VSEPR
Theory
VALENCE SHELL ELECTRON
PAIR REPULSION
VSEPR Theory
Predicts the molecular shape of a bonded molecule
Electrons around the central atom arrange themselves as far
apart from each other as possible
Unshared pairs of electrons (lone pairs) on the central atom
repel the most
So only look at what is connected to the central atom
Introduction
Linear
2 atoms attached to center atom
0 unshared pairs (lone pairs)
Bond angle = 180o
Type: AB2
Ex. : BeF2
Trigonal Planar
3 atoms attached to center atom
0 lone pairs
Bond angle = 120o
Type: AB3
Ex. : AlF3
Tetrahedral
4 atoms attached to center atom
0 lone pairs
Bond angle = 109.5o
Type: AB4
Ex. : CH4
Trigonal Bipyramidal
5 atoms attached to center atom
0 lone pairs
Bond angle =
equatorial -> 120o
axial -> 90o
Type: AB5
Ex. : PF5
Octahedral
6 atoms attached to center atom
0 lone pairs
Bond angle = 90o
Type: AB6
Ex. : SF6
Bent
2 atoms attached to center atom
2 lone pairs
Bond angle = 104.5o
Type: AB2E2
Ex. : H2O
Trigonal Pyramidal
3 atoms attached to center atom
1 lone pair
Bond angle = 107o
Type: AB3E
Ex. : NH3