Safety Data Sheet
SikaGrout-212
Revision Date 11/25/2013 Print Date 11/25/2013
1. Identification
Product name : SikaGrout-212
Supplier : Sika Corporation
Address : 201 Polito Avenue
Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone : (201) 933-8800
Telefax : (201) 804-1076
Emergency telephone : CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887
[email protected] Recommended use of the : For further information, refer to the product technical data
chemical and restrictions on sheet.
use
2. Hazards identification
GHS Classification
Skin irritation , Category 2 H315: Causes skin irritation.
Serious eye damage , Category 1 H318: Causes serious eye damage.
Carcinogenicity , Category 1A H350: May cause cancer.
Specific target organ systemic toxicity - H335: May cause respiratory irritation.
single exposure , Category 3, Respiratory
system
GHS Label element
Hazard pictograms :
Signal Word : Danger
Hazard Statements : H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H350 May cause cancer.
Precautionary Statements : Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/ face protection.
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Safety Data Sheet
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P280 Wear protective gloves.
P281 Use personal protective equipment as required.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep
at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P310 Immediately call a POISON CENTER or doctor/
physician.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Warning : Contains material that may cause target organ damage.
See Section 11 for more detailed information on health effects and symptoms.
3. Composition/information on ingredients
Hazardous ingredients
Chemical Name CAS-No. Concentration (%)
Quartz (SiO2) 14808-60-7 >= 50 - <= 100 %
Portland cement 65997-15-1 >= 25 - < 50 %
Quartz (SiO2) <5m 14808-60-7 >= 0 - < 1 %
There are no additional ingredients present which, within the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment
and hence require reporting in this section.
4. First aid measures
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.
In case of eye contact : Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
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Safety Data Sheet
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In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Induce vomiting immediately and call a physician.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Most important symptoms : Cough
and effects, both acute and Respiratory disorder
delayed Excessive lachrymation
Erythema
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
irritant effects
carcinogenic effects
Protection of first-aiders : Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in
attendance.
Notes to physician : Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Specific extinguishing : Collect contaminated fire extinguishing water separately. This
methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters
6. Accidental release measures
Personal precautions, : Use personal protective equipment.
protective equipment and Avoid breathing dust.
emergency procedures Deny access to unprotected persons.
Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.
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Safety Data Sheet
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Methods and materials for : Pick up and arrange disposal without creating dust.
containment and cleaning up Keep in suitable, closed containers for disposal.
7. Handling and storage
Advice on safe handling : Do not breathe vapors/dust.
Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage : Prevent unauthorized access.
Store in original container.
Keep in a well-ventilated place.
Observe label precautions.
Store in accordance with local regulations.
Materials to avoid : no data available
8. Exposure controls/personal protection
Component CAS-No. Basis ** Value Exposure limit(s)* /
Form of exposure
Quartz (SiO2) 14808-60-7 ACGIH TWA 0.025 mg/m3
Respirable fraction
OSHA Z-3 TWA
30 mg/m3/%SiO2+2
total dust
OSHA Z-3 TWA
10 mg/m3/%SiO2+2
respirable
OSHA Z-3 TWA
250 mppcf/%SiO2+5
respirable
OSHA P0 TWA 0.1 mg/m3
Respirable fraction
Portland cement 65997-15-1 ACGIH TWA 1 mg/m3
Respirable fraction
OSHA P0 TWA 10 mg/m3
Total
OSHA P0 TWA 5 mg/m3
Respirable fraction
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Safety Data Sheet
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OSHA Z-1 TWA 15 mg/m3
total dust
OSHA Z-1 TWA 5 mg/m3
respirable fraction
OSHA Z-3 TWA
50 Million particles
per cubic foot
Dust
Quartz (SiO2) <5m 14808-60-7 ACGIH TWA 0.025 mg/m3
Respirable fraction
OSHA Z-3 TWA
30 mg/m3/%SiO2+2
total dust
OSHA Z-3 TWA
10 mg/m3/%SiO2+2
respirable
OSHA Z-3 TWA
250 mppcf/%SiO2+5
respirable
OSHA P0 TWA 0.1 mg/m3
Respirable fraction
*The above mentioned values are in accordance with the legislation in effect at the date of the
release of this safety data sheet.
**Basis
ACGIH. Threshold Limit Values (TLV)
OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values)
OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant
OSHA P2. Permissible Exposure Limits (PEL), Table Z-2
OSHA Z3. Table Z-3, Mineral Dust
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any
recommended or statutory limits.
Personal protective equipment
Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk
assessment indicates this is necessary.
The filter class for the respirator must be suitable for the
maximum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when handling
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the product. If this concentration is exceeded, self-contained
breathing apparatus must be used.
Hand protection
Remarks : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary.
Eye protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary.
Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to
the specific work-place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
Wash hands before breaks and immediately after handling the
product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.
Avoid breathing dust.
9. Physical and chemical properties
Appearance : powder
Color : gray
Odor : odorless
Odor Threshold : no data available
Flash point : Note: not applicable
Ignition temperature : no data available
Decomposition temperature : no data available
Lower explosion limit (Vol%) : no data available
Upper explosion limit (Vol%) : no data available
Flammability (solid, gas) : no data available
Oxidizing properties : no data available
Autoignition temperature : no data available
pH : Note: not applicable
Melting point/range / : no data available
Freezing point
Boiling point/boiling range : no data available
Vapor pressure : no data available
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Safety Data Sheet
SikaGrout-212
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Density : ca.2.85 g/cm3
at 73 F (23 C)
Water solubility : Note: insoluble
Partition coefficient: n- : no data available
octanol/water
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Relative vapor density : no data available
Evaporation rate : no data available
Burning rate : no data available
Volatile organic compounds : 0 g/l
(VOC) content
10. Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : The product is chemically stable.
Possibility of hazardous : Stable under recommended storage conditions.
reactions
Conditions to avoid : no data available
Incompatible materials : no data available
11. Toxicological information
Acute toxicity
Product
Acute oral toxicity : no data available
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Skin corrosion/irritation
Product
Causes skin irritation.
Serious eye damage/eye irritation
Product
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Safety Data Sheet
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Causes serious eye damage.
Respiratory or skin sensitization
Product
no data available
Germ cell mutagenicity
Product
Mutagenicity : no data available
Carcinogenicity
Product
Carcinogenicity : May cause cancer.
IARC Group 1: Carcinogenic to humans
Quartz (SiO2) 14808-60-7
NTP not applicable
Reproductive Toxicity/Fertility
Product
Reproductive toxicity : no data available
Reproductive Toxicity/Development/Teratogenicity
Product
Teratogenicity : no data available
STOT-single exposure
Product
Assessment: May cause respiratory irritation.
STOT-repeated exposure
Prolonged exposure can cause silicosis.
Product
Assessment: no data available
Aspiration toxicity
Product
no data available
12. Ecological information
Other information Do not empty into drains; dispose of this material and its
container in a safe way.
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Safety Data Sheet
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13. Disposal considerations
Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
14. Transport information
DOT
Not dangerous goods
IATA
Not dangerous goods
IMDG
Not dangerous goods
Special precautions for user
no data available
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable
15. Regulatory information
TSCA list : All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA304 Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
SARA 302 : SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
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Safety Data Sheet
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SARA 313 : SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
Clean Air Act
Ozone-Depletion This product neither contains, nor was manufactured with a
Potential Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
Clean Water Act
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
California Prop 65 WARNING! This product contains a chemical known in the
State of California to cause cancer.
WARNING: This product contains a chemical known in the
State of California to cause birth defects or other reproductive
harm.
16. Other information
HMIS Classification
Health * 3
Flammability 0
Physical Hazard 0
Personal Protection X
Caution: HMIS rating is based on a 0-4 rating scale, with 0 representing minimal hazards or
risks, and 4 representing significant hazards or risks. Although HMIS rating is not required
on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS rating
is to be used with a fully implemented HMIS program. HMIS is a registered mark of the
National Paint & Coatings Association (NPCA). Please note HMIS attempts to convey full
health warning information to all employees.
Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika
Corporation ("Sika") product identified and described herein. This information is not intended
to address, nor does it address the use or application of the identified Sika product in
combination with any other material, product or process. All of the information set forth herein
is based on technical data regarding the identified product that Sika believes to be reliable as
of the date hereof. Prior to each use of any Sika product, the user must always read and
follow the warnings and instructions on the product's current Product Data Sheet, product
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Safety Data Sheet
SikaGrout-212
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label and Safety Data Sheet for each Sika product, which are available at web site and/or
telephone number listed in Section 1 of this SDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY
ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT
BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON
ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201-933-8800.
Revision Date 11/25/2013
Material number: 460323
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