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tugasatkII3 98 Alamak Macam Manapulaitu

1. The document describes four chemical reactions in a methanol production process: methane reforming, water-gas shift reaction, CO conversion, and methanol synthesis. 2. Methane reforming produces CO2 and H2 from CH4 and H2O. The water-gas shift reaction produces additional CO and H2. 3. CO is fully converted to CO2 in the CO converter. 4. In the methanol reactor, CO2, H2, and H2O react to produce methanol and byproducts.

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45 views5 pages

tugasatkII3 98 Alamak Macam Manapulaitu

1. The document describes four chemical reactions in a methanol production process: methane reforming, water-gas shift reaction, CO conversion, and methanol synthesis. 2. Methane reforming produces CO2 and H2 from CH4 and H2O. The water-gas shift reaction produces additional CO and H2. 3. CO is fully converted to CO2 in the CO converter. 4. In the methanol reactor, CO2, H2, and H2O react to produce methanol and byproducts.

Uploaded by

jakfara
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as XLS, PDF, TXT or read online on Scribd
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Reaksi inti di reformer (reaksi a) :

CH4 + 2H2O ----> CO2 + 4H2


Reaksi samping di reformer (reaksi b) :
CH4 + H2O ----> CO + 3H2
Reaksi di CO converter (reaksi c) :
2CO + O2 ----> 2CO2
Reaksi di methanol reactor (reaksi d) :
CO2 + 3H2 ----> CH3OH + H2 + 1/2O2 F4 system
system III
III
CO2 1

F3
O2 1
CO converter
system
system IIII
A
CO
CO2
F2 H2
CH4 0.99 F1 system II
Reformer
system H2O
N2 0.01 H2O 1
10% excess

No Komponen F1 F2
koef rx a jumlh mol
fraksi mol mol rate fraksi mol mol rate
1 CH4 0 0 0.99 100 -1 -90
2 N2 0 0 0.01 1.010101 0 0
3 H2 0 0 0 0 4 360
4 CO2 0 0 0 0 1 90
5 CO 0 0 0 0 0 0
6 O2 0 0 0 0 0 0
7 CH3OH 0 0 0 0 0 0
8 H2O 1 209 0 0 -2 -180
Total 1 209 1 101.0101 180

%excess steam 0.1


0.9
0.1
3
0.55
Recycled system
system VV Purge
N2 0.05 N2 0.05
CO2 CO2
H2 H2
C E condenser
CO2 CH3OH
H2 CO2
system
system III
IIIH2O D H2
N2 CO2 methanol H2O
reactor Product
B H2 N2 CH3OH
CO2 H2O system IV
H2O
H2 N2
CO converter
system
system IIII H2O
N2 - Konversi CH4 100%, 90% nya menghasilkan
- Konversi di methanol reactor 55%
- CO terkonversi sempurna di CO converter
- H2/CO2 di arus D : 3/1 = di arus B
- H2/CO2 di recycled : 3/1 = di purge
- Basis : 100 mol CH4

A F3 B
koef rx b jumlh mol koef rx c jmlh mol
fraksi mol mol rate fraksi mol mol rate fraksi mol
-1 -10 0 0 0 0 0 0 0
0 0 0.001981 1.010101 0 0 0 0 0.001981
3 30 0.764691 390 0 0 0 0 0.764691
0 0 0.176467 90 0 0 2 10 0.196075
1 10 0.019607 10 0 0 -2 -10 0
0 0 0 0 1 5 -1 -5 0
0 0 0 0 0 0 0 0 0
-1 -10 0.037254 19 0 0 0 0 0.037254
20 1 510.0101 1 -5 1

basis system I systerm II system III system IV trial 1 goal seek I system V trial II
Purge
N2 0.05
CO2
H2

Product
CH3OH
H2O

%, 90% nya menghasilkan CO2


nol reactor 55%
mpurna di CO converter
: 3/1 = di arus B
d : 3/1 = di purge
H4

B F4 C D
koef rx d jmlh mol
mol rate fraksi mol mol rate fraksi mol mol rate fraksi mol mol rate
0 0 0 0 0 0 0 0 0
1.010101 0 0 0.001871 1.010101 0.016075 12.31579 0 0
390 0 0 0.722209 390 0.719343 551.1061 -3 -214.5
100 1 30 0.240736 130 0.239781 183.702 -1 -71.5
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 1 71.5
19 0 0 0.035185 19 0.0248 19 1 71.5
510.0101 1 30 1 540.0101 1 766.1239 -143

175.5
0

dr trial II system VI system VII goal seek II


E Keluar Condenser Recycled Purge Product
fraksi mol mol rate fraksi mol mol rate fraksi mol mol rate fraksi mol mol rate fraksi mol
0 0 0 0 0 0 0 0 0
0.019765 12.31579 0.05 12.31579 0.05 11.30569 0.05 1.010101 0
0.540191 336.6061 0.7125 175.5 0.7125 161.1061 0.7125 14.39394 0
0.180064 112.202 0.2375 58.5 0.2375 53.70202 0.2375 4.79798 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0.114744 71.5 0 0 0 0 0 0 0.441358
0.145236 90.5 0 0 0 0 0 0 0.558642
1 623.1239 1 246.3158 1 226.1138 1 20.20202 1

20.20202
0
Product
mol rate
0
0
0
0
0
0
71.5
90.5
162

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