Safety Data Sheet
Revision Number: 003.0
Issue date: 08/28/2014
1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
LOCTITE 404 INSTANT ADHESIVE
known as 404 Quick Set(TM) Instant
Adhe
Cyanoacrylate
None identified
Product type:
Restriction of Use:
Company address:
Henkel Corporation
One Henkel Way
Rocky Hill, Connecticut 06067
IDH number:
234044
Item number:
46548
Region:
United States
Contact information:
Telephone: (860) 571-5100
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER:
BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE GENETIC DEFECTS.
HAZARD CLASS
FLAMMABLE LIQUID
EYE IRRITATION
GERM CELL MUTAGENICITY
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
HAZARD CATEGORY
4
2B
1B
3
PICTOGRAM(S)
Precautionary Statements
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat, sparks, open flames, hot surfaces - no smoking.
Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Use only outdoors or in
a well-ventilated area. Wear protective gloves, eye protection, and face protection. Use
personal protective equipment as required.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to remove. Continue rinsing. IF exposed or concerned: Get medical attention.
If eye irritation persists: Get medical attention. In case of fire: Use foam, dry chemical or carbon
dioxide to extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal:
IDH number: 234044
Product name: LOCTITE 404 INSTANT ADHESIVE known as 404 Quick Set(TM) Instant Adhe
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Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Component(s)
CAS Number
Percentage*
Ethyl 2-cyanoacrylate
Thickener
Hydroquinone
7085-85-0
Proprietary
123-31-9
60 - 100
5 - 10
0.1 - 1
* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.
4. FIRST AID MEASURES
Inhalation:
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.
Skin contact:
Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart
using a blunt instrument. If skin is burned due to the rapid generation of heat
by a large drop, seek medical attention. If lips are bonded, apply warm water
to the lips and encourage wetting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart with direct opposing force.
Eye contact:
Immediately flush with plenty of water for at least 15 minutes. Get medical
attention. If eyelids are bonded closed, release eyelashes with warm water by
covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and will cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually within 1-3
days. Medical attention should be sought in case solid particles of polymerized
cyanoacrylate trapped behind the eyelid caused abrasive damage.
Ingestion:
Ensure breathing passages are not obstructed. The product will polymerize
rapidly and bond to the mouth making it almost impossible to swallow. Saliva
will separate any solidified product in several hours. Prevent the patient from
swallowing any separated mass.
Symptoms:
See Section 11.
Notes to physician:
Surgery is not necessary to separate accidentally bonded tissues. Experience
has shown that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal burns they should be treated
symptomatically after adhesive is removed.
5. FIRE FIGHTING MEASURES
Extinguishing media:
Water spray (fog), foam, dry chemical or carbon dioxide.
Special firefighting procedures:
Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode.
Unusual fire or explosion hazards:
None
IDH number: 234044
Product name: LOCTITE 404 INSTANT ADHESIVE known as 404 Quick Set(TM) Instant Adhe
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Hazardous combustion products:
Trace amounts of toxic and/or irritating fumes may be released and the use of
breathing apparatus is recommended.
6. ACCIDENTAL RELEASE MEASURES
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions:
Ventilate area. Do not allow product to enter sewer or waterways.
Clean-up methods:
Do not use cloths for mopping up. Flood with water to complete polymerization
and scrape off the floor. Cured material can be disposed of as non-hazardous
waste. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.
7. HANDLING AND STORAGE
Handling:
Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Avoid contact with fabric or paper goods.
Contact with these materials may cause rapid polymerization which can
generate smoke and strong irritating vapors, and cause thermal burns.
Storage:
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
Hazardous Component(s)
Ethyl 2-cyanoacrylate
Thickener
Hydroquinone
ACGIH TLV
OSHA PEL
AIHA WEEL
OTHER
0.2 ppm TWA
None
1 mg/m3 TWA
(Dermal sensitization)
None
None
None
None
None
None
2 mg/m3 PEL
None
None
Engineering controls:
Use positive down-draft exhaust ventilation if general ventilation is insufficient
to maintain vapor concentration below established exposure limits.
Respiratory protection:
Use a NIOSH approved supplied air respirator with an organic cartridge if the
potential to exceed established exposure limits exists.
Eye/face protection:
Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.
Skin protection:
Use nitrile gloves and aprons as necessary to prevent contact. Do not use
PVC, nylon or cotton.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state:
Color:
Odor:
Odor threshold:
pH:
Vapor pressure:
Boiling point/range:
Melting point/ range:
Specific gravity:
Vapor density:
Flash point:
IDH number: 234044
Liquid
Clear, Colorless
Sharp, Irritating
1 - 2 ppm
Not applicable
< 0.2 mm hg
> 149 C (> 300.2 F)
Not determined
1.09 at 23.9 C (75.02 F)
3 Approximately
80 - 93 C (176F - 199.4 F) Tagliabue closed cup
Product name: LOCTITE 404 INSTANT ADHESIVE known as 404 Quick Set(TM) Instant Adhe
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Flammable/Explosive limits - lower:
Flammable/Explosive limits - upper:
Autoignition temperature:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
Viscosity:
Decomposition temperature:
Not determined
Not determined
485 C (905F)
Not available.
Polymerises in presence of water.
Not determined
< 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Not available.
Not available.
10. STABILITY AND REACTIVITY
Stability:
Stable under recommended storage conditions.
Hazardous reactions:
Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and
alcohols.
Hazardous decomposition
products:
None
Incompatible materials:
Water, amines, alkalis and alcohols.
Reactivity:
Not available.
Conditions to avoid:
Spontaneous polymerization.
11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure:
Skin, Inhalation, Eyes
Potential Health Effects/Symptoms
Inhalation:
Skin contact:
Eye contact:
Ingestion:
Hazardous Component(s)
Ethyl 2-cyanoacrylate
Thickener
Hydroquinone
Hazardous Component(s)
Ethyl 2-cyanoacrylate
Thickener
Hydroquinone
May cause respiratory tract irritation. Exposure to vapors above the established exposure limit
results in respiratory irritation, which may lead to difficulty in breathing and tightness in the
chest.
Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported to cause
allergic reaction but due to rapid polymerization at the skin surface, an allergic response is rare.
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop will burn the
skin. Cured adhesive does not present a health hazard even if bonded to the skin.
Irritating to eyes. Causes excessive tearing. Eyelids may bond.
Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It
is almost impossible to swallow.
LD50s and LC50s
Immediate and Delayed Health Effects
None
None
Oral LD50 (RAT) = 320 mg/kg
Oral LD50 (RABBIT) = 540 mg/kg
Dermal LD50 (RAT) = > 900 mg/kg
Irritant, Allergen, Respiratory
Irritant
Blood, Bone Marrow, Central nervous
system, Developmental, Eyes, Immune
system, Irritant, Liver, Mutagen, Skin, Thyroid
NTP Carcinogen
IARC Carcinogen
No
No
No
No
No
No
OSHA Carcinogen
(Specifically Regulated)
No
No
No
12. ECOLOGICAL INFORMATION
Ecological information:
IDH number: 234044
Not available.
Product name: LOCTITE 404 INSTANT ADHESIVE known as 404 Quick Set(TM) Instant Adhe
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13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal:
Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number:
Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name:
Combustible liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division:
Combustible Liquid
Identification number:
NA 1993
Packing group:
III
DOT Hazardous Substance(s):
Hydroquinone
International Air Transportation (ICAO/IATA)
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Exceptions:
Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
9
UN 3334
III
(Not more than 500ml) Unrestricted
Water Transportation (IMO/IMDG)
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Not regulated
None
None
None
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status:
TSCA 12 (b) Export Notification:
All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
None above reporting de minimis
CERCLA/SARA Section 302 EHS:
CERCLA/SARA Section 311/312:
CERCLA/SARA Section 313:
CERCLA Reportable quantity:
None above reporting de minimis
Immediate Health, Delayed Health, Fire, Reactive
None above reporting de minimis
Hydroquinone (CAS# 123-31-9) 100 lbs. (45.4 kg)
California Proposition 65:
No California Proposition 65 listed chemicals are known to be present.
Canada Regulatory Information
CEPA DSL/NDSL Status:
All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.
Prepared by:
Catherine Bimler, Regulatory Affairs Specialist
Issue date:
08/28/2014
IDH number: 234044
Product name: LOCTITE 404 INSTANT ADHESIVE known as 404 Quick Set(TM) Instant Adhe
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DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (Henkel) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the users responsibility to determine the suitability of Henkels products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkels products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkels products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
IDH number: 234044
Product name: LOCTITE 404 INSTANT ADHESIVE known as 404 Quick Set(TM) Instant Adhe
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