No.

1 in a series of essays on Radioactivity produced by the Royal Society of Chemistry, Radiochemical Methods Group

Discovery of Radioactivity
Ear th has been r adioactive
since it was formed 4500 million years ago. In fact the age
of the earth can be calculated
from a detailed examination of
its radioactivity, par ticularly
the decay of uranium to lead.

Being a mineralogist Becquerel had a

wide collection of minerals, many of
which exhibited phosphorescence. His
experiment was to wrap a photographic
plate in black paper (to protect it from
direct light), place a phosphorescent uranium mineral on it and expose it to bright
sunlight. When developed the plate bore
a clear image of the uranium mineral.
Initially, he thought of this as confirmation of his theory.

radioactivity blackens a photographic plate

even through a layer of black paper

By accident the sun did not shine in Paris

for several days in February 1896 (a common occurrence at that time of year). He
stopped his experiments and placed the
uranium mineral and wrapped photographic plate together in a drawer. After
several days he developed the plate expecting a weak image from the small
amount of phosphorescence which had
not yet decayed away.

Henri Becquerel

Following the discovery of x-rays in 1895

by Roentgen, Becquerel had the dea, mistakenly, that minerals made phosphorescent by visible light might emit x-rays.
(X-rays are still used in hospitals and by
dentists to look for faults such as breaks
and cavities. X-rays, not absorbed by
materials in the specimen examined,
blacken the film). Phosphorescence is the
ability of a crystal to absorb light and reemit light some time after the exciting
light has been switched off. The Romans
used phosphorescent minerals in the centre of some of their roads to illuminate
them at night. The minerals were stimulated by daylight then continued to reemit light during the hours of darkness.

Henri Becquerel

Imagine his surprise to find the image as

intense as in the original sunlight experiment. He now drew the correct conclusion that this had nothing to do with light,
but the exposure came from uranium itself, even in the dark. The Radioactivity
(always present on earth) had been discovered. He went on to show that uranium minerals were the only phosphorescent minerals to show this effect.

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The Curies

The first they called Polonium (Po) after

Maries native Poland, and the second Radium (Ra) for obvious reasons. Po was
60 and Ra 400 times more radioactive
than uranium (U). This was the invention of radiochemistry. In radiochemistry the destination of any species in physical or chemical separations is monitored
by their radioactivity.
Becquerel and the Curies got the 1903
Nobel Prize in Physics for these experiments.
During this period the Curies had a
young child (Irene) and did ALL the
heavy work themselves on an income of
20/month for Pierre. For this he gave
120 lectures/year. By 1902 they had produced about 0.lg of pure RaCl2, radium
chloride (about 70mCi, millicuries, or
2600 Mbq, megabecquerel)

Becquerel recommended that Marie

Sklodowska Curie choose the subject for
her doctoral thesis. She quickly established that the amount of radioactivity
emitted by a uranium mineral was proportional to the amount of uranium
present in it. Further, that thorium minerals behaved similarly.
When she examined the uranium ore
pitchblende she found that it was four
times more radioactive than would be
expected from the uranium content. The
only conclusion was that it contained
another unknown radioactive component.

Rutherford and Soddy

In 1899 Rutherford in studying the ionization of gases (ionization is the removal
of one, or more, electrons from an atom,
leaving it positively charged) by the
radiation from uranium identified
two types: -radiation which produces by far the greater part of the

ionization, but is absorbed by a single

sheet of paper. -radiation produces
much less ionization and is capable of
penetrating several mm of Al, Cu, etc. In
1900 -radiation was discovered by
Villard who found that Ra emitted an
extremely penetrating radiation capable
of detection through 20 cm of iron or several cm of lead. -radiation is electromagnetic radiation like light but the photons
have much shorter wavelengths and
higher energies.
Many experiments were carried out with
alpha decay, usually from radium prepared by the Curies, which suggested that
the alpha particle was a helium nucleus.
The definitive identity of -radiation was
established by Rutherford and Royds in
an elegant experiment: they put a large
quantity of purified radon gas into a thinwalled glass tube. Because of the skill of
the glassblower this tube was thin
enough to allow most of the alpha particles through. An evacuated collecting
tube surrounded the thin-walled tube
containing radon. After two days the yellow helium line was clearly visible in the
outer tube, and after six days the whole
spectrum of helium was visible.

With the help of her husband Pierre they

boiled 40 pound (20 kilo) batches of pitchblende in cast iron cauldrons, and in 1898
they succeeded in isolating two new radioactive elements.

The Curie laboratory

Rutherford

Proof alpha particle is helium

The alpha particles thus gave rise to the

observed helium. Identifying helium in
this way is like recognizing that a neon
light contains neon gas from its colour.
Uranium Decay Series

This concept was confirmed in the early

1920s when Aston, using the first massspectrometer, (a device which uses a magnetic field to separate atoms of different
mass) was able to separate and measure
isotopes for a number of elements, in particular 20Ne and 22Ne. The placement of
these new elements in the periodic table
in 1913 was remarkably accurate when
compared to the present allocation.
From the detailed chemistry of the decay
series Soddy, and others, noticed that the
chemistry of the daughter element was
connected with the emitted radiation. It
eventually dawned on the researchers
that alpha particle emission moved the
element two places down the Periodic
Table, whereas beta emission moved it
one place up the Table.

Measurement
Having identified the various types of radioactivity it was necessary to be able to
measure them.

When uranium and thorium emitted alpha and beta particles they decayed to
different elements, this sequence was
called the natural decay series. By studying the chemistry of the natural decay
series of uranium (U) and thorium (Th)
30 new radioactive elements were discovered, of which radium (Ra) was the best
known. This was a truly international effort, but much of the work was done by
Rutherford and Soddy who both obtained Nobel prizes in Chemistry for this
work. Unravelling this chemistry was
like the work of a detective.
Many of these elements could not be
separated by chemical methods, e.g. radiothorium from Th, Ra from mesothorium and RaD from lead (Pb). Soddy
concluded that such inseparable 11 elements must occupy the same position
in the Periodic Table and called them
isotopes. Isotopes are atoms of the
same nuclear charge but different mass;
that is they contain the same number of
protons (and are the same element) but
different numbers of neutrons.

Sir William Crookes (1832-1919) had a

private laboratory at his home in
Kensington Gardens, London. Here he
discovered thallium (Tl), and the
spintharoscope. The latter being a
method of quantitatively detecting radioactivity by eye from the light flashes produced on a zinc sulphide (ZnS) screen.
The light flash caused by radioactivity is
a scintillation.

Geiger-Muller Tube
Rutherfords doctoral thesis at the
Cavendish under J.J. Thompson in 1895
involved studying the effects of x-rays on
gases. This later extended to radioactivity. The work led to a clear understanding of the transport of electricity through
gases by charged ions being attracted to
the electrodes. This production of
charged ions was used for detecting radioactivity in ionization chambers and
Geiger-Muller counters.

The spintharoscope was widely used

by the early researchers, including
Rutherfords group when discovering
the nucleus. In addition, spintharoscopes were sold to the general public
for after dinner entertainment in well
to do houses.

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The cloud chamber was invented by

C.T.R. Wilson after studying the meteorological effects of clouds on Ben Nevis.
In effect, the track of an ionizing particle
could be photographed as it made a
cloud trail in a chamber saturated with
vapour. The principle is similar to the
formation of aircraft trails at high altitudes. Cloud chambers are still used today in many particle physics experiments.
Discovery of the Nucleus

Curie Electrometer
The electrometer was used to determine the
presence of radioactivity in solutions and
precipitates. It was used by the Curies to
measure the radioactivity of their solutions
when separating Po and Ra from pitchblende. Electroscopes consist of two light
gold leaves which, when charged, spring
apart. When radioactivity passes through
the electroscope the ionization causes the
charge to leak away and the gold leaves to
collapse together at a rate proportional to
the number of ions produced, which, in
turn, can be related to the amount of radioactivity. Modern versions are often a
metalcoated quartz fibre and are used as
personal dosimeters.

In 1911 Geiger and Marsden investigated

the outcome of bombarding various materials with alpha particles. While bombarding gold foils, it was noticed that
very occasionally one particle would be
scattered through an angle greater than
90 degrees. Rutherford was heard to say
..It was quite the most incredible event
that has ever happened to me in my life.
It was almost as incredible as if you had
fired a 15-inch shell at a piece of tissuepaper and it came back and hit you.
Rutherford drew the conclusion that the
major part of the mass of an atom must
be concentrated in a central nucleus and
from the scattering experiments he calculated that the size of the nucleus must
be about 10-14m compared to 10-10m the
approximate size of an atom. Assuming
a nucleus to be the size of a balloon, then
the outside of the atom would be about
3km away. A drop of water made of atoms that size would occupy the whole
galaxy.

Cloud Chamber Track

Further alpha bombardment experiments

were carried out by Rutherfords team.
Firstly, on hydrogen gas, then nitrogen gas.
In both cases protons were produced with
very high energies.
The conclusion was that a very few nitrogen atoms had been transformed into oxygen atoms. This was confirmed by photographing tracks in a Wilson cloud chamber. Thus nitrogen can be transmuted
(transformed from one element to another),
on a minute scale, to a stable isotope of
oxygen and the alchemists dream of transmutation had come true.

This gave rise to intense interest in experiments in which one nucleus was bombarded with another.

The nuclear atom shown by scattered alpha particles

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