6CI(g)

of of
and
1of temperature at adiabaticaily
the combustion
of
reversibly heat
ternperature gas Seiect (2) (4)
-179
-1368kJ/m
kJ/mol
(approz.). in energyadiabatically
internal 394
+ the
ideal s)
(2) -315
cal
(4) K. is
(white, 4H°=-
expanded -332 cal
kJ
3.10
(4) T, What 5-(2)40 2-(4)
90
done when kJ
gas 5.9
(2) compressed kJ/mol)?
[Thermochemistry] of that9) kJ/mol.
constant becomes
monoatomic
P, kJ. heat (CO,
compared Given
work 200°C for 1280
is 0.48] (in standard 286
monoatomic
of
mole reaction =-278kJ/mol,
AH°
(C,H,OH). kJ/mo
gasat the change
is
temperature PCI,(0) kJ/mol
atrn = by -
idealCalculate
log3 K is =
3 of T, relation. be (H,O,)
47132848
to -273
cal cal the increased
(1) 402
(3) reversibly?
(3) temperature (3)
4PCI,(0)
T,<T,Cannot of of
of atm 0.6, 2.50
kJ
(1) kJ
1.93mole T, T, -640
(1)
heat formation
320
(3) Calculate
moles is final > =
T, ethanol
4 K. = What Correct T,
The>
AH° (1) -(3)
from300[log4 One and (1) (2) (4)
2 is
7. 8. 9.
5. 6.
correct) change as gas.
capacity
at moles from
of energy
process pressure
property
property
property ideal isothermally
property containing
2 internal
heat
is Thermodynamics] -12
(2)
P,V-P,Vo
diatomic
option cyclic (4) heat
about extensive
extensive 4V, 2.1R
(2) constant
intensive
intensive in
diagram? V’ molar of 4R
(4)
(One statement in aofmixture change
expanded
moles
done
Questions and andandand
constant
atpressure. Vo average at L)
P-V 3 theatm
volume
of correctfunction work
function
function
function and
Law given 3P, constant
volume is is
the
Po
(1)
-6
P,Vo(3) the monoatomic
of gas What(in
Type the
[First 9PVo L system?
PathStateState
Pathis in
shown
P Calculate 3.2Rideal
(3) 5 atm. -3 (4)
Zero
(1) (2)
+3 -6
(3)
Obiective Select What (1)
R to
(1) (2) (3) (4) An 2L1.5 of
1.
.
10*. Amongfollowing standard enthalpy of formation [Second Law of Thermodynamics]
IS non-zero for 17. For which of the following
(1) C(graphite) (2) Br,() change is positive?
reaction, entropy
(3) H,(g) (4) 1,(g) (1) H,(g) + O,(g)’ H,0,1)
11. What is the heat of reaction of following 3
reaction? (2) CH,0H() + ,0,(9) ’ CO,(9) +2H,0(0)
H
(3) 2NO,g)’ N,O,(9)
3C(g) +4H,(g)’ H,CC CH,(g) (4) 2NH,(g) ’ N,(g) + 3H,(g)
18. What is the value of [Link] a spontaneous
reaction?
Given that BE of H-H = x, H-C =y and
C-C=z. (1) Greater than zero
(1) 4x -2z- 8y (2) x-y-z (2) Less than zero
(3) 4x - 2y- 2z (4) 4y + 5xz (3) Zero
12. The heat of formation of CO, is -407 kJ/mol. (4) Always negative
The energy required for the process 19. According to second law of thermodynamics,
3CO,(g) ’ 3(g) + 20,(g) is (1) Heat can't flow spontaneously from a
(1) Less than 1221 kJ reservoir at lower temperature to a reservoir
(2) More than 1221 kJ at higher temperature
(3) 0s equal to 1221kJ (2) Allspontaneous process leads to increase
(4) Cannot be predicted in entropy of universe
13. The heat of combustion of sucrose CpHO,, (s) (3) Melting of a solid (ice) increases entropy.
at constant volume is -1348.9 kcal molr at therefore aspontaneous process
25°C, then the heat of reaction at constant (4) Allof these
pressure, is 20. In which of the following process, the entropy
(1) 1348.9 kcal (2) - 1342.344 kcal decreases?
(3) 1250 kcal (4) -1250 kcal (1) 4NO,(g) +O,(g) 2N,Os(g)
14. For the reaction, (2) 2HCI(g) -H,(g) + Cl,(g)
C,Ha(l) + 90,(g) -7C0,(g) +4H,0(), (3) 2NH, (g) -N,(g) +3H,(g)
the calculated heat of reaction is 232 kJ molr (4) CH.(g) C(g) +4H(g)
and observed heat of reaction is 50.4 kJ mol", 21*. If the entropy of vaporisation of a liquid is
then the resonance energy is
110 JK mo'and its enthalpy of vaporisation
(1) - 181.6 kJ mol (2) + 181.6 kJ mor is 50 kJmol'. The boiling point of the liquid is
(3) 172 kJ mol (4) - 172 kJ mol (1) 354.5 K (2) 454.5 K
15. Giventhat (3) 554.5 K (4) 445.5 K
A(s) A(0) AH =x
22. 1 mole of an ideal gas is expanded from an
A() - A(g) AH =y initial pressure of 1bar to final pressure of
The heat of sublimation of A will be 0.1 bar at constant temperature of 273 K.
Predict which of the following is not true.
(1) X- y (2) x + y
(3) x or y (4) -x +t y (1) AE =0 (2) AH =0
16. AB, A, and B, are diatomic molecules. If the (3) PV is constant (4) AS <0
bond enthalpies of A, AB and B, are in the ratio 23. 1 mol of diatomic ideal gas expands from 1 L
[Link].5 and enthalpy of formation of AB from to 10 L in reversible isothermal process. The
A, and B, is -100 kJ mol. What is the bond entropy change AS of surrounding for this
enthalpy of A,? process
(1) 400 kJ mo (2) 200 kJ mol (1) + 1.9 J/mol K (2) -8.3 J/mol K
(3) 300 kJ mol (4) 100 kJ molr (3) - 19.15 J/mol K (4) + 14.2 J/mol K
 What is the change in entropy when 2.5 mole of 31. The free energy change due to a reaction is
water is heated from 27°C to 87°C? zero when
Given CpM(H,0) =4.2 Jlg [In 1.2 =0.18] (1) The reactants are initially mixed
(1) 16.4 JK-1 (2) 34.02 JK1 (2) Acatalyst is added
(3) 2.89 JK1 (4) 18.2 JK1 (3) The system is at equilibrium
6 For the reaction 2HgO(s) ’ 2Hg(l) + O,(g) (4) The reactants are completely consumed
(1) AH >0 and AS <0 32. From the given graph
Free
energy
>
(2) AH >0 and AS >0
(3) AH <0 and AS <0
(4) AH <0 and AS >0
26*. Which of the following conditions should
be satisfied for the given reaction to be
spontaneous at 0°C and 1 atm?
Reactant Product
H,O(s) H,O(|) Which of the following statement is correct?
(1) AH =AG (2) AH < TAS
(3) AH >TAS
(1) The point B represents the state of
(4) AH = TAS equilibrium
21. The reaction 4Al(s) + 30,(g) ’ 2AI,0,(s) is (2) The equilibrium composition strongly
exothermic in nature. The reaction would be favours the reactant
(1) Spontaneous at alltemperature (3) From the point B formation of product is
(2) Spontaneous at low temperature equally spontaneous as of reactant
(3) Spontaneous at high temperature (4) From the point B formation of reactant is
(4) Non-spontaneous always more spontaneous than that of product
8. Select the correct statement. 33*. The value of AG° is -1.2 kcal/mol at 600 K
(1) Exothermic reaction is always spontaneous for a reaction at equilibrium. The value of its
(2) Endothermic reaction is always non equilibrium constant is
spontaneous (1) e1 (2) e?
(3) Exothermic reaction is always spontaneous (3) e (4) e?
if entropy change of reaction is positive
(4) Endothermic reaction is always non [Miscellaneous]
34. Which of the following is(are) state function as
spontaneous if entropy change of reaction well as intensive property?
is positive
29
Consider the following sequence of reaction at (A) Entropy
300 K (B) Internal energy
Reaction: (C) Pressure
|: M N, AH° = x kJ (1) A, B and C (2) Only Aand B
I|: N’ O, AH° = y kJ (3) Only B (4) Only C
Ill : 0 ’ P, AH° = z kJ 35. In a process, 120 J heat is given to 0, gas and
X, y and zare positive integer and x > 180 Jwork is done on the gas. The molar heat
y> Z capacity for this process is
S°:M> N>0>P (at 300 K)
Select the non-spontaneous reaction at 300 K. (Assume gas is ideal and gas constant is R)
(1) P ’ N 2R 5R
(2) O ’ M (1) (2)
(3) M’ P 5 2
(4) P’ 0
R
Conversion of diamond to graphite is (3) R (4) 5
(1) Spontaneous only at
(2) high temperature 36. During an adiabatic process, a gas obey
Spontaneous only at low
(3) Always non-spontaneous temperature TV= constant. The gas could be
(4) Always Spontaneous (1) He (2) SO,
(3) N, (4) NH,
37. For the reaction, 45. The heat of neutralisation of a strong
NH,HS(s) NH3(g) +H,S(g) acid in dilute solution by NaOH is nearlydibasic
Thevalue of AHat 27°C is 12kcal, what is the (1) -27.4 kcalleg (2) 13.7 kcal/mol
value of AUfor thereaction? [R=2.0 cal K'mor') (3) -13.7 kcal/eg (4) -13.7 kcal/mol
(1) 10.8 kcal (2) 11.8 kcal 46. The heat released in neutralisation of HCL
(3) 9.8 kcal (4) 12.8 kcal and NaOH is 13.7 kcal/mol, the heat released
on neutralisation of NaOH with
38. In which of the following reaction, AH > AU at CH,COOH is
3.7 kcallmol. The AH° of ionisation of CH,COOH
25°C?
(1) H,(g) + 1,(9)2HI(g) (1) 10.2 kcal (2) 10kcal
(2) PCI,(g) ’ PCI,(g)+Cl,(g) (3) 3.7 kcal (4) 9.5 kcal
(3) 2H,0(g)’ 2H,(g) + 0,g)
(4) Allof these 47. Which of the following reactions represents the
enthalpy of formation of water?
39. C,H,OH() on complete combustion produce (1) H(aq) + OH(aq)’ H,0()
CO,(g) and H,o(1) at 300 K. The difference
between AH and AUat this temperature is (2) H,(g) + O,(g) ’ H,o()
(1) -2.49 kJ (2) + 2.49 kJ (3) 2H,(g) + O,(g) - 2H,0(|1)
(3) + 4.98 kJ (4) 4.98 kJ (4) 2H'(aq) + 20H(aq) ’ 2H,0()
40. 1 mol of Ca(OH), is completely neutralised by 48. The heat of combustion of yelow phosphorus
HCIthen heat released in the reaction is (Only and red phosphorus are-9.91 kJ/mol and-8.78
magnitude) kJ/mol respectively. Then the heat of transition
(1) More than 57.4 kJ of yellow phosphorus to red phosphorus is
(2) Less than 57.4 kJ (1) -18.69 kJ (2) +1.13 kJ
(3) Equal to 57.4 kJ (3) +18.69 kJ (4) -1.13 kJ
(4) Cannot be determined orcompared 49. Which of the following represents heat of
41. If an element X has three allotropes A, B and formation (AH,)?
C. If heat of combustion at standard state for (1) C(diamond) +O,(g) ’ Co,(g)
A, B and Care -100, -150 and -110 kJ/mol
respectively. The correct order of stability is (2) 2CO(g) + O,(g) ’ 2C0,(g)
(1) A>B> C (2) B>C>A (3) H,(g) + 2F,(g)’ HF(g)
(3) A> C>B (4) A= B= C (4) N,(g) +3H,(g) 2NH,(g)
42. The heat of combustion of ethene (C,H,) 50. Average bond eneray of S-Fand C-H is xand
is -1409.3 kJ/mol. Calculate the weight of y. If y is 2times of x
ethene required to produce 470 kJ of heat on SFs S(g) +6F (g) AH° =QkJ
(2 mol)
combustion.
(1) 12.5 g (2) 9.34 g CH.(g)
(1 mol)
C(g) + 4H(g) AH= PkJ
(3) 23 g (4) 18.4 g
43. The heat of neutralisation of a strong acid and Then
strong base is 57 kJ/mol. The heat released
when 0.4 moles of HCl solution reacts with 0.3
(1) 1
moles of NaOH is (2) 1.5
(1) 57.0 kJ (2) 11.4 kJ (3) 0.75
(3) 17.1 kJ (4) 22.8 kJ (4) 6 kJ/mol,
51. Bond energies of H - Hbond is 80 is
44*, The enthalpy of formation of H,o) is H-1bond
-280.70 kJ/mol and enthalpy of neutralisation of |-I bond is 100 kJ/mol and forreaction.
astrong acid and strong base is -56.70 kJ/mol. 200 kJ/mol, the enthalpy of the
What is the enthalpy of formation of OH jons? H,(g) + I,(g) ’ 2HI(g) is
(1) -22.9 kJ/mol (2) -224 kJ/mol (1) -120 kJ (2) -220 kJ
(3) -58.7 kJ/mol (4) -214 kJ/mol (3) +100 kJ (4) +120 kJ
 System A System B 2X-y X+ 2y
(1) (2) 2
2
(1) Temperature rises Temperature
remains same X-2y
(3) (4) 2y-X
2
(2) Temperature Temperature rises
remains same 66. Given below are two statements: isOrne
labelled as Assertion (A) and the other is
(3)| Temperature falls Temperature labelled as Reason (R).
remains same
Assertion (A) : Enthalpy of neutralisation of
(4)| Temperature falls Temperature rises strong monobasic acid with strong monoacidic
62. Choose the correct option for free expansion base is always -57 kJ mol1
of an ideal gas under adiabatic condition from Reason (R): Enthalpy of neut ralisation is the
the following. [JEE (Main)-2024] amount of heat liberated when one mole of H'
(1) q=0, AT < 0, w 0 jonsfurnished by acid combine with one mole
(2) q 0, AT = 0, w = 0 ofOHions furnished by base to form one mole
of water.
(3) q = 0, AT # 0, w = 0
(4) q= 0, AT = 0, w = 0 In the light of the above statements, choose the
correct answer from the options given below.
[Thermochemistry] [JEE (Main)-2024]
63. At 25°C and 1atm pressure, the enthalpies of (1) Both (A)and (R) are true but (R) is not the
combustion are as given below: correct explanation of (A)
Substance H, C(graphíte) C,H,(9) (2) (A) is false but (R) is true
AH -286.0 -394.0 -1560.0 (3) (A) is true but (R) is false
kJmol-1 (4) Both (A) and (R) are true and (R) is the
The enthalpy of formation of ethane is correct explanation of (A)
[JEE (Main)-2022] (Entropy and Second Law of Thermodynamics]
(1) +54.0 kJ molr (2) -68.0 kJ mor
(4) +97.0 kJ mor 67. During which of thefollowing processes, does
(3) -86.0kJ mol entropy decrease? [JEE (Main)-2021]
64. At 25°C and 1 atm pressure, the enthalpy (A) Freezing of water to ice at 0°C
of combustion of benzene () and acetylene
(g) are -3268 kJ mor' and -1300 kJ molr, (B) Freezing of water to ice at -10°C
respectively. The change inenthalpy for the (C) Nz(g) + 3H2(g) ’ 2NH,(g)
reaction 3C,H,(g)’ CçH(|), is
[JEE (Main)-2022] (D) Adsorption of CO(a) on lead surface
molr (E) Dissolution of NaCI in water
(1) +324 kJ options
molr Choose the correct answer from the
(2) +632 kJ
mol given below.
(3) -632 kJ
(4) -732 kJ molr (1) (A)and (E) only
65. Given (2) (A). (C) and (E) only
(A) 2C0(g)+ O2(g)- 2C0, (g) (3) (A). (B). (C) and (D) only
AH? = - x kJ mol-1 (4) (B) and (C)only Corect?
68. Which of the following relation is not
(B) C(graphite) +Oz(g)- CO,(g) (JEE(Main)-2022)
AHS =y kJ mol-1
(1) AH= AU- PAV
The AH° for the reaction
(2) AU=q+ W
C(graphite)+02(g)-cog) is (3) ASvs t AS,surr >0
[JEE (Main)-2023] (4) AG= AH TAS 2015
 Standard enthalpy of vapourisation for CCI, is 5
30.5kJ mol Heat required for vapourisation 96. An ideal gas, Cy=R
2
isexpanded adiabatically
of 284 gof CCI, at constant temperature is against aconstant pressure of 1 atm until it
kJ.
doubles in volume. f the initial temperature and
(Given molar mass in gmol;C=12, C| =35.5) pressure is 298 Kand 5 atm, respectively then
(JEE (Main)-2024] the final temperature is K (nearest
IMeasure of AU and AH:Calorimetry] integer).
91. The reaction of cyanamide, NH,CN,) with [Cv is the molar heat capacity at constant
oxygen was run in a bomb calorimeter and volume] [JEE (Main)-2024]
AUwas found to be -742.24 kJ mol, The
magnitude of AH98 for the reaction [Thermochemistryl
3 97. The standard heat of formation (A,Hse) of
NH,CN(s) + 2 -O2(9) ’ N2(g) + CO,(g) + H,0(0) ethane (in kJ/mol), if the heat of combustion
is kJ. (Rounded off to the nearest integer) of ethane, hydrogen and graphite are -1560,
-393.5 and -286 kJ/mol, respectively
[Assume ideal gases and R = 8.314 J mor K] [JEE (Main)-2020]
[JEE (Main)-2021]
98. The heat of combustion [Link] into carbon
92. 2.4 g coal is burnt in a bomb calorimeter in dioxide and water is -327 kcal at constant
excess of oxygen at 298Kand 1atm pressure. pressure. The heat evolved (in cal)at constant
The temperature of the calorimeter rises from
298 K to 300 K. The enthalpy change during volume and 27°C (if all gases behave ideally)
the combustion of coal is -x kJ mol". The value is (R =2 cal molK)
of x is (Nearest integer) [JEE (Main)-2020]
(Given : Heat capacity of bomb calorimeter is 99. 200 mL of 0.2 M HCI is mixed with 300 mL of
20.0 kJ K'. Assume coal to be pure carbon) 0.1 M NaOH. The molar heat of neutralization
(JEE (Main)-2022] of this reaction is -57.1 kJ. The increase in
93. Agas (Molar mass = 280 g mol') was burnt temperature in °C of the system on mixing is
in excess O, in a constant volume calorimeter X x 10, The value of x is (Nearest
and during combustion the temperature integer)
to
of calorimeter increased from 298.0 K [Given : Specific heat of water = 4.18 Jg K
298.45 K. If the heat capacity of calorimeter is
2.5 kJ K and enthalpy of combustion of gas Density of water = 1.00g cm
is 9 kJ mor then amount of gas burnt is (Assume no volume change on mixing)
g. (Nearest Integer) [JEE (Main)-2022] [JEE (Main)-2021]
94. 0.3 g of ethane undergoes combustion at 100. The standard enthalpies of formation of Al,O,
27°C in abomb calorimeter. The temperature and CaO are-1675 kJmor' and -635 kJ mor
of calorimeter system (including the water) is respectively.
found to rise by 0.5°C. The heat evolved during
combustion of ethane at constant pressure is For the reaction 3CaO + 2AI ’ 30a + Al,o,.
kJ mor. the standard reaction enthalpy A,H° =_kJ.
(Nearest integer) (Round off to the Nearest Integer).
[Given: The heat capacity of the calorimeter [JEE (Main)-2021]
System is 20 kJ K, R=8.3 JK mol". 101. For the reaction,
Assume ideal gas behaviour. CzH;’ CzH4+H2
Atomic mass of C and H are 12 and 1 g mol kJ molr1.
[JEE (Main)-2023] the reaction enthalpy A,H =
95
respectively] (Round off to the Nearest Integer).
When a 60 W electric heater is immersed in a
gas for 100s in a constant volume container with [Given: Bond enthalpiesin kJ molr':
adiabatic walls, the temperature of thegas rises C-C:347, C=C:611;
Oy 5°C. The heat capacity of the given gas IS C-H:414, HH:436]
JK (Nearest integer) [JEE (Main)-2021]
20231
102". The ionization enthalpy of Na' formation from utilized by the athlete for sports activities at the
Na, is 495.8kJ mo, while the electron gain event. In order to avoidstorage of energy, the
enthalpy of Br is -325.0 kJ mo". Given the weight of extra water he wouldneed to perspire
lattice enthalpyof NaBr is-728.4 kJmol", The is g(Nearest integer)
energy for the formation of NaBr ionic solid is Assume that there is no other way of consuming
(). x10 kJ molr, stored energy.
[JEE (Main)-2021] Given:The enthalpy of evaporation of water is
103. For complete combustion of methanol, 45 kJ mol
3 Molar mass of C, H& O are 12, 1and 16 a
CH,OH() +0,(9) ’ CO,(9) +2H,0(1) mor1 (JEE (Main)-2023]
the amount of heat produced as [Link] 25°C, the enthalpy of the following processes
measured by bomb calorimeter are given
is 726 kJ mol' at 27°C. The H,(g) + O,(g) ’ 20H(g) AH° =78 kJ mol
enthalpy of combustion for the
reaction is -x kJ mol', where x 1
is (Nearest integer) H,(g) +0,(9) ’> H,O(g)
AH° =-242 kJ mor
(Given:R= 8.3 JK mor)
H,(g) ’ 2H(g) AH° = 436 kJ mo
[JEE (Main)-2022]
1
104. 17.0 gof NH, completely vapourises at 0,(g)
2 ’ O(g) AH° = 249 kJ mo
-33.42°C and 1bar pressure and the enthalpy
change in the process is 23.4 kJ mol,The What would be the value of X for the following
reaction? (Nearest integer)
enthalpy change for the vapourisation of
85 gof NH, under the same conditions is H,O(g) > H(g) + OH(g) AH° = XkJ mof
kJ. [JEE (Main)-2022] [JEE (Main)-2023]
105. While performing a thermodynamics experiment, 109. Solid fuel used in rocket is a mixture of Fe,0,
astudent made the following observations. and Al (in ratio 1 :2). The heat evolved (kJ)
per gram of the mixture is (Nearest
HCI + NaOH ’ NaCl + H,0;
integer)
AH =-57.3 kJ mor Given :AH, (AI,O,) = -1700kJ mor
CH,COOH + NaOH’ CH,COONa + H,0; AH, (Fe,O,) =-840 kJ molr
AH =-55.3 kJ mol Molar mass of Fe, Al andO are 56, 27 and
The enthalpy of ionization of CH,COOH as 16g mol respectively (JEE (Main)-2023]
calculated by the student is kJ mol", 110. TwWO reactions are given below:
[Nearest integer] [JEE (Main)-2022] 3
106. C(s) +Oz(g) - CO,(g) +400 kJ 2Fe(s)t 2-O2 9- FezO3(s), AH°=-822 kJ/mol
1 - CO(9), AH° =-110 kJ/mol
C(s) +,0,(9)
2 - Co(g) +100 kJ C's)t 2
When coal of purity 60% is allowed to burn Then enthalpy change for following reaction
in presence of insufficient oxygen, 60% kJ/mol.
3Ce) + Fe,O3s) ’2Fe, +3CO is
of carbon is Converted into CO' and the (JEE (Main)-2024]
remaining is converted into 'CO,. The heat
generated when 0.6 kg of coal is burnt is 111. The enthalpy of formation of ethane (C,H;)
from ethylene by addition of hydrogen where
(in kJ) [JEE (Main)-2022] the bond-energies of C -H. CC,C=G,
107. An athlete is given 100 g of glucose H H are 414 kJ, 347 kJ. 615 kJ and 435 KJ
(CH,O,)
for energy. This is equivalent to 1800 kJ of respectively is - kJ
energy. The 50% of this energy gained is [JEE (Main)-2024]
 112. Combustionof 1 mole of benzene is expressed 118. The standard entropy change for the reaction
al 4Fe(s) + 30,(g) ’ 2Fe,O,(s) is -550 JK at
15 298 K.
C,Ha(0)+ O,(g)-6CO,(g) +3H,0(0).
2
[Given: The standard enthalpy change for the
Thestandard enthalpy of combustion of 2 mol reaction is -165 kJ mol1. The temperature in
of benzene is - 'x' kJ. x= Kat which the reaction attains equilibrium is
Given : (Nearest Integer) [JEE (Main)-2022]
1. Standard Enthalpy of formation of 1 mol of 119. When AHn = 30 kJ/mol and ASa 75 J
C,H, (), for the reaction 6C (graphite) + mol'K,then the temperature of vapour, of
3H,(g)> CoH,() is 48.5 kJ mol K.
one atmosphere is
2. Standard Enthalpy of formation of 1 mol of [JEE (Main)-2024]
CO,(9),for the reaction C(graphite) +O,(9)
CO,(g) is -393.5 kJ mol. [Free Energy]
3. Standard and Enthalpy of formation of
1 mol of H,O(),for the reaction 120*. For a dimerization reaction,
1 2A(g) ’ A,(g)
H,(g) + , O,(9) -’H,O(1) is-286 kJmol!
at 298 K, AU° = -20 kJ mol, AS° =-30JK
[JEE (Main)-2024] J
mol, then the AG° will be
113. The heat of combustion of solid benzoic acid
at constant volume is -321.30 kJ at 27°C. The [JEE (Main)-2020]
heat of combustion at constant pressure is 121. For the reaction,
(-321.30 - xR) kJ, the value of xis A() ’ 2B(g)
[JEE (Main)-2024] AU =2.1 kcal, AS=20 calK at 300 K.
114. When equal volume of 1M HCland 1MH,SO, Hence, AG in kcal is
are separately neutralised by excess volume
[JEE (Main)-2020]
of 1M NaOH solution. x and y kJ of heat is
122. Data given for the following reaction is as
liberated respectively. The value of y/x is follows:
[JEE (Main)-2024]
115. The heat of solutions of anhydrous CuSO,
FeO(s)t C(graphite) Fes +CO|g)
and CuSO,5H,0 are -70 kJ mol and A,H°
+12 kJ mol' respectively. The heat of hydration Substance
of CuSO, to CuSO, 5H,0 is -x kJ. The value (kJ mol')(Jmol'K')
of x is (Nearest integer)
[JEE (Main)-2024]
FeO)
(graphite )
-266.3 57.49
5.74

Fe 27.28
Entropy and Second Lawof Thermodynamics] -110,5 197.6
116. For a given chemical reaction A Bat 300K
CO)
The minimum temperature in Kat which the
the free energy change is -49,4 kJ mol and
the enthalpy of reaction is 51.4 kJ mol'. The reaction becomes spontaneous is
entropy change of the reaction is JK1 (Integer answer) [JEE (Main)-2021]
mol
[JEE (Main)-2021] 123. Assuming ideal behaviour, the magnitude of log
7. For a chemical reactionA+BC+ D Kfor the following reaction at 25°C is Xx 10-1
(A,H" = 80 kJ mol)the entropy change The value of x is (Integer answer)
A,S" depends on the temperature T (in K) as
3HC = CH CH0
A,S" =2T (JK mol).
[Given : A,G° (HC= CH) = - 2.04 x 1051
Minimum temperature at which it will become
spontaneous is K. (Integer) mol': A,G' (CsHs) = -1.24 x 10° J mort.
[JEE (Main)-2021] R= 8.314 JK' mol] (JEE (Main)-2021]
Corpr
 B,ol, the value of the [Thermodynamics of Equilibrium State]
124. For the reaction A,o
equilibrium constant at 300 Kand 1 atm is equal 129. 40% of Hl undergoes decomposition to H, and
to 100.0. The value of A,G for the reaction at L,at300 K. AG" for this decomposition reaction
300 Kand 1atm in Jmol is -xR, where xis at one atmosphere pressure is J mol.
(Rounded off to the nearest integer) [Nearest integer]
[R= 8.31 Jmo K and In 10 = 2.3) (Use R = 8,31 JK nol; log 2 = 0.3010, In
[JEE (Main)-2021] 10 = 2.3, log 3 = 0.477) [JEE (Main)-2022]

125. 20,(g)30,(g) 130. Consider the graph of Gibbs free energy G vs

extent of reaction. The number of staternent/s
At 300 K, ozone is fifty percent dissociated. from the following which are true with respect
The standard free energy change at this topoints (a), (b)and (c) is
temperature and 1 atm pressure is (-)_J Gibbs
energy
’
mol.(Nearest integer)
[Given: In 1.35 = 0.3 and R=8.3 JK molr]
[JEE (Main)-2022]
[Link] standard free energy change
(AG°) for 50% dissociation of
N,O, into NO, at 27°Cand 1atm
pressure is -x J [Link] value Extent of reaction ’
of x is . (Nearest Integer) A. Reaction is spontaneous at (a) and (b)
[Given : R=8.31 JK mol, log 1.33 = 0.1239 B. Reaction is at equilibrium at point (b) and
[JEE (Main)-2022] non-spontaneous at point (c)
In 10 = 2.3]
C. Reaction is spontaneous at (a) and non
127. One mole of an ideal gas at 350Kis in a 2.0 L spontaneous at (c)
vessel of thermally conducting walls,which are D. Reaction is non-spontaneous at (a) and (b)
in contact with the surroundings. It undergoes [JEE (Main)-2023]
isothermal reversible expansion from 2.0 L to 131. For the reaction at 298 K, 2A + B C.
3.0 Lagainst a constant pressure of 4 atm. The AH = 400 kJ molr and AS = 0.2 kJ mol K.
change in entropy of the surroundings (AS) is The reaction will become spontaneous above
JK (Nearest integer) K. (JEE (Main)-2024]
Given: R= 8.314 JK' mol 132. For acertain thermochemical reaction M ’N
at T= 400 K, AH° = 77.2 kJ mol, AS = 122
[JEE (Main)-2023] JK, log equilibrium constant (logK) is -
128. 30.4 kJof heat is required to melt one mole of x 10. (JEE (Main)-2024]
sodium chloride and the entropy change at the 133. For acertain reaction at 300 K, K= 10, then
melting point is 28.4 JK' mol at 1 atm. The AG° for the same reaction is - x 10 kJ
melting point of sodium chloride is K mol.(Given R = 8.314 JK mol)
(Nearest Integer) [JEE (Main)-2023] [JEE (Main)-2024]
 ASSIGNMENT (LEVEL-I)
1. (3) 2. (1) 3. (2) 4. (4) 5. (2) 6. (1) 7. (3)
8. (3) 9. (2) 10. (4) 11. (1) 12. (2) 13. (1) 14. (1)
15. (2) 16. (1) 17. (4) 18. (1) 19. (4) 20. (1) 21. (2)
22. (4) 23. (3) 24. (2) 25. (2) 26. (2) 27. (2) 28. (3)
29. (3) 30. (4) 31. (3) 32. (1) 33. (3) 34. (4) 35. (3)
36. (3) 37. (1) 38. (4) 39. (1) 40. (1) 41. (3) 42. (2)
43. (3) 44. (2) 45. (3) 46. (2) 47. (2) 48. (4) 49. (3)
50. (2) 51. (2) 52. (4) 53. 3 54. 46 55. 3 56. 78
57. 18 58. 23 59. 32 60. (2) 61. (1) 62. (4) 63. (3)
64. (3) 65. (3) 66. (4) 67. (3) 68. (1) 69. (2) 70. (4)
71. 48.00 72. 2218 73. 55 74. 28721 75. 12 76. 6.25 77. 189494
78. 84 79. 15 80. 31 81. 38 82. 8630 83. 84. 600
85. 195 86. 57 87. 2 88. 54 89. 150.00 90. 56 91. 741
92. 200 93. 35.00 94. 1006 95. 1200 96. 274 97. -192.5
98. -326400 99. 82 100. 230 101. 128 102. 5576 103. 727
104. 117 105. 2 106. 6600 107. 360 108. 499 109. 4 110. 492
111. 125 112. 6535 113. 150 114. 2 115. 82 116. 336 117. 200
118. 300 119. 400 120. -13537.57 121. -02.70 122. 964 123. 855
124. 1380 125. 747 126. 710 127. 03 128. 1070 129. 2735 130. 2
131. 2000 132. 37 133. 57