CHEMICAL KINETICS
•CHEMICAL KINETICS- refers to the study of the rate by which a reaction occurs.
•The rate of reaction is the speed at which a reaction occurs and measured as the
change in concentration of either reactants or products over time.
The rate of
disappearance of A
The rate of
formation of B
For the reaction A B, the rate is
Rate of Reaction Change in concentration of A
Used to indicate a change or Change in concentration of B
difference
Used to denote concentration
FACTORS AFFECTING RATE OF
CHEMICAL REACTION
Concentration of reactants
● As concentration of reactants increases, the rate of reaction generally
increases. A high concentration of reactants increases collisions per unit time
leading to an increase in reaction rate ( except for zero order reactions).
Temperature
● Temperature is a measure of the kinetic energy of a system thus an increase
in temperature makes the molecules more energetic thereby increasing
collisions per unit resulting to an increase in the reaction rate.
● Activation energy- the minimum energy needed for reaction.
Presence of catalysts
● A catalyst increases the rate of reaction although the catalysts itself is not
affected during the reaction. It increases the rate by helping break chemical
bonds in reactant molecules and lowers the activation energy of a chemical
reaction by providing a different pathway for the reaction.
Example:
a. Iron acts as a catalyst in the combination of nitrogen and hydrogen to form
ammonia
b. Enzymes (biological catalysts) in yeast convert sugar into alcohol
Surface area of the reactants or catalyst
● The greater the surface area of the reactants or catalyst the faster the rate
of the reaction. Smaller pieces of the same mass of solid have a greater
surface area compared to larger pieces of the solid. This causes a rate
increase because the reactant particle will have more chance to hit the solid
surface and react.