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Answers for Isomeris DPP ( Conceptual Improvement of Isomerism )

Q.1(a)
(f)
(k)
(p)
Q.2(a)
(f)
Q.3

Identical
(b)
Position
(g)
Functional
(l)
Chain
(q)
Metamers
(b)
Functional
(g)
A-Q, B-Q, C-R, D-S

Position (c)
Chain
Functional
Ring chain
Identical
Functional

1.
5.
8.
11.
13.
17.
21.

Position isomers
Identical
Functional
Ring chain
Position isomers
Chain
Identical

2.
6.
9.
12.
14.
18.
22.

1.
8.
Q.15

C
B
D

2.
9.

D
B

Answers of DPP No. 1

Position (d)
Functional
(e)
Position
(h)
Position (i)
Position (j)
Functional
(m)
Functional
(n)
Functional
(o)
(r)
Chain
(c)
Metamers
(d)
Metamers
(e)
(h)
Metamers

Answers of DPP No. 2

Metamers
3.
Positional
Functional
7.
Functional
Non-identical
10.
Non-identical
Non-identical / homologous
Chain isomers
15.
Position
Position
19.
Position
20.
Functional

3.
10.

Answers of DPP No. 3

4.
B
5.
C
Q.11 D
Q.12 C

B
C

Q.16.

(a) (1,2,3) CH3 CH2 CH2 CH2

CH2 CH3 (b)

4-ethyl-3-methyloctane

(c) (1,2,3, 4)

(5) DBE = 1

2
3 3

A
C

C
C

7.
Q.14

CH3

(1,2,3)

CH3

CH

1 3
1
1,2,7-trimethylcyclopentadecane

1
4
2

(d) (1,2,3, 4)

2
2

2
3

CH3

1
1,1,2,5-tetramethylcyclopentane

Q.17

Metamers

CH3
3
1
CH3
4 CH3

16.
Identical

2
2

Chain

CH3 CH2 CH CH CH3

Functional

4.

6.
Q.13
2

Functional

CH2 = CH CH2 CH3,

CH3
1

CH3 HC = CH CH2,

CH3 C = CH2
CH3

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OH
O
Q.18

DBE = 1 (5)C3H6O

CH3 C CH3 ,

CH3 CH2C
H

Q.19

CH2 = CH O CH3
CH2 = CH CH2 OH,
(5) DBE = 1
CH3CH2CH2HC=CH2,
CH3CH2HC=CH CH3,

CH3 CH2 CH = CH2 ,

CH3

CH3CH=CCH3 ,

CH2=CHCHCH3 ,

CH3
Q.20

CH3 CH2 C CH, CH3 C C CH3,

(9) DBE = 2 C4H6

CH3 CH = C = CH2,

(4)

O
Q.21

CH3

C CH2 OH,

CH2=CH CH = CH2,

CH3 C

H C O CH3 ,

OH

OH

Answers of DPP No. 4

Q.1(a) Position
(b)
Position (c)
Position (d)
Position (e)
Chain
(f)
Position (g)
Position (h)
Position (i)
Position (j)
Chain
(k)
Position
Q.2(a) 7
(b) 3
(c) 4
(d) 2
(e) 4
Q.3 (a) = 2, = 30 (b) = 5 = 17 (c) = 3 = 34
(d) = 4 = 27 (e) = 4 =3
(f) = 2 = 5 (g) = s2 = 7

Et
Et
Q.4

Q.5

Q.6

Q.7

Q.8

H
CH3

CH3
CH3

Br
Q.9

CH3CH2CH2Br

H
Q.10

CH3 CH CH3

Cl
Q.11

Cl

(anti)

(b) 1, 2

H
C

Q.13

Q.15

a>c>b

H
H

Cl

H
(a) (gauche)

Q.12

CH3

CH3

CH3

Cl
Q.14

0.75 D = 0.3 X gauche

gauche =

7.5
= 2.5 D.
3
CH3

Et
H
Q.16

CH3CH2CHCH2CH3 (a)
CH3

C2H5

H
(b) CH3CH 2CHCH 2CH 2CH 3

CH3
CH3

CH3

C2H5
H

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+
N(Me)3

OH O
CH

Q.17

O
C

Q.20

Q.19

CH3
O

CH3
Q.21

N
H

CH3 CH3

CH3

Q.18

(a) gauche

(b) anti

Q.22

CH3

CH3

(a)

CH3

Et
H

CH3

(b)

(c)

CH3

CH3

CH3

CH3

CH3

Ph

Ph

CH3

CH3
(d)

(e)

CH3

CH3
CH3

Ph
Q.23

(a) i > ii > iii

(b) i > ii > iii

Q.1
Q.5

(a) 120 (b) < 10928

E

(c) 0

(c) 3 > 2 > 1 > 4 (d) i > ii > iii

(e) i > ii
Answers of DPP No. 5
(d) 60
Q.2
C
Q.3
B

Q.4

Keq = 18
x

100-x

100 x
= 18
x

Q.6

18 = 100 x
19 = 100
X = 100/19
C
Q.7
D

O
C

Q.8

H
O

Q.13

Q.14

Q.9

Q.10

+1

+1

+1

C/A

B/D/F

Anti

All Gauche All eclipsed

Q.11

A, B, D Q.12

+1

+1

Highest in
energy

Lowest in
energy

F
Q.15

F
x

Keq = 1.5

100-x

100 x
= 1.5
x
1.5 = 100 x
25 = 100
X=
Q.16

100
10
25

= 40%
C

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Q.1
Q.4

A P, R; B Q, S; C P, R; D Q, R
Xanti = 3/4

Answers of DPP No. 6

Q.2
(IV) > (III) > (I) > (II)

OH
Q.5

Q.3

OH HO

(a)

and

HO
OH

HO

(b)

and

OH

OH

(c)

and

(d)

and

(e)

and

(f)

and

(g)

and

(h)

and

Cl
Cl
Q.6

(a)

Cl
Q.8

c>d>b>a

Cl
Cl

Cl

Cl
(b) Cl

Cl
Cl

Q.9

(a)

(b)

Trans
Q.1

Q.7

Cl

Cl

Cis

Cis

Answers of DPP No. 7

(1) Z (2) Z (3) E (4) Z (5) Z
(6) E (7) E
(8) Z (9) Z (10) E (11) Z
(14) E (15) Z (16) E (17) E (18) E (19) Z (20) E (21) Z (22) E (23) E (24) Z

Trans
(12) Z (13) E

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Z
(25) Z

(26) Z

Q.2

(1) (A) X

(B) X

(C)

(D) X

(2) (A) X

(B)

(C)

(D) X

(3) (A) Cis

(H) Trans

(B) Trans
(I) Cis

(4) (A) X

(B) X

Q.2
Q.4

Q.5
Q.1
Q.6
Q.8

A
D
(A)
(N)
B

Q.9

(28) E

(E)

(C) Cis
(J) X

(C)

(F)

(D) Cis
(K) Trans

(F) Cis

(G) Trans

Answers of DPP No. 8

2
31
(31)/2
31
(31)/2
3
(6) 2
(7) 2 +2
=6
(8) 2 + 2
=6
(9) 2
1
1
1
1
1
1
4
(12) 2 (13) 2 (14) 2 (15) 2 (16) 2 (17) 2 (18) 2
1
2
1
3
(21) 2 (22) 2 (23) 2 = 4
(24) 2 (25) 2 (26) 2 (27) 2
1
(33) 2

Answers of DPP No. 9

2
3
1
1
Q.4
(A) 2 (B) 2 (C) 2 (D) 2 (E) 2 (F) 2

C
Q.3
(A), (B)
(C) X (D)

D
(E)

(F) X

(G)

Q.10

Q.12

(A) = Keq < 1

Q.11

(E) Trans
(L) Cis

(D)

Q.2
Q.7
(B)

Compound

(29) Z

(2) 2
(3) 2
(4) 2
(5) 2
(1) 2
21
2/21
1
(10) 2 + 2
=2+1=3
(11) 2
31
(31)/2
3
=6
(20) 2 = 8
(19) 2 +2
2
2
2
2
(28) 2 (29) 2 (30) 2 (31) 4 (32) 2
Trans Q.3
Trans
31
(31)/2
=6
(A) 2 + 2
1
(B) 2 = 2
1
(C) 2 = 2
2
(D) 2 = 4
1
(E) 2 = 2
B, C
Q.6
B

Q.1

(27) E

(H)

(I)

(J) X

(B) Keq = 1

Answers of DPP No. 10

P.O.S.

(K)

Q.5

A,B,C

(L)

(M)

(C) Keq > 1

(D) Keq = 1

C.O.S.

Optically active

1.

CH3
H

CH3

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2.

CH3

CH3

3.

H
CH3
CH3
H

H
4.

5.

CH3

CH3

H
Cl

Cl
6.

Cl

Cl

Br

7.

Cl
Cl
H

Cl
H

8.

Cl
H

H
Cl

Cl
9.

H
Cl

10. H

Cl

C=C=C

H
Cl

C=C=C

Cl
Br

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11. H

Cl
12.

H
Cl

13.

14.

C=C=C=C

Cl

H
Cl

Cl

H
C

C
H

Cl

H
Cl

H
Cl

15.

CH 3
CH3
H
H
Cl

16. Cl

17.

H
18.

C
Cl

CH3

CH3

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19.

CH3

CH3

Cl

20.

21.

Cl

22.

Cl

23.

24. O = C = O
25.

26.

O=C=O
H

O=C=O

27.

N=N=N
H

H
C

28.

No. of POS = 4C2 = 6

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H
C

29.

Cl

No. of POS = 3

H
C=C

CH3

No. of POS = 2

CH3

CH3
31.

H
30.

H
C=C

No. of POS = 1

CH3

Answers of DPP No. 11

Q.1

(i) 2 (ii) 3 (iii) 4 (iv) 10

Q.3

(d) 3 > 1 > 2 > 4

(a) R (b) R (c) S
(n) R (o) S (p) S

Q.4

(a) R (b) R
(n) T (o) S
(v) R, S

Q.2

(a) 1 > 3 > 2 > 4

(b) 2 > 1 > 3 > 4

(e) 3 > 1 > 2 > 4

(f) 4 > 2 > 3 > 1
(d) S (e) R (f) S (g) R (h) S (i) S
(q) R, R
(r) R, R
(s) S, R

(c) S (d) S (e) R

(p) S (q) R,R
(w) R, S

(f) S (g) R
(r) S,R
(x) R, S

(h) S (i) S
(s) S, R
(y) R, R, R

(c) 2 > 1 > 4 > 3

(g) 4 > 3 > 2 > 1

(j) S (k) S (l) R (m) S
(t) R, S
(u) R, S
(j) S (k) S
(t) R, S
(z) R

(l) R (m) S
(u) R, S

Answers of DPP No. 12

Q.1
Q.3
Q.6
Q.7
Q.14

A Q; B Q; C R,S; D Q;
Q.2
A T,P,S; B T, P; C S; D Q;
B
Q.4
Q.5
D
A-B = Enantiomer, C-D = Enantiomer, A-C, A-D = distereomers, B-C & B-D = disteromers
A
Q.8
8
Q.9
5
Q.10
Q.11 C
Q.12
Q.13
(a) 4 (b) 4 (c) 7

Q.1
Q.3
Q.10
Q.14

A S,P; B Q; C S,P; D S,R;

A
Q.4
C
Q.5
A
Q.6
Q.11 A, B, D
Q.12
(a) diastereomers
(b) distereomers
(e) enantiomers
(f) distereomers
No-sym. Present
(i)
optical isomers = 27 = 128.
(ii)
optically active = 2n = 27 = 128
(iii)
meso = 0

Answers of DPP No. 13

Q.15

(iv)
Q.1

enantiopair

A Q, R;

A T; B S,R; C P; D T;
Q.7
A
Q.8
C
Q.9
Q.13 4
(c) distereomers
(d) distereomers
Q.2
A

2n 128
=
= 64.
2
2
Answers of DPP No. 14

B S, R, T; C Q, R, T; D P, Q;

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Q.2
Q.3
Q.7
Q.8

A P, R;
B
Q.4
= 125
(A) chiral
(H) achiral

B S;
D
Q.5

C P, R, S; D Q;
B
Q.6
(A) X (B) X (C)

(B) achiral
(I) chiral

(C) achiral
(J) chiral
H
N:
*

(a) 12.5

(b) + 8.6

(E) chiral
(L) chiral

(F) achiral
(M) achiral

(G) chiral

(v) achiral

(vi) achiral

(vii) chiral

* *

Q.9

(D) achiral
(K) chiral

(D)

(c)

O
COOH

Q.10

(i) achiral
(viii) chiral

(ii) achiral
(ix) achiral

(iii) chiral

(iv) chiral

Answers of DPP No. 16

1.

Diastereomer

2.

Identical (a & b); Diasteromer (a & b ; b & c)

3.

Diastereomer

4.

Diastereomer

5.

Identical

6.

Identical

7.

Identical

8.

Consitutional Isomer 9.

Diastereomer

10.

Enantiomer

11.

Enantiomer

12.

Diastereomer

Constitutional isomer 14.

15.

Constitutional isomer

13.

Consitutional isomer

Answers of DPP No. 17

1.

Constitutional isomer 2.

Constitutional isomer 3.

Constitutional isomer 4.

Enantiomer

5.

Enantiomer

6.

Enantiomer

7.

Diastereomer

8.

Consitutional Isomer

9.

Identical

10.

Constitutional isomer

11.

Diastereomer

12.

Enantiomer

13.

Constitutional isomer

14.

Identical

15.

Diastereomer

Answers of DPP No. 18

1.

Enantiomer

2.

Identical

3.

5.

Diastereomer

6.

Constitutional isomer

7.

Enantiomer (b & c); Diasteromer (a & b ; b & c)

10.

Constitutional isomer

11.

Constitutional isomer

12.

Constitutional isomer

13.

Constitutional isomer

14.

Identical

15.

Constitutional isomer

16.

Constitutional isomer

8.

Identical

4.

Diastereomer 9.

Diastereomer
Identical

Answers of DPP No. 19

1.

Constitutional isomer

2.

Constitutional isomer

3.

Constitutional isomer

4.

Constitutional isomer

5.

Constitutional isomer

6.

Constitutional isomer

7.

Other

8.

Constitutional isomer

9.

Other

10.

Other

11.

Constitutional isomer

12.

Constitutional isomer

13.

Constitutional isomer

14.

Constitutional isomer

15.

Enantiomer

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10

Answers of DPP No. 20

C2

C : The C2 axis lies along the Intersection of the 2 vertical -planes.

1.
N

2.

C2v
C2
H

H
C
3.

C2 D2d : 3 C2 axis with the 2 planes intersecting the principle (vertical) C2 axis.

C
C
H

C2 D6h : There are 3 pairs of vertical planes (not shown) and of C2 axis

C6

4.

intersecting the C6 axis. The C atoms lie in the horizontal -plane.

5.

6.

P.O.S. () ; C3

C2

7.

P.O.S.() ; C2 ; C3 ; S4 ; S2

Answers of DPP No. 21

1.

P.O.S. () ; C2

2.

P.O.S. () ; C2 ; C3 ; S4 ; S2

4.

P.O.S. () ; C2

5.

P.O.S. () ; C2

7.

C2

9.

C2

8.

C2

10.

6.

3.

P.O.S. () ; C2

P.O.S. () ; C2 ; S2

P.O.S. () ; C2 ; S2

Answers of DPP No. 22

S.NO.
1.
2.
3.
4.
5.

MESO
3
-

ACTIVE ISOMERS
2
4
8
16

TOTAL ISOMERS
5
4
2
8
16

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11

6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
15.

2
1
1
1
2
-

8
8
4
2
2
4
2
8
32
8

10
8
4
3
2
3
4
3
10
32
8

Answers of DPP No. 23

S.NO.
1.
2.
3.
4.
5.
6.
7.
8.

MESO
1
1
-

ACTIVE ISOMERS
2
4
2
16
32
4

TOTAL ISOMERS
3
4
3
16
2
32
3
4

Answers of DPP No. 24

S.NO.
1.
2.
3.
4.
5.
6.
7.
8.
9.

MESO
1
1
1
8

ACTIVE ISOMERS
2
16
16
16
2
2
2
4
128

TOTAL ISOMERS
3
16
16
16
3
2
3
4
136

Answers of DPP No. 25

S.NO.
1.
2.
3.
4.
5.
6.

MESO
1
1

ACTIVE ISOMERS
16
2
8
8
2

TOTAL ISOMERS
2
16
3
8
8
3

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12

7.
8.
9.
10.
11.

4
4
2
2
128

4
4
2
2
136

Answers of DPP No. 26

1.
4.
7.
10.
13.
16.

Optically active:- OA Chiral molecule:- CM

Achiral molecule:- AM
Optically inactive:- OI
No. of chiral cente:- CC
AM, Ol, CC = 1
2.
OA, CM, CC = 0
3.
OA, CM, CC = 1
OA, CM, CC = 1
5.
OA, CM, CC = 0
6.
AM, Ol, CC = 2
OA, CM, CC = 2
8.
OA, CM, CC = 5
9.
AM, Ol, CC = 2
AM, Ol, CC = 4
11.
OA, CM, CC = 2
12.
OA, CM, CC = 2
OA, CM, CC = 3
14.
OA, CM, CC = 2
15.
AM, Ol, CC = 2
AM, Ol, CC = 2

Answers of DPP No. 27

1.
4.
7.
10.
13.
16.

Optically active:- OA Chiral molecule:- CM

Achiral molecule:- AM
Optically inactive:- OI
No. of chiral cente:- CC
AM, Ol, CC = 0
2.
AM, Ol, CC = 0
3.
AM, Ol, CC = 0
AM, Ol, CC = 2
5.
AM, Ol, CC = 3
6.
AM, Ol, CC = 0
OA, CM, CC = 0
8.
AM, Ol, CC = 0
9.
AM, Ol, CC = 0
AM, Ol, CC = 4
11.
OA, CM, CC = 2
12.
OA, CM, CC = 2
AM, Ol, CC = 2
14.
AM, Ol, CC = 2
15.
CM, OA, CC = 2
AM, Ol, CC = 2

Answers of DPP No. 28

1.
4.
7.
10.
13.
16.

Optically active:- OA Chiral molecule:- CM

Achiral molecule:- AM
Optically inactive:- OI
No. of chiral cente:- CC
AM, Ol, CC = 0
2.
OA, CM, CC = 0
3.
OA, CM, CC = 1
OA, CM, CC = 2
5.
OI, AM, CC = 0
6.
AM, Ol, CC = 0
OA, CM, CC = 3
8.
OA, CM, CC = 2
9.
AM, Ol, CC = 0
AM, Ol, CC = 0
11.
AM, Ol, CC = 2
12.
OA, CM, CC = 0
AM, Ol, CC = 0
14.
CM, OA, CC = 0
15.
AM, Ol, CC = 0
CM, OA, CC = 0
17.
CM, OA, CC = 2

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