Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II - United Kingdom (UK)
SAFETY DATA SHEET
Jotamastic 87 Comp A
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
Product name
Product code
Product description
Product type
Other means of
identification
:
:
:
:
:
Jotamastic 87 Comp A
515
Coatings: Solvent-borne.
Liquid.
Not available.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Uses in Coatings - Industrial use
Uses in Coatings - Professional use
Industrial applications, Professional applications, Used by spraying.
See Annex to the Safety data sheet for additional information in the Exposure Scenario(s).
1.3 Details of the supplier of the safety data sheet
Jotun Paints (Europe) Ltd.
Stather Road
Flixborough, Scunthorpe
North Lincolnshire
DN15 8RR
England
Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
[email protected]
1.4 Emergency telephone number
Contact National Poison Centre via Hospital or Registered Medical Practitioner
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition
: Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Chronic 3, H412
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
: R10
Classification
Xi; R36/38
R43
R52/53
Physical/chemical hazards : Flammable.
Human health hazards
: Irritating to eyes and skin. May cause sensitisation by skin contact.
Environmental hazards
: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
See Section 16 for the full text of the R phrases or H statements declared above.
Date of issue
: 16.07.2013.
1/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 2: Hazards identification
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms
: Danger
: Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye damage.
May cause an allergic skin reaction.
Harmful to aquatic life with long lasting effects.
Signal word
Hazard statements
Precautionary statements
General
Prevention
Response
Storage
Disposal
Hazardous ingredients
Supplemental label
elements
: Not applicable.
: Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks,
open flames and hot surfaces. - No smoking. Avoid release to the environment.
: IF IN EYES: Rinse cautiously with water for several minutes. Immediately call a
POISON CENTER or physician.
: Keep cool.
: Not applicable.
: epoxy resin (MW 700)
2-methylpropan-1-ol
: Contains epoxy constituents. May produce an allergic reaction.
2.3 Other hazards
Other hazards which do not : Not available.
result in classification
SECTION 3: Composition/information on ingredients
Substance/mixture
: Mixture
Classification
Product/ingredient
name
epoxy resin (MW
700)
xylene
hydrocarbons, c9unsatd., polymd.
Identifiers
REACH #: 012119456619-26
EC: 500-033-5
CAS: 25068-38-6
Index: 603-074-00-8
5-25
REACH #: 012119488216-32
EC: 215-535-7
CAS: 1330-20-7
Index: 601-022-00-9
REACH #: 012119555292-40
CAS: 71302-83-5
5-10
67/548/EEC
Regulation (EC) No.
1272/2008 [CLP]
Type
Notes
Xi; R36/38
Skin Irrit. 2, H315
[1]
R43
N; R51/53
Eye Irrit. 2, H319
Skin Sens. 1, H317
Aquatic Chronic 2,
H411
Flam. Liq. 3, H226
[1] [2]
Acute Tox. 4, H312
Acute Tox. 4, H332
Skin Irrit. 2, H315
Skin Sens. 1, H317
[1]
[1]
[1] [2]
R10
Xn; R20/21
Xi; R38
2,5-25 R43
epoxy resin (MW 700- CAS: 25036-25-3
1200)
1-5
Xi; R36/38
R43
2-methylpropan-1-ol
1-5
R10
Aquatic Chronic 3,
H412
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Skin Sens. 1, H317
Flam. Liq. 3, H226
Xi; R41, R37/38
R67
Skin Irrit. 2, H315
Eye Dam. 1, H318
Date of issue
REACH #: 012119484609-23
EC: 201-148-0
CAS: 78-83-1
: 16.07.2013.
R52/53
2/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 3: Composition/information on ingredients
Index: 603-108-00-1
benzyl alcohol
ethylbenzene
REACH #: 012119492630-38
EC: 202-859-9
CAS: 100-51-6
Index: 603-057-00-5
REACH #: 012119489370-35
EC: 202-849-4
CAS: 100-41-4
Index: 601-023-00-4
1-3
STOT SE 3, H335 and
H336
[1]
Acute Tox. 4, H302
Xn; R20/22
Acute Tox. 4, H332
1-3
F; R11
Flam. Liq. 2, H225
Xn; R20
Acute Tox. 4, H332
See Section 16 for
the full text of the Rphrases declared
above.
See Section 16 for
the full text of the H
statements declared
above.
[1] [2]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a
workplace exposure limit and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give
General
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Inhalation
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognised skin cleanser. Do NOT use solvents or thinners.
: Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Eye contact
Ingestion
: If swallowed, seek medical advice immediately and show the container or label. Keep
person warm and at rest. Do not induce vomiting.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact
: Causes serious eye damage.
Inhalation
: May give off gas, vapor or dust that is very irritating or corrosive to the respiratory
system.
Skin contact
: Causes skin irritation. May cause an allergic skin reaction.
Ingestion
: May cause burns to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact
: Adverse symptoms may include the following:
pain
watering
redness
Inhalation
Skin contact
Date of issue
: No specific data.
: Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
: 16.07.2013.
3/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 4: First aid measures
Ingestion
: Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
: No specific treatment.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
: Recommended: alcohol-resistant foam, CO 2, powders, water spray.
: Do not use water jet.
5.2 Special hazards arising from the substance or mixture
: Flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and
Hazards from the
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
substance or mixture
create fire or explosion hazard. This material is harmful to aquatic life with long
lasting effects. Fire water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal
decomposition products
5.3 Advice for firefighters
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency
: No action shall be taken involving any personal risk or without suitable training.
personnel
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Do not breathe vapour or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders
6.2 Environmental
precautions
: If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For
non-emergency personnel".
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
6.3 Methods and materials for containment and cleaning up
Date of issue
: 16.07.2013.
4/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 6: Accidental release measures
Small spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Use spark-proof tools
and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Large spill
: Stop leak if without risk. Move containers from spill area. Approach the release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite
or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see section 1 for
emergency contact information and section 13 for waste disposal.
6.4 Reference to other
sections
: See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher
than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been
excluded. Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators
should wear antistatic footwear and clothing and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of
this preparation. Avoid inhalation of dust from sanding.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air.
When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to
control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed
respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen
below the exposure limits.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep
away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Recommendations
Industrial sector specific
solutions
Date of issue
: Not available.
: Not available.
: 16.07.2013.
5/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
Product/ingredient name
Exposure limit values
xylene
EH40/2005 WELs (United Kingdom (UK), 1/2012). Absorbed
through skin.
STEL: 441 mg/m 15 minute(s).
STEL: 100 ppm 15 minute(s).
TWA: 220 mg/m 8 hour(s).
TWA: 50 ppm 8 hour(s).
EH40/2005 WELs (United Kingdom (UK), 1/2012).
STEL: 231 mg/m 15 minute(s).
STEL: 75 ppm 15 minute(s).
TWA: 154 mg/m 8 hour(s).
TWA: 50 ppm 8 hour(s).
EH40/2005 WELs (United Kingdom (UK), 1/2012). Absorbed
through skin.
STEL: 552 mg/m 15 minute(s).
STEL: 125 ppm 15 minute(s).
TWA: 100 ppm 8 hour(s).
TWA: 441 mg/m 8 hour(s).
2-methylpropan-1-ol
ethylbenzene
Recommended monitoring
procedures
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
Derived no effect levels
Product/ingredient name
epoxy resin (MW 700)
Type
Exposure
DNEL Short term Dermal
DNEL Short term
Inhalation
DNEL Long term Dermal
DNEL Long term
Inhalation
DNEL Short term Dermal
DNEL Short term Oral
DNEL Long term Dermal
DNEL Long term Oral
xylene
DNEL Short term
Inhalation
DNEL Short term
Inhalation
DNEL Long term Dermal
DNEL Long term
Inhalation
DNEL Long term Dermal
DNEL Long term
Inhalation
DNEL Long term Oral
Date of issue
: 16.07.2013.
Value
8,33 mg/kg
bw/day
12,25
mg/m
8,33 mg/kg
bw/day
12,25
mg/m
3,571
mg/kg
bw/day
0,75 mg/kg
bw/day
3,571
mg/kg
bw/day
0,75 mg/kg
bw/day
289 mg/m
Population
Effects
Workers
Systemic
Workers
Systemic
Workers
Systemic
Workers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
Workers
Systemic
289 mg/m Workers
Local
180 mg/kg
bw/day
77 mg/m
Workers
Systemic
Workers
Systemic
108 mg/kg Consumers
bw/day
14,8 mg/m Consumers
Systemic
1,6 mg/kg
Systemic
Consumers
Systemic
6/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 8: Exposure controls/personal protection
hydrocarbons, c9-unsatd., polymd.
DNEL Long term Dermal
DNEL Long term
Inhalation
DNEL Long term Dermal
DNEL Long term
Inhalation
DNEL Long term Oral
2-methylpropan-1-ol
DNEL Long term
Inhalation
DNEL Long term Oral
DNEL Long term
Inhalation
DNEL Short term
Inhalation
DNEL Long term
Inhalation
DNEL Short term Dermal
benzyl alcohol
DNEL Long term Dermal
DNEL Short term Dermal
DNEL Short term Oral
DNEL Long term Dermal
DNEL Long term Oral
DNEL Long term
Inhalation
DNEL Short term
Inhalation
DNEL Short term
Inhalation
DNEL Long term Dermal
ethylbenzene
DNEL Long term
Inhalation
DNEL Long term
Inhalation
DNEL Long term Oral
bw/day
16,4 mg/kg Workers
bw/day
57 mg/m Workers
8 mg/kg
bw/day
28 mg/m
Systemic
Systemic
Consumers
Systemic
Consumers
Systemic
4 mg/kg
Consumers
bw/day
310 mg/m Workers
Systemic
25 mg/kg
bw/day
55 mg/m
Consumers
Systemic
Consumers
Local
Local
450 mg/m Workers
Systemic
90 mg/m
Workers
Systemic
47 mg/kg
bw/day
9,5 mg/kg
bw/day
28,5 mg/kg
bw/day
25 mg/kg
bw/day
5,7 mg/kg
bw/day
5 mg/kg
bw/day
8,11 mg/m
Workers
Systemic
Workers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
Consumers
Systemic
40,55
Consumers
mg/m
293 mg/m Workers
Systemic
180 mg/kg
bw/day
77 mg/m
Workers
Systemic
Workers
Systemic
15 mg/m
Consumers
Systemic
1,6 mg/kg
bw/day
Consumers
Systemic
Local
Predicted no effect concentrations
Product/ingredient name
epoxy resin (MW 700)
xylene
hydrocarbons, c9-unsatd., polymd.
Date of issue
Compartment Detail
Value
PNEC Fresh water
PNEC Marine
PNEC Sewage Treatment
Plant
PNEC Fresh water sediment
PNEC Marine water sediment
PNEC Soil
PNEC Fresh water
PNEC Marine
PNEC Sewage Treatment
Plant
PNEC Fresh water sediment
PNEC Marine water sediment
PNEC Soil
PNEC Fresh water
0,006 mg/l
0,0006 mg/l
10 mg/l
0,996 mg/l
0,0996 mg/l
0,196 mg/l
0,327 mg/l
0,327 mg/l
6,58 mg/l
12,46 mg/kg dwt
12,46 mg/kg dwt
2,31 mg/kg dwt
54 g/l
Type
: 16.07.2013.
Method Detail
7/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 8: Exposure controls/personal protection
2-methylpropan-1-ol
benzyl alcohol
ethylbenzene
8.2 Exposure controls
Appropriate engineering
controls
PNEC Marine
PNEC Sewage Treatment
Plant
PNEC Fresh water sediment
PNEC Marine water sediment
PNEC Marine water sediment
PNEC Soil
PNEC Secondary Poisoning
PNEC Fresh water
PNEC Marine
PNEC Sewage Treatment
Plant
PNEC Fresh water sediment
PNEC Marine water sediment
PNEC Soil
PNEC Fresh water
PNEC Marine
PNEC Sewage Treatment
Plant
PNEC Fresh water sediment
PNEC Marine water sediment
PNEC Soil
PNEC Fresh water
PNEC Marine
PNEC Sewage Treatment
Plant
PNEC Fresh water sediment
PNEC Soil
PNEC Secondary Poisoning
5,4 g/l
2,2 mg/l
1584 mg/kg dwt
158 mg/kg dwt
158 mg/kg dwt
316,7 mg/kg dwt
200 mg/kg
0,4 mg/l
0,04 mg/l
10 mg/l
1,52 mg/kg dwt
0,152 mg/kg dwt
0,0699 mg/kg dwt
1 mg/l
0,1 mg/l
39 mg/l
5,27 mg/kg dwt
0,527 mg/kg dwt
0,456 mg/kg dwt
0,1 mg/l
0,01 mg/l
9,6 mg/l
13,7 mg/kg dwt
2,68 mg/kg dwt
20 mg/kg
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits. The engineering controls also need to
keep gas, vapour or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.
Individual protection measures
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection
Skin protection
Hand protection
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
: For prolonged or repeated handling, use the following type of gloves: gloves:
polyvinyl alcohol or nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Body protection
: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by
a specialist before handling this product.
Date of issue
: 16.07.2013.
8/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 8: Exposure controls/personal protection
Respiratory protection
: If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product.(as filter combination A2-P2). In confined spaces, use
compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
: Liquid.
Physical state
: Various colours.
Colour
: Characteristic.
Odour
: Not available.
Odour threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
: Not applicable.
: Not available.
: Not available.
Flash point
: Closed cup: 35C
Evaporation rate
Flammability (solid, gas)
Burning time
Burning rate
Upper/lower flammability or
explosive limits
:
:
:
:
:
Vapour pressure
: Highest known value: 1.2 kPa (9 mm Hg) (at 20C) (2-methylpropan-1-ol).
Weighted average: 0.7 kPa (5.25 mm Hg) (at 20C)
Vapour density
Relative density
Solubility(ies)
Partition coefficient: noctanol/water
:
:
:
:
Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.49 (Air = 1)
1.5 g/cm 3
Insoluble in the following materials: cold water and hot water.
Not available.
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidising properties
:
:
:
:
:
Not available.
Not available.
Not applicable.
Not available.
Not available.
Not available.
Not available.
Not applicable.
Not applicable.
1.1 - 13%
9.2 Other information
No additional information.
SECTION 10: Stability and reactivity
10.1 Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
: The product is stable.
10.2 Chemical stability
10.3 Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
10.4 Conditions to avoid
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
10.5 Incompatible materials
: Reactive or incompatible with the following materials:
oxidizing materials
Date of issue
: 16.07.2013.
9/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 10: Stability and reactivity
10.6 Hazardous
decomposition products
: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
There are no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 2 and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss
of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin,
resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation and
chemical pneumonia.
Based on the properties of the epoxy constituent(s) and considering toxicological data on similar preparations, this
preparation may be a skin sensitiser and an irritant. It contains low molecular weight epoxy constituents which are
irritating to eyes, mucous membrane and skin. Repeated skin contact may lead to irritation and to sensitisation, possibly
with cross-sensitisation to other epoxies. Skin contact with the preparation and exposure to spray mist and vapour should
be avoided.
Contains epoxy resin (MW 700), hydrocarbons, c9-unsatd., polymd., epoxy resin (MW 700-1200). May produce an
allergic reaction.
Product/ingredient name
xylene
Result
LC50 Inhalation Gas.
LD50 Oral
LC50 Inhalation Gas.
LD50 Dermal
LD50 Oral
ethylbenzene
Species
Rat
Rat
Rabbit
Rabbit
Rat
Dose
6700 ppm
4300 mg/kg
4000 ppm
>5000 mg/kg
3500 mg/kg
Exposure
4 hours
4 hours
-
Acute toxicity estimates
Route
ATE value
Oral
Dermal
Inhalation (vapours)
22727,3 mg/kg
11939,7 mg/kg
82,71 mg/l
Specific target organ toxicity (single exposure)
Product/ingredient name
2-methylpropan-1-ol
Category
Category 3
Route of
exposure
Not determined
Target organs
Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Date of issue
: 16.07.2013.
10/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 12: Ecological information
12.1 Toxicity
Product/ingredient name
Result
Species
Exposure
epoxy resin (MW 700)
ethylbenzene
Acute EC50 1,4 mg/l
Acute LC50 3,1 mg/l
Acute EC50 7,2 mg/L
Acute EC50 2,93 mg/L
Acute LC50 4,2 mg/L
Daphnia
Fish - fathead minnow
Algae
Daphnia
Fish
48 hours
96 hours
48 hours
48 hours
96 hours
Conclusion/Summary
: This material is harmful to aquatic life with long lasting effects.
12.2 Persistence and degradability
Conclusion/Summary
: Not available.
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
epoxy resin (MW 700)
xylene
benzyl alcohol
ethylbenzene
Not readily
Readily
Readily
Readily
12.3 Bioaccumulative potential
Product/ingredient name
LogPow
BCF
Potential
epoxy resin (MW 700)
xylene
2-methylpropan-1-ol
benzyl alcohol
>3
3,12
0,76
1,1
<100
high
high
low
low
12.4 Mobility in soil
Soil/water partition
coefficient (K OC)
Mobility
: Not available.
: Not available.
12.5 Results of PBT and vPvB assessment
PBT
: Not applicable.
vPvB
: Not applicable.
12.6 Other adverse effects
: No known significant effects or critical hazards.
SECTION 13: Disposal considerations
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.
European waste catalogue
: 08 01 11* Waste paint and varnish containing organic solvents or other dangerous
(EWC)
substances. If this product is mixed with other wastes, this code may no longer apply. If
mixed with other wastes, the appropriate code should be assigned. For further
information, contact your local waste authority.
SECTION 14: Transport information
Transport within users premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
International transport regulations
14.1 UN number
: 1263
Date of issue
: 16.07.2013.
11/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 14: Transport information
14.2 UN proper shipping
name
14.3 Transport hazard
class(es)
: Paint.
14.4 Packing group
14.5 Environmental hazards
14.6 Special precautions
for user
Additional information
ADR / RID
: III
: No.
: Not available.
IMDG
14.7 Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code
: 3
: Tunnel restriction code: (D/E)
Hazard identification number: 30
Special provisions: 640E
ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to
receptacles < 450 litre capacity).
: Emergency schedules (EmS)
F-E, S-E
IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5
(applicable to receptacles < 30 litre capacity).
: Not available.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
Europe inventory
Black List Chemicals
Priority List Chemicals
Integrated pollution
prevention and control list
(IPPC) - Air
:
:
:
:
Not determined.
Not listed
Listed
Not listed
: Not listed
Integrated pollution
prevention and control list
(IPPC) - Water
International regulations
Chemical Weapons
Convention List Schedule I
Chemicals
Date of issue
: Not listed
: 16.07.2013.
12/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 15: Regulatory information
Chemical Weapons
Convention List Schedule II
Chemicals
: Not listed
Chemical Weapons
Convention List Schedule III
Chemicals
: Not listed
: This product contains substances for which Chemical Safety Assessments are still
required.
15.2 Chemical Safety
Assessment
SECTION 16: Other information
Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
Flam. Liq. 3, H226
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Chronic 3, H412
Full text of abbreviated H
statements
Full text of classifications
[CLP/GHS]
Date of issue
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Calculation method
Highly flammable liquid and vapour.
: H225
H226
Flammable liquid and vapour.
H302
Harmful if swallowed.
H312
Harmful in contact with skin.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H318
Causes serious eye damage.
H319
Causes serious eye irritation.
H332
Harmful if inhaled.
May cause respiratory irritation. May cause drowsiness or dizziness.
H335
and
H336
H411
Toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
ACUTE TOXICITY: ORAL - Category 4
: Acute Tox. 4, H302
Acute Tox. 4, H312
ACUTE TOXICITY: SKIN - Category 4
Acute Tox. 4, H332
ACUTE TOXICITY: INHALATION - Category 4
Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2
Aquatic Chronic 3, H412 AQUATIC TOXICITY (CHRONIC) - Category 3
Eye Dam. 1, H318
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2, H225
FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3, H226
FLAMMABLE LIQUIDS - Category 3
Skin Irrit. 2, H315
SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317
SKIN SENSITIZATION - Category 1
STOT SE 3, H335 and
SPECIFIC TARGET ORGAN TOXICITY (SINGLE
H336
EXPOSURE) [Respiratory tract irritation and Narcotic
effects] - Category 3
: 16.07.2013.
13/16
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Jotamastic 87 Comp A
SECTION 16: Other information
Full text of abbreviated R
phrases
: R11- Highly flammable.
R10- Flammable.
R20- Harmful by inhalation.
R20/21- Harmful by inhalation and in contact with skin.
R20/22- Harmful by inhalation and if swallowed.
R41- Risk of serious damage to eyes.
R38- Irritating to skin.
R36/38- Irritating to eyes and skin.
R37/38- Irritating to respiratory system and skin.
R43- May cause sensitisation by skin contact.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of classifications
[DSD/DPD]
: F - Highly flammable
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
: 16.07.2013.
Date of printing
: 16.07.2013.
Date of issue/ Date of
revision
Date of previous issue
: No previous validation.
Version
: 3
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue
: 16.07.2013.
14/16
Annex
Jotamastic 87 Comp A
Exposure Scenario: Uses in Coatings -
Industrial use
Sector of Use
: Industrial use
Process Category
: PROC05 PROC07 PROC08a PROC10
Environmental Release Categories
: ERC4
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush,
spray by hand or similar methods) and equipment cleaning.
Operational conditions and risk management measures
Control of worker exposure
Frequency and duration of use
: Covers daily exposures up to 8 hours (unless stated differently).
General - Operational conditions
: Assumes use at not more than 20C above ambient temperature (unless stated differently). Assumes a
good basic standard of occupational hygiene is implemented.
General - Risk Management Measures
: Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Wear
suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for
information on appropriate personal protective equipment.
Type of activity or process
Risk Management Measures
Preparation of material for application
: Provide extract ventilation to points where emissions occur.
Roller, spreader, flow application
: Provide extract ventilation to points where emissions occur. Wear a respirator conforming to EN140 with
Type A/P2 filter or better.
Spraying - Manual
: Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at
openings. Wear a respirator conforming to EN140 with Type A/P2 filter or better.
Control of environmental exposure
Organisational measures to prevent/limit
release from site
: Prevent environmental discharge consistent with regulatory requirements.
Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations.
treatment of waste for disposal
See Section 13 for additional waste treatment information.
Conditions and measures related to external
recovery of waste
: External recovery and recycling of waste should comply with applicable local and/or national regulations.
Additional information
The exposure scenario for the mixture is based on the following substances:
REACH #: 01-2119456619-26
REACH #: 01-2119488216-32
REACH #: 01-2119514687-32 (from Comp. B)
REACH #: 01-2119560598-25 (from Comp. B)
Page: 15/16
Annex
Jotamastic 87 Comp A
Exposure Scenario: Uses in Coatings -
Professional use
Sector of Use
: Professional use
Process Category
: PROC05 PROC08a PROC10 PROC11
Environmental Release Categories
: ERC8a ERC8d
Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush,
spray by hand or similar methods) and equipment cleaning.
Operational conditions and risk management measures
Control of worker exposure
Frequency and duration of use
: Covers daily exposures up to 8 hours (unless stated differently).
General - Operational conditions
: Assumes use at not more than 20C above ambient temperature (unless stated differently). Assumes a
good basic standard of occupational hygiene is implemented.
General - Risk Management Measures
: Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Wear
suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for
information on appropriate personal protective equipment.
Type of activity or process
Risk Management Measures
Preparation of material for application Indoor.
: Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Avoid carrying out
activities involving exposure for more than 1 hour or Wear a respirator conforming to EN140 with Type
A/P2 filter or better.
Preparation of material for application Outdoor.
: Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more than 1
hour or Wear a respirator conforming to EN140 with Type A/P2 filter or better.
Roller, spreader, flow application - Indoor.
: Provide extract ventilation to points where emissions occur. Wear a full-face respirator conforming to
EN136 with Type A/P2 filter or better.
Roller, spreader, flow application - Outdoor. : Ensure operation is undertaken outdoors. Wear a full-face respirator conforming to EN136 with Type
A/P2 filter or better.
Spraying - Manual - Indoor.
: Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at
openings. Wear a full-face respirator conforming to EN136 with Type A/P2 filter or better.
Spraying - Manual - Outdoor.
: Ensure operation is undertaken outdoors. Wear a full-face respirator conforming to EN136 with Type
A/P2 filter or better.
Control of environmental exposure
Organisational measures to prevent/limit
release from site
: Prevent environmental discharge consistent with regulatory requirements.
Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations.
treatment of waste for disposal
See Section 13 for additional waste treatment information.
Conditions and measures related to external
recovery of waste
: External recovery and recycling of waste should comply with applicable local and/or national regulations.
Additional information
The exposure scenario for the mixture is based on the following substances:
REACH #: 01-2119456619-26
REACH #: 01-2119488216-32
REACH #: 01-2119514687-32 (from Comp. B)
REACH #: 01-2119560598-25 (from Comp. B)
Page: 16/16
