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Gas.
‘Tuer Proceso Cunmrsny Rescrne Row Sora, Daniel E
Rosner @tts20)
(onan en back Map)ELEMENTS OF
GASDYNAMICS
LW. Liepmann
and
A. Roshko
California Institute of Technology
DOVER PUBLICATIONS, INC.
‘Mineola, New YorkCopy
© 157, 1085 by H.W Leann Ro
‘gece copyright© 1005 by Amen nate of Pyss
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Editors’ Preface
‘The sim ofthe present volume isto modernize and extend the treatment
ol compre id serodynamia which appeared in 1947 fn the GALCITY
teres under the authorship of Hane W. Lipasn and Allen B, Puckett,
‘The new volume includes a review of many problems of high-speed aero
dynamics which have secived incresed attention by engineers and sien=
‘its in the lat decade, The etre blve that nation to such exten-
slo in the treatment of aeodyaaiae problems, the reader wl wea the
{nlsin of the last chapter, containing a short presentation of the fda
mental concepts of the kinetic theory of gases, and also the references in
(Chapter 1 to ame problams in serothermochemstzy, auch athe le af
ras action and digoclaion, Tt appears that catan fundamentals of
‘physis and chemical Kinetics are gaining more and more importance inthe
Fld of seronastical enginerng.
"This bok i intended mal for the we of studets in aeronautics, but
ts hoped that it wil aso be usfl to practicing enginers and scientists
ho work on problems involving the aerodynamics of compresble fs
“Taronons vont Kina
‘Cuams B, Masa
seein Accnmtia! abrir, Cari eta TealAuthors’ Preface
Problems of fow of a compresible fu have been stu for along
time, For instance, shock waves were iavestgnted in the last centr,
some of the hodograph methods were studied areund 1900, and many
featues of moze ow, supersonic ets et, were known at about the sume
time, The fandamental formla for the theory of thin supersonic wings
‘ould ave been found in Lord Rayleih's “Theory of Sond" The interest
Jn this ld, owever, was zstvcted toa very small group of people. On
the one hand the unsolved problems interested ony w few physicists the
‘majority considered the subject closed and uninteresting. ‘On the other
Ind, the applications of gaiynamics were almost entirely restricted to
‘lists and steam tarbine design and thus interested only «small number
"The Tntadrton to Aerodynamics faComprarie Fld by 8, Puckett
snd the seaior author appeared in 1947. "That book, developed from war
tealning courses taught bythe author, was intended to fais a ebereat
account of the topics from gasdynamics which were of prime interest for
‘eronaticalappllation at that tine, For a numberof year now, it ha
‘ben apparent that a new edition, with revision and extension of that
‘atrial was nse. At the time of pblicatio, the book was practically
the nly English textbook onthe sujet, but a numberof exellent books
‘have appened since thea, and some rudients of compresble uid flow
‘am now be found in many elementary did mechanics tet
Tea therefore decide to abandon a revision ofthe erga text and
Instead to rewrite the book completly” The choice af mate today is
‘uch more dificult thas it wasat the tine the Induction ppered, After
some consideration it was decided to spl the mates into evo independent
‘yolumes. One ofthese the present one, includes the Frvamental material
‘of gasiyamies but goes no further into aplleation than what i necesary
tollustate the theory. Wehope this willbe flloved eventually by anather
ei AUTHORS PREFACE
volume in the GALCITY series, more advanced and specaied, with
rials emphasis on the aeronautical and eile els.
‘Thus the preent volume is inendel to cover the fundamentals of ene
ynanics. Even so the choice of material was not easy. Forte book to
‘be uptodate without being excessively larger and more expensive than the
rignal one, it was necessary to anit some topics and methods Which are
les interesting now than they were ten yeas ago, ‘Thee ae now mostly
of casa and historical intrest, or of special ites in some research
problems. Their omisin doesnot aller the sim ofthe Doak, to provide
1 working understanding ofthe eset ofp flow.
Compared othe Fniavacton the present vlume sate more vanced,
Hoowever, we fel that this completely inline withthe yeneral tread in
Dhysiy and enginering education snd thatthe present volume fits into the
‘fuentional program at about the same pont that the Fraction Sted
tthe time it appeared. The book is agua intended to form the founda
tion fora study of the specalined Ieratre and should yive the necessary
‘background for reading orginal papers onthe ebject. Tt ent Intend to
‘bea handbook in any sense ofthe word. We havent attempted to include
All posible approaches and methods; neither have we attempted to inchde
‘complete materi in tables, gaps, and eharte for speci ue in engineering
design. Tes often stated thatthe inclusion of such material wil make
‘book “practical” for enghering us. We believe that this isnot so but
‘that an inchon of sach mater would make the book very “Snipesti”
and very rapidly dated, ‘The choice of «specie conSgerntion, auch as
‘ptimum wing wind Luana, ora shock te, i governed bya large num
ber of stringent constraints, General pracpes wn extents canbe given
ina textbonk sch as the present ne but the applinton of thee to 8
specific design must be left to the designer. ‘Thus the omission of specie
‘exign data reflects hgh opinion of engineering design, nat the contrazy
“The exercves which re given atthe end of the book ae mainly intended
to demonstrate the use of the terial in the text and to otlne sional
‘abject, result and equations Simple umerial problems have been
Almost entirely omitted. We fel that thee problems are best mde up by
the instructor or even by the student himself Tn the tet they mould have
taken up much space with comparatively litle help to either insrctor or
student. Tn othr wars the function and competence of the Jstrctr
regarded in quite the sume way a that ofthe designe,
“The general prerequisites of the ook are sch that it can be wed as &
textbol in venir and first graduate courses. At the California Entitte of
‘Technology, part af the subject matter ir ven in an Introductory couse
and part in mae advanced, graduate cour, A working knowledge of
{Ose Arena! attr, Cali Tit of Teco
AvrnoRs resrace ‘
caleulus dnd elementary concepts of physics is assumed, Here and there
1 stare” artice of more advanced scope i inserted, but these do not
‘evoualy let the continuity ofthe tet and can be omitted a fie reading.
‘References in the text are usually made only where @apecic,receat
per hasbeen wed, Reference to work that hts Heome “lassie!” ave
ot bee yateratcally given, Ali of suggested veding i neladed atthe
‘dof the book. We apoogie forthe unystematic way in which references
fe given inthe text and for the obviows ominsons and inconsisteni in
‘rhith this result” Any author who is part of an active and cowely kit
‘esearch group tends toward the oulok a interest ofthe group. Since
‘were o exceptions, there isa certain predomiaance of GALCTT material
Jn some parts ofthe book
‘During he work on the manuscript we have Beaeited from contact with
many caleagues.Speifeally we Wish to expres our appreciation 1 Z.
Blevs, J.D, Cale, E- W. Graham, P. A, Lagestom, and C. B. Milian.
‘Much of the material in Chapter 5 developed frm discussions wits Dr. P
‘Wegener. We ate allo indebted to Dr, W. D. Hayes for hi cxitcal and
‘conrrotive review of an ety manuscript and to Mr, Brdord Starterant
for his cael and competent proofreading and checking. Mrs. Beverly
Cottingham and Ms. Alrae Tingley have contebuted greatly to the prepare-
tion and completion of the manusrpt.
HW. Lxenucans
A Resta
fom,Contents
CHAPTER 1, CONCEPTS FROM THERMODYNAMICS
Tumwooreiaae Sees
Vanna or Sane
{Dee Pe Pons Tae
mama are Raver Proce
Pree Cue
‘hat Gears or Enwors, Tet Seas Law
‘it Caromeas Egsanon of State Tate Bnew aso Pra Eereanry
Renvocry Rasaove
oor tn Tnuseom Proce
(CLAPPER 2 ONE-DIMENSIONAL GASDYNAMICS
‘ur Commies Eouaon
‘et ewer Eouaron
Resa Camunone
Busty Egearon
et Rowen tor
‘Stem of Soon; Sues Ness
‘Tee Amatuoary Reason
Rests Yow ve Exit Eycanon
‘Benoa Equiion; Dee Prout
Tow a Consra Atwe
‘Tee Noma Shock Haamons ron 4 Peer Gs
CLAPTER . ONEDIMENSIONAL FAYE MOTION
‘ar Poors Snook Wave
Ome Dacnonae lennon Eqcanons
SEUSUENE SEE econ
saenesensese&
cowrenrs
{Tue Acoure Egsaons
rorianon ov Acs Wares
‘Ter Sean on Sone
Prose a Pare Yet 4 Sova Wave
inueas” Soo Tae
lneytone Wares op Pee Aun
(Gammy Bxasaon Ware
CHAPTER 4 WAVES IN suPERSOMIC FLOR
niger Son Wat
oe mae bam ¢
Mar Lines aime!
Paro Amir
‘Wau Ontgce Sua
Sermon Conran ny Tone
Suet ao Nome Raton
Inetcno oF Shoces orm Suet Faster
Derscns Soc
Soak anunon Tasony
or
Ss
‘Te Monee Pass
Cine Sema Po
‘CuLAPrER 5. FLOW 1 DUCTS axD Wino TUNNELS
Tam or Coane oF Vane Ams
Noms Row
Nott Sac Racone
Barer or Satone Tear
{ew Paosseincr ap Wi Tovase. Dero
‘Ware Tomas Cousens
CHAPTER 6 atETHODS OF MEASUREMENT
gessezess
BERS Eesesceeras
BESS
&
ry
covrewrs a
462 Sri Presne wm
ft Mu Newnes oye Peasns Mason ie
1 Sone Pcie Consomnrons rt
18 Tie Stasow Merron ta
SM eaansce Marmon i
15. Mew Zemwne nereonees is
( Iesmanoutrs Teorege 1s
‘i Duc Massiewenr or See Paco Hm
0 Horne Pro i
(30 Shock Tear haraoweeanon m
CHAPTER 2. THE EQUATIONS OF FRICTIONLESS SLOP
12 Noramow i
13 Tee Baoanon or Oormnere 1
Th Tee Mower Eqeano ae
15 Tet Ermer Eguamon ms
3 Snuryve mn Bercy Hove ro
aS Rows oF tte Bqsnows oF Moron m0
CHAPTER 0, SMALLPERTURBATION THEORY
12 Danae or mut Parnarion Bxvinon Ps
35 TreDocnsonar Plow Pasr 4 WaveSuaras Wat me
Ne Ware War m Smut Pua a
CHAPTER 9. BODIES OF REVOLUTION. SLENDER BODY THEORY
54 Gummi, Coomanans ae
55 Domary Comnmone mLEee
- corres covrerrs .
24 Mam core = cuarren va. EFBCES OF VISCOSITY Axo coNoucrIriTy
25 Semone how ed 133 Rea freee a
Be Vase Seno He S Rt Hatter penn caer how m
2, Seca S BS rect umf bron Yoo &
Bin ie ana Str = star oomurtsm coc =
3H Si as Ce = eS Mv ms ee Far Pe %
32, Steer De’ = ep Cake tat Semana soon
2k Yr Rwermn me Sermon How 2 3S feteacner Sreror sr bom ie Aocane
fe Serie ser Eman FA er irene =
2s Gener Scere = vay an tn =
Be Git Fig rn San Bo 7 Reon & EM boomer Ltr Peas Ome rvs Rar Fae
s Ei Romi Swe Wan =
ie 1B To ma =
ClAeTeR 1. THE SIMRLANIFY RULES OF McSPE=D FLOR Be Sees eniarlse mene 7
S82 Festuca: Lm Ram, Pane so Gomer IEW Goo ow o 4 Dace ot ES
i 5
tay, stom: Taine Paw. vor Kis Ram CHAPTER. coveteTs Row cases
cas Soe ow = nen =
Pattie 5 Anno we Seam La = 1S ern ecm 5
Ki tic" nouan one Sea Fa {eRe cma =
16) Tits oS or Re =
cuarren n. reasome rior 1s, he Movas Saucon =
‘chee mo {ee Te rome at Ge EA
tele dae 2 16 nanos a rie Powe Rasaon Tae
BA ear Ms Ree = 1 Marva ent Cet =
BE Betws ow hr Wom 3 a {eb Sat aw on ats Ro Car =
1S Thame Faw Past Soom TwoDosesonas Saree Tae Qe Ao en ms
hs ‘eit Rete Bsc of Damm or mon
ae Bee woe cour g 1 flr Sor ar =
cuarren x. a usraoo oF cuanscrenstcs am eens
Inriovecnion ca =
rmente Faaon =
{er coms anon = som Cumin Tarmrone 7 Sm
2 lure aus = “
‘son So Fo a 1 i Tsar ye rn Sone ow =
‘uy Somes Ror = XH Roy Pus cs Soo Row °
Scene or = We Pacer ett Pw os
‘eat Pane = et aa en te Fain Pron
to ti 3 cums
Sas sro me = | 1 ras Stowe Ge 2
Shermer ans am Were EY E okte St at 3APPENDIX
covrenrs
or
|
|
|
|
CHAPTER Y
Concepts from
‘Thermodynamics
44 Introduction
“The base of any physical theory ita set of experimental results, Fimm
those special primary observation, general principles are abtacted, which
‘canbe formulate in words orn mathenaticl equations. These principles
fe then applied to corelat and explain a group of physical phenomena and
to predict new oes,
‘The experimental bass of thermodynamics is formalized in the so-called
principal lava. ‘The law of conservation of enery, which themsodynamce
{hues with mechanic, eletrodymamic, ee is oe of these peacpal avs.
eintroduces the concept of intemal exergy of system. The other principal
lume of thermodynamic intzoduce aud define the properties of entropy and
temperate, the two concept which are pactiular and fundamental for
‘enmodynaics.
"The principles ini down ia these ondamneatl we apply othe relations
between equim states of mater in bulk, For inate, thermody
amis yields th relation between the spcisc hats at constant pressure
fd at constant volume; i ates the temperature dependence ofthe vapor
Dresure to te tet het of evaporation; pves upper bounds for the
Uftceney af eytic pretence,
Fluid machanie of pores! Side, e, Buda without viscosity and heat
conlctivity, is an extension of equlbriam thermodynamics to moving
Aids. The Kael energy ofthe fad bas no tobe conabeed in adaton
{to te internal energy which the Gud poseates when at est. The ratio of
‘this Kinetic energy per unit mask tothe intoral energy pee unit mass i 8
‘Sharactrist dimensioalos questi of the flow problem and inthe simplest
‘aes dretly proportional tothe equate ofthe Bach number. Themna-
‘yous reals are taken over to petet fd How almost dec.
Fluid machi of rst ids goes beyond clases! thermodynamics. The
tcansport proces of momentum and heat are of primary interest hee,
And system through which morentum, Beat ater, et, are beng Wass.
Dore isnot ina state of thermodynamic equibrinm, except in some rather
{evil cae, such as uriform dow of matlerUbough xed system.
‘Bat, even though thermodyaacs not fly and det pliable to2 ELEMENTS OF GASDYNAMICS
al phases of veal ld lw, ii often extremely hulp in eating the nti
‘tod inal conditions. This complet of problems is best iustratd with =
simple emple- Assume a closed, Mea-insulting container divide into
‘oro compurtsents by a daghmm, ‘The cnpertnens contain the sae
gus but at diferent pressures fy sd pa, ad iferenttemperatutes 7 and
Ts. Tf the diaphragm is removed suddenly, a complicated system of hock
ad expansion wavea ocr, and nally subides due to viscous daping
‘Thermodynamics predicts the prere and temperatute in this fal sate
easily. Pid mechanics of «veal Hid shoud tackle the far more difclt
lack of computing the pressure, temperate ele a8 fanetion of te and
location within the container. |For large tne, presare and temperatre
vel approach the thermodynamizally given value, Sometimes we nec!
‘nly thse final, equlxium values and hence can make very good wse af
‘thermodynamic reasoning even fr problem that involve sel id fw.
"In fui mechanics of low-speed flow, thamodynanic considerations are
ot mended the heat content of the fd ie then so lage compared to the
“lnetic energy ofthe ow thatthe temperate remains neal constant even
ifthe whole Kinetic energy is transformed into het.
In modern high-speed flow problems, the oppoite can be true. The
inte energy can be large compare to the heat content of the moving ga,
and the varation in temperature ean become very lage indeed.” Cone”
‘quent the importance of thermodynatnie concepts has become stedily
ffouter. The chapter therfore incades material that it mere advanced
od no needed forthe blk of the later chapters. Ariles that ate starred
fan be onited at fist reading without ls of contin.
442 Thermodynamie Systems
|A thermodynamic sytem Is & quantity of matter spared from the
“surrounding” rte “eronment” by an endnure. ‘The systems studied
sth the lp of measurements arid outs ected in the suroundings
Ts Uhermometerisrtd into w sytem form part ofthe surovndings
Work done by moving piston measured by, ty the extension af peng
or the movement of weight nthe suroundings,” Heat transfered to the
‘system is measured allo by changes inthe suroundings, eg. eat may be
transfered by an electrical heating ol, ‘The cectic power meatred i
the surroundings.
The enclosure does not necasully consist af «solid boundary lke the
walls of a yeaa. Tt i ony necessary thatthe eclenare forme cet
face ad thats proper are defined evenynhere. An exlsire nay
‘ranamit heat or bea beat insulator. Ttmay be deformable and this xpabie
of tananiting wark tothe stam. Te may alo be xpabe of tant
‘nase, Every real wal as any one ofthese properties to certain degre.
CONCEPTS FROM THERMODYNAMICS a
‘There donot exis perfecty rg wall for example, and sniley there is
no perfect hst inate. However, it is conveaint to ase an Heald
‘enconue, contig of parts which have welleined properties such
‘ompete het insaltin, ete.
or our purposes iti sulicent to dea with fds only, ‘The aysteme
hat we sal cone hee are
(a) A simple, anageneous system composed a a single gas o i
(8) A homogenenon mixture of ges.
(@) A heterogeneous aystem composed ofthe quid and gscous phase of
single substance
19. Vavabes of State
‘Ha pte islet alone fora cnt log tine that neat and
no mars andre fo it no work x done on ug hs tng
Witveach sect equlium, Allmecronoplealysnanrble quan
Wil Lec independent of te. Forex the prewar py the value
rand temperature canbe eas edn clit nat pend
"Yrs that depen only won the tte ft syst ae called wri
sil of ants and V are evidetly sich vse, and hee to are
they fami metic, For «compete terodjeale do
Shomol caption we neal er arb state fen to mean Ths
Mina result ofexperience hat the pant of yt snot ons fnction
ode vlume, Ane vale of Ste, the tempera, has to beno-
dace Fore sinpesyten,
p= are) ay
Following R, H. Fowler, on states the “seoth law of thermodynamics":
“Thee exatsa vatible of tate the temperature Two sytem that
sein thermal contac, Le, separated by en enlosre that transmits
heat, ae in eulbrinm nly if @ the same in both
Consequently, with the lp of Eq. we can use the presse ad the
‘volume ofan atitary syrtom a « thenatmetr
Whe we discus the exchange of work or heat between a system and its
surrounding, we find the ned for avaible of sate, the internal eneey,
tmhich meesares the energy stored inthe system. The fst lw of tro.
ynamicy introdcen , a wl be see ater.
Purthermove we sal nt neceazy to introduce n variable of sate S,
the entropy, which, for example, is need to decide wheter a state i in
fable equilibrium. The svnd Tow of thomodspamics introduces $ and
(eines it proper.EEE Err
4 ELEMENTS OF GASDYNAMICS
Fora simple system Band S ae functions off, V8. Bu, sac pcan be
expressed by V and sing Bq 1 its aulicient to write:
B= BY.) 2)
s=s0,9) as)
Relations tke Bas. 14, 12 and 13 are ale aqatons of at. Specially
1g, I iscalle the “thermal equation of sate"; Bq. 1-2, the “are equa
lion of state” A speci mbstance is characterised hy ie equations of
state. The for of thee equations cannot be obtained from teem
‘ams but aze obtained from measurements or ele, for ptiaar mole
‘ar model, fom statistical mestanks or Kine theory.
“Any variable of states uniquely defined fr any equirium state of the
system. For example, a sytem changes from ove state of equilibrium,
sy A to another state By then fp ~ Bs lndependent of the process by
‘which the change ceared. ‘Th important consequences of this property
of the vaiables of state will become evident Inter
‘One distinguishes between intense and extensive variable of sate. A
arable is ale exe if ts vale depends on the mas of the system,
‘The mass fof system aU anextenie quantity, and sare, V, an.
or example the internal energy’ H of certain mass of gu doled i
the man is doubled the energy of a ystem tht conats of weveral pats
equal othe sur of the energies of the pars.
Varibles of state that do ot depend upon the total mass ofthe system
sre called flouise variables and are type intensive variable, For
very extensive viable ike Ewe can intoduce an intensive vars the
‘energy per unit mass or specie energy. Simlsiy we can define a specie
volume », specie entropy s, ete. Specie quantities il be denoted by
Tower cate Iter,
14 The Pirst Principal Law
Consider fui contained in a eat-ingulating encore, which slso
‘contains. parle whel that can beset into motion by falling weight. The
‘reaure ofthe system sept constant, The tesoperatue# and the volume
‘are measured iil (atte), The weigh allowed to drop «known
distance, and @ and ¥ are measured again afer the motions in the esters
Ihave died down and a new state of equibiam B has bon established,
Tn this waya certain arount of wack, equal tothe decreas in potential
energy of the weight, ha bon dane onthe sytem, Conservation of enerty
ques that this work i stored within the system, Hence there exit &
Sanction (0) such that
Bee wn
concxPTs FRow THERMODYNAMICS 5
1 sala posible to use work to produce an lets current and to apply
‘his work to the system inthe form of beat given of by aheting coll Hoth
‘ofthese experiments were pesformed by Joule in hs casi studies o the
‘echanicl equivalent of heat. A ven mount of work done on the stem
‘yes the same diferenc in internal eneegy regardless ofthe rate at which
the work i done and regal of how i is tnsmited.
‘One can furthenmae fax the eopdan of camplete heat insulation and
lw alo the pesnge of certain amount of heat Q through the enclrie
‘Qean be define clorialy by the change in temperature of» given mas of
‘rater, or one ean ate Joule’ experiments to deine Q entirely in mechanical
terms, Tes important, however, to dain Q and 17 in tems of changes
‘meneued inthe surroundings
‘We can thot formulate the rst aw
‘There exists vane of state, the intemal energy. If 2 system i
transformed from a state of equim 4 to another one, B, by a process
in which certain amount of work WV ix done bythe strondings and &
‘tan qusalty of heat Q lever the surroundags, the diference fa the
“internal energy of the gystem Is equal tothe sum of @ and W,
By~Ba=0+W pas)
{Ris often convenient to dacs simple delized enlout, the eylnder-
plston arrangement of Hig. i. ‘The einer walle ae assumed rigid. We
Y
7)
7A.
Pin 11 Cyndie agent,
can amime them to be hea insulting o capable of eat trnsmisin,
‘depending om the pecs chat we wih to stad. Work ean be done by the
suroundings only by the displacement of the plata. W is defined a in
rmechancs in terms of force vector anda displacement dr,
wa fe 0‘ RLEMENTS OF GASDYNAMICS
‘The fore actog os the piston i parallel tothe placement; thus, iato-
ducing the pessve pan the piston surface area A, we bave
wa frssrn—foar a
with the convention tha V i positive the volume ofthe ayn increase
This not dificult to sow that Eq, 16 leads to Bq. 17 even in the cae of
prenures acing ona deformable encloeare of any shape. (Sher forces an
be Intedced alo this is dane later in dnctsng the exations of motion
‘ofa real fi in Chapter 13.) Fora amall change of state, we can write
Eq. 15 in difereatl form,
ae ag+ aw as)
or, wing Ba 17,
aE» ag pav (1)
Bguation 18s can also be written for unit mas
dem dg ~ pan des)
Now Bis variable of stat, whereas Q and 7 depend om the proces fel
lowed In changing the ste. ‘This smetines nated by weg
nd 89 fsa of 7 and dQ. We sal not flow this castom here
15 erverile and Reverible Processes
A chang of tat of pte pol only by proces for which
ak=0+W
‘The fist lw dae not rete the parle process any farther.
‘Now in the pale whtelexpexinnt of Jol tx evident imposible
to reve the det of the proce Ope casot induce the Welt
txenct the energy AE from the sam ad ot the weg. "The ren
iver Tes vey ean to nd besa sitatins, abd indeed
ail nal oy “sponte” proces a7 rei TE one scenes
that reverie presi Becrmes evident tht the deviation of the
system fom eqn daring the ross is of primary inportance. A
‘tion tke the sng of ld, sudden beating, etna caren
in theyatem. ‘The tern rent resto the fs of goatty ie est,
mash momentum A creat of eat Bows fhe ext Gat em
perature difeence; a cent of mass ovo, if thre exist diferent
foocmntation of one componmt; a cent of moment dows, i the
‘it difeences in wey.
4 spi iin ae of quit fi foo erent. & proces
eding tom on stat to anothers roel the system renin rng
CONCEPTS PROM THERMODYNAMICS 7
the whole proces in equlibriumsi.e ifthe work Wand the beat Q are added
In auch a way that no carens are produced, Such an ial reversible
Brocesscan actually be cou approximated in an expeiment. For ex-
Ample instead of uring the paddle wheal, F could be transfered to aa in-
ulate aystem by alow daplacement of piston sn that the preaare and
temperature remain unilem within the aystem durag the whole proces
(rere 19 gives simple and instructive rample af an reversible proc
=)
"Th changes of state dca here ea from oe stale condition of the
rystam to another. Ttinaften much mare convenient to amide prosaies
that proceed at a steady rte. This ia true for many measurements in
‘thermodynamics and is esentil for Auid mechanics. Thus, instead of
‘dig with a padle whet in a closed “calorimeter,” as in Joe's exeri-
‘ment, we may condor hea-inalated dct Jn which Bd Sows at
steady rate trough a turbine whee orf ‘The eyster const now of
‘tan mas of ful which passes Cough the fan. Tastead of dealing with a
‘sytem befor and after the motion ofthe pale whet, we now deal withthe
Aud upstream and downsteam ofthe fan, Our definitions of te
dyna equllbriam canbe extended to this case ely, or tect com
‘ron with thermodynamic process like Joule’ experiment, we have to
requite the fd to flow very slowy so that its netic energy is nelle,
Th the next chapter we shall drop this restriction and extend the same
‘onsidetion to highaped fui fw.
16 Perfect Gases
TEs convenient to introduce at thi stage the concept of a perfect gas.
A pefot gas isthe simplest working id in thermodynamics and hence is
‘very uefa in the detaled study of thermodynamic process. For applica-
tions to nerodyramics, the concept is even more important since we deal
‘there almost exclusively with gates, and often under conditions where they
se nearly pete.
Measarements of the themal properties of mses show that for Sow
laos the thermal equation of state approaches the same form for all
tes, amely,
pom RO) a9)
or, in terms ofthe density» = 1/
9 pRO-+ 6)
‘Hace yi a characteristic temperate which tums out to be the some for
i gave, and in character constant for spartan.
Tis tefl to define an "ea” o "perfec gs which satisfies Ba, 19’ ELEMENTS OF GASDYNAMICS
exactly. More precy, a. 19 defines a fomily of perfect ges, one for
{ich value of R Any fu at low enough deny approaches & pees gs,
ith particular value of
‘Since Gy is found tobe the same fo ll ass, one can define «new, more
convent temperature 7,
re
sh
and then replnce Bq. 19 by
po oRr dovto)
Tis caled the abate mpeatre, Tis possible to show that 7, which is
here defined a6 ys temperature, has manning forall thermodynamic
systems. ‘The sale andthe zo plat of T are determined from the scale
td zero point of the thermometer used to measured. Thus inthe Cnt-
irae sale one finds
“
nase
sod in the Fahreneit cle
y= 459.090"
‘Thus the absolute temperature Tcan be writen
T= 6427816 degrees Centigrade absolute or Kevin (°K)
T= 0+ 459.69 degrees Fabeabeit absolte or Rankine (°8)
Ras define in Eq, 110 has the dimensions (velocy)*/tempernure, Tt
is rated to the vay of sound in the gas, R32, as willbe en
i a
‘fw emit Eq 10 fora given mins A by puting» = 4/7, we ave
pv = RT. (108)
‘A stad ofthe beavia of diferent gases Je very early to the concept that
‘uses are composed of molecules aud tha the characteristic parameter of
the family of perfect gases defined by Eqs. £10 and 1100 isthe mass of
thee molecules, Ths Hay 1106 can be waiten in terms of «dimensionless
‘mass aio A/m = y where m denotes the mas of one asmaecule. Written
{in thi reduced or “inary” form, the family of B10 can be reduced to
singe one:
”
xr (308)
smhere lisa anise constant, he so-called Boltzmann constant, Instead
‘fm, the mass of a molecl, one often uses the “molecular weight” min
po
CONGHPTS PROM THERMODYNAALICS °
‘elative sits sch that My = 32, Tn terms of m one ba:
wy
Weer 110)
e ae)
Am, and Ris called to aniosl ge constant, One casio use
ss onit of mass te mle and thus make p= Ln Ey 10e. V then becomes
‘the mae sotome. We shall not use the moe in the following ails but
shall continue to refer to unit mas, and alinat aay shall we the pecect.
‘1s low inthe form p= pT (Eq. 110).
"The internal energy o' peclect gas Bie «function of temperature oly,
En ED) au)
‘Equation 1-1 canbe taken as the rent of experience. We shall se lates,
however, that iis abo a diet consequence of Ea, 110.
(Often a gas is called “calorcally erect” fa. 1-11 simpies further to
(ua)
Equation 112 does not follow directly from Bq. 140 by pur theemodyoamic
reasoning. For certain ranges of temperature ican be atid by exere
ence, and it alo follows from statistical mechanies (Chapter 14)
"To jadge the degre to which real gases are approximate by Bas 140
‘and Hf, we mast sn afew word boat the equations of tate fea! pss,
(We shall return once more to this subject in Artie 118.)
‘vey real gas canbe liquid. ‘The highest temperature at which this is
posible is alld the erika lemperature Te the corespondig presse and
Aleoity are called eritzalpresire abd eric! deny ye These cual
‘aiabes are characters of «gs; they depend upon the intermoleclar
fares,
‘An equation of sate for ral gases must therfore involve at Ist two
prumeters besides for example T, ad This the casein the fase
‘an der Waals equation of state which can be used to eatimste he appro
tion in considering ral gases at moderate densi, tobe perfect. The
san der Wea equation is
Ee cone -7
cas)
2
Sam
Tes plat oH unc n 1sy th nry eond olywp o08
uve omen Fors gl paso age naan ot pron
dint ne or min Ey 142. Themen ther eee va
RTs
ane