Scribd
Upload
303 views4 pages

Viscosity Calculations for Liquids

This document contains sample calculations for determining viscosity of pure liquids and solutions. It examines the effect of concentration on 1-propanol viscosity and uses linear regression to determine calibration constants. It also examines the effect of temperature on 1-propanol viscosity and determines viscosity and activation energy using linear regression. Finally, it calculates intrinsic viscosity, hydrodynamic volume, and radius of gyration for sodium carboxymethylcellulose (NaCMC) solutions using reduced and inherent viscosity measurements.

Uploaded by

Snow Drop
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
303 views4 pages

Viscosity Calculations for Liquids

This document contains sample calculations for determining viscosity of pure liquids and solutions. It examines the effect of concentration on 1-propanol viscosity and uses linear regression to determine calibration constants. It also examines the effect of temperature on 1-propanol viscosity and determines viscosity and activation energy using linear regression. Finally, it calculates intrinsic viscosity, hydrodynamic volume, and radius of gyration for sodium carboxymethylcellulose (NaCMC) solutions using reduced and inherent viscosity measurements.

Uploaded by

Snow Drop
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 4

EXERCISE 8

VISCOSITY OF PURE LIQUIDS AND SOLUTIONS


Sample Calculations
Section: 1L, Group 1

A. Effect of concentration (sample: 1-propanol)


1. Calibration constants A and B
( )

Plotted values:

water

acetone

ethyl acetate

Using linear regression analysis:


Slope:

y-int:
r2 = 0.930167989

2. Calculation of ρsolution

3. Calculation of ƞ

( )( )

1|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)


B. Effect of temperature (sample: 1-propanol)
1. Calculation of ƞ

( )( )

2. Calculation of ̅
̅ ( )
̅

( )( )
( ) ( )
( )( )

3. Determination of ̅ and ̅
̅ ̅ ̅

Plotted values:
,K ̅ , J/mol
293.15 53986.56052
298.15 54562.89921
303.15 55188.07577
308.15 55761.19665
313.15 56396.7653
318.15 57015.61803
323.15 57629.16984

Using linear regression analysis:


Slope: ̅

y-int: ̅

r2 = 0.999835163

C. Polymer (sample: NaCMC)


1. Calculation of ƞsp

2|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)


2a. [ƞ] from ƞred
Plotted values:
, g/dL
1.00 3.285714286
0.75 2.476190476
0.50 1.392857143
0.25 2.071428571
0.10 3.303571429
0.05 2.142857143

Using linear regression:


y-int: [ ]
r2 = 0.049484093

2b. [ƞ] from ƞinh


Plotted values:

, g/dL ( )
1.00 1.455287233
0.75 1.399762833
0.50 1.057050402
0.25 1.669198263
0.10 2.854474347
0.05 2.035653886

Using linear regression:


y-int: [ ]
r2 = 0.432083309

3a. ̅ from ƞred


[ ] ̅
̅
̅

3b. ̅ from ƞinh


[ ] ̅
̅
̅

4a. s from ƞred


̅

( )( )

3|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)


4b. s from ƞinh
̅

( )( )

5a. r from ƞred


⁄
( )
⁄
( )
( )

5b. r from ƞinh


⁄
( )
⁄
( )
( )

⁄
6a. from ƞred
[ ]̅ ⁄
⁄
[ ]
⁄
( )( )
⁄
[ ]

⁄
6b. from ƞinh
[ ]̅ ⁄
⁄
[ ]
⁄
( )( )
⁄
[ ]

4|Chem 111.1 Exercise 8 Sample Calculations (Section 1L, Group 1)

You might also like