ML eet hs earele eee eel HPS: Diaplaement of _e= demi Movement ef e7 density =r b ti - bond o-bonid Sea ern aes, Resonance Frnlchive effot lope Mine Mesomeor’e —~—~—— acct Eypet Freed eppeck aa aap He mR SIR sxe Stesae Inhibit on im Stouts Inhibttfon on, Resonamce Protonation om lca ore . Promeatt eee Stabtlity Addity amd. Bosietg Resonance “ on why? 8 pnseson, terx* + oS 1, ot ar ‘ eu j—-h-S-S “o Dipete moment. — — > > Bo LP GPG ‘ ng i N Aaa Ne a Quai- aS ai os| 3 Oe eS ne co ok Na Hoo? «Al adjacemt cenitixs ahould have p-orbi tel. + ACL p-orbital should be same-plane SR SL AL ie hee oe oO eo hm eA a — Sp Hybd"® SEE) 6p byl’) 4 4 (lone pain im sp? hybrid overtal’) —C=C¢ sp Clone ore inp orbilee) fox ens EZONANI CE ters oe a ot pa . <> Q ae Cpovotte? ) Cp? byt our tal)) spt sp Crd CepPhybrid) ‘yCote IE c No spt a0 Se oe a ae Buen A ae ? Ho — Fors, tp ee hy brief Co caksed) . ‘ Nok wnvebtred an resonance > c= Cae N-—>Sp* : 4 Ap sp? ( tocalteed >) : - Sp (localised), = < le | P= BQ] QM CNG - SN aN, Sa Re ee i sr | ’ i ofa P (debrcalised) | ) Gus; - ne or (localised) | aa BS ope | , Der > Sp* Clocalised) J > 2st opt o- sp? ) fw Bp > Sp? hye orbtta). | ) ik; } Up esp 7 ) » 2. sp e ay | Py Ep ) a P Clelocalesed ) , > ) ? y ) )3+) ‘Vacant p-orbitaf and dlocalised _loral'ted) P CdelocarsedS Lente ctl sp Corbouakion 0 i 1 OD) A>B— ome ‘— 6 -Me 4 Usp Oop a“O per back bow de oak, : ate “d wy gc ee Ques. a } ese et aoe N \ Nose To \ 2b, Borarine eae cx ene) ae n n we Bengere Sa nee Srovgan’ a spt 4+ NO 1s sp? oe ae ee oe Ques s- "0 sp* ay ane> Cre « \ +s Trigonal planer ia 4 an) a” se nt a ane~ oH on, ate { i 2ne~ L se* i ee a A am hh ew ma, Raclicaf 9nd n-bond | 7 ae eg. NBs ene nae Ae 4 av @ sp> hv Ga oa Tos . nv See plane u oO - a, =o = =f d . = a ie * No atoms dhoutd clidtocte from ith Product =3 [Link]) or Gtraf position. . Onley T-bonds dhoutdl break ow pe. res) o-4 Sues UL : + e a en, — oMe <> CL=O0Me ( 5 eg. gun ee ce Ss Coches ls 1 ” CH= C=NH (Lautornes)) eg. a oO mm se Resonance somes (S-rvctural’) 4s Molecule with mémimury no. of charges ix meit dtebk. 4 0-4 av Gd oh 2 with max. me- ef 1 bonds 43 more atabh. » Molecule ey. Gh—o-Me < Oh =0-MeGia SR Gre) Gin) a mean C attroct’on) eg: o7 < ae — ian 3 fe sw Le Sy tae PE Ofk +0. z w (ay tone cy 2 C4) Sa - pe OR - Hocmoy u 1 par 27324] ‘ f i ig a> 27394 rey @ 3) <2 cf Cased) > Chase demaite, T + C d : > Choe demaitiy ee 5 9 8-5 Hand attack : (actt) : 5 a Te in L t iL "l + & { L (tani) Cuntabic) y More coria'bulion ° Suss;- CHyng x its Phy Gar PROPIA PRACGEO2AHSS—F,-c, -@y,-2 Strength Comparison of +4 |. Extent of overbapping 9 a Q.0 @ 09 Q eg. C= -# > 5766" > o Ss On ata or ap 9P ee CHA NL > CH =CH— OH > C4, = CA- F 2p... Pee fe ale e-g- CH= CH — PHL >? CH=CH-SH > CH= CH CR \. A427 On = cH O# cu, = cu — CO —e— cH, ° g on pre chy, aw Ss ho snk Ka Le pag Vee Ochs a Reason a. + Reason 2 0 =o > 2&, nye Oe a. Cr ccmer td) Ox> Oy Gay dome, | We Know, Ot em tal P ' ’ —oMmMe Cmere en.) 1 ' wa: Wt »_£6 es r7o™ ely ele er OeCs Ac Na, uss i- t&) eo “ O88 © © 4. mem) tk) ) is) ku) uss + + = e + Shaki Lit = CH, - On O4,- NHa on, -0- Een, ty CH, [par] o ~ ® cay ae Carb eactive oO 7 i ! kectrophi le u = —= -move el a . me : : ae o Y —c—O0cn, ~—3 i Ee eon eo 2 o —d-NRLFFTCSESEFSGIFSIFGFSOUCVCLCsEFesegeegsrugcs Vacant p-orbttal Vacant d-orbite} pared 2 euate vacant P ; - Orbited = i _99 Pie W 0. do v - _90 one oO cxc ve see Ot, ~ : ORO. 6 Ree (back bowling) 2p <— cac —b— oct, w Cac r eT Oy aS ° te Resta Ben, @e-Gas — ° ee Cf et ON AR | ae? e=c-c NR, > Over order C-M) ele ae ° 7 ° ° a Nu oA den x Xe'y uC HOA, > 5 sg O [Josevain Ao Gar TA Coa wt) CF @ycry- On, “ean) Papas (3) CH cr —eH— Cy ea haa oan @ C5) 2 n7 SH (on) aa) Yd Com)e — dH — cong) (0 «) ao exw) DMD FX} Pr aie ba] 4 : Mw, sted } ( Electeonie > Stet ~ act “s wee > (factor factor Heat cbr, von 5 Ae I, 2 La sta Pale Soa Att=-ve CRelened) L Kak of Hydration CE) Sac Le Dig < Ate + | a we & |b, PL L senane = 6 Pekene e 6 R s Hon ~6o Oe ~65 —10 Cks|met’) anal” Ua a b e qd Stability — boc rads a HoH — asd re> &_— = J Sus mieten he fpttowing - SS Cio 7S (ict), @ AN (64) r Co oe ee} a 4 4 4 ie Ez \ / ee _ he y of 4 ky kK, pe pease bee = a a) «SOB a (a) w 2, | me,s uss \— ba Ou os are, b> a) aX & Gus 7 eR gt = —. psa 4a) Leotepic Espect 4 D Asie n—c— da > pe — a TS H 1 ' a 4 D < 2 3 (opener (weak ord) > VT out [chore] farr (strong bel) srretching frequen L oulBurs; Onder of rede = ° Dee eles Aewory [TSW Ses Res ia (ics \ ch a wo wie A CH, eda Cl , = oS od a af ras mest ; kn) Ks) athvatek Ce Q ( =) = == Hox. 2 g-o-R, e ar er pene cab Ft Zs q a LES oes + a“ — or Lee: oe a Guus most ve Gus a fo affects ty ahorger shan Hy peronfugation © Tope oe fet rerhenties ac bp. donate — Gare + ase 4 acuptot on — Base yy cere Cats ced | : tone parr acceptor —» A | | . Ka = * THay * pha = — fog Ka pa sH Sues — HE g HO < HBr CHT . Guss;- we < a (ge, S>0) = = el = = = . Ht > Ad Ht donee > Aetd = a = => 2 a oe 2 . > i:2>UwO>NHy>cHy, qo, NE -t dees ee — HF Guar Mtg Oty, HO, o Quer CNECH , Oh= mn ax b- © a Quer cnet, cH en NMS) 20 2 3 oe Qussi- i eco" on NE ty Req. Bull ay ~~ 3) wot 1) 4eq. Bul 2) Ek oe on 1 3e9.6: wy oe" oe On pels 4>Br13Z we mriae eT * bee asa > = Hw Pen eS ago u Va ar > Nog 3 - Bo > - eBN > Te nK b ses oy ra oO * a cM on > -d-NR FR S KOR DH OH D> CECH > MA's csp) — CH=CH, 2 2 on eeis 4 orter: 6 —ch > NR > - p> -co8 > 3°27 >a! SAN ~ * -T > —p4 ay one ‘ A Dan >P Rute o) 7 saat,” ie TAs eRe Gas) “Dfitone Numer Power a Ge Gus- No, : aie < AT’? 46 Exo ° @aeo i BD N Sues + Os mek > po c-coo~ 5 7 > 4” Tefck : [OMSGAP | o>m>s> p> 4 dimed@licn _cooH _-cooy on, (<5), ~cooy coor (Matonie act, Conccing acd) — (Glutune ac f ore coo} { a ous (%), 274 dinociatior, coe = CoUH O © con AON 7 ss 1 if Ka, 2» F274Asay of Beate WL — oH ie por, a ae Oo €1 a et oH *- Oo Gi. OG 8D & ry rw &ss ©, coun 55 = ee Les i) (a5355) em ey e ® coy, eS OS ox @x) (percrfugny — ® @) 1 uae Metonet spetytaoreacic acd , Ce es hen; aa 2s cricot gen d-on ) S | Kgic oa BrHra pha (2543273) a eee o-4 ee a | eee cae Concony”n Uydroeators | H Gu Fm ~ ~ Cm ~ e& @ a a a * q s ai “SIR | Contho _tipst) Cstecte Intitbitin rm Resonance) ately = Oa J ae oF Aone S| se ia tie ° cay o oO 2 cn, a e fol w © sey re) wy Cem ome cYM oot = Suy'- = 2 w Bre, o* @ QD ESTEZES] ' me ty fed : im Ne $a) sh phenol. a 2 > = Ao ea & a @ of wo ¢4 @ — a Q Chine coe wo [Rea para Onde, Ce - ig ° ay : Le, or iS fe 325453) o A>8>Qr4 ~ expected [Bz SS 254) AtakSusi: on im i ” Se & on o e & wo peealin ow Ont (a) ° es ° Oo wat > LiPo tal “an Nap ~~ Findon Resonance les ° Sussi- Re r a H> oy me We is : ° a Ye ie e eC pa>b rma ae 4 mes Coon > CooR z aye ' Sila aici ce tr ona Gyehie vs wes ak < oa Cdond wtation) cde Jerry March tot — Pka = 13-3 ee S ° ° ° om ee oS aye 2 Conetdnam aud) °. maa x a pha 8-5 ott gly af de 7 ° a” a o 9 a : : a b> arc a. ve a on boats & Comparision ° g bia or te a Vere Pha z- [BSase] o o deprotonate easily fn P of bare ae eo HA oe more — asasey| Cry he OHRHMMR CHE C-He — [e> EP I ne ‘o a Cy CHa | CHS EH HOM, CH= OH — OME VICE CMY sp Fs [astse Seg>b >d>c [Bape] emrty |x Tendoney to domale e pain f | Netra Pnton [ge Py Nay ena, ete C4. Fo, oH, OR ek FF gaan | i. Electromenativty pee Te “Basietey oe bb co Sus & a ie ee acl | | Quz- ENA Ch EN-H | Cy cen [A>b 56 spe P 2 Resor Xx say a © a. fee Oe NA, bo CHE ae CH= OH NH Cn eae 5p? See spe Sp [ase >¢ >) Be SP Ge WGP “> Vspe a sp? bs ? cen P pe Gea 3 Prromatieity Case eadetlny ‘ > hae Se 4 se >.QA>b>d>c 3 fd laa ch sp> b tachi Effyeek = Ae & " Go E a oa eS aie Co 5es Y* wnt, 2 i ee ie | x | aL ® Ay in onjigle A eugate oefel fee =a id ® ane eee ee 2, ockd, fweak Bose <= SHY ONG Aenut = AH - Baaiet ty - ay eo SO GD GO oe ve yo = b- : actatty — (B25) Bu: 2 Ww DP Soa Nae naan ie oS Bastetty - x : ° fe el a en ences spoon hn oe ae Piety - [AP E> Eb Casey Q>C>d>b Ge ee af ee en A a > os a Bus Phy NAT ph Nast Pr Mie eee ON Qe eh-n Ayer Phat cobsa mee ok kat a>b>e Sponge Eiger cemerte “aS ei oe ae « ey Peony CSponge pyreey ETL CRRA I SEL rrPee ae. Sma Cow he - ee at e } D Ig ene) or Stability— earercbh Busi FT NAL cHEcy CH=CH” On aes © aa 4 na oe 4 spe Gasisty- gr>b> cre? > o = ae < ge dr craeb a J a 2 eat 7 S = (aly Erase ft) OD, Glu, Chey j i: o> fie a cry se 7 ss a>bre we ve i) a Nor © a 2 oD & 2 Gastetty — fig et ET nt te ch Oe Bg teeth ZS envelope Ytone aie in feepperd, Bont Sty Coed cn : POTCCICISIITt oe TANSa, spr tiiotdiged Cplaner) yee Resonance © Hucktls Re 402 (Prromaxie) un (Amat arvemabie) Citar ran trere ane mon aromatic NA Promatishy i f-membonid OG ae = 1. rt LI ay aromall, Aromat ese a aaoav Fromattcthy in _6- membered Bit oO TL! Nee, 0. x 7 spe GI oo & Q@ © a AA A in _ eae eee se a Os MO ONS of A le 4 eee wwe ea eneee eae eeseaePrrvenechiet ty A 8 embed rg : ¥ “> donee Ooo O° corte Shaped Feast pAamo a NBMO — — Aemo Lame a Ours O= 4 Sey, | 5 oe 2 LEN, oe z ) ab aL co C > Se a ol JJ Ca oe onnbent at avemalto. Crle gets Reenance) Ossie ch ots a bree 4 é wf : Me une wreAu Pproenakie. Suasi_ froment o==— © Non- folaw Ce 2 f] more dtabls > Groat Fromme a igh Dipole momerd nS a C7 <6 ° Sabk in polar form (mune stable) MD Tie etek ath tery.) Barun Sues 6 = oa Ye \ \) ae pis . g pm tt D8 SF poten Garver T x Y usc g ss Oks A 8 Senders ~ gut roe = SID a A NA fee nA 16 - Anaulene, Ae: Arrwtene sete © 16 - Brnutere_ ls age LF wa (non- planer) sh aah hy PIPPPSCPIIIPTIPOPR SP TLOLAR ate eeGe eee Je a ce EN __ Sees | & nae er aarsoaa? eee cH, Orn = Ge On-O Homo axomatic — yee ° Thy hove sp? hybd. Carbon center adfacet 42 a tre ov -ve Charge, my Tah op? hybd carton ts pred te Lie out of plone Box lane, 4. ee ", ar © : * Homo - avornahie eg FY = i-t a af a sS wD YrersD 4 a Bengond Ring 7, Armatiiity,Buse oct es | (O. = Go ie pane positon Resonance enenauy- Toxat Resorance- per ae Boog BE Kk cal met”? BE keel mt! BoeS kcal mot” GA Kee met *L = 29 Kal met"! BY Keal mot4 *3= Bo Keal mot Fo K cal mot! x3 = Stability 5 Gengere > Naphielens > Phenantinrene > Amtirra cen gar remit D> OO * BMO very Aiacaxt ‘ ° low a. en. Arme| ation eet > Shantag of double bond. @ . Go, ae Be —I Ji> lk he me Heeso, ser ES Aco Higiy ote Ho. } A co © ° a ret care Neale 4 I >It > 5 Aaa oe ena re Dd H! (Squaic aid) fv Zurac NowleneraToRe_ simple Bicycte ce L e own eta cn Btoyelo (4-2° 0) Octaome eo Blacko [y-3-0JNonane Conger oe fe Bieyebe (42.8) nee tae Bagh Od CE ok SS pre Ween (Cope a in oo fey clo [4.3.4 > mw see ‘io8 Bateyeto [aa-083 fentane 1K 4