MATTER – composed of molecules in KE.
- Involved in solution processes like sodium
chloride dissolving in water.
SOLID - Exist when polar molecules are attracted to
- Physical state characterized by a ions.
dominance of PE over KE. - + pole is attracted to – ion (anion)
- Particles are drawn close together in a - - pole is attracted to + ion (cation)
regular pattern by presence of strong HYDROGEN BONDING
cohesive forces
- Occupies a fixed position (vibrates) - Weak bond formed when hydrogen with
- Definite volume and shape partial +charge is close to an atom in a
molecule with lone pairs of electrons (-)
LIQUID - Result of weak electrostatic attraction (2-10
kcal/mol)
- Physical state characterized by KE and PE.
- Strength is influenced by the
- Particles are randomly packed but relatively
near one another. electronegativity of atom to which it is
- Particles are in constant, random motion bonded.
- Indefinite shape and definite volume - Water maximum density is 4℃
- Follows the shape of its container LONDON DISPERSION FORCE
GAS - Nonpolar molecules such as 𝐻2 can
- Physical state characterized by a develop instantaneous and induce dipoles.
dominance of KE over PE. - Increase with increasing molecular mass
- Attractive forces among particles are very - Decrease with increasing distance between
weak and considered to be 0. molecules
- Particles move independently in a total SURFACE TENSION
random manner.
- Completely fill their container and shape is - Force that causes molecules on the surface
that of the container. of a liquid to tighten their hold to one
another creating the effect of a thin
INTERMOLECULAR FORCES (Van der Waals) membrane on the surface.
- Electrical in nature - When small amount of liquid is dropped it
- Named after a dutch chemist, Johannes forms a spherical shape.
Van der Waals (1837-1923) - Substances with strong attractive forces
- Result from the attraction between centers have high surface tensions
of opposite charge in two molecules close to - Temperature-dependent
each other. - Decreases as temperature increases.
DIPOLE- DIPOLE FORCES VISCOSITY
- Attraction of dipoles in different molecules. - Measure of tendency to resist flowing
- Arise from unequal sharing of electrons by motion
covalently bonded electrons. - Polar and complex structure molecules
- Effective at reasonably larger distance have higher viscosity
- CIF Molecules – positive is attracted to - Liquid with high viscosity is thick
negative end of neighbouring molecule - When viscosity is high that it cannot flow
anymore it is said to be glassy.
ION-DIPOLE FORCES
FLUIDITY
- Opposite of viscosity
- High fluid liquid is said to be free-flowing,
mobile or thin.
CAPILLARY ACTION
- Spontaneous rising of a liquid in a narrow
tube.
- Explains how plants get nourishment from
soil through their roots.
INCOMPRESSIBILITY
- Since molecules in liquid are already close
they can’t be crowded together anymore.
DIFFUSIBILITY
- Much less in a liquid than in gas
EVAPORATION
- Indication of the escaped molecules from
the surface of liquid.
- Evidence of molecular motion
COOLING EFFECT OF VAPORIZATION
- Escaped molecules are ones with greatest
velocity
VAPOR PRESSURE
- Saturated with vapour and an equilibrium
state exists between the liquid and the
vapor.
BOILING POINT
- Temperature at which the vapour pressure
of a liquid is equal to the external pressure.
HEAT OF VAPORIZATION
- Energy required to change exactly one
gram of liquid to vapour at its normal boiling
point.
- Cal/g, kcal/g-atom, kJ/kg