AS 2917.

1—1994
ISO 10258:1994

Australian Standard
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Copper sulfide concentrates

Part 1: Determination of copper

content—Titrimetric methods

[ISO title: Copper sulfide concentrates—Determination of copper

content—Titrimetric methods]
 This Australian Standard was prepared by Committee MN/5, Copper, Lead, Zinc, Gold
and Silver Ores and Concentrates. It was approved on behalf of the Council of
Standards Australia on 2 September 1994 and published on 5 December 1994.
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The following interests are represented on Committee MN/5:

Australasian Institute of Mining and Metallurgy
Australian Lead Development Association
Australian Mining Industry Council
CSIRO, Division of Mineral and Processing Engineering

Review of Australian Standards. To keep abreast of progress in industry, Australi an Standards are subject
to periodic review and are kept up to date by the issue of amendments or new editi ons as necessary. It is
important therefore that Standards users ensure that they are in possession of the latest editi on, and any
amendments thereto.
Full detail s of all Australian Standards and related publi cati ons wil l be found in the Standards Australi a
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 AS 2917.1—1994

Australian Standard
This is a free 7 page sample. Access the full version at http://infostore.saiglobal.com.

Copper sulfide concentrates

Part 1: Determination of copper

content—Titrimetric methods

First published as AS 2917.1— 1986.

Second edition 1994.

PUBLISHED BY STANDARDS AUSTRALIA

(STANDARDS ASSOCIATION OF AUSTRALIA)
1 THE CRESCENT, HOMEBUSH, NSW 2140
ISBN 0 7262 9275 3
 ii

PREFACE

This Standard was prepared by the Standards Australia Committee MN/5 on Copper, Lead, Zinc, Gold
and Silver Ores and Concentrates as part of a programme of standardizing methods for the
determination of elements of commercial interest in such materials. It supersedes AS 2917.1— 1986,
Methods for the analysis of copper sulphide concentrates , Part 1: Determination of copper (short iodide
titrimetric method).
The objective of this Standard is to provide those involved in the analysis of copper sulfide concentrates
with a standardized method of determining copper content supported by precision data obtained from
an inter-laboratory test programme.
It is identical with and has been reproduced from ISO 10258 which has been prepared by ISO/TC 183
Copper, Lead and Zinc Ores and Concentrates. Australia holds the Chairmanship and Secretariat of
ISO/TC 183 and has made a significant contribution to the preparation of ISO 10258.
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As this Standard is reproduced from an international Standard, the following applies:

(a) Its number does not appear on each page of text and its identity is shown only on its cover and
title page.
(b) In the source text, ‘this international Standard’ should read ‘this Australian Standard’.
(c) A full point substitutes for a comma when referring to a decimal point.
References to international Standard ISO 9599 should be replaced by equivalent Australian Standard
AS 2816, as follows:
Reference to International Standard Australian Standard

ISO AS
9599 Copper, lead and zinc sulfide 2816 Copper, lead and zinc sulfide
concentrates—Determination of concentrates—Determination of
hygroscopic moisture in the analysis hygroscopic moisture in the analysis
sample — Gravimetric method sample — Gravimetric method

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 iii

CONTENTS
Page
1 Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
2 Normative references . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
3 Principle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
4 Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
5 Apparatus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
6 Sample . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
7 Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
8 Expression of results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
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9 Precision . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
10 Test report . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Annexes
A Procedure for the preparation and determination of the mass of a
predried test portion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
B Flowsheet of the procedure for the acceptance of analytical values for
test samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
C Derivation of precision equations . . . . . . . . . . . . . . . . . . . . . . . . 12
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iv

NOTES
 1

AUSTRALIAN STANDARD

Copper sulfide concentrates — Determination of

copper content — Titrimetric methods
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1 Scope 3 Principle

This International Standard specifies two titrimetric 3.1 Method 1 (Long iodide method)
methods for the determination of the copper content of
copper sulfide concentrates in the range 15 % (m/m) to A test portion is decomposed in nitric and sulfuric
50 % (m/m), using sodium thiosulfate after separation acids, and arsenic, antimony and tin are removed by
(method 1) or without separation (method 2) of copper treatment with hydrobromic acid. Copper is separated
from interfering elements. from interfering elements by precipitation of copper
sulfide with sodium thiosulfate. The precipitate is dis-
solved in nitric and sulfuric acids, ammonium hydrogen
2 Normative references difluoride is added to eliminate interference of residual
iron, and excess potassium iodide is also added. Free
The following standards contain provisions which, iodine isolated by reaction between iodide ions and
through reference in this text, constitute provisions of copper(II) ions is titrated with sodium thiosulfate using
this International Standard. At the time of publication, soluble starch as the indicator.
the editions indicated were valid. All standards are
subject to revision, and parties to agreements based on
this International Standard are encouraged to investi- 3.2 Method 2 (Short iodide method)
gate the possibility of applying the most recent editions
of the standards indicated below. Members of IEC and A test portion is decomposed in nitric and sulfuric
ISO maintain registers of currently valid International acids, and arsenic, antimony and tin are removed by
Standards. treatment with hydrobromic acid. Ammonium hydrogen
difluoride is added to eliminate interference of iron, and
ISO 385-1:1984, Laboratory glassware — Burettes — excess potassium iodide is also added. Free iodine
Part 1: General requirements. isolated by reaction between iodide ions and copper(II)
ions is titrated with sodium thiosulfate using soluble
ISO 648:1977, Laboratory glassware — One-mark starch as the indicator.
pipettes.

ISO 1042:1983, Laboratory glassware — One-mark

volumetric flasks. 4 Reagents

ISO 4787:1984, Laboratory glassware — Volumetric During the analysis, use only reagents of recognized
glassware — Methods for use and testing of capacity analytical grade and distilled water or water of equiva-
lent purity.
ISO 9599:1991, Copper, lead and zinc sulfide con-
centrates — Determination of hygroscopic moisture in 4.1 Copper metal, minimum purity 99,99 %.
the analysis sample — Gravimetric method.
4.2 Potassium iodide.
ISO Guide 35:1985, Certification of reference ma-
terials — General and statistical principles. 4.3 Ammonium hydrogen difluoride.

COPYRIGHT
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AS 2917.1-1994, Copper sulfide concentrates

Determination of copper content - Titrimetric
methods
This is a free 7 page sample. Access the full version at http://infostore.saiglobal.com.

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