Glyphosate Herbicide Safety Data Sheet
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SAFETY DATA SHEET
SUMIGLIFO 480 SL
Glyphosate (C3H8NO5P)
Non-selective systemic foliar herbicide.
Phosphonate / organophosphate compound.
N-(phosphonomethyl) glycine, Glialka
Yellowish white crystals, no smell.
Risk of harm to the skin and eyes.
Toxicological category: IV (low toxicity)
CAS [38641-94-0]
UN: 2811
RISKS AND PRECAUTIONS:
Inhalation may irritate the respiratory tract. Contact irritates skin and eyes causing redness. Low oral toxicity.
in animals; there is no data for humans.
Keep in well-closed containers. Avoid direct contact. In case of contact, wash thoroughly with water.
IMPORTANT PHYSICOCHEMICAL PROPERTIES:
Molecular weight: 169.1 pH:2.5 ( 1% solución en agua)
Gravedad específica:1.74 Punto de Fusión:228-232°C (descomposición)
Solubility: Poorly soluble in water (10.62 g/L), insoluble in organic solvents.
FIRST AID
Inhalation: Move the victim to fresh air; trained personnel should administer oxygen if the victim is breathing with difficulty.
or artificial respiration if the victim is not breathing. Seek medical attention.
Skin contact: Carefully remove chemical residues from the skin. Wash with plenty of water, then wash with water.
and non-abrasive soap. Remove contaminated clothes and shoes immediately. If irritation persists, see a doctor.
Ingestion: Administer 1 or 2 glasses of water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, rinse the mouth with water.
Seek medical attention immediately. If she is unconscious, do not give her anything or induce vomiting, place her in a resting position.
and maintain the normal body temperature (37 °C).
Eye contact: Rinse with plenty of water for 20 minutes, using warm water while keeping the eyelids open.
If irritation persists, repeat the washing. See an ophthalmologist. Do not take neutralization measures. Do not rub your eyes.
FIRE:
This material is not flammable.
Procedure: Evacuate and isolate the area 150 m in all directions. Use full protective clothing and self-contained equipment.
Remove the other exposed containers if you can do so without risk. Avoid inhaling fumes.
Ventilate the place.
Appropriate extinguishing media: Carbon dioxide, dry chemical powder, foam, water.
ACCIDENTAL SPILL:
Evacuate and isolate 20 meters in all directions. Use special protective clothing. Avoid entering water sources.
Ensure that the spill management is done by properly trained personnel. Carefully collect and deposit in
airtight containers. Label these containers for subsequent ecological disposal. If it is diluted in water
contain with polyurethane dikes or special socks and absorb with vermiculite, pads or special mats. Wash the
Area with water, preventing it from draining into the sewage. Dispose of the waste in an approved incinerator.
Absorbentes Recomendados:Calcetines, Almohadas, Tapetes.
STABILITY AND REACTIVITY:
It is normally stable. Under appropriate temperature conditions, it can be stored for up to four years.
Conditions to avoid: High temperatures.
Incompatible materials: It can react with iron or galvanized steel producing hydrogen gas, which is highly
flammable and explosive. Reacts violently with strong bases.
Decomposition products: Carbon monoxide, nitrogen oxides, and phosphorus oxides.
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CONTROL PARAMETERS BY EXPOSURE: Not established.
MANIPULATION AND STORAGE:
4H (Silver Shield) Safety goggles. Butyl rubber
Filter respirator for
dust and mist. Full suit in polypropylene. Shower. Eyewash.
Appropriate temperature 15-25°C.
Keep away from incompatible materials such as strong bases. Do not store near food and beverages.
Protect the containers from light, moisture, and extreme temperatures. Only use aluminum and steel containers.
stainless steel, fiberglass, and plastic.
Store in airtight containers, preferably in the original containers, in a well-ventilated area.
Only handle the necessary quantities and in well-ventilated areas. Identify the containers.
Maintain strict hygiene and cleanliness practices in the workplace. Do not eat, drink, or smoke.
Keep the insulated protective clothing separate from street clothes. Wash your hands very well after handling the product.
TRANSPORT
Load it only in vehicles specially equipped for the transport of hazardous substances.
Label the containers properly and keep them closed. Secure all the containers in the vehicle.
against movement. Avoid inhaling the product and any direct contact.
Transport it isolated from food or drinks.
Place it on pallets at least 10 cm off the floor, or load it in such a way that prevents mixing with others.
hazardous materials in the event of a spill. The vehicle floor must be smooth. You can use a false floor inside.
insured against movement.
Have emergency response equipment available such as multipurpose fire extinguishers, protective clothing, and if transporting the
liquid product carries enough material to absorb.
Hazard classification: Not regulated by DOT
TOXICOLOGICAL INFORMATION:
Skin contact: Irritation. Causes redness and pain on skin that has suffered abrasion.
Eye contact: Severe irritation.
Inhalation: It is irritating to the nose and airways.
Acute Toxicity: Subacute Toxicity: Chronic toxicity:
DL50(oral, rat) > 5000 mg/kg NOEL (rata): 3000 ppm NOEL (Rata): 3000 ppm
DL50> 5000 mg/kg (oral, mouse) NOEL (mouse): 5000 ppm NOEL (Mouse): 8000 ppm
DL50(skin, rat) > 2000 mg/kg NOEL (dog): 40000 ppm NOEL (Dog): 8000 ppm
CL50 (rat, 4 hours) > 5.48 mg/L
Chronic effects: It causes irritation, dryness, and mild corrosive lesions on the skin.
ECOLOGICAL INFORMATION:
Acute effects on aquatic organisms: Carp (CL50118.3 ppm - 96 hr); Rainbow trout (CL50123.6 ppm - 96 hr); Daphnia
(CL5088.7 ppm - 24 hr)
Acute effects for beesDL500.05 mg/bee Birds:Japanese bird DL502000 mg/Kg
Persistence: the half-life depends on soil condition: in volcanic ash: approx. 20 days.
Clay: approx. 23 days. Do not incorporate the product or its waste into soils or aquifers.
BIBLIOGRAPHY:
1. GLYPHOSATE TECHNICAL. MSDS Sankyo Co. January 1999
2. Forsberg, K., et al. Quick selection guide to chemical protective clothing. 3a ed. Van Nostrand Reinhold, 1997.
3. CCOHS. CHEMINFO database (99-3). CD-ROM. Canada. April 1999. Record 375.
FECHA DE EMISION:Enero del 2000
The data provided in this sheet is based on our knowledge.
actual. They do not represent a guarantee regarding the properties of this product.
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