2013 HSC Chemistry
2013 HSC Chemistry
H I G H E R S C H O O L C E R T I F I C AT E
E X A M I N AT I O N
Chemistry
2060
Section I
75 marks
Part A 20 marks
Attempt Questions 120
Allow about 35 minutes for this part
(A) H2 and C
(B) H2 and N2
(C) H2O and N2
(D) H2O and NO2
How many moles of carbon dioxide would form if two moles of butan-1-ol were burnt in
excess oxygen?
(A) 2
(B) 4
(C) 8
(D) 10
5 When placed in the Periodic Table, the recently discovered element 116 would be found
in the same group as
6 A representation of the Periodic Table is shown. The positions of six different elements,
P, Q, R, S, T and U are given.
P Q R
S
T U
Which row of the following table shows the correct acid and base reactivities of the
oxides of these elements?
(B) C8H18(l) + 25
O (g)
2 2
8CO2(g) + 9H2O(l)
(C) C8H18(l) + 6O2(g) 3CO(g) + 5C(s) + 9H2O(l)
(D) C8H18(l) + 13O2(g) 4CO(g) + 4C(s) + 9H2O(l)
8 Which of the following structural formulae shows citric acid, also known as
2-hydroxypropane-1,2,3-tricarboxylic acid?
O OH O OH O OH
C C C
(A) H C C C H
H OH H
O OH O OH O OH
C C C
(B) H C C C OH
OH OH H
O OH O OH O OH
C C C
(C) HO C C C H
H H H
O OH O OH O OH
C C C
(D) HO C C C OH
H H H
O OH O OH
C C
CH2 CH CH2 CH
n
(A) Addition
(B) Condensation
(C) Dehydration
(D) Esterification
Which of these compounds would produce the greatest amount of energy if 1.00 g of
each is burnt?
(A) CO
(B) CH4
(C) C2H2
(D) C2H6
Pt(s) Zn(s)
Cl2(g)
ZnCl2(aq)
13
What is the structure of the polymer most likely to have been used in the manufacture of
the cup shown?
(A)
H H H H H H
C C C C C C
H H H H H H
n
(B)
H H H H H H
C C C C C C
H H H
n
(C)
H Cl H Cl H Cl
C C C C C C
H H H H H H
n
(D)
CH2OH H OH CH2OH
C O C C C O
H O H H O
H OH H H
C C C C C C
OH H H OH H
O H H O H
C C C O C C
H OH CH2OH H OH n
14 Sodium reacts with water to give hydrogen gas and sodium hydroxide solution.
What volume of gas would be produced from the reaction of 22.99 g of sodium at 25C
and 100 kPa?
(A) 11.36 L
(B) 12.40 L
(C) 22.71 L
(D) 24.79 L
Which row in the following table correctly identifies an appropriate volume of the
original solution and the volume of water added for this dilution?
16 Which two species will react to form a product containing a coordinate covalent bond?
17 A 25.0 mL sample of a 0.100 mol L1 hydrochloric acid solution completely reacted with
23.4 mL of sodium hydroxide solution.
What volume of the same sodium hydroxide solution would be required to completely
react with 25.0 mL of a 0.100 mol L1 acetic acid solution?
Petroleum fractions
Catalytic cracking
Compound X
Compound Y
Propanoic acid
Concentrated sulfuric acid
Compound Z
19 A solution was obtained by boiling flowers in water. After various substances were added
to separate samples of the solution, the colour of each was noted.
For which of the following titrations would it be appropriate to use this solution as an
indicator?
O
O O O O
Ozone Oxygen
(A) it is polar.
(B) it is a bent molecule.
(C) it has a greater molecular mass.
(D) it has a lower average bond energy.
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Chemistry
Centre Number
Section I (continued)
Part B 55 marks
Attempt Questions 2131 Student Number
Allow about 1 hour and 40 minutes for this part
Answer the questions in the spaces provided. These spaces provide guidance for the expected
length of response.
Question 21 (6 marks)
2061 13
Question 21 (6 marks)
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Question 22 (5 marks)
A solution contains three cations, Ba2+, Cu2+ and Pb2+. The flow chart indicates the
plan used to confirm the identity of these cations.
(b) Write a balanced net ionic equation for the formation of Precipitate 1. 2
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(c) Suggest a test and the expected result that would confirm the identity of the 2
metal cation remaining in Filtrate 2.
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 23 (7 marks)
A 20.72 g sample of solid lead was placed into 0.100 L of 1.00 mol L1 silver nitrate
solution.
(a) Complete the table. Show relevant calculations in the space below the table. 5
Chemical
Pb2+(aq) Pb(s) Ag+(aq) Ag(s) NO3(aq)
species
Moles in
final mixture
Balanced
chemical
equation
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(b) With reference to only ONE species in the product mixture, explain why care 2
must be taken in disposing of the final mixture.
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2062 17
Question 24 (4 marks)
(a) Explain the effect of decreasing the volume of the reaction vessel. 2
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Question 25 (4 marks)
An indicator is placed in water. The resulting solution contains the green ion, Ind , and 4
the red molecule, HInd.
Explain why this solution can be used as an indicator. In your response, include a
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 26 (4 marks)
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2063 19
Question 27 (4 marks)
A 0.259 g sample of ethanol is burnt to raise the temperature of 120 g of an oily liquid, 4
as shown in the graph. There is no loss of heat to the surroundings.
50.0
40.0
30.0
20.0
10.0
0
Heating Heating Measurements
commenced completed stopped
Time
Using the information shown on the graph, calculate the specific heat capacity of the
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 28 (5 marks)
2064 21
Question 28 (5 marks)
Step 3. The student filled the pipette with a standard sodium carbonate solution to the
Gradation mark
Step 4. The standard sodium carbonate solution in the pipette was transferred to the
conical flask. The student ensured that all of the sodium carbonate solution
was transferred to the conical flask by blowing through the pipette. Three
drops of an appropriate indicator were added to the conical flask.
Step 5. A burette was rinsed with the hydrochloric acid solution and then filled with
the acid. The student then carried out a titration to determine the
concentration of the hydrochloric acid solution.
In steps 2, 3 and 4 above the student did not follow acceptable procedures.
(a) Identify the mistake the student made in step 4 and propose a change that would 2
improve the validity of the result.
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Question 28 (continued)
(b) Explain the effect of the mistakes made in steps 2 and 3 on the calculation of the 3
concentration of the hydrochloric acid solution.
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End of Question 28
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Question 29 (2 marks)
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 30 (6 marks)
2065 25
Question 30 (6 marks)
The images below represent the concentration of ozone in the atmosphere above 6
Antarctica near the South Pole for the years 1979, 1994 and 2012, measured at the
same time each year.
South Pole
1979
1994
2012
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Question 30 (continued)
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End of Question 30
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Question 31 (8 marks)
(a) Construct separate flow diagrams to show the steps used in the production of 5
polyethylene and those used in the production of a recently developed biopolymer.
Name of biopolymer:
Polyethylene
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(b) Justify the use of a recently developed biopolymer over a polymer obtained from 3
fossil fuel.
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28
Chemistry
Section II
25 marks
Attempt ONE question from Questions 3236
Allow about 45 minutes for this section
Pages
2066 29
(a) The diagram shows a sequence of steps in the removal of grease from a surface. 3
Grease
Surface
Step 1 Step 2 Step 3
(b) Hydrogen iodide is a colourless gas that will decompose into colourless
hydrogen gas and purple iodine gas according to the following endothermic
reaction.
(i) A 1.0 L glass container was filled with 0.60 moles of hydrogen iodide 3
gas. When equilibrium was established, there were 0.25 moles of iodine
gas present in the container.
30
Question 32 (continued)
(c) The diagram shows a region where construction of a Solvay plant is being
considered.
Ocean
Port City
Limestone 50 km
deposit
Key
B
Railway line
(ii) Justify which of sites A or B would be the preferred location for a Solvay 3
plant.
31
Question 32 (continued)
(i) Justify the use of a safety precaution, other than wearing safety glasses, 2
when carrying out this investigation.
(ii) Describe how the THREE products of this electrolysis could be identified. 3
(e) There is often a compromise between maximising yield and minimising the 7
environmental impact of industrial processes.
End of Question 32
32
Power supply
Connection to
metal mesh cage
Electrolyte
solution
Insulating stand
for artefact
(b) (i) Write a balanced chemical equation for the corrosion of tin in shallow 2
water.
33
Question 33 (continued)
(c) The solubility of oxygen in sea water at various temperatures is shown in the
graph.
12
11
4
0 10 20 30 40 50
Temperature (C)
(ii) Analyse the factors that affect the concentration of dissolved oxygen at 3
increasing depths in the ocean.
(d) (i) Design a suitable first-hand investigation that could be carried out in a 3
school laboratory to compare the effectiveness of different ways of
preventing the corrosion of iron in a marine environment. Include
relevant diagrams in your answer.
(ii) Use the expected results of the investigation to justify the ongoing use of 2
iron in the construction of ocean-going vessels.
(e) From the scientists studied in this option, assess whose work has most changed 7
the nature of scientific thinking about redox reactions.
End of Question 33
34
NH2
N C
C N
HC
C CH
O O O N N
O P O P O P O CH2 O
O O O HC CH
CH CH
OH OH
X Y Z
35
Question 34 (continued)
(b) The table below gives the abbreviation and structural formulae for two amino
acids.
H H
Tyrosine Tyr HO C C COOH
H NH2
(i) Write an equation using the correct structural formulae showing the 2
formation of a dipeptide between glycine and tyrosine.
36
Question 34 (continued)
(c) The following energy profile is for the combustion of glucose during cellular
respiration.
Glucose
and oxygen 181 kJ mol1
Energy
2997 kJ mol1
Carbon dioxide
and water
Progress of reaction
Using the energy profile above, determine the energy required by the
astronaut in one hour.
(ii) Calculate the volume of oxygen consumed by the astronaut in one hour. 3
The conditions are 25C and 100 kPa. Include a chemical equation in
your answer.
37
Question 34 (continued)
Rate of
reaction
Temperature
(e) Give me a muscle biopsy and Ill tell you whether you should be a sprinter or a 7
marathon runner.
End of Question 34
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A B
Blue Red
Explain the processes by which emission lines arise. Include an energy level
diagram for the lines marked A and B in your response.
(b) (i) Identify in which of the s, p, d or f blocks of the Periodic Table the 2
element Ra is found. Justify your answer.
(ii) An atom has FIVE valence electrons in its d orbital. Using an orbital 3
diagram of the valence shell of the atom, explain how Hunds rule
determines the electronic configuration.
3
CN
CN
NC Ni
CN
CN
(i) What is the oxidation state of nickel in this complex? Justify your 2
answer.
(ii) Explain the bonding of the complex with the aid of a Lewis structure for 3
the cyanide ligand.
39
Question 35 (continued)
(ii) What does this investigation show about the oxidising strength of 3
potassium permanganate? Use half-equations in your answer.
(e) Discuss the principles involved in using infra-red and ultraviolet spectroscopy for 7
the analysis of pigments.
End of Question 35
40
(a) A sample was collected from inside a reaction vessel at a suspected illegal 3
drug laboratory. The sample was analysed by high performance liquid
chromatography (HPLC). The chromatogram obtained from the collected
sample is provided below.
Sample chromatogram
from the reaction vessel
Signal
intensity
0 5 10 15
Retention time (minutes)
Standard chromatogram
C
Key
B
A Amphetamine
D B Methamphetamine
Signal
intensity A
C Methcathinone
D MDMA
0 5 10 15
Retention time (minutes)
41
Question 36 (continued)
(b) (i) Information about three polysaccharides (cellulose, glycogen and starch) 2
is provided in the table below.
X Y Z
Plant polysaccharide Animal polysaccharide Plant polysaccharide
Contains branched Contains highly Contains linear
and linear chains branched chains chains
Identify X, Y and Z.
(ii) Select ONE of cellulose, glycogen or starch and explain its primary 3
function in terms of its composition and structure.
42
Question 36 (continued)
(i) Use the following emission spectra to identify a metal pollutant in the 2
river. Justify your answer.
Cadmium
Mercury
Lead
River sample
43
Question 36 (continued)
(d) Alkanes, alkenes, alkanols and alkanoic acids are four different classes of organic
compounds.
(i) Describe a simple test that would confirm that a compound is organic. 2
End of paper
44
Chemistry
DATA SHEET
Avogadro constant, NA .................................................................. 6.022 1023 mol1
Volume of 1 mole ideal gas: at 100 kPa and
at 0C (273.15 K) ...................... 22.71 L
at 25C (298.15 K) .................... 24.79 L
Ionisation constant for water at 25C (298.15 K), Kw ................. 1.0 1014
Specific heat capacity of water ..................................................... 4.18 103 J kg1 K1
Some useful formulae
pH = log10 [H+ ] DH = m C DT
Some standard potentials
Aylward and Findlay, SI Chemical Data (5th Edition) is the principal source of data for
2067 this examination paper. Some data may have been modified for examination purposes.
45
PERIODIC TABLE OF THE ELEMENTS
1 2
H He
1.008 4.003
Hydrogen KEY Helium
3 4 Atomic Number 79 5 6 7 8 9 10
Li Be Symbol Au B C N O F Ne
6.941 9.012 Standard Atomic Weight 197.0 10.81 12.01 14.01 16.00 19.00 20.18
Lithium Beryllium Name Gold Boron Carbon Nitrogen Oxygen Fluorine Neon
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.64 74.92 78.96 79.90 83.80
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.61 88.91 91.22 92.91 95.96 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
55 56 5771 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0
46
Caesium Barium Lanthanoids Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
87 88 89103 104 105 106 107 108 109 110 111 112
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn
Francium Radium Actinoids Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium
Lanthanoids
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
138.9 140.1 140.9 144.2 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0
Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
Actinoids
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 231.0 238.0
Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
Elements with atomic numbers 113 and above have been reported but not fully authenticated.
The International Union of Pure and Applied Chemistry Periodic Table of the Elements (February 2010 version) is the principal source of data. Some data may have been modified.