.3 J K-1mol-1)
(a)83 (b) 166 (c) 249 (d) 332
67. Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that
follows Arrhenius equation is

68. The activation energy for a reaction is 9.0 kcal/mol. The increase in the rate constant when its
temperature is increased from 298 K to 308 K is
(a) 63% (b) 50% (c) 100% (d) 10%
69. For the reaction P → B, the values of frequency factor A and activation energy EA are 4 × 10-1s-1 and
8.3 kJ mol-1 respectively. If the reaction is of first order, the temperature at which the rate constant is
2 × 10-1s-1 is _____ x 10-1K.
(Given: In 10=2.3, R=8.3 JK-1 mol-1, log 2=0.30)
(a) 220 (b) 114 (c) 225 (d) 830
70. Activation energy of the reaction is
(a) the energy released during the reaction
(b) the energy evolved when activated complex is formed
(c) minimum amount of energy needed to overcome the potential barrier
(d) the energy needed to form one mole of the product
71. In a reaction, the threshold energy is equal to
(a)activation energy + normal energy of reactants
(b) activation energy- normal energy of reactants
(c) normal energy of reactants - activation energy
(d) average kinetic energy of molecules of reactants
72. For the exothermic reaction A +B → C+D, ∆H is the heat of reaction and Ea is the energy of activation.

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 The energy of activation for the formation of A + B will be
(a) Ea (b) ΔΗ (c) Εa + ΔΗ (d) ΔΗ – Εa
73. Consider the following statements:
(i) Increase in concentration of reactant increases the rate of a zero order reaction.
(ii) Rate constant k is equal to collision frequency A if Εa =0.
(iii) Rate constant k is equal to collision frequency A if Εa =∞.
(iv) In k vs T is a straight line.
(v) In k vs 1/T is a straight line.
Correct statements are
(a) (i) and (iv) (b) (ii) and (v) (c) (iii) and (iv) (d) (ii) and (iii)
12 -1 -26000K/T
74. The equation k - ( 6.5 x 10 s ) e is followed for the decomposition of compound A. The
activation energy for the reaction is _____kJ mol-1.
(Given: R=8.314JK-1 mol-1)
(a) 216 (b) 6.5 × 103 (c) 200 (d) 260
75. The activation energy for a hypothetical reaction, A → Product, is 12.49 kcal/mol. If temperature is
raised from 295 K to 305 K, the rate of reaction increased by
(a) 60% (b) 100% (c) 50% (d) 20%
76. The activation energy of one of the reactions in a biochemical process is 532611 J mol-1. When the
temperature falls from 310 K to 300 K, the change in rate constant observed is k300 = x x 10-3 k310 .
The value of x is
[Given: In10 = 2.3, R=8.3 JK-1 mol-1]
(a) 2.5 (b) 1 (c) 0 (d) 3
77. The rate constant for a first order reaction is given by the following equation:
2.0 x 104 K
Ink=33.24 -
T
The Activation energy for the reaction is given by _____ KJ mol-1.
(Given: R= 8.3 JK-1 mol-1)
(a) 33.2 (b) 532 (c) 166 (d) 150
-1
78. Catalyst A reduces the activation energy for a reaction by 10 KJ mol at 300 K. The ratio of rate
kt ,catalysed
constants, is ex. The value of x is _____.
kt ,Uncatalysed
[Assume that the pre-exponential factor is same in both the cases. Given R = 8.31 JK-1 mol-1]
(a) 1 (b) 3.5 (c) 2 (d) 4
[Link] rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at 25℃ are
3.0 × 10-4s-1, 104.4 kJ mol-1 and 6.0 x 1014s-1 respectively. The value of the rate constant as T → ∞ is
(a) 2.0 × 1018s-1 (b) 6.0 × 1014s-1 (c) Infinity (d) 3.6× 1030s-1
80. Which of the following statements is incorrect ?
(a) Energy is always released when activated complex decomposes to form products.
(b) Peak of the energy distribution curve corresponds to the most probable potential energy.
(c) Peak of the energy distribution curve corresponds tothe most probable kinectic energy.
(d) When the temperature is raised maximum of energy distribution curve moves to higher energy
value and broadens out.
81. In terms of the 'Collision Theory Chemical Kinetics the rate of a chemical reaction is proportional to
(a) the change per second in free energy (b) the change in temperature per second
(c) the number collisions of per second (d) the number of products molecules
82. According to collision theory, which of the following is NOT a true statement concerning a catalyst?
(a) A catalyst changes the temperature of react
(b) The mechanism of a reaction will change catalyst is added.
(c) A catalyst provides a different activation energy for a reaction.
(d) A catalyst changes the speed of a reaction, but not the equilibrium constant.

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83. According to the collision theory of reaction rates, the rate of reaction increases with temperature due
to
(a) greater number of collision (b) higher velocity of reacting molecules
(c) greater number of molecules having the activation energy (d) decrease in the activation energy
84. According to which theory activation energy and proper orientation of the molecules together
determine the criteria for an effective collision ?
(a) Arrhenius theory (b) Activated complex theory (c) Collision theory (d) Both (a) and (c)
85. Collision theory is applicable to
(a) first order reactions (b)zero order reactions
(c) bimolecular reactions (d) intra molecular reactions
86. The reason for almost doubling the rate of reaction on increasing the temperature of the reaction
system by 10ºC is
(a) the value of threshold energy increases
(b) collision frequency increases
(c) the fraction of the molecule having energy equal to threshold energy or more increases
(d) activation energy decreases
87. In most cases, for a rise of 10 K temperature, the rate constant is doubled to tripled. This is due to the
reason that
(a) collision frequency increases by a factor of 2 to 3.
(b) fraction of molecules possessing threshold energy increases by a factor of 2 to 3
(c) activation energy is lowered by a factor of 2 to 3.
(d) none of these
88. Activation energy of a chemical reaction can be determined by
(a) evaluating rate constant at standard temperature
(b) evaluating velocities of reaction at two different temperatures
(c) evaluating rate constants at two different temperatures
(d) changing concentration of reactants
89. The role of a catalyst is to change ………
(a) Gibbs energy of reaction (b) enthalpy of reaction
(c) activation energy of reaction (d) equilibrium constant
90. In the presence of a catalyst the heat evolved or absorbed during the reaction
(a) increases (b) decreases (c) remains unchanged (d) may increase or decrease
[Link] energy of a chemical reaction can be determined by …….
(a) determining the rate constant at standard temperature
(b) determining the rate constant at two temperatures
(c) determining probability of collision
(d) using catalyst
92. Consider the Arrhenius equation given below and mark the correct option.

(a)Rate constant increases exponentially with increasing activation energy and decreasing temperature
(b)Rate constant decreases exponentially with increasing activation energy and decreasing temperature
(c) Rate constant increases exponentially with decreasing activation energy and decreasing temperature
(d) Rate constant increases exponentially with decreasing activation energy and increasing temperature
93. Which of the following statements is not correct about order of a reaction?
(a) The order of a reaction can be a fractional number
(b) Order of a reaction is experimentally determined quantity
(c) The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in the
balanced chemical equation for a reaction
(d) The order of a reaction is the sum of the powers of molar concentration of the reactants in the rate law
Expression

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94. Which of the following statements is correct?
(a) The rate of a reaction decreases with passage of time as the concentration of reactants decreases.
(b) The rate of a reaction is same at any time during the reaction.
(c) Therate of a reaction is independent of temperature change.
(d) The rate of a reaction decreases with increase in concentration of reactant(s).
95. Which of the following expressions is correct for the rate reaction of given below?
5B𝑟 − (aq)+BrO3− (aq)+6H + (𝑎𝑞) → 3𝐵𝑟2 (aq)+3H2 O(1)

96. Rate law for the reaction A + 2B→ C is found to be Rate= k[A] [B] Concentration of reactant 'B' is
doubled, keeping the of Concentration 'A' constant, the value of rate constant will be ……
(a) the same (b) doubled (c) quadrupled (d) halved
97. Which of the following statements is incorrect about the collision theory of chemical reaction?
(a) It considers reacting molecules or atoms to be hard spheres and ignores their structural features
(b) Number of effective collisions determines the rate of reaction
(c) Collision of atoms or molecules possessing sufficient threshold energy results into the product
formation
(d) Molecules should collide with sufficient threshold energy and proper orientation for the collision to
be effective
98. A first order reaction is 50% completed in 1.26 × 1014 s. How much time would it take for 100%
completion?
(a) 1.26 × 1015s (b) 2.52 × 1014 s (c) 2.52 × 1028 s (d) Infinite
99. Compounds 'A' and 'B' react according to the following chemical equation.
A(g) + 2B(g)→2C(g)
Concentration of either 'A' or 'B' were changed keeping the concentrations of one of the reactants
constant and rates were measured as a function of initial concentration. Following results were obtained.
Choose the correct
option for the rate equations for this reaction.

Exeperiment Initial Initial Initial concentration of

concentration concentration [C]∕ mol L-1 s-1
of [A]/mol L-1 of [B]/mol L-1
1. 0.30 0.30 0.10
2. 0.30 0.60 0.40
3. 0.60 0.30 0.20
2
(a)Rate=k[A] [B] (b)Rate=k[A] [B]2 (c)Rate=k[A] [B] (d) Rate=k[A]2 [B]0
100. Consider figure and mark the correct option.

(a) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant
(b) Activation energy of forward reaction is E1 + E2 and product is more stable than reactant

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 (c) Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable than
product
(d) Activation energy of backward reaction is E1 and product is more stable than reactant
101. Consider a first order gas phase decomposition reaction given below
A(g) →B(g)+C(g)
The initial pressure of the system before decomposition of A was pi . After lapse of time 't' total
pressure of the system increased by x units and became ′pt'. The rate constant k for the reaction is given
as …….

102. According to Arrhenius equation, rate constant k is equal to A e‒Ea / RT. Which of the following
1
options represents the graph of In k vs
𝑇

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103. A graph of volume of hydrogen released vs time for the reaction between zinc and dil. HCl is given in
Figure on the basis of this, mark the correct option.

𝑣3 −𝑣2 3 2 𝑣 −𝑣
(a) Average rate upto 40s is (b) Average rate upto 40s is 40−30
40
𝑣 𝑣 −𝑣
(c) Average rate upto 40s is 403 3 2
(d) Average rate upto 40s is 40−30
104. Consider the graph given in figure. Which of the following options does not show instantaneous rate
of reaction at 40th second?

105. Which of the following graphs represents exothermic reaction ?

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 (a) Only (I) (b) Only (II) (c) Only (III) (d) Only (I) and (III)
106. Which of the following statement is not correct for the catalyst?
(a) It catalyses the forward and backward reactions to same extent
(b) It alters ∆G of the reaction
(c) It is a substance that does not changes the equilibrium constant of a reaction
(d) It provides an alternate mechanism by reducing activation energy between reactants and products.
107. Consider the reaction A→[Link] concentration of both the reactants and the products varies
exponentially with time. Which of the following figures correctly describes the change concentration
of reactants and products with time ?

[Link] value of rate constant of a pseudo first order reaction .............

(a) depends on the concentration of reactants present in small amount
(b) depends on the concentration of reactants present in excess
(c) is independent of the concentration of reactants depends only on temperature
(d) depends only on temperature
109. Given below are two statements : one is labelled as
Assertion A and the other is labelled as Reason R :
Assertion A : A reaction can have zero activation energy.

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 Reasons R : The minimum extra amount of energy absorbed by reactant molecules so that their energy
becomes equal to threshold value, is called activation energy. In the light of the above statements,
choose the correct answer from the options given below :
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true and R is NOT the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
110. For a certain reaction, the rate = k[A]2[B], when the initial concentration of A is tripled keeping
concentration of B constant, the initial rate would
(a) Decrease by a factor of nine (b) Increase by a factor of six
(c) Increase by a factor of nine (d) Increase by a factor of three
111. For a first order reaction A → Products, initial concentration of A is 0.1 M, which becomes 0.001 M
after 5 minutes. Rate constant for the reaction in min‒1 is
(a) 0.9212 (b) 0.4606 (c) 0.2303 (d) 1.3818
112. The given graph is a representation of kinetics of reaction.

The y and x axes for zero and first order reactions, respectively are
(a) zero order (y = concentration and x = time), first order (y = rate constant and x = concentration)
(b) zero order (y = rate and x = concentration), first order (y = t1/2 and x = concentration)
(c) zero order (y= rate and x = concentration), first order (y = rate and x = t1/2)
(d) zero order (y= concentration and x = time), first order (y = t1/2 and x = concentration)
113. For a reaction A → B, enthalpy of reaction is 4.2 kJ mol-1 and enthalpy of activation is 9.6 KJ mol-1
The correct potential energy profile for the reaction is shown in option.

114. The rate constant for a first order reaction is 4.606 × 10‒3 s‒1. The time required to reduce 2.0 g of
the reactant to 0.2g is :
(a) 200s (b) 500s (c) 1000s (d) 100s
115. For the chemical reaction N2(g)+3H,(g) ⇌ 2NH3(g) the gas is correct option is:

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116. If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of
the reaction is given by :
(a) t=0.693/k (b) t=6.909/k (c) t=4.606/k (d) t=2.303/k
117. The correct difference between first and second order reactions is that
(a) The rate of a first-order reaction does not depend on reactant concentrations, the rate of a second-
Order reaction does depend on reactant concentrations
(b)The half-life of a first-order reaction does not depend on [A]0, the half-life of a second-order
reaction does depend on [A]0
(c)The rate of a first-order reaction does depend on reactant concentrations, the rate of a second-order
reaction does not depend on reactant concentrations
(d) A first-order reaction can be catalyzed, a second- order reaction cannot be catalyzed
118. A first order reaction has a specific reaction rate of 10‒2 sec‒1. How much time will it take for 20g of
the reactant to reduce to 5 g ?
(a)138.6 sec (b) 346.5 sec (c) 693.0 sec (d) 238.6 sec
119. Mechanism of a hypothetical reaction X2 + Y2 →2XY is given below :
(i) X2→ X+X(fast) (ii) X+Y2⇋XY+Y(slow) (iii) X +Y →XY (fast)
The overall order of the reaction will be :
(a) 2 (b) 0 (c) 1.5 (d) 1
120. The addition of a catalyst during a chemical reaction alters which of the following quantities?
(a)Entropy (b) Internal energy (c) Enthalpy (d) Activation energy
121. The rate of a first-order reaction is 0.04 mol L‒1s‒1at 10 seconds and 0.03 mol L‒1s‒1 20 seconds
after initiation of the reaction. The half-life period of the reaction is
(a)24.1 s (b) 34.1s (c)44.1s (d) 54.1

122. Match Colum- I with Colum- II

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123. Match Colum – I and Colum - II

124. Consider the energy diagram of a reaction : B → A. On the basis of given diagram, select the correct
code for matching Column-I and Column-II

125. DIRECTIONS : Read the statements carefully and answer the question on the basis of
following options.
(a) Both statement I and II are correct.
(b) Both statement I and II are incorrect.
(c) Statement I is correct but statement II is incorrect.
(d) Statement II is correct but statement I is incorrect.
i. Statement I : Molecularity is defined as the number of reacting species taking part in a complex
reaction,
Statement II : Molecularity helps in understanding the mechanism of reaction.
ii. Statement I : Reactions with the molecularity three are very rare and slow to proceed.
Statement II : Complex reactions involving more than three molecules take place in more than one
step.
iii. Statement I: e ‒Ea /RT corresponds to the fraction molecules that have kinetic energy greater than Ea.

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 Statement II : Ea can be calculated as follows

iv. Statement I : Catalyst can alter a reaction both ways means can or increase rate of reaction.
Statement II : A catalyst Statement always decreases the activation energy of the reaction but does
not alter Gibb's energy.
126. Study the following graphs and choose th correct option

(i) in fig. a, A represents average rate and B represents instantaneous rate

(ii) in fig. b, D represents average rate and C represents instantaneous rate
(iii) fig. a, A represents instantaneous rate and B represents average rate
(iv) fig. b, C represents average rate and D represents instantaneous rate
(a) (i) and (ii) are correct (b) (ii) and (iv) are correct
(c) (i) and (iv) are correct (d) (ii) and (iii) are correct
127. Which of the following statement(s) is/are correct?
(i) Rate of reaction decreases with passage of time as the concentration of reactants decrease.
For a reaction
(ii) For a reaction

(iii) Rate law is the expression in which reaction rate is given in terms of molar concentration of
reactants with each term raised to some power, which may or may not be same as the stoichiometric
coefficient of the reacting species in a balanced chemical equation.
(iv) The integrated rate equations are same for the of different order of reaction. reactions
(a) (i) and (iii) (b) (i) and (ii) (d) (iv) only (c) (ii) and (iii)
128. At high pressure, the following reaction is of zero order.

Which of the following statements are correct for above reaction?

(i) Rate of reaction = Rate constant
(ii) Rate of reaction depends on concentration of ammonia.
(iii) Rate of decomposition of ammonia will remain constant until ammonia disappears
(iv) Further increase in pressure will change the rate of reaction.
(a) (i), (iii) and (i) (b) (i), (ii) and (iii) (c) (ii) and (iv) (d) (i), (ii) and (iv)
129. Which of the following statement(s) is/are correct ?
(i) For a zero order reaction concentration [R] vs time (t) gives a straight line plot
[𝑅]
(ii) For a first order reaction log [𝑅]0 does not vary linearly with time.
(iii) Inversion of cane sugar is a pseudo first order reaction.
(iv) The slop for plot of log [R]0/[R] v/s time for a first order reaction is equal to -k/2.303.
(a) (i) and (iii) (b) (i) and (iv) (c) (ii) and (iii) (d) (iii) and (iv)
130. The following statement (s) is(are ) correct.
(i) A plot of log KP versus 1/T is linear
(ii) A plot of log [X] versus time is linear for a first order reaction, X → P

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 (iii) A plot of log P versus 1/T is linear at constant volume
(iv) A plot of P versus 1/V is linear at constant temperature
(a) (i) only (b) (ii) only (c) (i) and (iv) (d) (i), (ii) and (iv)
131. During decomposition of an activated complex.
(i) energy is always released (ii) energy is always absorbed
(iii) energy does not change (iv) reactants may be formed
(a) (i), (ii) and (iii) (b) (i) and (iv) (c) (ii) and (iii) (d) (ii), (iii) and (iv)
132. According to collision theory, not all collisions between molecules lead to reaction. Which of the
following statements provide reasons for the same ?
(i) The total energy of the two colliding molecules is less than some minimum amount of energy.
(ii) Molecules cannot react with each other unless a catalyst is present
(iii) Molecules that are improperly oriented during collision will not react.
(iv) Molecules in different states of matter cannot react with each other.
(a) (i) and (ii) (b) (i) and (iii) (c) (ii) and (iii) (d) (i) and (iv)
133. DIRECTIONS : These questions consist of two statements, each printed as Assertion and Reason.
While answering these questions, you are required to choose any one of the following four responses.
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If the Assertion is incorrect and Reason is correct.
i) Assertion: The rate of the reaction is the rate of change of concentration of a reactant or a product.
Reason: Rate of reaction remains constant during the course of reaction.
ii) Assertion: The rate of reaction is never negative.
Reason: Minus sign used in expressing the rate shows that concentration of reactant is decreasing.
iii) Assertion: The order w.r.t a reactant may be negative.
Reason: In some cases, the rate of reaction decreases as the concentration of the reactant increases.
iv) Assertion: Hydrolysis of cane sugar is a first order reaction.
Reason: Water is present in large excesss during hydrolysis.
v) Assertion : The order of a reaction can have fractional value.
Reason : The order of a reaction cannot be written from balanced equation of a reaction.
vi) Assertion : For each ten degree rise of temperature the specific rate constant of a reaction
Reason : Energy-wise distribution of molecules in a gas is an experimental function of temperature.

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