Understanding Cathodic Protection Systems
Understanding Cathodic Protection Systems
The corrosion of metals in contact with aqueous environments (water, soils, concrete,...) is of a nature
electrochemical. In these environments, the application of cathodic protection technique has
to reduce the metal's polarization potential to a level at which the speed of
the corrosion of metal is significantly reduced. The threshold of cathodic protection
it can be determined thermodynamically. It corresponds to the threshold of immunity as
represented in the corresponding Pourbaix diagram from a state from which corrosion
becomes theoretically impossible.
Let the anodes have a more electronegative potential than the metal to be protected (anodes
sacrificial or galvanic.
Note:
The choice of one system over another must be made taking into account the
technical comparisons (see the table) and economic criteria (design,
equipment, maintenance, material and energy consumption.
The metal to be protected is electrically connected to an electrode made of a less noble metal.
who plays the role of the anode in the first battery. In this type of protection, the anode is
consumed by dissolution by bringing the surface of the metal to be protected beyond its potential
of immunity. The implementation is schematized in the following figure:
That the battery discharges, so that the anode is electrically connected to the metal.
that the surface to be protected and the anode are both immersed in the same medium
electrolytic,
-that the installation should be suited to the surface to be protected (dimensions, quantity, distribution of
anodes).
Under free corrosion conditions, the metallic structure has a corrosion potential.
mixed E and corrodes at a speed proportional to IcorrosionIf we apply polarization
cathodic so that the potential of the structure decreases to E1 by the applied current I1
externally, then the object is partially protected, since the rate of corrosion has
decreased and is worth itcorrosionIf the external current is increased to I2to harness the potential
descend to E2corresponding to the reversible potential of the anodic reaction, then the
anodic dissolution will be stopped. The object is then under cathodic protection.
When all the points of the work have reached the potential for protection (EP) which is equal to
that of the anode (EA) , the whole will have become a single cathode thus canceling the current
of corrosion (icorr) by a minimum protection current (Ipro-menWe can lower the
potential of the whole to a lower potential (EPwith a current (IPThe current IPis
always higher than corrosion current Icorrand that it depends on the respective slopes of
curves of the anode and the cathode.
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Note:
Cathodic protection by sacrificial anodes does not have an indefinite duration, it stops.
with the disappearance of the sacrificial metal or by electrochemical blocking. The most relevant metals
employees by cathodic protection are: Al, Zn, Mn which have potentials of
very negative dissolution.
the ships,
The relative value of the potential that the two metals acquire when immersed in an electrolyte
given can vary with temperature. So, a less noble metal at temperature
ordinary can become more noble at a high temperature, which leads to an inversion of the
polarity of the battery. This is the case of the Iron-Zinc couple in water.
At a temperature of 30°C, the standard potential of Iron is more noble than that of Zinc, so...
that at a temperature of 40°C it becomes less noble. It follows that the protection of a
Iron piping by Zinc (galvanization) can be used without risk when the
The temperature is high (this is the case for central heating systems).
It involves connecting the structure to be protected to the negative pole of a direct current generator.
where the negative pole is connected to a current drain plunging into the same electrolyte
that the structure to be protected (soil or water). The direct current supplied by the generator is distributed
in the ambient electrolyte through the overflow and is captured by the structure to be protected which is thus
brought to an electronegativity potential relative to the environment in which it is located. The
current spillway must be made of a metal as corrosion-resistant as possible to have a
relatively long lifespan (inert alloy (15% Fe and Si), graphite, lead, and precious metals.
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Fig. 3: Principle of cathodic protection by imposed current
a
RT Ox
EP E 0
ln b
nF Red
IP ip S
It is used for:
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oil drilling platforms
This method is quite delicate and sensitive to mechanical and electrical incidents.
requires complete insulation. It demands regular monitoring because any modification
current risk of causing a potential variation that involves the corrosion of the
structure.
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Surveillance Easy and casual Surveillance frequent
required by a specialist
The Zinc alloys used for cathodic protection are made from Zinc at
high purity with a particularly low iron content. It contains the following metals:
Pb, Fe, Cd, Cu, Al, Mg and Zn according to the French standard whereas the American standard uses
the following metals as an alloy: Pb, Fe, Cd, Cu, Al, Si, and Zn.
Electrochemical yield 95 90
(%)
(3) with corrosion regulating mixture (75% Bentonite and 25% gypsum).
Submerged structures,
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II.4.1.3: Advantages of Zinc-Based Anodes:
High cost,
The alloys used for the case of mercury anodes are: Zn, Hg, Fe, Si, Cu, and Al. The
The composition of the Indium anodes is: Zn, In, Fe, Si, Cu, Mg, and Al.
Electrochemical yield 95 81
(%)
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II.4.2.2: Scope of application for aluminum (Al) based anodes:
Offshore platforms,
Not recommended for the protection of completely painted works as there is a risk of
passivation if the anode is only lightly stressed.
The yield is better for the mercury anode than for indium.
The distribution of mercury is difficult within the metal, leading to the creation of heterogeneity.
from the surface,
Indium alloys have a more negative potential than those of mercury, hence the dissolution.
is uniform,
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The composition of standard type anodes is: Al, Zn, Mn, Fe, Cu, Ni, Si, and Mg.
The composition of high purity (high potential) type anodes is: Al, Mn, Fe, Cu, Ni,
Si, Sn, Pb, and Mg.
Electrochemical yield 55 55
(%)
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II.5.: Practical implementation of cathodic protection:
There are two ways to lower the potential of a metal structure below threshold.
of immunity (sacrificial anodes and imposed current).
First of all, it is about measuring, when possible, but most often estimating by the
calculate the cathodic protection current requirement of the structure. Values of the density
current ones are provided in the standards and professional references:
sun or seawater 5 ÷ 50
Mediterranean Sea 60 ÷ 80
Gulf of Mexico 50 ÷ 80
Marine bottom 20 ÷ 30
Note:
horizontal or 2l Dwight
verticals R ln 1
2 l r
deeply
buried
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- horizontal Dwight
l 2l4h l 2 2
2h 4h2 l 2
buried à R
depth 'h' 2 l h l l l
The approach to calculation differs depending on whether the metal to be protected is bare or coated. Indeed,
In this last case, the value of the insulation resistance of the coating must be taken into account.
who in an electrolyte (sol or water) has a specific meaning.
For offshore platforms: one of the calculation methods used (by ELF Aquitaine)
based on the hypothesis of cathodic polarization curves.
the potential of the structure is located within the range (-0.80 to -1.00).
IP JS S
IP JS S x
Note: generally, the protection current IPis calculated by the following relationship:
IP I S I Well
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IP I S I Well
m n
IP J Ye S
s i
J Ye S
s i
x J S P P
I 0 i m1
Surface of the wells
Uncoated surface Surface coating
b-Number of anodes:
M n D I m
D I m
n
M
The dimensions of the anodes must be such that: Ecathode EPr Protection
Ecathode Eanode R i E
Where:
EcathodeCathode potential,
R: The resistance,
IP
The current of a single anode, i n
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c- Domain of potential protection EPrecommended
Carbon steel:
S2 20000m, 2 J 2 150mA/m2
S3 15000m2 ,x 0.02,J
3 3 150mA/m
2
Calculate the number of anodes necessary for the protection of the structure.
Lifespan: D= 25 years,
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S1 400m,2 x1 0.05 J S1 35mA/m2
S2 150m2 , J S2 35mA/m2
J well 50mA/m2
We report that there are surface wells S in the [Link] the current IP= 30% of
current consumed by the structure.
The mass of an anode is 7.8 Kg, of which 60% of their mass is consumed over a duration
of a 15-year life.
During a check, the value of ddp increased by 10%, calculate the new current if the
resistance remains constant.
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III. Cathodic protection by imposed current:
The positive pole of the generator is connected to the spillway while the negative pole is connected to the
structure to protect. The current coming from the overflow passes through the ground and then enters the structure
thus creating the desired potential reduction. The following figure illustrates the principle of the
cathodic protection by current withdrawal.
The current withdrawal is used whenever the intensity required for protection is
important or that the required scope is high: buried or immersed coated conduits
or nude, drilling casings, important marine structures, large storage tanks
dimensions.
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III.3.2 The characteristics of the generator:
I U
R
Where U is the voltage of the direct current source and R is the resistance of the circuit.
The voltage is generally in the very low voltage (ELV) category below 50V.
The resistance of the circuit is generally conditioned by the resistance of the anode mass. Therefore, there is
interest in obtaining for this anodic mass a resistance as low as possible.
The installation of the withdrawal station is determined by taking into account the considerations
following practices:
In general, it is advisable to avoid placing a tapping point at the end of a pipeline because
of poor distribution of potentials.
The generators,
Thermoelectric generators,
Fuel cells....
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III.3. 3.2 Spillway or anodic mass:
The graphite,
Ferro-silicon,
Platinum titanium,
The cross-section of the cables is determined based on the allowable voltage drop and
the heating. The nature of the cable insulation is determined based on the environment (the
hydrocarbon clothing, seawater, chlorine, soils, ..)
The positive (+) and negative (-) terminals on the extraction device and the cables that connect to them.
must be identified to prevent inversions that would cause corrosion to the structure.
Spillway (+)
Structure (-)
These are essentially the circuit breaking, protection, and measurement devices installed at the station.
fixed.
Cut-off devices: they allow to establish or interrupt the power supply to the station
extraction.
The choice of the type of anodes to install depends on the following conditions:
The environment,
Consumption (lifetime),
The use of scrap metal can be interesting when it is already buried nearby.
the structure to be protected.
Ferro-silicon:
These anodes are easier to implement than the previous ones because they can be
delivered ready to use.
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Magnetite :
The disadvantage of these anodes lies in their fragility when exposed to the sun or
at the high temperature during the installation work.
Graphite :
Environment: all environments, provided there is the presence of a backfill especially in impermeable environments
where it ensures the evacuation of gases.
In case of use in water, it is necessary to provide impregnated anodes (impregnation carried out
with linseed oil).
Consumption: 1 Kg /A year,
Platinum titanium :
Consumption: 9 Kg / A year,
Niobium platinum :
These anodes have better mechanical resistance than those made of platinum titanium. They can
admitted tensions of 30 V. The drawback is their high cost.
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Platinum tantalum:
This type of anode has the advantage over the two previous ones of supporting up to
110 V. The downside remains the high price.
Note: for these three types of anodes, it is important to specify that the consumption
only concerns platinum, the other metal serves only as a support metal, that of
platinum (21.3 g/cm)3).
The location of the overflow is determined by a preliminary study of the terrain and the structure.
to protect.
The distance between the overflow and the structure must not be too short. A minimum of 50 m.
is recommended.
The soil resistivity is measured, the choice is made in the area where the resistivity is the highest.
weak.
The resistance of the spillway must be as low as possible to avoid excessive tension.
at the terminals of the rectifier.
Anodes installed horizontally: this installation method should be considered when the soil resistivity is
shallow on the surface and when there is space available on the land. It is recommended in the case
where discarded rails are used.
Anodes placed vertically: these are surface overflows but the anodes are buried.
in holes dug at the bottom of the trench where the cables are laid.
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The surface soil resistivity does not allow for an acceptable value.
The process consists of: drilling a hole whose steel casing is made from a tube of diameter
interior ranging from 120 to 200mm.
The casing must be installed as the drilling progresses. The tubes being
butted end to end.
Drill below this depth to receive the total number of anodes planned.
Introduce the anodes into the drilling (we will form several electrically connected groups)
independent). By ensuring the maintenance of the anodes with rot-resistant cordage and not by the
electrical cables).
Fill the space between anodes and tubing with graphite (if the tube is empty of water) or
iron shot.
Application :
The overflow must carry a current of 15 A and its expected lifespan is 10 years. We want
limit the voltage at the output of the rectifier to 24 V. the resistance of the reservoir should not
exceed 1.6 Ω. The resistivity of the soil measured at the location of the spillway is 20Ωm.
It was decided to use impregnated graphite anodes. Data: length L=1550mm,
ϕ=150mm
The length of the anode is 1550mm, the diameter is 150mm, the approximate weight is 50Kg.
consumption is 1Kg/[Link].
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Basic principle of cathodic protection
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Soluble anodes on the hull of a boat
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Soluble anodes 'diffused' on an immersed structure
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Principle of protection by soluble anode on underwater pipelines
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Reference electrode on the ground, along a pipeline
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Principle of imposed current
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Three main spillway systems are used. In each system, the anodes can
to be installed vertically or horizontally.
Overflow at a distance: the overflows are installed at a point distant from the structure.
protect. This type of spillway is used for both coated and non-coated pipelines.
Distributed overflow anode: this method is used to effectively protect a
drilling network and geometrically complex structures, such as those of the stations
compression, pumping, storage parks, pipeline terminals, refineries, and areas
urban.
Parallel weir: this type of weir can be installed with anodes in
parallel and proximity of the protected structure.
For each method, the anodes are in principle installed in coke breeze, which will
prolong the life of the anode.
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Typical installation of an anode in the ground
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Example of a centralized cathodic protection control system
Examples of calculation in protection: the 2 exercises below (platform and pipeline) are more
to be considered as examples (and not exercises) to be presented and solved 'together'
with the instructor.
Simplified calculation of the anodic mass and the number of anodes needed for protection
against the corrosion of the piles of a production platform.
Data
Surface to protect:
Tidal zone: 500 m²
Submerged area: 10,000 m²
Listed area: 400 m²
Assessment of current needs
Tidal zone: 90 mA/m²
Submerged zone: 60 mA/m²
Zone recorded: 30 mA/m²
Types of anodes
Aluminum-indium alloy
Charge potential: -1.05 V/Ag-AgCl
Consumption: 3.4 kg/A/year
Rendement : 0,9
Cylindrical anodes l = 2.50 m, D = 140 mm, net weight: 90 kg
Lifespan:
20 years
% remaining anode at end of life: 15%
Determine
6. The total current requirement
7. The anode mass to be installed to ensure protection during the expected lifespan
8. The number of anodes
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Determine
9. The total current requirement
10. The voltage required at each station to provide the protective current, considering
the resistance of the circuit structure - electrolyte - drain is 5 Ω
11. The power delivered by each extraction point
12. The anode mass to be installed to ensure a lifespan of 25 years
Redo the following calculations assuming an uncoated pipeline externally. Density of
necessary current: 30 mA / m2
13. The total need for current
14. The voltage necessary at each post to provide the protection current, considering
that the resistance of the circuit structure - electrolyte - drain is 5 Ω
15. The power delivered by each withdrawal point
16. The total current demand
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