For LG Electronics supplier

LG Electronics manual of the hazardous substance

management in the parts and models
The Seventh edition

2014. 3. 1

LG Electronics Manual for hazardous substance management 7.0 edition

Introduction
LG Electronics make this manual to comply with the global environmental regulations and
directives effectively and secure environmentally friendly product competitiveness.
The suppliers of LG Electronics must adhere to LG Electronics green strategy and policy based
on this manual. This manual specifies LG Electronics global product environmental requirements.
The target scope includes subassemblies, parts, raw materials, batteries, packaging materials that
are incorporated into LG Electronics brand products.

All LG Electronics products must meet or

exceed the applicable legal requirements in each country in which these third-party products will be
sold, leased, or marketed.
This manual is regularly updated to be in tune with the revision of the existed global
environmental regulation / directives and/or new global environment-regulations.

When this

manual is updated, it would be spread out for the LG Electronics suppliers and uploaded on the LG
Electronics supplier portal.
LG Electronics have a Copyright and all intellectual property rights in the content of this manual.
Unauthorized reproduction and distribution is prohibited.

Mar. 1st, 2014 / The seventh editions

Product Testing Laboratory

Quality Center

Copyright 2014 LG Electronics Inc.

LG Electronics Manual for hazardous substance management 7.0 edition

Document History
Edition

Issued

Written by

th

1st

18 Nov,

Quality

Edition

2004

Management
Team,
LG Electronics

Contents
The very first preparation of manual throughout
the company/ Division/ Distribution to
cooperating suppliers
1. Standard of environment-related substance
management and operation
2. Standard of environment-related substance
analysis result submission

2nd

10th Mar,

Quality

Edition

2005

Management
Team,

Outline of environment-friendly certification

system (LG Green ship) added
Modification in environment-related substance

LG Electronics classification and management standard

1.Particulars of environment-friendly certification
system promotion added
2.Evaluation check list for environment-friendly
certification system of cooperating suppliers
added
3.Environment-related substance classification
redefined and management standard
reorganized
4.Permitted limit of cadmium content in zinc diecast parts and of hexavalent chromium content
in chromate plate parts redefined
5.Particulars of exemption from the recently
confirmed RoHS regulation reflected
th

3rd

13 June,

Quality/Supply

Main Change

Edition

2006

Management

1.LG Electronics Green Program renamed

Team,

2.Maximum Allowable Concentration Value

LG Electronics

revised
3.Submitted documents and effective term
added for mass production items guarantee
4.RoHS Free Mark revised
5.Organization and method for analysis updated

th

11 June,

Quality/Supply

2006

Management
Team,

1. Exceptions of environment-related substance

management standard added

LG Electronics
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LG Electronics Manual for hazardous substance management 7.0 edition

4th

May, 2007

Production

1. Main Change

Research

Chapter 2. Standard for management of

Institute,

hazardous substances

Edition

LG Electronics

1) Level A-II/B substances are added and

modified
- Level A-II added substances: PFOS, PCP,
Ugilec 121, 141, DBBT, Phthalate, PVC, BFRs
2) Related regulations, harmfulness, and
Analyzing method of detailed standard for
managing of environment-related substances
are added
3) Analyzing authorities and approving standard
for analysis report are up-dated
4) Redefinition of terminology and modification
of form for operating Hazardous Substance
Management System (HSMS) are reflected

nd

5th

22 Aug,

Eco strategy

edition

2008

team,
LG Electronics

Manual name change and contents

divided/deleted
1. Manual for Preparation Environmental
Regulations Guidance manual for
management of hazardous substances in
product
2. LG ElectronicsGP operation standard /
supplier assessment checklist deleted
3. Definition of terms contents arranged
- plastic, ICP, XRF, IC, UV/VIS, GS-MS
4. Analyzing Agency List and Analysis report
deleted
environment-related substance management
standard added and changed
1. REACH 52 restriction substances and
restricted conditions added
2. REACH 16 SVHC substances added
3. Norway PoHS, new RoHS regulation
expected materials added
4. Level B application timeline/phased out time
line management, substance added (Phthalates,
antimony, beryllium etc)
5. Halogen Free Mark revised

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LG Electronics Manual for hazardous substance management 7.0 edition

5.1

11th Nov,

Eco strategy

edition

2009

team,
LG Electronics

Hazardous substances management standard

changed
1. Unit (ppm mg/kg)
2. Analysis method by the substance
3. Added and deletion exemptions in EU RoHS
4. Lead in Battery (40 4 000 mg/kg)
5. Added in management for DMF
6. Level B management criteria change
- Product and application time

st

Sixth

1 Sep,

Edition

2011

Product Testing 1. Definitions and Exemptions rearranged to

Laboratory
LG Electronics

separate groups, e.g. RoHS revised exemption,

The candidate list of SVHCs in REACH.
2. Level B substances are separated into Level
B-I and B-II.
3. Analysis method and criteria for several
substances are added and changed.
4. The date of LG Electronics phase-out
substance is breakdown according to the
models.

Seventh

1st Mar,

Edition

2014

Product Testing 1. Adjustment of substance (Level A-II, BI, B-II)

Laboratory
LG Electronics

of the management class

2. Analysis method and criteria for several
substances are added and changed.
3. Add to EU RoHS exemptions
4. Add to Warranty document for non-use of
hazardous substances

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LG Electronics Manual for hazardous substance management 7.0 edition

Table of Contents
1. Purpose ..................................................................................................................................... 6
2. Scope ......................................................................................................................................... 6
3. Definition of terms .................................................................................................................... 7
3.1 Classification of Environment-related Substances ........................................................................ 7
3.2 Maximum Allowable Concentration Value (MCV) ............................................................................ 8
3.3 Contained ............................................................................................................................................ 8
3.4 Impurity ............................................................................................................................................... 8
3.5 Prohibition of Use .............................................................................................................................. 8
3.6 Exemptions ......................................................................................................................................... 8
3.7 Homogeneous materials .................................................................................................................... 9
3.8 HSMS (Hazardous Substances Management System) ................................................................... 9
3.9 Evidence of material composition .................................................................................................... 9
3.10 Analytical report ............................................................................................................................... 9
3.11 High risk parts .................................................................................................................................. 9
3.12 SVHC (Substances of Very High Concern) .................................................................................... 9
3.13 Warranty document .......................................................................................................................... 9

4. Standard for management of hazardous substances .......................................................... 10

4.1 Level A-I (Prohibited substance) .................................................................................................... 10
4.2 Level A-II (Restricted substances) .................................................................................................. 10
4.3 3 Level B-I (Voluntary phase-out substances) ............................................................................... 12
4.4 Level B-II (Monitored substances) .................................................................................................. 12
4.5 The criteria of the verification data for the material information ................................................ 13
4.6 Identification of Halogen free part .................................................................................................. 13
4.7 The work process that the suppliers part included the hazardous substances over the
LG Electronics criteria ...................................................................................................................... 13
4.8 Voluntary phase-out substances / Monitored substances (Level B-I, B-II) ................................ 14

5. Detailed standard for the environment-related substances................................................. 16

5.1 Level A-I Substances ....................................................................................................................... 16
5.2 Level A-II Substances ...................................................................................................................... 19
5.3 Level B-I Substances ....................................................................................................................... 25
5.4 Standard for management of hazardous substances for Packaging Materials ......................... 28
5.5 Standard for management of hazardous substances for Battery and Battery Pack ................. 28

Appendix 1. Applications exempted from the restriction ........................................................ 29

Appendix 2. Chemical substances list ...................................................................................... 38
Appendix 3. Warranty document for non-use of hazardous substances ................................ 53

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LG Electronics Manual for hazardous substance management 7.0 edition

1. Purpose
LG Electronics manages the substance / material information of the LG Electronics parts /
products including the hazardous substance for the global environmental regulatoin compliance. In
addition, LG Electronics try to conserve the Earth system and ultimately provide a better
environment for the next generation.

To comply with the global environmental laws and regulations, directives;

To reduce the environmental impact upon the ecosystem; and

To contribute to the preservation of the global environment.

This manual help the suppliers to comply with the LG Electronics standard of the substance /
material information.

2. Scope
This standard is to be applied to the activities of the substance testing and analysis method,
Maximum Allowable Concentration Value (MCV) and verification processes performed on all parts,
raw materials, packaging materials and batteries, etc. produced and supplied by the LG Electronics
suppliers.
2.1 Target
The targets shall satisfy the criteria specified in this manual. Targets are the parts, materials, and
other articles that are procured by the LG Electronics, or by third parties to which the LG
Electronics outsources the design and manufacture of its Electronics products.
1) Parts
1-1) Semi-finished products
ex) Module parts, function-unit board assemblies and other assembly parts
1-2) Accessories
1-3) Subsidiary substances required in part and product composition
ex) Adhesives, adhesive tapes and soldering substances, etc
1-4) Product manual
1-5) Plastic and plastic constituting substances
2) Packaging materials
3) Battery

*CKD : Complete KnockDown, SKD : Semi KnockDown

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LG Electronics Manual for hazardous substance management 7.0 edition

2.2 This standard is applied to the following products transacted with LG Electronics
1) All products designed, produced, sold and supplied by LG Electronics
2) Products designed and produced by the suppliers, but supplied to market with the trademark
of LG Electronics attached (ODM1) part / model)
3) Products designed by LG Electronics, produced by the suppliers and supplied to market with
the trademark of LG Electronics attached. (OEM2) part / model)
1) ODM : Original Design Manufacturing / Manufacturer
2) OEM : Original Equipment Manufacturing / Manufacturer

3. Definition of terms
3.1 Classification of Environment-related Substances
1) Level A substances
Level A substances are harmful to human body and environment of the earth, thus are prohibited
to use in products by law per each region and country. The intentional use of these substances is
prohibited in all items supplied to LG Electronics. Level A Substances also divided into Level A-I
and Level A-II.
Level A-I : Level A-I substances are six restriction substances (Pb, Cd, Hg, Cr6+,
PBDEs, PBBs) in RoHS Directives. Any use of six restriction substances must be
halted immediately. If a parts include any of six restriction substances over the
maximum allowable concentration value of LG Electronics, it cant be imported into LG
Electronics, and be used into LG Electronics products.

Level A-II : Level A-II substances are subject to the restriction substances by
international / local laws or international conventions except RoHS Directives. These
substances are prohibited of use in all parts constituting products of LG Electronics.

2) Level B Substances (Voluntary phase-out substances and Monitored substances)

Level B Substances also divided into Level B-I and Level B-II.
Level B-I : Level B-I substances means the voluntary phase-out substances of LG
Electronics. LG Electronics have a plan to phase out several hazardous substances for
contribution of the human health and conservation of the environment.
Level B-II : Level B-II substances are subject to the monitored substances of LG
Electronics.

These substances refer to substances considered harmful to human

being and environment that are not currently prohibited of use, but are scheduled for
the information provision and/or prohibition by the law and regulation in the future.
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LG Electronics Manual for hazardous substance management 7.0 edition

LG Electronics divisions should request the test report for Level A-II and Level B-I
substances in the part to indentify the inclusion of Level A-II and/or Level B-II substances
in the part.

All parts must be registered the substances / materials information of the part on HSMS
with the evidence such as MSDS, Material composition sheet, Material data sheet,
Material declaration etc).

3.2 Maximum Allowable Concentration Value (MCV)

Maximum allowable concentration value means the maximum permitted level of hazardous
substance in the part considering unavoidable impurities in the nature and the limitation of current
manufacturing and refining techniques and measurement errors of analysis test equipments,
except intentional use. It reflects the permitted limit decided by local, regional, and international
environment regulations. It shall be recorded by % weight or parts per million (mg/kg).
3.3 Contained
The term contained refers to all cases of where the substances are contained in components
and materials used in a part or product or packaging material both intentionally or unintentionally.
For example, the following conditions are included. adding, blending, filling or adhering a
substance use a substance in the manufacturing process and remains on or attached to the
finished product or its components or materials (for example, if a product risks being contaminated
by a mold, tool, or machine that directly contacts the product during the manufacturing process,
contamination of such section needs to be regarded as prohibited).
3.4 Impurity
A substance contained in natural materials but which cannot be fully eliminated during the refining
process, or which is generated in a reaction process but cannot be eliminated technically.

3.5 Prohibition of Use

Prohibition of use means that environment-related substances specified by LG Electronics must
not be intentionally contained in raw materials and parts in the courses of manufacturing. Impurities
which are inevitably contained in raw materials or parts due to limitation in raw material purification
technology or technical difficulty in the course of substance compounding, therefore, cannot be
completely removed, are managed by setting maximum concentration value.
3.6 Exemptions
Exemptions refer to the cases in which use of a fixed level of environment-related substance is
intentionally allowed because it is considered that alternative items are not possible with the
currently available technologies, or social impact by the occurrence of an accident after
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LG Electronics Manual for hazardous substance management 7.0 edition

alternation is expected too big.

3.7 Homogeneous materials
Homogenous Material means a material that cannot be mechanically disjointed into different
materials. The term homogeneous is understood as of uniform composition throughout, e.g.,
individual types of plastics, ceramics, glass, metal, alloys, paper, board, resins and coatings.
Paints and painted parts are not homogeneous materials and are to be considered different from
each other. Therefore, concentration of environment-related substances in painted and plated
layers must be analyzed by measuring the weight of these payers.
3.8 HSMS (Hazardous Substances Management System)
As system managed hazardous substances information in products and parts, request for
concerned substances information to suppliers in process of product development. Suppliers have
to input for hazardous substances by homogeneous materials
3.9 Evidence of material composition
Evidence of material composition is the basic analysis data on raw materials and substances of
parts and products supplied to LG Electronics, of which checking of constituting elements and
environment-related substance contents in the natural state is possible.
(Ex. Material Safety Data Sheet, Mill Sheet, Material Declaration, etc.).
3.10 Analytical report
It means the report tested with international standard at accredited laboratories comply with
ISO/IEC 17025.
3.11 High risk parts
It means parts have potential environmental risk of materials and process feature.
3.12 SVHC (Substances of Very High Concern)
It means substances of very high concern defined in European chemicals agency and
companies have a role such as information, notification, authorization under REACH.
3.13 Warranty document
The non-use certification is used by the supplier to verify that environment-related substances
specified by LG Electronics are not contained in the part and/or product.
Warranty document follows the form of Appendix 3.

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LG Electronics Manual for hazardous substance management 7.0 edition

4. Standard for management of hazardous substances

Any use of the restricted substances must be halted immediately. If a parts include any of the
restriction substances over the maximum allowable concentration value of LG Electronics, it cant
be imported into LG Electronics, and be used into LG Electronics products.

4.1 Level A-I (Prohibited substance)

Type

Substances

Regulation
EU RoHS Directive

Lead and its compounds

EU Battery Directive
EU Packaging Directive
EU REACH Regulation
EU RoHS Directive

Cadmium and its compounds

EU Battery Directive
EU Packaging Directive
EU REACH Regulation
EU RoHS Directive

Level A-I
Mercury and its compounds

EU Battery Directive
EU Packaging Directive
EU REACH Regulation
EU RoHS Directive

Hexavalent chromium and its compounds

EU Packaging Directive
EU REACH Regulation

PBB (Polybrominated biphenyls)

PBDE (Polybrominated diphenyl ethers)

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EU REACH Regulation
EU RoHS Directive
EU REACH Regulation

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4.2 Level A-II (Restricted substances)

Type

Substances

Regulation

Polychlorinated biphenyls (PCBs)

OSPAR Priority Chemicals

Polychlorinated naphthalenes (PCNs)

EU REACH Regulation

Polychlorinated terhphenyls (PCTs)

EU POPs Regulation
EU POPs Regulation

Short-chain chlorinated paraffin, C10-13 (SCCP)

Level A-II

OSPAR Priority Chemicals

PFOS (Perfluoro octane sulfonate)

EU POPs Regulation

Nickel and its compounds

EU REACH Regulation

Asbestos

EU REACH Regulation

Azo compounds

EU REACH Regulation

Ugilec 121, 141, DBBT

EU REACH Regulation

Specified organic tin compounds

EU REACH Regulation

Arsenic and its compounds

EU REACH Regulation
EU ODC Regulation

Ozone layer depleting substances

Montreal Protocol
EU REACH Regulation

Polycyclic aromatic hydrocarbons(PAHs)

Germany GS mark
ChemG (Germany)

Formaldehydes

Formalin Act (Denmark)

California ATCM

Dimethylfumarate (DMF)

Commission decision
2009/251/EC
EU REACH Regulation

Volatile organic compound (VOC)

Health-friendly housing
construction standards

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4.3 Level B-I (Voluntary phase-out substances)

Type

Substances
Poly vinyl chloride (PVC)
Ruminated flame retardants (Except PBB, PBDE)
Phthalates

Level B-I

Antimony and its compounds

Beryllium and its compounds
Chlorinated flame retardants
Bisphenol A
Perfluoro octanoic acid (PFOA)

LG Electronics shall phase out Level B-I substance of each product group according to the phase out
program of the relevant division.

4.4 Level B-II (Monitored substances)

Type

Substances
Cobalt and its compounds, including alloy
Selenium and its compounds, including alloy
Bismuth and its compounds, including alloy
Volatile Organic Compound- Emission
Bisphenol A
Triclosan
Surfactant

Level B-II

Chlorinated flame retardants

Boron and its compounds
Acrylamide
2-methoxyethanol
2-ethoxyethanol
2-ethoxyethyl acetate
Hydrazine
1-methyl-2-pyrrolidone
1,2,3-trichloropropane

Level B-II are substances considered harmful to human being and environment that are not currently
prohibited of use, but are scheduled for the information provision in REACH and/or prohibition by the law
and regulation in the future.

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LG Electronics Manual for hazardous substance management 7.0 edition

4.5 The criteria of the verification data for the material information
The supplier shall upload the following data on HSMS at the stage / process of new product
approval, 4M modification, and first article evaluation. In case of the LG Electronics request the
verification data, the supplier shall submit it.
1) At the stage of new approval and 4M modification of the part.
Test report *
- Each company and/or division of LG Electronics has the criteria of the validation period of
the test report. Therefore the supplier check the criteria of the validation period of the test
report.
Non-use certification report / Warranty.
MSDS or Mill sheet or Material Composition sheet, Material declaration etc.
Samples (more than 5, raw material condition when necessary)*
* If a LG Electronics company (or division) request the test report, the supplier shall submit
the test report to the department in charge of the examination for hazardous substances
directly.
2) At the stage of first article evaluation
Simplified analysis result (Desk-type XRF, Portable XRF etc) *
Samples (more than 5, raw material condition when necessary) *
* If a LG Electronics company (or division) request the test report, the supplier shall submit
the test report to the department in charge of the examination for hazardous substances
directly.
3) Periodical guarantee of parts for mass production
Test report If the validation period of test report is expired, it would be renewed. **
semi analysis result (XRF etc) *
Samples (more than 5, raw material condition when necessary)*
* If a LG Electronics company (or division) requests the test report, the supplier shall submit
the test report to the department in charge of the examination for hazardous substances
directly.
- Each company and/or division of LG Electronics has the criteria of the validation period of
the test report. Therefore the supplier checks the criteria of the validation period of the test
report.
4) Common mandatory data
The supplier shall register the material information of the part on HSMS, before it is supplied
into LG Electronics.
mass production.

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4.6 Identification of Halogen free part

If the RoHS 6 restriction substances and Halogen (Br, Cl) arent included in the part, the supplier
shall attach the below red mark on the packaging box(carton box, inner box, reel etc.) of the part at
the delivery of mass production lot and first article for mass production.

Size
- Well-recognized size (Free size)
- The upper mark is recommended for the large packaging box
- If the supplier use small packaging (ex. Reel), it is acceptable that the mark is smaller
than the upper mark
Color
- Red color is basically recommended for letter and boundary
- Black color is allowed if the mark is printed on the label.
Position and attaching method for the mark
- Well-recognizable shape outside packaging (Print/Stamp/Label etc.)
- Attached the mark up to small packaging such as the reel for small circuits like IC and
Chip SIZE
4.7 The work process that the suppliers part included the hazardous substances over the
LG Electronics criteria.
1) If any products and parts contain the 6 restriction substances of RoHS Directives (Level A-I
substances), they cant import into LG Electronics. And then LG Electronics stop to trade the
supplier which imported the part including any of the 6 restriction substances of RoHS
Directives. The suppliers shall prepare and submit an improvement plan for the parts
concerned. In addition, the supplier improves the part not to include any RoHS restriction
substances and verifies the non use of 6 RoHS restriction substances in the part with the
verification data such as the test report, XRF data etc.
2) Also, Level A-II must not be used in parts and products. If LG Electronics of supplier detect
Level A-II substances in the parts and products, LG Electronics stop to trade the parts and
products immediately.
3) No Detection means the supplier should verify that the substances are not used in its parts/
products, packaging materials and batteries (non-use certificate: Mill-sheet, MSDS, or Material
declaration, Material composition sheet etc.).
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LG Electronics Manual for hazardous substance management 7.0 edition

4.8 Voluntary phase-out substances / Monitored substances (Level B-I, B-II)

LG Electronics have a plan to phase out several hazardous substances for contribution of the
human health and conservation of the environment.

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LG Electronics Manual for hazardous substance management 7.0 edition

5. Detailed standard for the environment-related substances

[General notice]
The test report for Level A-I substances (RoHS 6 restriction substances) must be submitted and
LG Electronics checked it at the stage of part approval. The supplier shall submit the test report
of Level A-II substances if a LG Electronics division and/or company can request the test report
to the supplier.
The evidence must be upload on HSMS by the CAS No., weight, the percentage of material
and purpose of usage for detailed chemical substances used for all homogeneous materials
and parts.
Fundamentally, all the part must be followed the standards as mentioned in 5. Detailed
standard for the environment-related substances of this manual. If LG Electronics Division
and/or Company request that the supplier abide by the divisions or companys own standard,
the supplier must follow it.
5.1 Level A-I Substances
(1) Pb, Lead and its compounds
Regulated parts and materials
Plastic, rubber, painting, ink, coating, adhesives, tape,
label, paper
Solder (bar/wire/cream solder, solder ball),
Pb inside of lead-wire plating of parts
Pb inside of lead-wire plating of parts All parts except
and

Maximum Allowable
Concentration Level
200 mg/kg
800 mg/kg
500 mg/kg

rubber hardener, pigment, paint and varnish, lubricant, plastic stabilizer,

Main Containing
Purpose

battery material, free cutting brass/optics materials, soldering, rubber

vulcanizing agent, derivative bon steel, material, resin stabilizer, plating
material, alloy element, resin additives

Harmfulness

the central nerve damage, joint weakening, high blood pressure, brain
damage, sterility and miscarriage, sperm reducing by tissue damage
IEC 62321:2008

Analyzing method EN 62321:2009

IEC 62321-5:2013
Measurement

ICP-AES/OES, AAS, ICP-MS

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LG Electronics Manual for hazardous substance management 7.0 edition

(2) Cd, Cadmium and its compounds

Maximum Allowable

Regulated parts and materials

Concentration Level

Rubber, plastic, paints, inks, and plastic surface treatment,

50 mg/kg

adhesives tape, label, paper

All parts except

75 mg/kg

pigment, corrosion-resisting surface treatment, electric/electronic

Main Containing

materials, optics materials, stabilizer, plating material, resin pigment,

Purpose

fluorescent material for optical glass, electrode, soldering materials,

electrical contacts
stomach cramps, the kidney damage, high blood pressure, serum

Harmfulness

ferritin reducing, the central nerve and brain damage

IEC 62321:2008

Analyzing method

EN 62321:2009
IEC62321-5:2013

Measurement

ICP-AES/OES, AAS, ICP-MS

(3) Hg, Mercury and its compounds

Maximum Allowable

Regulated parts and materials

Interior

and

exterior

plastic,

paint

and

Concentration Level
varnish,

ink,

coating/soldering, wattmeter, electrical contacts (relay, switch,

500 mg/kg

sensor)
Main Containing
Purpose
Harmfulness

fluorescent material, electrical contacts material, pigment, anticorrosion preparation, high efficiency illuminant, antibiosis treatment
vomiting, wheal, eye spasm, the kidney and brain damage, visually
handicap, loss of eyesight, failing of memory
IEC 62321:2008

Analyzing method

EN 62321:2009
IEC62321-4:2013

Measurement

ICP-AES/OES, AAS, ICP-MS, TD-AAS, CV-AAS/AFS

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LG Electronics Manual for hazardous substance management 7.0 edition

(4) Cr(VI), Hexavalent chromium and its compounds

Maximum Allowable

Regulated parts and materials

Concentration Level

Plastic, rubber, painting, ink, non-plating parts as

metal/plastic coating

500 mg/kg

1)

Hexavalent chromium surface treatment parts

(Screw, Bolt, Nut, plate etc.) and electroplating
Soluble Cr(VI) of the cement
Main Containing
Purpose
Harmfulness

Negative

2)

The total dry weight 2 mg/kg

paints, pigment, ink, catalyzer, plating, corrosion protection surface

treatment, dyes, pigment desiccant, surface treatment, chromate
treatment, adhesion improvement for pigment
sniff, sneeze, nose bleeding, tumor, convulsions, asthma, lung cancer,
the kidney and liver damage, sudden death
IEC 62321:2008

Analyzing method

EN 62321:2009
Metal : IEC62321-7-1:2013
Polymer : IEC62321-7-2:2013

Measurement

UV-VIS, IC (Cr(VI))
ICP-AES/OES, AAS, ICP-MS (Total Cr)

1) If total Cr (measured by ICP or AAS) could not be detected, that data can be the Cr(VI) data.
2) Every surface treatment parts must not use Cr(VI) intendedly, and Cr(VI) should not be detected on
electroplating.

(5) PBBs (Polybrominated biphenyls)

Regulated parts and materials
Plastic
Main Containing
Purpose
Harmfulness

Maximum Allowable
Concentration Level
800 mg/kg

Flame retardants
Abnormal symptom on skin, loss of hair, weight losses, the central
nerve, liver, kidney, thyroid gland, and immune system damage
IEC 62321:2008

Analyzing method

EN 62321:2009
IEC62321-6:2013

Measurement

GC-MS

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(6) PBDEs (Polybrominated diphenylethers)

Regulated parts and materials
Plastic

Maximum Allowable
Concentration Level
800 mg/kg

Main Containing
Purpose

Flame retardants
Abnormal symptom on skin, loss of hair, weight losses, the

Harmfulness

central nerve, liver, kidney, thyroid gland, and immune system

damage
IEC 62321:2008

Analyzing method

EN 62321:2009
IEC62321-6:2013

Measurement

GC-MS

5.2 Level A-II Substances

(1) Polychlorinated biphenyls (PCBs), Polychlorinated naphthalenes (PCNs),
Polychlorinated terphenyls (PCTs)
Regulated parts and materials
All parts

Maximum Allowable
Concentration Level
50 mg/kg

- plasticizer for insulating oil, heat medium, specific lubricant, insulating

properties, and heat-resisting insulation of transformer/condenser/paper
Main
Containing
Purpose

condenser
- machine oil, plasticizer, pigment, copy paper as heat medium, which need
heat like 200400
- flame retardant pigment, Chlorinated Rubber pigment, vinyl pigment,
polyurethane pigment, pigment (weatherproofed, polish, insulation),
printing ink

Harmfulness
Analyzing
method
Measurement

Abnormal symptom on skin, loss of hair, weight losses, the central nerve,
liver, kidney, thyroid gland, and immune system damage
EPA 8082 etc
GC-MS

Polychloronaphthalence (PCN) is prohibited to use in case that the number of chlorine is more than 4

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(2) Short-chain chlorinated paraffin, C10-13 (SCCP)

Regulated parts and materials
All parts

Maximum Allowable
Concentration Level
1,000 mg/kg

Main Containing

PVC plasticizer, flame retardant

Purpose
Harmfulness

Cancer-causing, possible to generate dioxin by incineration

Analyzing method

EPA 3540C, 3550C etc., Extraction with organic solvent etc

Measurement

GC-MS

(3) Perfluoro octane sulfonate (PFOS)

Regulated parts and materials
Substance and Preparation
Article and parts

Maximum Allowable
Concentration Level
50 mg/kg
1,000 mg/kg

Textiles, coating material

Main Containing

1 g/m

carpet, textiles, cotton, leather, clothes, paper packaging, Metal plating,

Purpose

Fire fighting foam

Harmfulness

High persistent, Bioaccumulative, toxicity for mammalia

Analyzing method Solvent Extraction

Measurement

LC-MS

Exemptions for PFOS

- photoresist or anti-reflection coating use for photolithography
- coating for photo used for film and paper print lithography
- mist suppressants for nondecorational chrome plating
- aircraft hydraulic fluid

(4) Nickel and its compounds

Regulated parts and materials

Maximum Allowable
Concentration Level

Exterior plating parts contact with customer body continuously

(earphone, necklace, handle, mobile phone, etc.)
Main Containing
Purpose
Harmfulness

0.5 g -Ni/cm /week

coating or alloy compounds, surface treatment(coating), bottom layer

coating of parts, protecting coating, accessory coating
Allergy stimuli

Analyzing method EN 1811, EN 12471, EN 12472 etc

Measurement

ICP-AES/OES, AAS, ICP-MS

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(5) Asbestos
Regulated parts and materials
Fire-resistant, lagging materials, heat insulator,
electric insulator, filter
Main Containing

Maximum Allowable
Concentration Level
Not Detected

Asbestos fibers, insulator, packing material, abrasive material, heat

Purpose

insulating material, fireproof material

Harmfulness

Lung cancer, Asbestosis

Analyzing method
Measurement

NIOSH 9000, NIOSH 9002, NIOSH 7402 etc

XRD, PLM, TEM

(6) Azo compounds

Regulated parts and materials
Textiles and leather contact with customer body continuously
(belt, leather strap, earphone, headphone, shoulder pad, etc.)
Main Containing
Purpose

Maximum Allowable
Concentration Level
30 mg/kg

Paint, pigment, coloring agent for textiles and leather

Azo dyes is absorbed into human body through sweat, and then
body enzyme decomposes azo dyes, and the decomposed azo dyes

Harmfulness

produces aromatic amine compounds which are carcinogenic

substance

Analyzing method
Measurement

Leather : CEN ISO/TS 17234

Textiles : EN 14362-1, 2
GC-MS

1) Azodyes over 30mg/kg shall not be used in contact a contiguous portion of the skin .
2) Diaminodiphenylmethane (MDA) shall not be used in substance, part and product after Aug. 2014

(7) Ugilec 121, 141, DBBT

Regulated parts and materials
All parts
Main Containing
Purpose
Harmfulness
Analyzing method
Measurement

Maximum Allowable
Concentration Level
Not Detected

Transformer insulating oil, plasticizers, flame retardants, lubricants

and excavators
In product persistent, dioxin, since the 1990s a number of
discontinued
EPA 3540C, Solvent Extraction
GC-MS

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(8) Organic tin compounds

Maximum Allowable

Regulated parts and materials

Concentration Level

All parts

1,000 mg/kg

Main Containing
Purpose

PVC stabilizer, antioxidant, antifungal, antipollution, Painting, ink,

sterilizer, antiseptic, Antifoulant biocides

Harmfulness
Analyzing method
Measurement

Obstacle destruction of the ecosystem of the wild, carcinogens,

nervous system disorders substance, the immune system
DIN 17353, DIN 38407, KS K 0737 etc
GC-MS

(9) Arsenic and its compounds

Maximum Allowable

Regulated parts and materials

Concentration Level

All parts

100 mg/kg

Main Containing
Purpose
Harmfulness
Analyzing method
Measurement

Paint, ink, sterilizer, wood preservative

Vomiting,

skin

browning/blackening,

red

blood

reducing, loss of appetite, enlarged spleen, dry eruption

EPA 3052, EPA 3050B, EN 1122 etc. Microwave digestion
ICP-AES/OES, AAS, ICP-MS

Exemption for parts of semiconductor, glass, magnetic filter, copper foil and battery.

(10) Ozone layer depleting substances

Regulated parts and materials

Maximum Allowable
Concentration Level

All parts

Not Detected

Main Containing
Purpose
Analyzing method
Measurement

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cell

refrigerant, foaming agent, digestive, detergent

EPA5021A, EPA 8260B, PNNL-16813
GC-MS, GC-ECD, Headspace

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(11) PAHs (Polycyclic aromatic hydrocarbons)

Maximum Allowable

Regulated parts and materials

Concentration Level

Rubber, plastic, rubber foam used in parts possible

Not Detected

contact in body, polymer

Cable, Plug, Plastic shaft, Plastic package, box,

Main Containing
Purpose

Strange smell plastic, Rubber product, Rubber shaft, coating agent

Coating solution and brightening agents, preservatives material
(such as naphthalene)

Harmfulness
Analyzing method
Measurement

DNA change, harmful , mutation, cancer

EPA 8100, EPA 3540C/8270D, ISO 187287 etc
GC-MS

(12) Formaldehydes
Maximum Allowable

Regulated parts and materials

Concentration Level

Wooden products like HWPW-VC / HWPW-CC / PB /

0.05 / 0.05 / 0.09

MDF, (Fiberboard, plywood, speaker, shelf, etc.) /

/ 0.11 / 0.13 mg/kg

Thin MDF
Other product and parts (adhesive, vinyl, tape etc.)

0.1 mg/kg or 0.15 mg/m

Built-in household products

Main Containing
Purpose
Harmfulness
Analyzing method
Measurement

0.05 mg/m

Wooden product, adhesives, sterilizer, antiseptic, coating agent

Cancer-causing, promoting cancer-causing, atopic dermatitis, allergy
VDA275, DIN53315, ISO 16000 etc. Chamber method
KS X ISO/IEC 28360 (Product emmission)
HPLC-UV, UV-VIS

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(13) Dimethylfumarate (DMF)

Regulated parts and materials
All parts

Maximum Allowable
Concentration Level
Not Detected

Main Containing

leather, insecticide treatment in wrapped fiber product or must

Purpose

protection agent
easily passing skin due to strong fat-solubility

Harmfulness

strong stimulus into eyes, eczema

Analyzing method

EPA 3540C, Solvent Extraction

Measurement

GC-MS

(14) Volatile Organic Compound (VOC)

Regulated parts and materials
Adhesive, paint
(Refrigerator, microwave, oven, washing machine, etc.)
Purpose
Harmfulness
Analyzing method
Measurement

Concentration Level
Toluene, Benzene 1,000 mg/kg

Built-in household products

Main Containing

Maximum Allowable

Total VOC 5 mg/m

solvent (toluene, benzene)

Atopic dermatitis, allergy, head ache, lethargic
EPA 5012 A (Toluene, Benzene),
KS X ISO/IEC 28360 (Product emmission : TVOC, Formaldehyde)
Headspace-GC-MS

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5.3 Level B-I Substances

(1) PVC, Poly vinyl chloride
Maximum Allowable

Regulated parts and materials

Concentration Level

All parts

Not detected

Main Containing
Purpose

Insulation, poly vinyl electric wire, tube, power supply code

1. plasticizer, stabilizer, filler, lubricant, and coloring agent are used on
processing stage, and there are lots of hazardous substances which
can cause nervous system damage, immune system abnormal

Harmfulness

condition, Peripheral Vascular abnormal condition, liver cancer

2. lots of hydrogen chloride could be occurred by pyrolyzing PVC
3.experiments on animals discover that long-term exposure causes
damage on sperm and testicles

Analyzing method
Measurement

KS 0210 etc
Beilstein-Test

or FT-IR

(2) Bromated Flame Retardants (Except PBBs, PBDEs)

Maximum Allowable

Regulated parts and materials

All parts contain plastic including flame retardant
Main Containing
Purpose
Harmfulness

Concentration Level
HBCDD 1,000 mg/kg
others : 900 mg/kg (Total Br)

Plastic as PCB
EU regulated as potential hazardous substance, Possible to be
decomposed into Endocrine disruptor
EPA 3540C, EPA 3550B etc

Analyzing method

Total Br : IEC62321-3-2:2013, EN 50267-2-2, ASTM D 7359,

KS M 0180:2009, EN 14582 etc

Measurement

HBCDD : GC-MS, GC-ECD

Total Br : Combustion-IC, Oxygen Bomb-IC

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(3) Phthalates
Maximum Allowable

Regulated parts and materials

Concentration Level

All parts

1,000 mg/kg

Main Containing

Plasticizer to be soften plastic

Purpose

lung, kidney, heart, blood harmful, deformed birth, genital

Harmfulness

generation repression

Analyzing method

KS M 1991, ASTM D 3421 etc

Measurement

GC-MS

(4) Antimony and its compounds, including alloy

Maximum Allowable

Regulated parts and materials

Concentration Level

All parts contain plastic including flame retardant

Main Containing
Purpose
Harmfulness
Analyzing method
Measurement

1,000 mg/kg

pigment, dye, catalyzer, flame retardant, stabilization, optical lens,

solder, ink
pneumoconiosis, physiology problem, premature birth, abortion
EPA 3052, EPA 3050B etc
ICP-AES/OES, AAS, ICP-MS

Antimony, which is used for the attribute of flame-retardant except the phase-out.

(5) Beryllium and its compounds, including alloy

Maximum Allowable

Regulated parts and materials

Concentration Level
BeO : Not detected

All parts

others : 1,000 mg/kg

Main Containing
Purpose
Harmfulness
Analyzing method
Measurement

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Ceramic

materials,

alloy,

catalyzer,

electrodes,

electrical contacts, spring materials, connectors

carcinogenity, mutagenicity, toxicity for reproduction
EPA 3052, EPA 3050B etc
ICP-AES/OES, AAS, ICP-MS

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molds,

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(6) Chlorinated flame retardants

Maximum Allowable

Regulated parts and materials

TCEP : 1 000 mg/kg

All parts contain plastic

Main Containing
Purpose
Harmfulness

Concentration Level
others : 900 mg/kg (Total Cl)

Plastic as PCB
EU regulated as potential hazardous substance, Possible to be
decomposed into Endocrine disruptor
TCEP : KS M 1991, Solvent Extraction etc

Analyzing method

Total Cl : EN 50267-2-2, ASTM D 7359, KS M 0180:2009,

EN 14582 etc

Measurement

GC-MS, AQF-IC, Oxygen Bomb-IC

In the MC department, Chlorinated flame retardants shall not be used in substance, part and product
after Jan. 2010.

(7) Bisphenol A
Regulated parts and materials

Maximum Allowable Concentration

Polycarbonate resin, Epoxy resin

Main Containing
Purpose
Harmfulness
Analyzing method
Measurement

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Level
Not Detected

PC raw material, Epoxy Resin raw material

vinyl chloride stabilizer, antioxidant
Endocrine disruptors, nerve developmental disability
EPA 3540C etc, Solvent Extraction
GC-MS, LC-MS, HPLC

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(8) Perfluorooctyl acid (PFOA )

Maximum Allowable Concentration

Regulated parts and materials

Level

Substance and Preparation

50 mg/kg

Article and parts

1,000 mg/kg

Textiles, coating material

Main Containing
Purpose
Harmfulness

1 g/m

fire fighting foam, antiseptic

High persistent, Bioaccumulative, toxicity for mammalia

Analyzing method
Measurement

Solvent Extraction
LC-MS

5.4 Standard for management of hazardous substances for Packaging Materials

Maximum Allowable
Regulated parts and materials
Concentration Level
Pb, Cd, Hg, Cr+6
Packaging materials for all products on market

total 100 mg/kg

(Cd under 50mg/kg managed separately)

Br 900 mg/kg, Cl 900 mg/kg

packaging materials made from Lead crystal glass

5.5 Standard for management of hazardous substances for Battery and Battery Pack
Maximum Allowable
Regulated parts and materials 1)
Concentration Level
Pb and its
compounds

Carbon zinc, Alkaline battery

2000 mg/kg

The other all battery

4000 mg/kg

Cd and its compounds

Hg and its
compounds

20 mg/kg

Carbon zinc, Alkaline battery

1 mg/kg
5 mg/kg
exemption) button cell 2%

The other all battery

Not including hazardous

substances
Marking
Including hazardous substances

2)

1) Above the spec. is regulation for Battery Cell, and instrument/circuit parts used in Battery Pack have
to be followed standard stated in 5.1)~2) items.
2) Above the spec. is based on the weight of Battery Cell, and the name of substance have to marked on
in case of that is above Pb 40, Cd 20, Hg 5 mg/kg.

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Appendix 1. Applications exempted from the restriction

Exemption

Scope and dates of applicability

Mercury in single capped (compact)

1

fluorescent lamps not exceeding (per

Expires on 21 July 2016

burner):
Expires on 31 December 2011; 3,5
1(a)

For general lighting purposes < 30 W:

5 mg

mg may be used per burner after 31

December 2011 until 31 December
2012; 2,5 mg shall be used per
burner after 31 December 2012

1(b)

1(c)

1(d)

1(e)

1(f)

For general lighting purposes 30 W

and < 50 W: 5 mg

Expires on 31 December 2011; 3,5

mg may be used per burner after 31
December 2011.

For general lighting purposes 50 W

and < 150 W: 5 mg

Expires on 21 July 2016

Hg

For general lighting purposes 150

W: 15 mg

Expires on 21 July 2016

For general lighting purposes with

No limitation of use until 31

circular or square structural shape

December 2011; 7 mg may be used

and tube diameter 17 mm

per burner after 31 December 2011.

For special purposes: 5 mg

Expires on 21 July 2016

For general lighting purposes < 30 W

1(g)

with a lifetime equal or above

Expires on 31 December 2017

20 000 h: 3,5 mg
Mercury in double-capped linear
2(a)

fluorescent lamps for general lighting

Expires on 21 July 2016

purposes not exceeding (per lamp):

Hg
2(a)(1)

Tri-band phosphor with normal

Expires on 31 December 2011; 4 mg

lifetime and a tube diameter < 9 mm

may be used per lamp after 31

(e.g. T2): 5 mg

December 2011.

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2(a)(2)

2(a)(3)

2(a)(4)

2(a)(5)

2(b)

2(b)(1)

2(b)(2)

2(b)(3)

Tri-band phosphor with normal

Expires on 31 December 2011; 3 mg

lifetime and a tube diameter 9 mm

may be used per lamp after 31

and 17 mm (e.g. T5): 5 mg

December 2011.

Tri-band phosphor with normal

Expires on 31 December 2011; 3,5

lifetime and a tube diameter > 17 mm

mg may be used per lamp after 31

and 28 mm (e.g. T8): 5 mg

December 2011.

Tri-band phosphor with normal

Expires on 31 December 2012; 3,5

lifetime and a tube diameter > 28 mm

mg may be used per lamp after 31

(e.g. T12): 5 mg

December 2012.

Tri-band phosphor with long lifetime

( 25 000 h): 8 mg

may be used per lamp after 31

December 2011.
Hg

Mercury in other fluorescent lamps

not exceeding (per lamp):
Linear halophosphate lamps with tube
> 28 mm (e.g. T10 and T12): 10 mg
Non-linear halophosphate lamps (all
diameters): 15 mg
Non-linear tri-band phosphor lamps
with tube diameter > 17 mm (e.g. T9)

2(b)(4)

Expires on 31 December 2011; 5 mg

Expires on 21 July 2016

Expires on 13 April 2012

Expires on 13 April 2016

No limitation of use until 31
December 2011; 15 mg may be used
per lamp after 31 December 2011

Lamps for other general lighting and

No limitation of use until 31

special purposes (e.g. induction

December 2011; 15 mg may be used

lamps)

per lamp after 31 December 2011

Mercury in cold cathode fluorescent

lamps and external electrode
3

fluorescent lamps (CCFL and EEFL)

Expires on 21 July 2016

for special purposes not exceeding

(per lamp):

Hg
No limitation of use until 31

3(a)

Short length ( 500 mm)

December 2011; 3,5 mg may be

used per lamp after 31 December
2011

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3(b)

Medium length (> 500 mm and 1

500 mm)

No limitation of use until 31

December 2011; 5 mg may be used
per lamp after 31 December 2011
Hg
No limitation of use until 31

3(c)

Long length (> 1 500 mm)

December 2011; 13 mg may be used

per lamp after 31 December 2011

4(a)

Mercury in other low pressure

discharge lamps (per lamp)

No limitation of use until 31

December 2011; 15 mg may be used
per lamp after 31 December 2011

Mercury in High Pressure Sodium

(vapour) lamps for general lighting
4(b)

purposes not exceeding (per burner)

Expires on 21 July 2016

in lamps with improved colour

rendering index Ra > 60:
No limitation of use until 31
4(b)-I

P 155 W

December 2011; 30 mg may be used

per burner after 31 December 2011
No limitation of use until 31

4(b)-II

155 W < P 405 W

December 2011; 40 mg may be used

per burner after 31 December 2011
No limitation of use until 31

4(b)-III

P > 405 W

December 2011; 40 mg may be used

per burner after 31 December 2011

Mercury in other High Pressure

4(c)

Sodium (vapour) lamps for general

lighting purposes not exceeding (per

Expires on 21 July 2016

burner):
No limitation of use until 31
4(c)-I

P 155 W

December 2011; 25 mg may be used

per burner after 31 Dec. 2011
No limitation of use until 31

4(c)-II

155 W < P 405 W

December 2011; 30 mg may be used

per burner after 31 December 2011

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LG Electronics Manual for hazardous substance management 7.0 edition

No limitation of use until 31 Dec.

4(c)-III

P > 405 W

2011; 40 mg may be used per burner

after 31 December 2011

4(d)
4(e)

Mercury in High Pressure Mercury

(vapour) lamps (HPMV)
Mercury in metal halide lamps (MH)

Expires on 13 April 2015

Hg
Expires on 21 July 2016

Mercury in other discharge lamps for

4(f)

special purposes not specifically

Expires on 21 July 2016

mentioned in this Annex

5(a)
5(b)

Lead in glass of cathode ray tubes

Lead in glass of fluorescent tubes not
exceeding 0,2 % by weight

Expires on 21 July 2016

Pb
Expires on 21 July 2016

Lead as an alloying element in steel

6(a)

for machining purposes and in

galvanised steel containing up to 0,35

Expires on 21 July 2016

% lead by weight
Lead as an alloying element in
6(b)

aluminium containing up to 0,4 %

Pb
Expires on 21 July 2016

lead by weight
6(c)

Copper alloy containing up to 4 %

lead by weight

Expires on 21 July 2016

Lead in high melting temperature type

7(a)

solders (i.e. lead- based alloys

containing 85 % by weight or more

Expires on 21 July 2016

lead)
Pb

Lead in solders for servers, storage

and storage array systems, network
7(b)

infrastructure equipment for

switching, signalling, transmission,

Expires on 21 July 2016

and network management for

telecommunications

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Electrical and electronic components

containing lead in a glass or ceramic
7(c)-I

other than dielectric ceramic in

capacitors, e.g. piezoelectronic

Expires on 21 July 2016

devices, or in a glass or ceramic

matrix compound
Lead in dielectric ceramic in
7(c)-II

capacitors for a rated voltage of 125

Expires on 21 July 2016

V AC or 250 V DC or higher
Lead in dielectric ceramic in
7(c)-III

capacitors for a rated voltage of less

than 125 V AC or 250 V DC

Pb
Expires on 1 January 2013 and after
that date may be used in spare parts
for EEE placed on the market before
1 January 2013

Lead in PZT based dielectric ceramic

7(c)-IV

materials for capacitors being part of

integrated circuits or discrete

Expires on 21 July 2016

semiconductors
Expires on 1 January 2012 and after
8(a)

Cadmium and its compounds in one

that date may be used in spare parts

shot pellet type thermal cut-offs

for EEE placed on the market before

Cd

1 January 2012
8(b)

Cadmium and its compounds in

electrical contacts

Expires on 21 July 2016

Hexavalent chromium as an
anticorrosion agent of the carbon
9

steel cooling system in absorption

Expires on 21 July 2016

Cr(VI)

Expires on 21 July 2016

Pb

refrigerators up to 0,75 % by weight in

the cooling solution
Lead in bearing shells and bushes for
refrigerant-containing compressors
9(b)

for heating, ventilation, air

conditioning and refrigeration
(HVACR) applications

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11(a)

Lead used in C-press compliant pin

connector systems

May be used in spare parts for EEE

placed on the market before 24
September 2010
Expires on 1 January 2013 and after

11(b)

Lead used in other than C-press

that date may be used in spare parts

compliant pin connector systems

for EEE placed on the market before

Pb

1 January 2013

12

13(a)

Lead as a coating material for the

thermal conduction module C-ring
Lead in white glasses used for optical
applications

May be used in spare parts for EEE

Pb

placed on the market before 24

September 2010
Expires on 21 July 2016

Pb

Expires on 21 July 2016

Cd, Pb

Cadmium and lead in filter glasses

13(b)

and glasses used for reflectance

standards
Lead in solders consisting of more

14

than two elements for the connection

Expired on 1 January 2011 and after

between the pins and the package of

that date may be used in spare parts

microprocessors with a lead content

for EEE placed on the market before

of more than 80 % and less than 85

1 January 2011

Pb

% by weight

Lead in solders to complete a viable

15

electrical connection between

semiconductor die and carrier within

Expires on 21 July 2016

Pb

Expires on 1 September 2013

Pb

Expires on 21 July 2016

Pb

integrated circuit flip chip packages

16

Lead in linear incandescent lamps

with silicate coated tubes
Lead halide as radiant agent in high

17

intensity discharge (HID) lamps used

for professional reprography
applications

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LG Electronics Manual for hazardous substance management 7.0 edition

Lead as activator in the fluorescent

powder (1 % lead by weight or less)
of discharge lamps when used as
18(a)

speciality lamps for diazoprinting

reprography, lithography, insect traps,

Expired on 1 January 2011

photochemical and curing processes

containing phosphors such as SMS

Pb

((Sr,Ba) 2 MgSi 2 O 7 :Pb)

Lead as activator in the fluorescent
powder (1 % lead by weight or less)
18(b)

of discharge lamps when used as sun

Expires on 21 July 2016

tanning lamps containing phosphors

such as BSP (BaSi 2 O 5 :Pb)
Lead with PbBiSn-Hg and PbInSn-Hg
in specific compositions as main
19

amalgam and with PbSn-Hg as

Expires on 1 June 2011

Pb

Expires on 1 June 2011

Pb

auxiliary amalgam in very compact

energy saving lamps (ESL)
Lead oxide in glass used for bonding
20

front and rear substrates of flat

fluorescent lamps used for Liquid
Crystal Displays (LCDs)
Lead and cadmium in printing inks for

21

the application of enamels on

glasses, such as borosilicate and

Pb,
Expires on 21 July 2016
Cd

soda lime glasses

23

Lead in finishes of fine pitch

May be used in spare parts for EEE

components other than connectors

placed on the market before 24

with a pitch of 0,65 mm and less

September 2010

Pb

Lead in solders for the soldering to

24

machined through hole discoidal and

planar array ceramic multilayer

Expires on 21 July 2016

Pb

capacitors

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LG Electronics Manual for hazardous substance management 7.0 edition

Lead oxide in surface conduction

25

electron emitter displays (SED) used

in structural elements, notably in the

Expires on 21 July 2016

Pb

Expires on 1 June 2011

Pb

Expired on 24 September 2010

Pb

Expires on 21 July 2016

Pb

Expires on 21 July 2016

Cd

Expires on 21 July 2016

Pb

Expires on 21 July 2016

Pb

Expires on 21 July 2016

Pb

Expires on 21 July 2016

Pb

seal frit and frit ring

26

Lead oxide in the glass envelope of

black light blue lamps
Lead alloys as solder for transducers
used in high-powered (designated to

27

operate for several hours at acoustic

power levels of 125 dB SPL and
above) loudspeakers
Lead bound in crystal glass as

29

defined in Annex I (Categories 1, 2, 3

and 4) of Council Directive
69/493/EEC ( 1 )
Cadmium alloys as
electrical/mechanical solder joints to
electrical conductors located directly

30

on the voice coil in transducers used

in high-powered loudspeakers with
sound pressure levels of 100 dB (A)
and more
Lead in soldering materials in

31

mercury free flat fluorescent lamps

(which, e.g. are used for liquid crystal
displays, design or industrial lighting)
Lead oxide in seal frit used for making

32

window assemblies for Argon and

Krypton laser tubes
Lead in solders for the soldering of

33

thin copper wires of 100 m diameter

and less in power transformers

34

Lead in cermet-based trimmer

potentiometer elements

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LG Electronics Manual for hazardous substance management 7.0 edition

Mercury used as a cathode sputtering

36

inhibitor in DC plasma displays with a

Expired on 1 July 2010

Hg

Expires on 21 July 2016

Pb

Expires on 21 July 2016

Cd

Expires on 1 July 2014

Cd

Expires on 31 December 2013

Cd

content up to 30 mg per display

Lead in the plating layer of high
37

voltage diodes on the basis of a zinc

borate glass body
Cadmium and cadmium oxide in thick

38

film pastes used on aluminium

bonded beryllium oxide
Cadmium in colour converting II-VI

39

LEDs (< 10 g Cd per mm 2 of lightemitting area) for use in solid state

illumination or display systems

40

Cadmium in photoresistors for

analogue optocouplers

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LG Electronics Manual for hazardous substance management 7.0 edition

Appendix 2. Chemical substances list

(1) Pb, Lead and its compounds
Name

Chemical symbol

CAS No.

Lead

Pb

7439-92-1

Lead(II) carbonate

PbCO3

598-63-0

Lead(IV) oxide

PbO2

1309-60-0

Lead(II,IV) oxide

Pb3O4

1314-41-6

Lead(II) sulfide

PbS

1314-87-0

Lead azide

Pb(N3)2

13424-46-9

Lead(II) oxide

PbO

1317-36-8

Lead(II) fluoride

PbF2

7783-46-2

Lead(II) chloride

PbCl2

7758-95-4

Lead(IV) chloride

PbCl4

13463-30-4

Lead(II) carbonate basic

PB3(CO3)2(OH)2

1319-46-6

Lead(II) iodide

Pbl2

10101-63-0

Lead hydroxycarbonate

(PbCO3 ) 2 Pb(OH)2

1344-36-1

Lead(II) cyanide

Pb(CN)2

592-05-2

Lead(II) fluoroborate

Pb(BF4)2

13814-96-5

Lead(II) fluosilicate

PbSiF6

25808-74-6

Lead(II) sulfate

PbSO4

7446-14-2

Lead(II) phosphate

Pb3(PO4)2

7446-27-7

Lead thiocyanate

Pb(SCN)2

592-87-0

Lead(II) chromate

PbCrO4

7758-97-6

Lead(II) titanate

PbTiO3

12060-00-3

Lead(II) acetate, trihydrate

Pb(CH3COO)2 3H2O

6080-56-4

Lead(II) acetate

Pb(CH3COO)2

301-04-2

Lead(II) metaborate

Pb(BO2)2 H2O

10214-39-8

Lead metasilicate

PbSiO3

11120-22-2

Lead silicate

H2O3Si.xPb

22569-74-0

Lead antimonite

Pb(SbO4)3

13510-89-9

Lead hydrogen arsenate

PbHAsO4

7784-40-9

Lead(II) arsenite

Pb(AsO2)2

10031-13-7

Lead(IV) acetate / Lead tetraacetate Pb(C2H3O2)4 / C8H12O8Pb

546-67-8

Sulphuric acid, lead salt

PbSO4

15739-80-7

Lead sulfate, tribasic

Pb4SO7 / PbSO4(PbO)3

12202-17-4

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Lead nitrate

Pb(NO3)2

10099-74-8

Lead sulfochromate yellow

1344-37-2

Lead oxide sulfate

Pb2O(SO4)

12036-76-9

Lead molybdate

PbMoO4

10190-55-3

Tetramethyl lead

Pb(CH3)4

75-74-1

Tetraethyl lead

Pb(C2H5)4

78-00-2

Lead selenide

PbSe

12069-00-0

Pb(ClHO4)2

13637-76-8

C36H70O4Pb

1072-35-1

Lead stearate (stearic acid, lead salt) C36H70O4Pb

7428-48-0

Lead stearate, dibasic

2PbO / Pb(C17H35COO)2

56189-09-4

Other lead compounds

Lead perchlorate

ClHO4.1/2Pb

Lead distearate

(2) Cd, Cadmium and its compounds

Name

Chemical symbol

CAS No.

Cadmium

Cd

7440-43-9

Cadmium oxide

CdO

1306-19-0

Cadmium sulfide

CdS

1306-23-6

Cadmium zinc sulfide yellow

8048-07-5

Cadmium carbonate

CdCO3

513-78-0

Cadmium chloride

CdCl2

10108-64-2

Cadmium sulfate

CdSO4

10124-36-4

Cadmium nitrate

Cd(NO3)2

10325-94-7

Cadmium nitrate tetrahydrate

Cd(NO3)2 4H2O

10022-68-1

Cadmium stearate

Cd(C18H35O2)2

2223-93-0

Other cadmium compounds

(3) Hg, Mercury and its compounds

Name

Chemical symbol

CAS No.

Mercury

Hg

7439-97-6

Mercury(I) chloride

Hg2Cl2

10112-91-1

Mercury(II) chloride

HgCl2

7487-94-7

Mercury(I) oxide

Hg2O

15829-53-5

Mercury(II) oxide

HgO

21908-53-2

Mercury(II) nitrate

Hg(NO3)2

10045-94-0

Mercury(I) sulfate

Hg2(SO)4

7783-35-9

Mercury(II) fulminate

Hg(CNO)2

628-86-4

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Mercury(II) acetate

Hg(CH3COO)2

1600-27-7

Methylmercury salts

CH3HgX (X: halogen)

Ethylmercury salts

C2H5HgX

Propylmercury salts

C3H7HgX

Methoxyethyl-mercury salts

CH3OC2H4HgX

Diphenylmercury

(C6H5)2Hg

587-85-9

Dialkylmercury

R2Hg(R: alkyl group)

Phenylmercury nitrate

C6H5HgNO3

55-68-5

Other mercury compounds

(4) Cr(VI), Hexavalent chromium and its compounds

Name

Chemical symbol

CAS No.

Sodium dichromate

Na2Cr2O7

10588-01-9

Sodium dichromate, dihydrate

Na2Cr2H2O7

7789-12-0

Chromium(VI) oxide / Chromium trioxide

CrO3

1333-82-0

Calcium chromate

CaCrO4

13765-19-0

Lead(II) chromate

PbCrO4

7758-97-6

Potassium dichromate

K2Cr2O7

7778-50-9

Potassium chromate

K2CrO7

7789-00-6

Lithium chromate

Li2CrO4

14307-35-8

Sodium chromate

Na2CrO4

7775-11-03

Potassium chlorochromate

K[CrO3Cl]

16037-50-6

Ammonium chromate

(NH4)2CrO4

7788-98-9

Copper chromate

CuCrO4

13548-42-0

Magnesium chromate

MgCrO4

13423-61-5

Strontium chromate

SrCrO4

7789-06-02

Barium chromate

BaCrO4

10294-40-3

Lead chromate (orange color)

PbCrO4

1344-38-3

Lead chromate (yellow color)

PbCrO4+PbSO4

1344-37-2

Dichromium zinc tetraoxide

Cr2O4Zn

12018-19-8

Zinc chromate

ZnCrO4

13530-65-9

Zinc dichromate

ZnCr2H2O7

14018-95-2

Ammonium dichromate

(NH4)2Cr2O7

7789-09-05

Calcium dichromate

CaCr2O7

14307-33-6

Dichromic acid

H2Cr2O7

13530-68-2

Copper chromite

CuCrO3

12053-18-8

Other hexavalent chromium compounds

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(5) Polybrominated biphenyls (PBBs)

Name

Chemical symbol

CAS No.

Polybrominated biphenyl (PBB)

C12HXBr(10-X)

67774-32-7

2-bromodiphenyl

C12H9Br

2502-07-5

3-bromodiphenyl

C12H9Br

2113-57-7

4-bromodiphenyl

C12H9Br

92-66-0

4,4'-Dibromodiphenyl

C12H8Br2

92-86-4

3,4,5-Tribromodiphenyl

C12H7Br3

115245-08-4

2,4,6-Tribromodiphenyl

C12H7Br3

59080-33-0

3,3',4,4',-tetrabromobiphenyl

C12H6Br4

77102-82-0

2,2',4,5',-tetrabromobiphenyl

C12H6Br4

60044-24-8

2,2',4,5',6-pentabromobiphenyl

C12H5Br5

59080-39-6

3,3',4,4',5,5'-Hexabromodiphenyl

C12H4Br6

60044-26-0

2,2',4,4',5,5'-Hexabromodiphenyl

C12H4Br6

59080-40-9

2,2',3,3,4,5,6,6'-Octabromodiphenyl

C12H2Br8

119264-60-7

2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl

C12Br10

13654-09-6

Other PBBs compounds

(6) Polybrominated diphenylethers (PBDEs)

Name

Chemical symbol

CAS No.

Polybrominated diphenyl ether(PBDE)

Polybrominated diphenyl oxide(PBDO)

C12H(10-X)BrXO

4-Bromophenyldiphenyl ether

C12H9BrO

101-55-3

4,4-Dibromodiphenyl ether

C12H8Br2O

2050-47-7

Tribromodiphenyl ether

C12H7Br3O

49690-94-0

Tetrabromodiphenyl ether

C12H6Br4O

40088-47-9

Pentabromodiphenyl ether

C12H5Br5O

32534-81-9

Hexabromodiphenyl ether

C12H4Br6O

36483-60-0

Heptabromodiphenyl ether

C12H3Br7O

68928-80-3

Octabromodiphenyl ether

C12H2Br8O

32536-52-0

Nonabromodiphenyl ether

C12HBr9O

63936-56-1

Decabromodiphenyl ether

C12Br10O

1163-19-5

Other PBDEs compounds

Polybrominated byphenyl ethers(PBBE)

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(7) Polychlorinated biphenyls (PCBs), Polychlorinated Naphthalenes (PCNs),

Polychlorinated Terphenyls (PCTs)
Name

Chemical symbol

CAS No.

Polychlorinated biphenyls (PCBs)

C12H10-xClX

1336-36-3

Polychlorinated terphenyls (PCTs)

C18H14-x ClX

61788-33-8

Polychlorinated naphthalenes (PCNs)

C10H8-xClX

70776-03-3

Trichloronaphthalene

C10H5Cl3

1321-65-9

Tetrachloronaphthalene

C10H4Cl4

1335-88-2

Pentachloronaphthalene

C10H3Cl5

1321-64-8

Octachloronaphthalene

C10Cl8

2234-13-1

Other PCBs, PCNs, PCTs compounds

(8) Short Chain Chlorinated Paraffin, C10-13 (SCCP)

Name
Short-chain chlorinated paraffine (C10~13)

Chemical symbol
-

CAS No.
85535-84-8

(9) Perfluoro octane sulfonate (PFOS)

Name
AMMONIUM
HEPTADECAFLUOROOCTANESULPHONATE
HEPTADECAFLUORO-1-OCTANESULFONIC
ACID, COMPD. WITH DIETHANOLAMINE
LITHIUM PERFLUOROOCTANE SULFONATE

Chemical symbol

CAS No.

C8H4F17NO3S

29081-56-9

C12H12F17NO5S

70225-14-8

C8F17LiO3S

29457-72-5

HEPTADECAFLUOROOCTANESULFONIC ACID C8HF17O3S

1763-23-1

POTASSIUM PERFLUOROOCTANESULFONATE C8F17KO3S

2795-39-3

Other PFOS compounds

(10) Nickel and its compounds

Name

Chemical symbol

CAS No.

Nickel

Ni

7440-02-0

Nickel(II) oxide

NiO

1313-99-1

Nickel sulfate

NiSO4

7786-81-4

Nickel carbonate

NiCO3

3333-67-3

Nickel chloride

NiCl2

7718-54-9

Dinickel trioxide

Ni2O3

1314-06-3

Nickel dihydroxide

NiH2O2

12054-48-7

Nickel acetate

NiC4H6O4

373-02-4

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Nickel carbonyl

Ni(CO)4

13463-39-3

Other nickel compounds

(11) Asbestos
Name

Chemical symbol

CAS No.

Actinolite

Ca2(Mg,Fe)5Si8O22(OH)2

77536-66-4

Amosite

(Mg,Fe)7Si8O22(OH)2

12172-73-5

Anthophylite

(Mg,Fe)7Si8O22(OH)2

77536-67-5

Chrysotile

Mg3Si2O5(OH)4

12001-29-5

Crocidolite

Na2F5Si8O22(OH)2

12001-28-4

Tremolite

Ca2(Mg,Fe)5Si8O22(OH)2

77536-68-6

(12) Azo compounds

Name

Chemical symbol

CAS No.

2,4,5-Trimethylaniline

C9H13N

137-17-7

2,4-Diaminoanisole

C7H10N2O

615-05-4

2,4-Toluenediamine

C7H10N2

95-80-7

2-Amino-4-nitrotoluene

C7H8N2O2

99-55-8

2-Naphthylamine

C10H9N

91-59-8

3,3-Dichlorobenzidine

C12H10Cl2N2

91-94-1

3,3-Dimethoxybenzidine

C14H16N2O2

119-90-4

3,3-Dimethyl-4,4diaminodiphenylmethane

C15H18N2

838-88-0

3,3-Dimethylbenzidine

C14H16N2

119-93-7

4,4-Diaminodiphenylmethane

C13H14N2

101-77-9

4,4-Methylene-bis-(2-chloraniline)

C13H12Cl2N2

101-14-4

4,4-Oxydianiline

C12H12N2O

101-80-4

4,4-Thiodianiline

C12H12N2S

139-65-1

4-amino azobenzene

C12H11N3

60-09-3

4-Aminodiphenyl

C12H11N

92-67-1

4-Chloro-o-toluidine

C7H8ClN

95-69-2

Benzidine

C12H12N2

92-87-5

o-Aminoazotoluene

C14H15N3

97-56-3

o-anisidine

C7H9NO

90-04-0

o-Toluidine

C7H9N

95-53-4

p-Chloroaniline

C6H6ClN

106-47-8

p-Cresidine

C8H11NO

120-71-8

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(13) Ugilec 121, 141, DBBT

Name

Chemical symbol

CAS No.

DBBT (Monomethyl dibromo diphenyl methane)

C14H12Br2

99688-47-8

Ugilec 121 (Monomethyl dichloro diphenyl methane)

C14H12Cl2

81161-70-8

Ugilec 141 (Monomethyl tetrachloro diphenyl methane) C14H10Cl4

76253-60-6

(14) Organic tin compounds

Name

Chemical symbol

CAS No.

Bis(tri-n-butyltin) oxide

O(Sn(C4H9)3)2

56-35-9

Tributyltin(TBT)

(C4H9)3Sn

56573-85-4

Triphenyltin (TPT)

(C6H5)3Sn

668-34-8

Tributyltin bromide

(C4H9)3SnBr

1461-23-0

Triphenyltin N,N'-dimethyldithiocarbamate

(C6H5)3Sn(CH3)2NCS2

1803-12-9

Triphenyltin fluoride

(C6H5)3SnF

379-52-2

Triphenyltin acetate

(C6H5)3SnOCOCH3

900-95-8

Triphenyltin chloride

(C6H5)3SnCl

639-58-7

Triphenyltin hydroxide

(C6H5)3SnOH

76-87-9

Triphenyltin fatty acid salts (C=9~11)

47672-31-1

Triphenyltin chloroacetate

(C6H5)3SnOCOCH3Cl

7094-94-2

Tributyltin methacrylate

(C4H9)3SnC4H5O2

2155-70-6 / 18380-71-7

Bis(tributyltin) fumarate

C2H2(COO)2((C4H9)3Sn)2

6454-35-9

Tributyltin fluoride

(C4H9)3SnF

1983-10-4

Bis(tributyltin) 2,3-dibromosuccinate

((C4H9)3Sn)2C2H2(Br)2(COO)2

31732-71-5

Tributyltin acetate

(C4H9)3SnOCOCH3

56-36-0

Tributyltin laurate

(C4H9)3SnC12H23O2

3090-36-6

Bis(tributyltin) phthalate

C6H4(COO)2((C4H9)3Sn)2

4782-29-0

Copolymer

of

alkyl

acrylate,

methyl

methacrylate and tributyltin methacrylate

(alkyl; C=8)
Tributyltin sulfamate

(C4H9)3SnSO3NH2

6517-25-5

Bis(tributyltin) maleate

C2H2(COO)2((C4H9)3Sn)2

14275-57-1

Tributyltin chloride

(C4H9)3SnCl

1461-22-9

(C4H9)3SnSO3C5H9

26239-64-5

Tributyltin naphthennate

(C4H9)3Sn(C10H8)

85409-17-2

Dibutylltin

C8H20Sn

1002-53-5

Mixture of tributyltin cyclopentane-carboxylate

and its analogs
(Tributyltin rosin salts)

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Dioctylltin

C16H36Sn

15231-44-4

Dibutylltin X

C8H20SnX

Dioctylltin X

C16H36SnX

Other organotin compounds

(15) Arsenic and its compounds

Name

Chemical symbol

CAS No.

ARSENIC

As

7440-38-2

TRIETHYL ARSENATE

C6H15AsO4

15606-95-8

AsH15Na2O11

10048-95-0

ARSENIC ACID, CALCIUM SALT

As2Ca3O8

7778-44-1

ARSENIC ACID, COPPER SALT

As2Cu3O8

10103-61-4

ARSENIC ACID, DIAMMONIUM SALT

AsH9N2O4

7784-44-3

ARSENIC ACID, LEAD SALT

AsHO4Pb

7784-40-9

ARSENIC ACID, MAGNESIUM SALT

As2Mg3O8

10103-50-1

ARSENIC PENTOXIDE

As2O5

1303-28-2

ARSENIC TRICHLORIDE

AsCl3

7784-34-1

ARSENIC TRIHYDRIDE

AsH3

7784-42-1

ARSENIC TRIOXIDE

As2O3

1327-53-3

ARSENIOUS ACID, COPPER (II) SALT

AsCuHO3

10290-12-7

GALLIUM ARSENIDE

AsGa

1303-00-0

ARSENIOUS ACID, POTASSIUM SALT

AsKO2

10124-50-2

ARSENIC ACID DISODIUM SALT,

HEPTAHYDRATE

(16) Ozone layer depleting substances

Name

Chemical symbol

CAS No.

Chloroform

CHCl3

67-66-3

1,1,2 Trichloroethane

C2H3Cl3

79-00-5

1,1,2,2 Tetrachloroethane

C2H2Cl4

79-34-5

1,1,1,2 Tetrachloroethane

C2H2Cl4

630-20-6

Pentachloroethane

C2HCl5

76-01-7

1,1 Dichloroethylene

C2H2Cl2

75-35-4

CFC 11

CCl3F

75-69-4

CFC 111

C2Cl5F

354-56-3

CFC 112

C2Cl4F2

76-12-0 / 28605-74-5

CFC 113

C2Cl3F3

76-13-1

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CFC 114

C2Cl2F4

76-14-2 / 1320-37-2

CFC 115

C2ClF5

76-15-3

CFC 12

CCl2F2

75-71-8

CFC 13

CClF3

75-72-9

CFC 211

C3Cl7F

422-78-6 / 135401-87-5

CFC 212

C3Cl6F2

3182-26-1

CFC 213

C3Cl5F3

2354-06-5

CFC 214

C3Cl4F4

2268-46-4

CFC 215

C3Cl3F5

1652-81-9

CFC 216

C3Cl2F6

661-97-2

CFC 217

C3ClF7

422-86-6

Halon 1211

CBrClF2

353-59-3

Halon 1301

CBrF3

75-63-8

Halon 2402

C2Br2F4

124-73-2

bromochloromethane

CH2BrCl

74-97-5

HBFC-121B4

C2HFBr4

306-80-9

HBFC-122B3

C2HF2Br3

HBFC-123B2

C2HF3Br2

354-04-1

HBFC-124B1

C2HF4Br

HBFC-131B3

C2H2FBr3

HBFC-132B2

C2H2F2Br2

75-82-1

HBFC-141B2

C2H3FBr2

358-97-4

HBFC-133B1

C2H2F3Br

HBFC-142B1

C2H3F2Br

HBFC-151B1

C2H4FBr

762-49-2

HBFC-21B2

CHFBr2

HBFC-221B6

C3HFBr6

HBFC-222B5

C3HF2Br5

HBFC-223B4

C3HF3Br4

HBFC-224B3

C3HF4Br3

HBFC-226B1

C3HF6Br

HBFC-225B2

C3HF5Br2

431-78-7

HBFC-22B1

CHF2Br

HBFC-231B5

C3H2FBr5

HBFC-232B4

C3H2F2Br4

HBFC-233B3

C3H2F3Br3

HBFC-234B2

C3H2F4Br2

HBFC-235B1

C3H2F5Br

460-88-8

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HBFC-242B3

C3H3F2Br3

70192-80-2

HBFC-241B4

C3H3FBr4

HBFC-243B2

C3H3F3Br2

70192-83-5

HBFC-244B1

C3H3F4Br

679-84-5

HBFC-251B3

C3H4FBr3

75372-14-1

HBFC-253B1

C3H4F3Br

421-46-5

HBFC-252B2

C3H4F2Br2

460-25-3

HBFC-261B2

C3H5FBr2

51584-26-0

HBFC-262B1

C3H5F2Br

HBFC-31B1

CH2FBr

HBFC-271B1

C3H6FBr

352-91-0

HCFC-31

CH2FCl

373-52-4

HCFC-121

C2HFCl4

354-14-3

HCFC-122

C2HF2Cl3

354-21-2

HCFC-123

C2HF3Cl2

306-83-2

HCFC-124

C2HF4Cl

2837-89-0

HCFC-131

C2H2FCl3

134237-34-6

HCFC-132

C2H2F2Cl2

25915-78-0

HCFC-133

C2H2F3Cl

75-88-7

HCFC-141

C2H3FCl2

25167-88-8

HCFC-141b

C2H3FCl2

1717-00-6

HCFC-142

C2H3F2Cl

25497-29-4

HCFC-142b

CH3CF2Cl

75-68-3

HCFC-151

C2H4FCl

1615-75-4

HCFC-21

CHFCl2

75-43-4

HCFC-22

CHF2Cl

75-45-6

HCFC-221

C3HFCl6

134237-35-7

HCFC-222

C3HF2Cl5

134237-36-8

HCFC-223

C3HF3Cl4

34237-37-9

HCFC-224

C3HF4Cl3

134237-38-0

HCFC-225

C3HF5Cl2

128903-21-9

HCFC-225ca

CF3CF2CHCl2

422-56-0

HCFC-225cb

CF2ClCF2CHClF

507-55-1

HCFC-226

C3HF6Cl

134308-72-8

HCFC-231

C3H2FCl5

134190-48-0

HCFC-232

C3H2F2Cl4

134237-39-1

HCFC-233

C3H2F3Cl3

134237-40-4

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HCFC-234

C3H2F4Cl2

127564-83-4

HCFC-235

C3H2F5Cl

134237-41-5

HCFC-241

C3H3FCl4

134190-49-1

HCFC-242

C3H3F2Cl3

134237-42-6

HCFC-243

C3H3F3Cl2

134237-43-7

HCFC-244

C3H3F4Cl

134190-50-4

HCFC-251

C3H4FCl3

134190-51-5

HCFC-252

C3H4F2Cl2

134190-52-6

HCFC-253

C3H4F3Cl

134237-44-8

HCFC-261

C3H5FCl2

134237-45-9

HCFC-262

C3H5F2Cl

134190-53-7

HCFC-271

C3H6FCl

134190-54-8

methyl bromide

CH3Br

74-83-9

1,1,1-trichloroethane

C2H3Cl3

71-55-6

Carbon tetrachloride

CCl4

56-23-5

Trichloroethylene

C2HCl3

79-01-06

sulfur hexafluoride

F6S

2551-62-4

HFCs

PFCs

(17) PAHs
Name

Chemical symbol

CAS No.

NAPHTHALENE

C10H8

91-20-3

ACENAPHTHYLENE

C12H8

208-96-8

ACENAPHTHENE

C12H8

83-32-9

FLUORENE

C13H10

86-73-7

PHENANTHRENE

C14H10

85-01-8

ANTHRACENE

C14H10

120-12-7

FLUORANTHENE

C16H10

206-44-0

INDENO[c,d]PYRENE

C22H12

193-39-5

PYRENE

C16H10

129-00-0

BENZO[g,h,i]PERYLENE

C22H12

129-24-2

Benzo(a)pyrene(BaP)

C20H12

50-32-8

Benzo(e)pyrene(BeP)

C20H12

192-97-2

Benzoanthracenepyrene(BaA)

C18H12

56-55-3

Chrysen

C18H12

218-01-9

Benzofluoranthene(BbFA)

C20H12

205-99-2

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Benzofluoranthene(BjFA)

C20H12

205-82-3

Benzofluoranthene(BkFA)

C20H12

207-08-9

Dibenzoanthracene(DBAhA)

C22H14

53-70-3

(18) Formaldehydes
Name
Formaldehyde

Chemical symbol
HCHO

CAS No.
50-00-0

(19) Dimethylfumarate (DMF)

Name
Dimethylfumarate

Chemical symbol
C6H8O4

CAS No.
624-49-7

(20) Volatile Organic Compound

Name

Chemical symbol

CAS No.

Benzene

C6H6

71-43-2

Toluene

C7H8

108-88-3

Ethylbenzene

C8H10

100-41-4

Xylene

C6H4(CH3)2

1330-20-7

Styrene

C8H8

100-42-5

Other VOC compounds

(21) Poly vinyl chloride

Name
Poly vinyl chloride

Chemical symbol
H(CH2CHCl)nH

CAS No.
9002-86-2 / 93050-82-9

(22) Bromated Flame Retardants (Except PBB, PBDE)

Name

Chemical symbol

CAS No.

Tetrabromobisphenol A

C15H12Br4O2

79-94-7

Tetrabromobisphenol A dimethylether

C17H16Br4O2

37853-61-5

Tetrabromobisphenol A dibromopropyl ether

C21H20Br8O2

21850-44-2

Tetrabromobisphenol A bisallylether

C21H20Br4O2

25327-89-3

C19H20Br4O4

4162-45-2

Tri(2, 3-dibromopropyl) phosphate

C9H15Br6O4P

126-72-7

Bis(2, 3-dibromopropyl) phosphate

C6H11Br4O4P

5412-25-9

Tetradecabromo (p-diphenoxybenzene)

C18Br14O2

58965-66-5

Tetrabromobisphenol A bis(2-hydroxyethyl
ether)

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Bis(2, 4, 6-tribromophenyl) carbonate

C13H4Br6O3

67990-32-3

(C10H5Br5O2)n

59447-57-3

Polystyrene, brominated

(C8H5Br3)n

88497-56-7

1, 2-Bis (2, 4, 6-tribromophenoxy) ethane

C14H8Br6O2

37853-59-1

Disodium tetrabromophthalate

C8H2Br4O4.2Na

25357-79-3

TBBPA bis (2, 3-dibromopropyl) ether

C21H20Br8O2

21850-44-2

C18H4Br8N2O4

32588-76-4

C12H18Br6

25637-99-4

2-Propenoic acid (pentabromophenylmethyl)

ester, homopolymer

1H-Isoindole-1, 3(2H)-dione2,2-(1,2-ethanediyl)bis[4,5,6,7-tetrabromo]
Hexabromocyclododecane
3,4,5,6-Tetrabromo-1,2-benzenedicarboylic

mixed esters acid, propylene with diethylene -

77098-07-8

glycol and glycol

Polymer of TBBPA, phosgene, and phenol

(C7H5O2).(C16H10Br4O3)n.(C6H5O) 94334-64-2

Tris(tribromoneopentyl) phosphate

C15H24Br9O4P

19186-97-1

(C21H20Br4O4)n.(C15H12Br4O2)n

68928-70-1

TBBPA, 2,2-bis[4-(2,3-epoxypropyloxy)
dibromo Phenyl]propane polymer
Phosphoric
dimethylpropyl

acid,

mixed

and

3-bromo-2,2-

2-bromoethyl

and

2- -

125997-20-8

chloroethyl esters
2,4,6-Tribromophenyl terminated carbonate

(C7H2Br3O2).(C16H10Br4O3)n.

oligomer

(C6H2Br3O)

Tetrabromocyclooctane

C8H12Br4

31454-48-5

Brominated aliphatic Compounds

Dibromoethyl dibromo cyclohexane

C8H12Br4

3322-93-8

N,N-Ethylene-bis(tetrabromophthalimide)

C18H4Br8N2O4

32588-76-4

Brominated polystylene

(C8H5Br3)n

57137-10-7

Tetrabromophthalic anhydride

C8Br4O3

632-79-1

Ethylenebis(Tetrabromophthalimide)

C18H4Br8N2O4

32588-76-4

Other BFRs compounds

71342-77-3

(23) Phthalates
Name

Chemical symbol

CAS No.

Dimethyl phthalate (DMP)

C10H10O4

131-11-3

Diethyl phthalate (DEP)

C12H14O4

84-66-2

Bis(2-ethyl-hexyl) phthalate(DEHP)

C24H38O4

117-81-7

Dibutyl phthalate(DBP)

C16H22O4

84-74-2

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Benzyl butyl phthalate(BBP)

C19H20O4

85-68-7

Di-isononyl phthalate(DINP)

C26H42O4

28553-12-1 / 68515-48-0

di-isodecyl phthalate(DIDP)

C28H46O4

26761-40-0 / 68515-49-1

di-n-octyl phthalate(DNOP)

C24H38O4

117-84-0

1,2-Benzenedicarboxylic acid,

68515-42-4

di-C7-11-branched and linear alkyl esters

1,2-Benzenedicarboxylic acid,

71888-89-6

di-C6-8-branched alkyl esters, C7-rich (DIHP)

Other Phthalates compounds

(24) Antimony and its compounds

Name

Chemical symbol

CAS No.

Antimony trioxide

Sb2O3

1309-64-4

Antimony pentoxide

Sb2O5

1314-60-9

(25) Beryllium and its compounds

Name

Chemical symbol

CAS No.

BERYLLIUM

Be

7440-41-7

BERYLLIUM CARBONATE

Be2CO3(OH)2

66104-24-3

BERYLLIUM CHLORIDE

BeCl2

7787-47-5

BERYLLIUM FLUORIDE

BeF2

7787-49-7

BERYLLIUM HYDROXIDE

BeH2O2

13327-32-7

BERYLLIUM NITRATE

Be.2HNO3

13597-99-4

BERYLLIUM PHOSPHATE

BeHO4P

13598-15-7

BERYLLIUM SULFATE

Be.H2O4S

13510-49-1

BERYLLIUM SULPHATE TETRAHYDRATE

BeH8O8S

7787-56-6

BERYLLIUM OXIDE

BeO

1304-56-9

BERYLLIUM-ALUMINUM ALLOY

12770-50-2

BERYLLIUM COPPER AND OTHER METAL

ALLOYS CONTAINING GREATER AMOUNTS -

OF BERYLLIUM
Other BERYLLIUM compounds

(26) Chlorinated flame retardants

Name

Chemical symbol

CAS No.

Chlorinated paraffin

Chlorinated polyethylene

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(27) Bisphenol A
Name

Chemical symbol
C15H16O2

Bisphenol A

CAS No.
80-05-7

(28) Perfluoro octanoic acid (PFOA)

Name

Chemical symbol

CAS No.

PENTADECAFLUOROOCTANOIC ACID

C8HF15O2

335-67-1

PERFLUOROOCTANOIC ANHYDRIDE

C16F30O3

33496-48-9

C8H4F15NO2

3825-26-1

Perfluorooctanoic acid sodium salt

C8F15NaO2

335-95-5

Potassium perfluorooctanoate

C8H2F15KO2

2395-00-8

Silver perfluorooctanoate

C8AgF15O2

335-93-3

Perfluorooctanoyl fluoride

C8F16O

335-66-0

Methyl Perfluorooctanoate

C9H3F15O2

376-27-2

Other PFOA compounds

PERFLUOROOCTANOIC ACID
AMMONIUM SALT

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Appendix 3. Warranty document for non-use of hazardous substances

Warranty Document
Date of submission : YYYY

MM

DD

, company hereby warrants that all products

being provided to LG Electronics Inc. do not contain certain hazardous substances according
to the newest version of Manual of the hazardous substance management for suppliers, and
are complying with all kinds of regulations on hazardous substances

The responsibility for all non-compliance issues on hazardous substances caused by the
products is belong to the

(company name).

Company Information
Supplier code

Person in charge

Contact number

E-Mail

Name
Supplier
Address
Name
Maker
Address

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LG Electronics Manual for hazardous substance management 7.0 edition

List of hazardous substances

Last Updated : February 2014
Substance Name
Lead and its compounds
Cadmium and its compounds
Mercury and its compounds
Hexavalent chromium and its compounds
PBB (Polybrominated biphenyls)
PBDE (Polybrominated diphenyl ethers)
Polychlorinated biphenyls(PCBs), Polychlorinated naphthalenes(PCNs), Polychlorinated terhphenyls (PCTs)
Short-chain chlorinated paraffin, C10-13 (SCCP)
PFOS (Perfluoro octane sulfonate)
Nickel and its compounds
Asbestos
Azo compounds
Ugilec 121, 141, DBBT
Specified organic tin compounds
Arsenic and its compounds
Ozone layer depleting substances
Polycyclic aromatic hydrocarbons (PAHs)
Formaldehydes
Dimethylfumarate (DMF)
Volatile organic compound (VOC)

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LG Electronics Manual for hazardous substance management 7.0 edition

List of hazardous substances

Last Updated : February 2014
Substance Name
Poly vinyl chloride (PVC)
Ruminated flame retardants (Except PBB, PBDE)
Phthalates
Antimony and its compounds
Beryllium and its compounds
Chlorinated flame retardants
Bisphenol A
PFOA (Perfluoro octanoic acid)
Cobalt and its compounds, including alloy
Selenium and its compounds, including alloy
Bismuth and its compounds, including alloy
Triclosan
Surfactant (DTDMAC, DODMAC, DSDMAC, DHTDMAC)
MCCP (Medium-chained chlorinated paraffin, C14-C17)
PCP (Pentachlorophenol)
Musk xylene
Green House Gases

SVHCs candidate and the substance restricted by US California Proposition65 should be involved List of
hazardous substances, although the list of hazardous substances does not show.

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