Ore genesis
Concentrations of PGEs can be considered to form in a number of ways: Normal crystallisation
Compatible elements in early forming minerals Incompatible (PGE) elements building up in the residual fluids
Liquid Immiscibility Podiform
Normal Crystallization
PGEs a are associated in the various ultramafic / mafic rocks with chromite layers.
Schematic of PGE in a layered intrusion Basic rock norite, anorthosite, bronzitite
Chromite layer
PGE values
bronzite / olivine
Based on fig 8.13 Naldrett 1989
Robb 2005
Two versions of PGE enrichment
Ascending PGE sulphide (Cl-) rich fluids (hydrothermal/late magmatic) enrich the sulphide rich layer (a settling or existing cumulate)
Less dense
Fresh magma enters the already layered chamber . This is turbulent and allows mixing with the layers (high R factor).
More dense
Problems : Is there enough fluid to give sufficient enrichment. S tenor values too low expect highest ones lower down the intrusion as PGE sulphides attach to the those first
The mixing allows time for the sulphide droplets in the magma to scavenge the PGE from the other layers- giving enrichment as the layer settles out .
MAGMA MIXING