Sodium phosphate is an inorganic compound with sodium (Na+) cation and phosphate (PO43-) anions. It is also known as Phospho soda. The molecular formula of sodium phosphate is Na3PO4. These salts can be found in both anhydrous (water-free) and hydrated forms, with hydrates being more common. Sodium phosphate is used in various applications, including food processing, water treatment, and pharmaceuticals. In this article, we will look into what Sodium Phosphate is, its structure, properties, reactions, uses, etc.
What is Sodium Phosphate?
Sodium Phosphate is an inorganic salt composed of sodium and phosphate ions. The molecular symbol of sodium phosphate is Na3PO4. Sodium phosphate is also called Trisodium Phosphate, Sodium Orthophosphate and Tribasic Sodium Phosphate. These salts can be found in both anhydrous (water-free) and hydrated forms, with hydrates being more common. Sodium phosphate is used in various applications, including food processing, water treatment, and pharmaceuticals. In food processing, sodium phosphates are used as emulsifiers, thickening agents, leavening agents, and pH control agents. They are also used in water treatment to control pH and as a mild laxative. In pharmaceuticals, sodium phosphates are used as buffers and chelating agents and in preparing other pharmaceutical compounds.
Sodium Phosphate Formula
The molecular of chemical formula of Sodium Phosphate is Na3PO4
Sodium Phosphate Molecular Mass
Molar mass of Sodium Phosphate is 163.94 g/mol
Types of Sodium Phosphate
The most common sodium phosphate salts are:
Monosodium Phosphate (MSP)
Also known as sodium dihydrogen phosphate (NaH2PO4), it comes in anhydrous, monohydrate, and dihydrate forms:
- Anhydrous formula: NaH2PO4
- Monohydrate formula: NaH2PO4·H2O
- Dihydrate formula: NaH2PO4·2H2O
Disodium Phosphate (DSP)
Also known as sodium hydrogen phosphate (Na2HPO4), it comes in anhydrous, heptahydrate, octahydrate, and dodecahydrate forms:
- Anhydrous formula: Na2HPO4
- Heptahydrate formula: Na2HPO4·2H2O
- Octahydrate formula: Na2HPO4·8H2O
- Dodecahydrate formula: Na2HPO4·12H2O
Trisodium Phosphate (TSP)
Comes in anhydrous and various hydrated forms such as hemihydrate, hexahydrate, octahydrate, and dodecahydrate:
- Anhydrous formula: Na3PO4
- Hemihydrate formula: Na3PO4·0.5H2O
- Hexahydrate formula: Na3PO4·6H2O
- Octahydrate formula: Na3PO4·8H2O
- Dodecahydrate formula: Na3PO4·12H2O
Pyrophosphates (DIPs)
Examples include disodium pyrophosphate (Na2H2P2O7) and tetrasodium pyrophosphate (Na4P2O7)
Polyphosphates
Examples include sodium tripolyphosphate (Na5P3O10) and higher molecular weight polymers like Graham's salt (sodium hexametaphosphate)
Structure of Sodium Phosphate (Na3PO4)
Sodium phosphate (Na3PO4) is an ionic compound composed of sodium cations (Na+) and phosphate anions (PO43-). The phosphate anion is covalent, while sodium forms sodium cations by losing one electron. In the structure of sodium phosphate, three sodium cations are attracted to one phosphate anion, resulting in a zero net charge. The compound exhibits an electrovalent chemical structure and appears as white or off-white crystals, granules, or powder.

Properties of Sodium Phosphate (Na3PO4)
The properties of sodium phosphate is as follows:
Property
| Value
|
|---|
Appearance
| Off-white powder
|
|---|
Odor
| Odorless
|
|---|
Covalently-bonded unit
| 4
|
|---|
Complexity
| 36.8
|
|---|
Hydrogen bond acceptor
| 4
|
|---|
Molar Mass
| 163.94 g/mol
|
|---|
Physical Property
The physical properties of sodium phosphate (Na3PO4) are as follows:
- Appearance: Sodium phosphate appears as an off-white powder
- Solubility: Sodium phosphate is soluble in water
- Density: The density of sodium phosphate is approximately 1.62 g/cm³
- Melting Point: The melting point of sodium phosphate is 1,583 °C
- Boiling Point: Sodium phosphate has a boiling point of 100 °C
Chemical Properties
The chemical properties of sodium phosphate (Na3PO4) are as follows:
- Acid-Base Nature: Sodium phosphate is a salt that can act as a buffer, helping maintain a solution's pH.
- Chelating Agent: It can act as a chelating agent, binding to metal ions to form a stable, water-soluble complex.
- Reactivity: Sodium phosphate can undergo various chemical reactions, such as reacting with acids to form phosphoric acid and corresponding salt and reacting with metal ions to form insoluble precipitates.
- Sodium phosphate is an ionic compound with an electrovalent chemical structure.
Chemical Reactions of Sodium Phosphate(Na3PO4)
The chemical properties of sodium phosphate (Na3PO4) are as follows:
Reaction with Hydrochloric Acid: Sodium phosphate reacts with hydrochloric acid to form phosphoric acid and sodium chloride. The chemical reaction is illustrated below:
Na3PO4 + 3HCl → H3PO4 + 3NaCl
Reaction with Calcium Chloride: Sodium phosphate reacts with calcium chloride to form calcium phosphate and sodium chloride. The chemical reaction is illustrated below:
2Na3PO4 + 3CaCl2 → 6NaCl + Ca3 (PO4)2
Uses of Sodium Phosphate
The uses of Sodium Phosphate (Na3PO4) include:
- Short-term, local treatment of inflammation with neomycin as bacterial prevention, such as after glaucoma surgery or cataract surgery
- As a mild laxative, stimulating the emptying of the gallbladder
- One of the most palatable saline laxatives
- Used in the form of an oral solution as an anti-hypercalcemia
- Control of the pH of water hardness precipitation and as a control agent in mildly acidic solutions
- In the preparation of pharmaceutical compounds as buffers and the formulation of many pharmaceutically beneficial compounds
- In detergents to soften water and as an effective anti-rust solution
- In the food industry, as an emulsifier, thickening agent, and starting agent for baked goods
- In the control of pH in processed foods
Environmental Impact of Sodium Phosphate (Na3PO4)
Here are the environmental impacts of Sodium Phosphate (Na3PO4) in pointer format:
- Sodium Phosphate can cause skin and eye irritation and burns, respiratory tract irritation, and other acute health effects. Chronic health effects such as cancer can occur at some time after exposure to sodium phosphate and can last for months or years.
- Sodium Phosphate can cause eutrophication of water bodies, acidification of soil, and accumulation of organisms during its use.
- Sodium Phosphate can cause the imbalance of phosphorus and sodium in the organism, causing hyperphosphatemia, hypernatremia, calcium and phosphorus deposition, renal function damage, hypertension, and other problems affecting the organism's health.
- Sodium Phosphate can cause soil acidification and adversely affect the activity and diversity of soil microorganisms if the amount of sodium phosphate applied is too large.
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