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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 * Revision: 14.12.2010

1 Identification of the substance/mixture and of the company/undertaking

Product identifier Trade name: ALWA-MOULD D, Komponente 2, Gieharz Article number: 6001 Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Tooling material Details of the supplier of the safety data sheet Manufacturer/Supplier: ALWA Technische Produkte fr Kunststoffverarbeitung, Modell- und Formbau GmbH Rntgenstr.1, D-48599 Gronau Further information obtainable from: Abteilung Produktsicherheit Tel.: +49 (0) 25 62 - 9 81 57 Fax: +49 (0) 25 62 - 9 81 59 Email: [email protected] Emergency telephone number: Giftinformationszentrum (GIZ) Bonn Tel.: 0228/19 240

2 Hazards identification
Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 3 H226 Flammable liquid and vapour. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R20: Harmful by inhalation. Xi; Irritant R36/38: Irritating to eyes and skin.

Xi; Sensitising R43: May cause sensitisation by skin contact.

R10: Flammable. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 1)

Revision: 14.12.2010

Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: Xn Harmful Hazard-determining components of labelling: methyl methacrylate styrene Risk phrases: 10 Flammable. 20 Harmful by inhalation. 36/38 Irritating to eyes and skin. 43 May cause sensitisation by skin contact. Safety phrases: 9 Keep container in a well-ventilated place. 23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

3 Composition/information on ingredients
Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: 100-42-5 styrene EINECS: 202-851-5 Xn R20; Xi R36/38 R10 Flam. Liq. 3, H226; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319 CAS: 80-62-6 methyl methacrylate EINECS: 201-297-1 Xi R37/38; Xi R43; F R11 Flam. Liq. 2, H225; Skin Irrit. 2, H315; Skin Sens. 1, H317; STOT SE 3, H335 Additional information: For the wording of the listed risk phrases refer to section 16. *

25-50%

2.5-10%

4 First aid measures

Description of first aid measures General information: Take affected persons out into the fresh air. Take affected persons out of danger area and lay down. Keep quiet and cover. Position and transport stably in side position. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 2)

Revision: 14.12.2010

After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Call a doctor immediately. Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Information for doctor: Most important symptoms and effects, both acute and delayed Headache Dizziness Dizziness Unconsciousness Nausea Coughing *

5 Firefighting measures
Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Advice for firefighters Protective equipment: Do not inhale explosion gases or combustion gases. Wear fully protective suit. Mouth respiratory protective device. Additional information Cool endangered receptacles with water spray. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Collect contaminated fire fighting water separately. It must not enter the sewage system.

6 Accidental release measures

Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Keep away from ignition sources. Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Prevent from spreading (e.g. by damming-in or oil barriers). Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 3)

Revision: 14.12.2010

7 Handling and storage

Handling: Precautions for safe handling Keep receptacles tightly sealed. Keep away from heat and direct sunlight. Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about fire - and explosion protection: Fumes can combine with air to form an explosive mixture. Use explosion-proof apparatus / fittings and spark-proof tools. Use only in explosion protected area. Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Information about storage in one common storage facility: Not required. Further information about storage conditions: Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting. Keep container tightly sealed.

8 Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: 100-42-5 styrene WEL Short-term value: 1080 mg/m, 250 ppm Long-term value: 430 mg/m, 100 ppm 80-62-6 methyl methacrylate WEL Short-term value: 416 mg/m, 100 ppm Long-term value: 208 mg/m, 50 ppm Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Do not eat, drink, smoke or sniff while working. Use skin protection cream for skin protection. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Recommended filter device for short term use: Combination filter A-P2
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 4)

Revision: 14.12.2010

Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves Butyl rubber, BR Nitrile rubber, NBR PVA gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Solvent resistant protective clothing *

9 Physical and chemical properties

Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Yellow Odour: Characteristic Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 146 C Flash point: Ignition temperature: Self-igniting: Danger of explosion: Explosion limits: Lower: Upper: Vapour pressure at 20 C: 21 - 55 C (ISO 1523) 480 C Product is not selfigniting. Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. 1.2 Vol % 8.9 Vol % 6 hPa
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 5)

Revision: 14.12.2010

Density at 20 C:

1.1 g/cm

Solubility in / Miscibility with water: Fully miscible. Solvent content: Organic solvents: 36.3 %

10 Stability and reactivity

Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions Exothermic polymerization. Reacts with peroxides. Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: 100-42-5 styrene Oral LD50 5000 mg/kg (rat) Inhalative LC50/4 h 24 mg/l (rat) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Irritant Sensitisation May cause sensitisation by skin contact. *

12 Ecological information
Toxicity Acquatic toxicity: No further relevant information available. Additional ecological information: General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vPvB assessment PBT: Not applicable.
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 6)

Revision: 14.12.2010

vPvB: Not applicable. *

13 Disposal considerations
Waste treatment methods Recommendation Must be specially treated adhering to official regulations. Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Non contaminated packagings may be recycled. Packagings that may not be cleansed are to be disposed of in the same manner as the product. Recommended cleansing agents: Water, if necessary together with cleansing agents.

14 Transport information
Land transport ADR/RID (cross-border)

ADR/RID class: 3 Flammable liquids. Danger code (Kemler): 30 UN-Number: 1866 Packaging group: III Hazard label: 3 UN proper shipping name: 1866 RESIN SOLUTION Tunnel restriction code D/E Maritime transport IMDG:

IMDG Class: UN Number: Label Packaging group: EMS Number: Marine pollutant: Proper shipping name:

3 1866 3 III F-E,S-E No RESIN SOLUTION

Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: UN/ID Number: Label Packaging group:

3 1866 3 III
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 16.12.2010 Trade name: ALWA-MOULD D, Komponente 2, Gieharz
(Contd. of page 7)

Revision: 14.12.2010

Proper shipping name:

RESIN SOLUTION

UN "Model Regulation": UN1866, RESIN SOLUTION, 3, III Special precautions for user Warning: Flammable liquids. *

15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: Information about limitation of use: Employment restrictions concerning juveniles must be observed. Employment restrictions concerning pregnant and lactating women must be observed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. R37/38 Irritating to respiratory system and skin. R43 May cause sensitisation by skin contact. Department issuing MSDS: Abteilung Produktsicherheit Contact: Hr. Hazejager Abbreviations and acronyms:
ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

* Data compared to the previous version altered.

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