Scribd
Upload
82 views

Chapter 3

This document discusses gravimetric analysis methods for quantitatively analyzing various analytes. It lists the analyte, precipitate formed, measured form of the precipitate, and common interferences for each analyte. Gravimetric analysis relies on precipitating the analyte as an insoluble salt and weighing it. Various metal ions can be analyzed by precipitating salts such as sulfates, chromates, oxides, and complexes. Non-metal analytes include anions that precipitate as silver, barium, or other salts that can be isolated and weighed. Interferences that also form insoluble precipitates with the same ions must be avoided or accounted for.

Uploaded by

Prasad Yarra
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
82 views

Chapter 3

This document discusses gravimetric analysis methods for quantitatively analyzing various analytes. It lists the analyte, precipitate formed, measured form of the precipitate, and common interferences for each analyte. Gravimetric analysis relies on precipitating the analyte as an insoluble salt and weighing it. Various metal ions can be analyzed by precipitating salts such as sulfates, chromates, oxides, and complexes. Non-metal analytes include anions that precipitate as silver, barium, or other salts that can be isolated and weighed. Interferences that also form insoluble precipitates with the same ions must be avoided or accounted for.

Uploaded by

Prasad Yarra
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

5/25/2016

Chapter3.Gravimetry

Analyte

Precipitate

Measuredform

Interferences

K+

KB(C6H5)4

KB(C6H5)4

NH4+ ,Ag+ ,Hg2+ ,Tl+ ,Rb+ ,Cs+

Mg2+

Mg(NH4)PO4.6H2O

Mg2P2O7

Manymetals(nonefrom
Na+ andK+ )

Ca2+

CaC2O4.H2O

CaCO3orCaO

Manymetals(nonefromMg2+ ,
Na+ andK+ )

Ba2+

BaSO4

BaSO4

Na+ ,K+ ,Li+ ,Ca2+ ,Al3


+ ,Cr3+ ,Fe3+ ,Sr2+ ,Pb2+

Ti4+

TiO(5,7dibromo8
hydroxyquinoline)2

TiO(5,7dibromo8
hydroxyquinoline)2

Fe3+ ,Zr4+ ,Cu2+ ,C2O42,citrate,


HF

VO43

Hg3VO4

V2O5

Cl,Br,I,SO42,
CrO42,AsO43,PO43</sup>

Cr3+

PbCrO4

PbCrO4

NH4+ ,Ag+

Mn2+

Mn(NH4)PO4.H2O

Mn2P2O7

Interferencesfromnumerous
metals

Fe3+

Fe(HCO2)3

Fe2O3

Interferencesfromnumerous
metals

Co2+

Co(1nitroso2
naphtholate)3

CoSO4(byreactionwith
H2SO4)

Fe3+ ,Zr4+ ,Pd2+

Ni2+

Ni(dimethylglyoximate)2

Ni(dimethylglyoximate)2 Pd2+ ,Pt2+ ,Bi3+ ,Au3+

Cu2+

CuSCN

CuSCN

NH4+ ,Pb2+ ,Hg2+ ,Ag+

Zn2+

Zn(NH4)PO4.H2O

Zn2P2O7

Interferencesfromnumerous
metals

Ce4+

Ce(IO3)4

CeO2

Th4+ ,Ti4+ ,Zr4+

Al3+

Al(8hydroxyquinolate)3

Al(8hydroxyquinolate)3

Interferencesfromnumerous
metals

Sn4+

Sn(cupferron)4

SnO2

Cu2+ ,Pb2+ ,As(III)

Pb2+

PbSO4

PbSO4

Ca2+ ,Sr2+ ,Ba2+ ,Hg2+ ,


Ag+ ,HCl,HNO3

NH4+

NH4B(C6H5)4

NH4B(C6H5)4

K+ ,Rb+ ,Cs+

Cl

AgCl

AgCl

Br,I,SCN,S2,S2O32,CN

http://www.csudh.edu/oliver/che230/textbook/ch03.htm

1/2

5/25/2016

Chapter3.Gravimetry

Br

AgBr

AgBr

Cl,I,SCN,S2,S2O32,CN

AgI

AgI

Br,Cl,SCN,S2,S2O32,CN

SCN

CuSCN

CuSCN

NH4+ ,Pb2+ ,Hg2+ ,Ag+

CN

AgCN

AgCN

Cl,Br,I,SCN,S2,S2O32

(C6H5)3SnF

(C6H5)3SnF

Exceptalkalimetals,many
interferences,
andSiO44,CO32

ClO4

KClO4

KClO4

SO42

BaSO4

BaSO4

Na+ ,K+ ,Li+ ,Ca2+ ,Al3


+ ,Cr3+ ,Fe3+ ,Sr2+ ,Pb2+

PO43

Mg(NH4)PO4.6H2O

Mg2P2O7

Manyinterferencesexcept
Na+ ,K+

NO3

Nitronnitrate

Nitronnitrate

ClO4,I,SCN,CrO42,ClO3,
NO2,Br,C2O42

CO32

CO2(byadditionofacid)

http://www.csudh.edu/oliver/che230/textbook/ch03.htm

CO2

CO2istrappedasNa2CO3on
Ascarite

2/2

You might also like