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Physical Significance of Wave Function

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55 views13 pages

Physical Significance of Wave Function

Uploaded by

maneeshraj422007
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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MODULE - II

QUANTUM PHYSICS

Dr. C. R. Kesavulu, Associate Professor, Dept. of Physics

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MODULE - II
QUANTUM PHYSICS
TOPICS IN QUANTUM PHYSICS

 Introduction to quantum physics

 Wave Particle Duality-de-Broglie’s hypothesis

 Davisson and Germer experiment,

 Time-independent Schrodinger equation for wave function,

 Physical significance of the wave function,

 Schrodinger equation for one dimensional problems–particle in a


box.

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SCHRODINGER TIME INDEPENDENT WAVE
EQUATION
 Austrian Scientist, Erwin Schrodinger developed the
wave equation of (matter wave or de-Broglie wave)
the moving particles whose solutions give the possible
wave functions that can be associated with a particle
in a given situation.
Schrodinger
This equation
waveis equation
popularly
is aknown as Schrodinger wave
mathematical
equationdescribing the energy and position of
expression
the electron in space and time, taking into
account the matter wave nature of the electron
inside an atom.

Erwin Schrodinge
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SCHRODINGER TIME INDEPENDENT WAVE
EQUATION

wave function --------------> (1)


Where
is amplitude,
,
,

The Schrödinger wave equation is a linear partial


differential equation that governs the wave function of a
quantum-mechanical system.

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SCHRODINGER TIME INDEPENDENT WAVE
EQUATION

Now, differentiating (1) with respect to ‘x’ we get


=
=> =
= > = [from (1)
= > = 0 ----------------- (2)
OR
= > + Ψ = 0 --------------- (3)

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SCHRODINGER TIME INDEPENDENT WAVE
EQUATION

we know that Debroglie wavelength λ= h/mv


+ = 0 ------------------ (4)

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Now, we know that the total energy E of the particle is
sum of its kinetic energy K and potential energy V
Therefore,
E = K + V and K= ½ mv2 =>
m2v2 = 2m (E-V)--------- (5)
From (4) & (5)
+=0
The value of h/2π is considered as
Therefore, =h/2π
+ = 0 ---------- (6)
This is Schrodinger time independent wave equation in
1-D

In three dimensional it can be written as


+ + + = 0 ---------- (7)
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PHYSICAL SIGNIFICANCE OF 
The actual physical significance was not clear.
Max Born’s interpretation of ‘’, given in 1926, is generally
accepted at present.
As ‘’ is a complex function is a real value.
|Ψ|2 at a point is proportional to the probability of finding the
particle at the point at any given instant.
The probability density at any point is represented by , the
probability P of finding the particle within any element of
volume dxdydz is given by

Since the total probability of finding the particle somewhere is


unity,
is such a function that satisfies condition

satisfying above equation is called a normalized function.


Besides this is a single valued continuous function.

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Characteristics of Wave Function

 function must be finite


The wave function should not tend to infinity. It must remain finite for
all values of x, y, z.
 function must be single–valued
Any physical quantity can have only one value at a point. For this
reason, the function related to a physical quantity cannot have more than one
value at that point.
 function must be continuous
the wave function y and its space derivatives should be continuous
across any boundary.

Wave functions satisfying the above mathematical conditions are


called well-behaved wave functions.

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The Nobel Prize in Physics
2024

The Nobel Prize in Physics 2024 was awarded jointly to John


J. Hopfield and Geoffrey E. Hinton "for foundational
discoveries and inventions that enable machine learning with
artificial neural networks"
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The Nobel Prize in Chemistry
2024

The Nobel Prize in Chemistry 2024 was awarded with one half
to David Baker “for computational protein design” and the other
half jointly to Demis Hassabis and John M. Jumper “for protein
structure prediction”.
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