Schmidt + Clemens

Mrker/Centralloy G/CA 4852 Micro

GX45NiCrSiNbTi35-25
Features, Product Forms, Chemical Composition, Applications . . . . . . . . . . . . . .2 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . .3 Mechanical Properties . . . . . . . . . . . . . . . . . . . . . . .4 Carburization / Oxidation Resistance . . . . . . . . . . . . .5 Parametric Stress Rupture Strength . . . . . . . . . . . . . .6 Parametric Minimum Creep Rate . . . . . . . . . . . . . . . .7 Manufacturing Characteristics, Health and Safety Information . . . . . . . . . . . . . . . . . . . . . . . . . .7

Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

Mrker / Centralloy G/CA 4852 Micro

MATERIAL DATA SHEET

Schmidt + Clemens
Mrker/Centralloy 4852 Micro
GX45NiCrSiNbTi35-25

Mrker/Centralloy 4852 Micro

GX45NiCrSiNbTi35-25 Features
Mrker/Centralloy4852 Micro, is a cast austenitic steel 35% nickel 25% chromium alloy plus niobium, titanium and others. The alloy possesses excellent structural stability, very good high temperature stress rupture strength and good carburization/oxidation resistance. The presence of carbon leads to the formation of a series of carbides: a) Intergranularly occurring primary carbides, nitrides or carbonitrides of the general form M (C,N) where M is usually niobium, titanium. These greatly affect the generation of good high temperature properties. The phase is visible in unetched micro specimens, its color varying from the orange/yellow of the nitride to the grey/mauve of the carbide. b) Chromium-rich intergranular carbides of the M7C3 and M23C6 types. These carbides have a profound influence on properties due to decomposition and re-precipitation reactions in service producing secondary carbides in a rather uniform dispersion. By this mechanism dislocation movement is impeded with the result of significant strengthening at elevated temperatures. Carbon . . . . . . . . . . . . . . . . . . . . . . . . . .0.45 Silicon . . . . . . . . . . . . . . . . . . . . . . . . . .1.50 Manganese . . . . . . . . . . . . . . . . . . . . . .1.00 Chromium . . . . . . . . . . . . . . . . . . . . . . .25.00 Nickel . . . . . . . . . . . . . . . . . . . . . . . . .35.00 Niobium . . . . . . . . . . . . . . . . . . . . . . . . .1.50 Titanium . . . . . . . . . . . . . . . . . . . . . .Additions Iron . . . . . . . . . . . . . . . . . . . . . . . . . .Balance
*) This is a typical composition which may be slightly modified according to the application.

Chemical Composition
mass percent*)

Applications
Tubular systems requiring very high creep rupture strength combined with good oxidation and carburization resistance. No heat treatment is required for most applications of this alloy. Main high temperature applications for the material are:

Product Forms
Process:

Max. operating temperature, C

Mrker/Centralloy4852 Micro was designed as centrispun tube material to meet specific design criteria in terms of carburization and oxidation resistance, creep rupture strength and weldability. lt is available as centrispun tubes, statically cast and investment cast product forms. Other forms may be supplied upon request. Further information regarding these topics and maximum and minimum sizes, may be obtained from the sales department.

Steam cracking pyrolysis Steam reforming applications

1130 1130

Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

Mrker/Centralloy 4852 Micro

GX45NiCrSiNbTi35-25

Physical Properties
Density Thermal Conductivity (20C) 8.0 g/cm3 14.6 W/mK

Mean Coefficient of Linear Thermal Expansion 19 Coefficient of Thermal Expansion, 10 -6/C

18

17

16

15 0 200 400 600 Temperature, C 800 1000 1200

Youngs Modulus of Elasticity 180

Youngs Modulus, GPa

160

100

60 0 200 400 600 Temperature, C 800 1000 1200

Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

Schmidt + Clemens
Mrker/Centralloy 4852 Micro
GX45NiCrSiNbTi35-25

Mechanical Properties
Tensile Properties

(only for wall thickness less than 25 mm in the as cast condition) 0.2% Yield Strength: 230 MPa Ultimate Tensile Strength: 470 MPa Elongation (l = 5d): 8 % for centricast tubes 6 % for static castings

Minimum tensile properties at 20C:

Typical Tensile Strength and 0.2% Yield Strength vs. Temperature 500
Ultimate Tensile Strength 0.2 % Yield Strength

400 Strength, MPa

300

200

100

0 0 200 400 600 800 1000 Temperature, C

Typical Tensile Test Elongation vs. Temperature 60 50 Elongation (l=4d), % 40 30 20 10 0 0 200 400 600 800 1000 Temperature, C
Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

Mrker/Centralloy 4852 Micro

GX45NiCrSiNbTi35-25

Carburization Resistance
Increase in Carbon Content vs. Temperature after Pack Carburization for 260 Hours at Indicated Test Temperature 2,0

Carbon increase, %

1,5

1,0

0,5

0 1000 1025 1050 1075 1100 1125 1150 1175 Temperature, C

Oxidation Resistance

Oxidation Weight Loss vs. Temperature for 10 Thermal Cycles in Air between Indicated Temperature and Room Temperature 40 7 hours hold time per cycle at test temperature Weight Loss, mg/cm2 30

20

10

0 1000 1050 1100 Temperature, C 1150 1200

Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

Schmidt + Clemens
Mrker/Centralloy 4852 Micro
GX45NiCrSiNbTi35-25

Parametric Stress Rupture Strength

Initial Stress, MPa 100 10 1 30 31 32 33 34 35 36
Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

LMP 37 38 39 40

LMP = Larson Miller Parameter LMP = T (22,9 + log tr) /1000 Where T: [K] and tr: rupture time [h] Lower scatter band represents 95% confidence level

Average Lower scatter band

Mrker/Centralloy 4852 Micro

GX45NiCrSiNbTi35-25

Parametric Minimum Creep Rate

33

P=(T+273) (20-log(min.creep rate in % per h))/1000

32

31

30 9 10 11 12 13 Initial Stress, MPa 14 15 16 17

ADDITIONAL INFORMATION Manufacturing Characteristics

Machining
In general terms the machinability of 4852 Micro is similar to that of other heat resistant alloys.

Health and Safety Information

The operation and maintenance of welding equipment should conform to the provisions of relevant national standards for the protection of personnel.

Welding
For critical, highly stressed and corrosion resistant joints coated electrodes, flux cored wire and bare filler material are commercially available. These welding consumables have high strength properties at elevated temperatures with good retained ductilities. Besides fillerless PAW, TIG and MAW have been used satisfactorily for component fabrication or repair welding. Preheating and postweld heat treatment of the joint is not necessary. For dissimilar weld joints to austenitic materials the same filler materials are recommended. Further information will be supplied upon request. Nickel- and iron-base materials may contain, in varying concentrations, elemental constitutions of chromium, iron, manganese, molybdenum, cobalt, nickel, tungsten and aluminium. Inhalation of metal dust from welding, grinding, melting and dross handling of these alloy systems may cause adverse health effects. Mechanical ventilation is advisable and, under certain conditions in confined spaces, is necessary during welding operations to prevent possible exposure to hazardous fumes, gases or dust that may occur.

Publication January 2001 Revision No. 01 Copyright Schmidt + Clemens GmbH+Co. KG Schmidt + Clemens GmbH+Co. KG Edelstahlwerk Kaiserau, P.O. Box 1140, 51779 Lindlar, Germany Schmidt - Clemens Spain, S.A. Centracero, Ctra. Estella-Vitoria, Km 12, 31280 Murieta, Navarra, Spain

Schmidt + Clemens

Production Locations and Sales Offices:

Schmidt + Clemens GmbH + Co. KG Centrifugal Casting Division D-51789 Lindlar - Kaiserau, Germany Telephone: +49 22 66 92 333 Fax: +49 22 66 92 369 E-Mail: [email protected] Postal Address: P.O. Box 1140 D-51779 Lindlar-Kaiserau, Germany Schmidt - Clemens Spain, S.A. Centracero Ctra. Estella-Vitoria, Km. 12 E-31280 Murieta, Navarra, Spain Telephone: +34 948 53 4600 Fax: +34 948 53 4601 E-Mail: [email protected] Postal Address: P.O. Box 67 E-31200 Estella, Navarra, Spain Schmidt + Clemens Brasil Ltda. Av. Eng Joao Fernandes Gimenez Molina, 905 - Bloco II, 13208-990 Jundiai, Brazil Telephone: +55 (0) 11 4589 2572 Fax: +55 (0) 11 4589 2571 E-Mail: [email protected] For more information contact us: http://www.schmidt-clemens.com

Schmidt + Clemens (Asia) Sdn. Bhd. 40000 Shah Alam, Selangor, Malaysia Lot No. 60, Jalan Ijuk 26/5 SS 26 HICOM Industrial Estates Telephone: +60 3 705 4760 Fax: +60 3 705 4770 E-Mail: [email protected] Schmidt + Clemens GmbH + Co. KG India Liaison Office A 214 Mahindra Gardens, S.V. Road Goregaon (W) Mumbai 400 062 India Telephone: +91 250 501 174 Fax: +91 250 504 909 E-Mail: [email protected] Schmidt & Clemens Inc. 9618 Green Valley Lane USA-Houston, Texas 77064 Telephone: +1 281 807 5880 Fax: +1 281 807 5889 E-Mail: [email protected] Schmidt + Clemens Mexicana, S.A. de CV Schiller 108 11570 Polanco, Mexico D.F. Mexico Contact: Francisco Xabier Valero-Ivon Telephone: +52 (5) 545 66 17 Fax: +52 (5) 545 33 12

WERKSTOFF/012001

Mrker and Centralloy are trademarks of the Schmidt + Clemens - Group