Uç Fü - Ç - Ätá Gâä - Á (Xàà - Àé À (X WXW - Vtàxw V (Xå - Vtä XÇZ - Çxxüá: Technical Questions in Chemical Engineering
Uç Fü - Ç - Ätá Gâä - Á (Xàà - Àé À (X WXW - Vtàxw V (Xå - Vtä XÇZ - Çxxüá: Technical Questions in Chemical Engineering
u
f||t g|{x|
(2009)
2.
Develop an expression for the specific reaction rate constant based on activated complex
theory.
3.
Distinguish between the methods available for establishing the kinetics of chemical reactions
from the data obtained in a batch or continuous reactor.
4.
Compare the performances and merits of the plug flow and the stirred tank reactors behaving
ideally.
5.
Derive expressions for the overall conversions for a reaction of known order.
6.
A homogeneous first order reaction is carried out in a batch reactor under adiabatic
conditions. Develop a suitable method to find the relation temperature-conversion-time. State
the assumptions made.
7.
Briefly explain the E and the F - curves. Draw the E and the F - curves for series and parallel
combinations of one plug flow and one stirred tank reactors with unequal volumes. Comment.
8.
9.
What is understood by order of a chemical reaction? How is this different from "molecularity
of the reaction", if a difference between the two exists.
10.
11.
Derive an expression for the concentration in the N-th reactor, if N equal sized stirred tank
reactors are assembled in series. Assume first order reaction.
12.
Discuss, how best you will arrange two unequal-sized stirred tank reactors for a given
conversion and reaction order.
13.
Derive the relation between conversion and temperature for an adiabatic reactor using the
energy balance and explain how you determine the reactor size for adiabatic operation of a
plug flow and a stirred tank reactor.
14.
Discuss the principles of reactor stability and how it is established in a stirred tank reactor.
Show qualitatively how endothermic reactions are always stable.
15.
Briefly discuss the models to explain the non-ideal behavior of tubular reactors. Describe one
experiment to evaluate the parameters in any one of the models.
16.
What do you understand by "order of a reaction"? Indicate the methods available for
determining the order of a given reaction.
17.
An elementary reaction A
_____
>R
_____
condition for maximum concentration of R. What is its value? (Assume no R and S initially)
18.
"There exists a conversion below which the performance of a mixed flow reactor is better or
at least equal to that of plug flow reactor for adiabatic exothermic reaction" - Explain.
19.
Discuss briefly the shrinking core model used for describing the global rate of fluid-solid noncatalytic reactions, and outline design methods for such reactions.
20.
Explain the different models for gas-solid non-catalytic reactions of the type,
A(g) + bB(s)
21.
_____
>E(g) + F(s)
Discuss the differences between chemisorption and physical adsorption and their role in
catalytic reactions.
22.
Discuss the effect of mass and heat transfer on the performance of industrial catalytic
reactors.
23.
24.
A first order reaction is to be treated in a series of two mixed reactors. Show that the total
volume of the two reactors is minimum when the reactors are equal in size.
25.
26.
27.
Catalyst poisoning
28.
Adsorption isotherm
29.
30.
Auto-catalytic reactions
31.
32.
Feasibility of reactions
33.
34.
35.
36.
Recycle reactors
37.
38.
39.
40.
2.
3.
4.
5.
6.
7.
What are the geometric properties that influence the activity of a catalyst?
8.
9.
10.
11.
12.
13.
Why fluidized bed catalytic reactors are more advantageous than fixed bed reactors?
14.
15.
16.
What methods are used for the determination of pore size and pore size distribution?
17.
18.
19.
20.
21.
22.
23.
How is activation energy altered by catalyst? Explain briefly with suitable example.
24.
25.
26.
27.
28.
29.
30.
31.
32.
How is chain radical reaction carried out using catalyst? Give example.
33.
34.
Name the factors that influence the catalytic activity of a solid porous catalyst.
35.
Name the factors to be considered while designing a reactor for heterogeneous catalytic
reactions.
36.
37.
How are reversible exothermic gas phase catalytic reactions are carried out?
38.
How is double heat exchange tube catalytic reactor used in the manufacture of ammonia?
39.
40.
41.
42.
Name any two methods used for the removal of catalytic poison.
43.
44.
45.
46.
Name the device used to collect the catalyst dust in the moving bed catalytic reactor.
47.
48.
49.
50.
51.
52.
53.
How do the impurities present in the catalyst mixture affect the activity of catalyst?
54.
55.
56.
What is meant by codeposition? Name any two catalysts prepared by this method.
57.
How does the surface area influences the catalytic activity of catalyst? Explain.
58.
Write down the Langmuir isotherm equation and explain the terms in it.
59.
60.
2.
3.
4.
5.
6.
7.
8.
Relative roughness of a pipe surface is its absolute roughness divided by its __________
9.
In laminar flow through pipe as Reynolds number increases the friction coefficient
__________
10.
11.
12.
For a solid sphere falling under gravity at terminal settling velocity in a fluid the buoyant force
is equal to __________
13.
14.
15.
Reciprocating pumps are suitable for high pressure rise and __________ discharge
16.
17.
18.
Power required by a fan is proportional to the discharge, pressure rise and __________
19.
20.
21.
22.
23.
The pressure inside a soap bubble will be ______________ than the surrounding atmospheric
pressure
24.
25.
26.
27.
28.
29.
30.
31.
For flow over flat plate, the critical Reynolds number is ______________
32.
33.
34.
35.
The suppressed sharp crested weir is 0.6 m high and discharges water at a head of 1.2 m.
The coefficient of discharge of the weir is ______________
36.
The gas flow velocity through a fluidized bed should be less than or equal to ______________
velocity
37.
38.
39.
Mass and weight of a body are differentiated in terms of the ____________ acting on it
40.
41.
42.
43.
Pressure of a liquid can be converted into the ____________ of the liquid by dividing by the
corresponding density
44.
45.
46.
47.
48.
The length required to establish fully developed flow in the entire cross section of the pipe is
called ____________
49.
50.
For scaling up laboratory data to an industrial scale, the three similarities are ____________
____________ and ____________
51.
52.
53.
The forces acting on an aeroplane flying at a constant speed at a given altitude are
____________, ____________ and ____________
54.
The forces acting on a particle in a batch fluidized bed at steady state are ____________
____________ and ____________
55.
56.
57.
58.
three
59.
For an orifice meter, the pressure recovery is ________ than that for a venturi meter
60.
61.
62.
63.
64.
65.
Inclined manometer.
2.
3.
4.
5.
6.
7.
8.
Pneumatic transport.
9.
10.
11.
12.
13.
14.
State any three dimensionless number related to fluid flow and explain their significance
15.
16.
Explain the following terms (i) Vapor pressure and (ii) Bulk modulus
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
Write the differential form of continuity equation for two-dimensional steady flow of
incompressible fluid.
27.
28.
29.
30.
31.
What is the optimum included angle of the divergent section of a venturi meter?
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
What is the relationship between the drag coefficient and Reynolds number in the Stoke's law
range (Reynolds number < 1)?
45.
46.
What is the head loss of the fluid at the entrance of a straight pipe?
47.
48.
49.
Define 'Equivalent diameter' for fluid flow through channels of non-circular cross section.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
Write the Hagen Poiseuille's equation for laminar flow in Newtonian fluid.
Technical Questions in Chemical Engineering by Srinivas Tulishetti
60.
61.
62.
63.
64.
65.
What is Mach number? Define the Mach number for an ideal gas.
66.
67.
68.
69.
Write an expression for head loss due to sudden expansion of the fluid.
70.
71.
72.
73.
74.
75.
76.
What is Priming?
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
Why the length of divergent section of a venturimeter is much longer than its convergent
section.
91.
92.
Write the expression for discharge through a V-notch with an included angle of
93.
10
94.
95.
96.
97.
98.
99.
Which fan produce a high static pressure rise, a backward curved fan or a forward curved fan
100.
101.
102.
Differentiate between absolute viscosity and kinematic viscosity. Write the units.
103.
Define 'Equivalent diameter' for fluid flow through ducts of noncircular diameter.
104.
105.
106.
Explain the terms maximum velocity and average velocity for a flow of fluid in a circular pipe.
107.
108.
109.
Name two types of fluidization and give two important industrial application.
110.
111.
112.
113.
114.
115.
116.
117.
118.
119.
120.
121.
122.
123.
124.
What is the relation between maximum velocity and average velocity in laminar flow and
turbulent flow
125.
126.
127.
11
128.
129.
130.
131.
132.
133.
134.
135.
136.
137.
138.
139.
140.
141.
142.
143.
Give the relationship between Drag coefficient and Reynolds number in a) Newton's range of
operation b) Intermediate range of operation
144.
145.
146.
147.
148.
149.
150.
151.
152.
153.
154.
155.
156.
157.
158.
159.
Water hammer.
160.
161.
162.
12
163.
164.
165.
166.
167.
168.
Consider a duct of square cross section of side 'b'. The hydraulic radius is given by
(A) b/8
169.
(B) b/4
(C) b/2
(D) b
A rotameter, through which air at room temperature and atmospheric pressure is flowing,
gives a certain reading for a flow rate of 100 cc/s. If helium (Molecular weight 4) is used and
the rotameter shows the same reading, the flow rate is
(A) 26 cc/s
(B) 42 cc/s
13
Fluid which obeys the Newton's law of viscosity, are said to be Newtonian fluids. Examples:
water, air, kerosene. Newton's law of viscosity, = du/dy
3. Give suitable examples for (a) Bingham plastic fluid, (b) Thixotropic fluid
u = 2x2 + zy, v = -2xy + 3y2 + 3zy, w = -1.5z2 - 2xz - 6yz are given
Where u, v and w are velocity components in the directions of x, y and z respectively.
TRANSPORT PHENOMENA
1.
2.
3.
4.
5.
6.
7.
8.
14
9.
10.
Define porosity
11.
12.
13.
14.
15.
16.
17.
18.
19.
What is diffusion?
20.
21.
22.
Give the ranges of Reynolds number for laminar flow and turbulent flow.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
For Newtonian fluids flowing through two parallel infinite flat plates, the average velocity is
__________ of maximum velocity.
15
2.
Draw a equilibrium diagram and boiling point diagram for an azeotropic binary system.
3.
Raoult's law applies to the __________ and Henry's law applies to the _________
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
What is distillation?
23.
24.
25.
26.
27.
What is the use of open steam and how to calculate the number of stages in case of open
steam
28.
29.
30.
31.
32.
33.
16
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
Sketch the operating line and equilibrium curve for an absorber and stripper
50.
51.
52.
53.
54.
What is electrodialysis?
55.
56.
57.
58.
59.
60.
61.
62.
(i)
64.
65.
66.
Spray drying
67.
Dehumidification process
68.
17
69.
Vacuum crystallizer
70.
71.
Cooling towers
72.
Reynolds analogy
73.
Wet-bulb temperature
74.
75.
76.
Psychrometric chart
77.
78.
79.
80.
81.
82.
83.
Air-conditioning equipments
84.
Swenson-Walker crystallizer
85.
86.
J - factors
87.
Estimation of diffusivities
88.
89.
Rotary dryers
90.
91.
Nucleation
92.
93.
94.
95.
Give the Wilke-Chang equation and explain the terms involved in it.
96.
97.
98.
99.
100.
101.
102.
103.
104.
Explain the effect of temperature and mass flow rate of air on the constant drying rate, NC.
Technical Questions in Chemical Engineering by Srinivas Tulishetti
18
105.
106.
Which type of drier is used in the manufacture of (a) tablets (b) Paraffin wax?
107.
What is crystallization?
108.
State McCabe's
109.
110.
112.
113.
114.
115.
116.
What is the effect of pressure and temperature on the diffusion coefficient in gases?
117.
118.
119.
120.
121.
Define the term Equilibrium moisture and free moisture content of solid
122.
What is freeze-drying?
123.
124.
125.
126.
127.
What is magma?
128.
129.
130.
Absorption
131.
What do you understand by 'liquid film controlling' in gas absorption? Suggest methods of
increasing the rate of transfer for this condition.
132.
19
133.
Compare the performance of bubble-cap column, sieve-tray column and packed bed column.
Discuss in detail the operation of any column.
134.
When are the concepts of HETP and HTU used? What is the difference between the two?
Drawing an equilibrium diagram, indicate clearly the two concepts.
135.
Illustrate the significance of operating line and equilibrium line for a steady state countercurrent process.
136.
Discuss briefly the 'flooding' and 'loading' conditions in a packed tower stating the factors
which influence them.
137.
2.
138.
Define absorption factor. Indicate its physical significance and uses in the design of absorbers.
139.
140.
Discuss briefly how the minimum solvent requirement in counter-current gas absorption may
be determined.
141.
What is flooding velocity? What role does it play in the design of absorption column?
142.
Specify the important properties a packing material should possess for being used in mass
transfer equipment. Name a few packing materials.
143.
How do you express the efficiency of an absorption plate and an absorption column? Give an
idea of an ideal plate.
144.
Indicate the methods used for the design of absorption towers for absorption with chemical
reaction. Explain the type of data needed in the design and how this data is obtained.
Adsorption
145.
Compare the several adsorption isotherms you know of and discuss their importance in
adsorption steps in a chemical engineering operation.
146.
Draw the break-through curve for an adiabatic batch adsorption bed. Discuss the main
features.
147.
What are the characteristics to be possessed by industrial adsorbents? What are the
commonly used adsorbents?
Extraction
148.
Discuss the factors which govern the selection of solvents to be used for liquid-liquid
extractions.
149.
Write in short the procedure to determine the number of theoretical stages for countercurrent multistage extraction.
Technical Questions in Chemical Engineering by Srinivas Tulishetti
20
Leaching
150.
151.
Explain the graphical method of determining the number of theoretical stages in a multistage
counter-current leaching.
Distillation
152.
153.
What is flash vaporization? Obtain relationship for liquid to vapor product ratio in terms of
enthalpies of different streams.
154.
155.
Why the reflux is used and how does it affect the size of the distillation tower?
156.
Explain, with necessary equations, the utility of Ponchon-Savarit method of determining the
number of ideal plates in a fractionating column. How is the McCabe-Thiele method a
simplification of this?
157.
When is distillation by steam used? Explain with necessary expressions, the effect of using
vacuum in steam consumption in such an operation.
158.
Discuss the principles, operation and industrial applications of the following giving examples.
1)
Azeotropic distillation
159.
2) Extractive distillation
3) Molecular distillation
Indicate how the use of the enthalpy-composition diagram and McCabe-Thiele diagram could
be utilized for the design of distillation columns. Specify the application of each method.
Explain by means of both the methods to determine:
1.
minimum reflux 2)
2.
Location of the correct feed plate in the fractionation of liquid mixture in a bubble plate
column using open steam.
160.
State with reasons whether the following statements are correct or not, give appropriate
equations wherever possible.
1.
Raoult's law applies to the solute and Henry's law applies to the solvent.
2.
In a rectification column, the heat requirement in the re-boiler gets fixed if the reflux
ratio is fixed.
3.
21
What are the different ways adopted for size reduction in process industries?
2.
3.
4.
What is the ratio of actual mesh dimension in one screen to that of the next smaller screen as
per Tylers standard scale?
5.
6.
7.
What are the different methods adopted for prevention of swirling in an agitated tank?
8.
9.
10.
What are the different types of impellers commonly used for agitation of liquids?
11.
Write the relationships between drag coefficient and Reynolds number in various regimes of
settling
12.
13.
14.
15.
Classify the particle size measuring techniques on the basis of size range
16.
17.
18.
19.
20.
21.
22.
23.
Cumulative analysis for determining surface is more precise than differential analysis. Why?
24.
25.
26.
The operating speed of a ball mill should be less than the critical speed.
27.
28.
What is disintegrator?
29.
30.
31.
32.
22
33.
What are filter aids? Name few commonly used filter aids
34.
35.
36.
Explain the Kozeny's equation for determining the pressure drop across the cake for batch
filtration
37.
38.
39.
40.
41.
What is a screen?
42.
Give the various methods for finding the size distribution of a mixture of particles
43.
44.
45.
What is the main difference between tube mill and ball mill?
46.
47.
48.
49.
50.
51.
52.
53.
Define filtration
54.
55.
56.
57.
58.
59.
Name the agitator which is suitable for mixing low viscosity fluids
60.
61.
Give the sphericity of rasching ring whose length and diameter are equal
62.
63.
Name the different methods of particle size measurement for fine particles
64.
65.
66.
67.
23
68.
69.
70.
71.
72.
73.
What is filtration?
74.
75.
76.
77.
78.
What are the important properties that influence the mixing of fluids?
79.
80.
81.
Give the shape factor for a cylinder whose length equals its diameter.
82.
83.
84.
Which is the most suitable equipment for removing the fine dust particle of less than one
micron dia from air?
85.
86.
87.
88.
What are the factors that affect energy consumption in a ball mill?
89.
90.
91.
92.
93.
94.
What are filter aids? Name few commonly used filter aids
95.
96.
97.
98.
Name the agitator which is suitable for mixing low viscosity fluids
99.
What are the types of mixers suitable for pastes and plastic masses?
24
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
Name the machine used for making paper from wet pulp
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
What is hydroforming?
32.
Name a few important large-scale petrochemicals that can be obtained from benzene
33.
34.
25
35.
36.
37.
38.
39.
40.
Give two examples of unit operations. Also give the schematic representations
41.
42.
43.
44.
45.
Explain the term Hydrogenation with reference to oil and fat industry
46.
47.
48.
Give examples of byproducts from natural gasoline. Also indicate its uses
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
69.
70.
26
71.
72.
73.
74.
75.
76.
What is Neoprene?
77.
78.
79.
27
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
Control valves
23.
Interacting systems
24.
25.
Instrument lag
26.
Proportional band
27.
28.
29.
Linearization
30.
Routh test
31.
Pneumatic relay
32.
Dead time
33.
28
34.
35.
36.
Pressure transducers
37.
Transportation lag
38.
Nichols chart
39.
40.
Ratio control
41.
42.
43.
Stability analysis
44.
On-off controllers
45.
Decay ratio
46.
47.
Integral action.
48.
1)
50.
Discuss the manometer dynamics with respect to the damping coefficient. On what physical
parameters of the manometer does this coefficient depend?
51.
Draw the block diagram of a control system illustrating a cascade control loop. Explain its
purpose.
52.
Discuss on the criteria for specifying the control and controller settings.
53.
Draw the instrumentation flow diagram for a shell and tube heat exchanger. State the
importance of such diagrams.
54.
With a neat sketch, explain the working of a proportional plus derivative mode of control.
Why the derivative controller cannot be used independently.
55.
Show by plot the transient output response of a derivative controller when it has been
disturbed by 1) Linear input 2) Sinusoidal input 3)Step input
56.
Write short notes on the dynamic behavior and dynamic characteristics of an instrument.
57.
Explain the terms 'amplitude ratio', 'proportional band', 'transducer', 'distance velocity lag'
and 'offset'.
58.
Describe how proportional plus integral action can be generated in a pneumatic controller.
State under what circumstances it is an advantage to use this combination. Under what
conditions would you prefer to replace the integral by derivative action?
59.
29
60.
Name and define all the basic elements of a control system and show in a block diagram
their positions in the closed-loop which forms the system. Indicate where and how time lags
can arise in the system and explain how they add to the difficulty of control.
61.
Give one example each of a system with zero order and first order dynamics. Derive the
transfer function of a first order system.
62.
Discuss the merits and demerits in using hydraulic, pneumatic and electric control system in
process control.
63.
64.
c) transportation lag
a)
d) dead time
Explain with the help of a control circuit, how temperature of water in a shell and tube heat
exchanger, heated by hot oil (shell side) can be controlled.
65.
Explain how an on-off controller having no differential gap, is used to control liquid level in a
tank and indicate the draw backs.
66.
Discuss the factors that are to be considered in choosing a feed back or feed forward
controller in process control.
67.
Explain with the help of a neat sketch, the working of a pneumatic proportional plus integral
(PI) controller to control temperature in a process.
68.
Write the expression for proportional (P), proportional plus integral (PI), proportional plus
derivative (PD) and proportional plus integral plus derivative (PID) control actions and
explain the terms used therein.
69.
Derive an expression for the step response in inlet flow rate to two non-inter acting tanks in
series with equal time constant.
30
2.
What is amortization?
3.
Define depletion
4.
5.
6.
7.
8.
9.
Profitability index of company X is 1.3 and that of company Y is 1.6. Which company has
economic dependence?
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
What is depletion?
23.
24.
What is amortization?
25.
26.
27.
28.
29.
30.
31.
What is inflation?
32.
33.
31
34.
35.
Define B.E.P
36.
37.
38.
39.
40.
Define fatigue
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
What is GDP?
55.
In the sinking fund deposit method the annual uniform payment 'R', when the principal is 'P'
sinking fund interest is 'I' and the period is 'n', is given by ______.
56.
Define 'Depletion'
57.
58.
59.
A storage tank was priced at Rs.5000 in 1982 when the cost index was 460. What is its value
today when the cost index is 800?
60.
61.
List the factors to be considered in the evaluation of capital requirements for a process plant
62.
63.
64.
65.
66.
67.
32
68.
69.
70.
What is GNP?
71.
What is fatigue?
72.
73.
74.
33
2.
When radio graphic tests are conducted for pressure vessels, the joint efficiency is 0.85 for
spot radiography and 1.00 for 100% radiography.
3.
4.
For elliptical heads the ratio of major axis to minor axis is 2:1
5.
What losses are taking place in the storage of volatile liquids? Evaporation losses, filling
losses, breathing losses.
6.
What is TEMA? Tubular Exchangers Manufacturers Association, USA. Heat Exchanger design
and fabrication Code.
7.
Corrosive fluids are passed through tube side of a shell and tube heat exchanger
8.
9.
10.
11.
12.
At minimum reflux ratio infinite number of plates are required for distillation.
13.
Define loading
14.
A redistributor is used for every 3D (i.e., 3 times the diameter of height) of the packed
section.
15.
16.
Define cut size for a cyclone separator. (The minimum diameter of particle that can be
collected with 100% efficiency)
17.
18.
What is an induced draft cooling tower? (Air is sucked by the fans at the top of the tower)
19.
20.
21.
22.
Why triangular pitch is preferred than square pitch in tube layout in heat exchanger?
23.
24.
25.
26.
The most common standard size of a bubble cap is marketed with _________ inches diameter
cup and _________ inches riser
27.
34
28.
29.
30.
31.
Relative humidity is the ratio of vapor pressure of high volatile component, vapor pressure of
low volatile component
32.
33.
34.
35.
In case of cooling towers the ratio of rates of heat and mass transfer is indicated by Lewis
number
36.
Reaction vessels with the same thickness of shell but smaller in diameter withstands higher
pressure
37.
38.
39.
40.
41.
A pump operating under specified conditions delivers insufficient quantity of fluid. How it can
be set right?
42.
43.
44.
45.
46.
47.
48.
49.
Suggest a suitable type of storage vessel for storing liquid ammonia. Give reasons for such
recommendation.
50.
51.
52.
53.
54.
55.
56.
57.
35
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
What is an azeotrope?
68.
69.
70.
71.
72.
73.
What are the standard lengths adopted in shell and tube heat exchangers?
74.
75.
76.
77.
Name the methods used for the determination of number of plates for multi component
systems.
78.
79.
80.
What methods are available for the determination of equilibrium data of nonideal mixtures?
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
91.
Graphically represent how temperature profile varies with distance in a counter-current heat
exchanger
Technical Questions in Chemical Engineering by Srinivas Tulishetti
36
92.
Define the term 'relative volatility' and indicate its importance in the design of distillation
columns
93.
94.
95.
State the advantage of using backward feed multiple effect evaporators over forward feed
units
96.
97.
State the assumptions made in McCabe-Thiele method of estimating the number of stages in
a distillation column
98.
Define the term 'number of transfer units' and 'height of transfer units' in a packed column
absorber
99.
Suggest what type of absorber do you use for absorbing hydrochloric acid gas
100. State the factors to be considered in the selection of a solvent for the given extraction
operation
101. Define computer logic.
102. What are the different types of operational systems?
103. Explain time-sharing.
104. Name some commonly used high level languages.
105. What is a source program and object program?
106. Define activity and fugacity.
107. What is meant by a single pass and multi pass heat exchanger?
108. What are the different equations available for calculating VLE data?
109. What are the advantages of a double pipe heat exchanger?
110. Draw a neat sketch of a single effect evaporator.
111. When do you use finned tube heat exchanger?
112. On what basis are heat exchangers classified?
113. Evaporators are classified according to _________.
114. What are the accessories that have to be used with the evaporators?
115. Define elevation in boiling point.
116. What are the different types of tower packing?
117. What is Henry's law; where is it applied?
118. Define HETP.
119. Describe triangular diagrams.
120. Define correction factors; where is it used in heat exchanger.
37
THERMODYNAMICS
1.
2.
3.
The ratio of specific heat of a gas at constant pressure and at constant volume always
varies with _______
4.
5.
Carnot cycle comprises _______ isothermal process and two _______ process
6.
A heat engine is supplied with 300 kJ/sec of heat at 600 K and heat rejection takes place at
300 K. Heat rejected is 100 kJ/sec. The data refers to _______ cycle
7.
8.
9.
For a higher value of polytropic index the compressor work for a given pressure ratio is
_______
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
Define activity
26.
What is an adiabatic process? Write the expression for work done during reversible adiabatic
process
27.
28.
29.
30.
38
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
List out any five thermodynamic property changes for an ideal gas
42.
43.
What is an equation of state? Give the expression for any two equations of state
44.
45.
46.
47.
48.
49.
50.
51.
52.
Give any two thermodynamic relations for calculating the entropy change of a real gas
53.
54.
55.
56.
57.
58.
What is the use of making free energy change calculations in the thermodynamic analysis of
chemical reaction equilibria?
59.
60.
61.
62.
63.
Define entropy
64.
65.
39
66.
67.
68.
69.
70.
Explain C.O.P
71.
72.
73.
74.
75.
Explain activity
76.
77.
78.
79.
80.
Explain enthalpy
81.
82.
83.
84.
85.
What is fugacity
86.
87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
97.
What is equilibrium?
98.
99.
State at least three equations of state for gases and discuss the general applicability of
these equations.
40
100.
101.
102.
103.
Derive an expression for the work involved in case of an ideal single stage reciprocating
compressor having no clearance volume.
104.
105.
106.
107.
108.
With the help of temperature-entropy diagram and flow diagram, explain the working of a
single stage vapor compression refrigeration system. Deduce expressions for the coefficient
of performance, and horse power requirement per ton of refrigeration.
109.
What is Carnot's principle? With the help of Carnot's principle, show mathematically that it is
possible to define an absolute temperature scale, independent of the properties of any
particular substance. How would you fix up the length of a degree in such an absolute scale
of temperature?
110.
111.
112.
State first law of thermodynamics and derive an energy equation for a steady state flow
process.
113.
114.
What is meant by residual volume of a gas? Show mathematically that the residual volume
of a gas does not necessarily approach zero as the temperature approaches zero along an
isotherm.
115.
Discuss the T-x-y, P-x-y and P'-T (vapor pressure vs temperature) diagram for binary
miscible systems. How does pressure affect the T-x-y diagram?
116.
Discuss Margules, Wohl and Wilson equation for estimation of activity coefficient.
117.
118.
119.
120.
Discuss the effects of pressure, inerts, reactants ratio and temperature on chemical
reactions.
41
121.
What is the significance of the second law of thermodynamics with respect to transformation
of energy? Briefly make a general statement of the law.
122.
What is the objective of arranging for compressing air in stages with intermediate water
cooling to the original atmospheric temperature? Give the usual rules for the values of the
intermediate pressures in the case of (i) two stage and (ii) three stage compressor.
123.
124.
42
2.
3.
4.
5.
6.
7.
Which is more effective, a single extraction unit with a large volume of solvent or several
extraction units with small volumes? Explain.
8.
Name of the fraction at which benzene xylene and toluene is obtained during coal tar
distillation
9.
For a centrifugal pump if the pump is running and we close the discharge valve what is the
effect
10.
What is difference between overall heat transfer coefficient & individual heat transfer
coefficient?
11.
12.
13.
What are the ignition temperatures of Aluminum, Copper & Iron respectively?
14.
What is the ignition temperature of Diesel, Petrol & Carosion oil respectively?
15.
What are the apt definitions for apparent power, active power and reactive power? And give
explanation about different types of lamps?
16.
17.
18.
When selecting psv (pressure safety valve), what are all things we have to keep it in mind?
19.
20.
21.
22.
23.
24.
How the plate heat exchangers are used in an ammonia refrigeration system?
25.
What are some good estimates for heat transfer coefficients for coils in tanks?
26.
27.
How to calculate the release flow rates from pressurized gas systems?
28.
What is a good estimate for the absolute roughness for epoxy lined carbon steel pipe?
29.
43
30.
31.
What steps can be taken to avoid stress corrosion cracking (SCC) in steel vessels used for
storing anhydrous ammonia?
32.
33.
What are the main terms in Unit Operations? And what are its characteristics?
34.
MECHANICAL + CHEMICAL
1.
2.
3.
4.
5.
Draw a convergent uniform and divergent circular pipe and draw hydraulic gradient line and
total energy line.
6.
7.
b) Melting ice
c) Water
d) Boiling water
8.
Why we are not using the unit joule for torque instead of N-m.
9.
10.
Is it the relation between friction and power losses? is it relation among stress, friction and
power loses in circular ring ?
11.
12.
What is screw, centrifugal and rotary type compressors, how do they work and what is Principle
13.
What is the trigonometry of lifting tools using the wire rope? Any formula for trigonometry?
14.
15.
16.
17.
What is friction?
18.
19.
20.
44
21.
Why we cant measure absolute entropy directly, but the change we can?
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
What is knocking?
32.
33.
34.
35.
How can we avoid gas bubbles formation while mixing high viscous liquids?
36.
What will happens when the head of a selected pump is not utilized in a closed loop water
circuit? Flow will increase or decrease or remain same?
37.
B) At Compressor
D) At condenser
38.
39.
40.
41.
How the velocity of the liquid is converted into pressure energy in a volute casing? How we
finally get the fluid at high velocity or high pressure?
42.
43.
44.
45.
What is meant by velocity & gravity? What is the difference between the normal liquid flow and
the gravity liquid flow?
46.
47.
What is cavitation?
Ans: Cavitation is formation of air bubbles due to decrease in water pressure below its vapor
pressure
48.
49.
45
50.
51.
52.
Why the efficiency of multiple effects evaporator is less than the single effect evaporator?
53.
What is unit operation? What are the main terms in Unit Operations? And what are the main
characteristics its?
54.
55.
56.
Define: A)
57.
58.
59.
60.
Distillation Vs Fractionation
61.
62.
What are the basis for selecting Deaerator operating pressure and temperature?
Activity and B)
Partial Pressure
Ans: Generally deaerator is designed slight high pressure than the atmospheric pressure. and
temperature is maintained at about 120 130 oC because dm water should supply at this temp
process heat is recovered by circulating this dm water down stream of deaerator.
63.
64.
65.
66.
67.
68.
69.
70.
For a centrifugal pump if the pump is running and we close the discharge valve what is the
effect?
71.
72.
73.
74.
How much experience you are having in commercial software for protein design?
75.
How much maximum power can be generated by 320v, 10kg-cm synchronous motor if shaft is
rotated mechanically at 50 to 60 rpm?
76.
77.
How to calculate the release flow rates from pressurized gas systems?
78.
79.
How to determine the particle size distribution for a given bulk solid?
Technical Questions in Chemical Engineering by Srinivas Tulishetti
46
80.
81.
82.
83.
Name of the fraction at which benzene xylene and toulene are obtained during coal tar
distillation.
84.
85.
What are some good estimates for heat transfer coefficients for coils in tanks?
86.
87.
88.
89.
90.
91.
What compounds are responsible for the odors that come from wastewater treatment plants?
92.
93.
What is a good estimate for the absolute roughness for epoxy lined carbon steel pipe?
94.
What are the main terms in Unit Operations? And what are its characteristics?
95.
What is difference between Overall heat transfer coefficient & individual heat transfer coefficient
96.
97.
98.
99.
100. What is the Import Procurement Cycle? And what are the customization steps in SAP?
101. What is the most common cause of solid size segregation in bulk solid systems?
102. What is the purpose of capacitor? What is capacitor load? How does it connect?
103. What is the reason for removing silicon from aluminum?
104. What is the speed of a rotary drier
105. What is the symbol of sodium?
106. What are the various utilities of the process plant?
107. What regulates, or gives a substance the viscosity it has?
108. What steps can be taken to avoid stress corrosion cracking (SCC) in steel vessels used for
storing anhydrous ammonia?
109. Which thing is responsible for making petroleum?
110. Why is post-weld heat treatment sometimes necessary for welded vessels?
111. Why is steam added into the cracker in thermal cracking?
47
48
EIL-2009:
141. Polymers molecular weight range
Ans: 10^3 to 10^7
142. If the insulation thickness is greater than the critical radius Rc then what is effect on the heat
losses? Explain the phenomena.
Ans: Increases the Heat Transfer Rate.
143. Initially Pulp has 75% Water in it. After removal Of 100 kg of Water the Pulp then composition
of water in it is 30%. So what is the initial weight of the Pulp?
144. What is the Order and molecularity Of the reaction? H2+Cl2
___
>
2HCl
145. Heat of the Reaction One Question They gave some Reaction and The heat o formations of
Reactants and Products.
Ans: The heat o formations of (Products Reactants)
146. The kinetics of two reactions are r1=k1CA and r2=K2 CA2 and they have E1 < E2 to maximize the
selectivity which reactor configuration should we use?
Ans: PFR with low Temperature
147. Write relation for the reaction 1/2 N2+O2
___
>NO2
a)
156. What is the range of applicability for Dittus Bolteuss correlation in transport processes?
157. What is the function of the baffles in a heat exchanger
49
158. What will you do to enhance the heat transfer coefficient in natural convection
159. Which of the following requires Power /Kg Crushed is minimum
a) boll mill
b)rod mill
c) jaw Crusher
160. Classify the mills based on the A) material size B) the power consumption
161. State the stokes law and mention its limitations
162. Write the transfer functions for various controllers.
163. State the Phase rule and its application
164. What do you call the conversion of aromatics to alkanes?
165. What is the working principle of the cyclone separator?
166. What is the fanning factor?
167. What is the effect of the Pressure on specific heat of a gas and liquid?
be a Chemical Engineer.
With Best Wishes,
Srinivas Tulishetti
50