Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 29-12-18
Time: 09:00 AM to12:00 Noon CODE-D Max.Marks:360
KEY SHEET
CHEMISTRY
1 2 2 4 3 3 4 2 5 3

6 3 7 1 8 3 9 4 10 3

11 2 12 2 13 3 14 3 15 3
16 1 17 1 18 1 19 4 20 2

21 2 22 4 23 2 24 1 25 4

26 2 27 1 28 1 29 3 30 4

MATHS
31 4 32 4 33 1 34 1 35 2

36 1 37 1 38 3 39 2 40 1

41 2 42 1 43 1 44 2 45 3
46 2 47 1 48 4 49 2 50 3

51 3 52 2 53 2 54 2 55 4

56 2 57 1 58 1 59 2 60 4

PHYSICS
61 4 62 2 63 4 64 2 65 1

66 3 67 2 68 2 69 3 70 2

71 3 72 1 73 1 74 2 75 4
76 3 77 4 78 3 79 1 80 1

81 2 82 3 83 4 84 3 85 1

86 1 87 1 88 2 89 4 90 2
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
SOLUTIONS
CHEMISTRY
1. A  2 BC

t0 p0 0 0

t  10mby p0  x 2x x

t 0 2 p0 p0

3 p0  270

p0  90

 t  10 mm Pt  90  x  2 x  x

176  90  2x

2 x  86

x  43 mm

 A  90  43
 47 mm of Hg

2. 4<1<2<3
3. The successive ionization enthalpies of an element show a regular increase but when
the inert – gas configuration is reached, suddenly there is an abrupt increase. Thus, the
valency of an element is equal to the number of successive ionization enthalpies till
regular increase is observed. Thus, in the present case, number of successive ionisation
enthalpies, i.e., 191,578,872 which show a regular increase are three and hence the
valency of the element is 3.
1 1
4.   RZ 2  2  2 
 n1 n2 
1 1  27 R
 R  9   
1 4  4
5. BDE  Cl2  Br2  F2  I 2
6. ΔG  ΔH  TΔS
Sec: Sr. ICON ALL Page 2
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
a) For a system, total entropy change  ΔStotal
ΔH total  0
 ΔGsystem  TΔStotal

ΔGsystem
  T
ΔStotal
Thus (a) is correct
b) For isothermal reversible process, ΔE  0
By first law of thermodynamics, ΔE  q  W
Vf
 Wreversible   q    p dV
Vi

Vf
 Wreversible   nRT ln
Vi
Thus, (b) is correct.
c) ΔG 0  ΔH 0  TΔS 0
Also, ΔG 0   RT ln K
 ΔG 0
ln K 
RT

ln K 
 ΔH TΔS  0 0

 from Eq.1 
RT
Thus (c) is incorrect.

 
d) The standard free energy ΔG 0 is released to equilibrium constant K as

ΔG 0   RT ln K

ΔG 0
 ln K  K
RT
0 / RT
 e ΔG
Thus, (d) is also correct.
7. A 2B  2C  D
1 1.5 0 0
1 x 1.5  2 x 2x x
1  x  1.5  2 x

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
x  0.5
1  0.5
KC  4
0.5  0.5  0.5
8. [Mn(CN)6]3 d2sp3, octahedral and [MnBr4]2 sp3, tetrahedral
2 2 2 1
9. Li2  σ 1s σ * 1s  σ  2s  , Bond order   4  2  1
2
2 2 1 1 1
Li2  σ 1s σ * 1s  σ  2s  , Bond order   3  2 
2 2
2 2 2 1 1 1
Li2  σ 1s σ * 1s  σ  2 s  σ *  2s  , Bond order   4  3 
2 2
Li2 is less stable than Li2 because Li2 has more number of electrons in the
antibonding molecular orbtital. Otherwise greater the bond order, greater is the
stability. Hence, the correct order is Li2  Li2  Li2
1 dCB dC
10.  k1.C A ; B  2k1C A
2 dt 2t
 2  2  103  2  8  10 3 M s 1
11.
F

Cl  F

A) F
(Planar distorted-T shape and polar)

F F
Xe F  Pentagonal planar and non  polar 
F F
B)
Cl Cl

P
 Non  planar and non  polar 
Cl Cl
C) Cl

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s

F F
Br
 Non  planar and polar 
F F
D) F

6
12. number of Cl  ions oxidized =6 , n f 
14
P0  PS M
13.  m
P0 1000
10 1000
m   0.73
760 18
14. Only Au 3 , Ag  and Cu 2 will deposit at cathode.

Li will not deposit at cathode because SRP of water is 0.8274 V so after Cu 2 ; H 2

will evolve at cathode.
15. primary aliphatic amines
16. Volume of nitrogen collected at 300Kand 715mm pressure is 50 mL
Actual pressure = 715 – 15 = 700 mm
273  700  50
Volume of nitrogen at STP 
300  760
 41.9 mL
22, 400 mL of N 2 at STP weighs = 28 g
28  41.9
41.9 mL of nitrogen weighs  g
22400
28  41.9  100
Percentage of nitrogen 
22400  0.3
 17.46%
17. As the process is carrying out at constant temperature, therefore this type of expansion
is called isothermal reversible expansion, for which, ΔU  0 . Hence, q  W
i.e., heat absorbed by the system is equal to the work done by the system.
Thus, q  208 J
W  208J
18. internal aldol condensation

Sec: Sr. ICON ALL Page 5

Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s

19. No. of X Particles per unit cell = 4

No. of Y particles = 4
No. of Z particles = 8
Along one body diagonal 2 X atoms from 2 corners, one Y particle and 2Z particles
will be removed.
1 15
So, effective no. of X particles in a unit cell  4   2 
8 4
Effective no. of Y particles in a unit cell  4  1  3
Effective no. of Z particles in a unit cell  8  2  6
X : Y : Z
15
: 3 : 6
4
5 : 4 : 8
20. (CN) group is given the highest priority

OH

5
4 6
2- Bromo -5- hydroxy benzonitrile
3 1
2 CN

Br

21. Na2  B4O5  OH  4  .8H 2O

22. NCERT
23. NCERT
24. NCERT – 435
25. Ca 2
26. C1  C4   linkage
27. Anti mark addition.

Sec: Sr. ICON ALL Page 6

Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s

H
28. CH 3 MgBr  CO2   CH 3COOH
29.
 
K
OH
 HO
2 
Aromatic
salt


ΘK

3
30. KE  nRT
2
n  1 , for molar kinetic energy
3  3 
  1  R  T     1  R  400 
2  Helium  2  Argon
T  400 K
MATHS
31. Let the four numbers in A.P. be p  a  3d , q  a  d , r  a  d , s  a  3d
p  q  2, r  s  18
Given that pq  A, rs  B
 p  q  r  s  4a  20
a5
Now,
p  q  2  10  4d  2
r  s  18  10  4d  18
d  2
Hence the numbers are 1,3,7,11
pq  A  3, rs  B  77
32. Let h  x  f  x  2 g  x 
As h  0  h 1  2
Hence, using Rolle’s theorem
h ' c   0
 f ' c   2 g '  c 
 1 if x0

33. f  x  x  x  1  2 x  1 if 0  x 1
 1 if x 1

 f  x  is increasing in  0,1
x2 y 2
34. The given ellipse is  1
4 1
So A   2,0 and B   0,1

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
If PQRS is the rectangle in which it is inscribed, then P   2,1 .
x2 y 2
Let 2  2  1 be the ellipse circumscribing the rectangle PQRS .
a b

Then it passed through P  2,1

4 1
 2  2  1 ... A
a b
Also, given that, it passes through  4,0
16
 2  0  1 a 2  16
a
 b 2  4 / 3 [substituting a 2  16 in eq n  A ]
x2 y2
 The required ellipse is   1 or x 2  12 y 2  16
16 4 / 3
35. We have,
x2 y2
 1
cos 2  sin 2 
Vertices of this curves are
  cos ,0 and  0,  sin   .
Foci of this curves are  1,0 .
Eccentricity  sec 
 Equation of directrix is
x   cos 2 
If we change , then foci are remain unchanged.
36.

Any tangent of x 2  y 2  4 is y  mx  2 1  m 2 . If it passes through  2, 4 , then

3
 
 2m  4 2  4 1  m 2 or 4m 2  16  16m  4  4m 2 or m  , m 
4
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
Hence, the slope of the reflected ray is 3/ 4 . Thus, the equation of the incident ray is
3
 y  4    x  2 i.e., 4 y  3x  22  0
4
d
37.
2
 7  6 x  x 2  16   x  3 and
dx
7  6 x  x 2  2 x  6  
2x  5 2x  6 1
So,  dx    dx   dx
7  6 x  x2 7  6x  x2 16   x  3
2

 x  3
 2 7  6 x  x 2  sin 1  C
 4 
Therefore, A  2, & B  1 .
38.

We have x 2  8 x  9
x2  9 x  x  9  0
x  x  9  1 x  9  0
 x  9 x  1  0
x  9,1 for x  1, y  2 2 x  2 2
2
L1  Length of AB   2 22 2  2
 1  1  4 2
L2  Length of lotus rectum  4a  4  2  8
L1  L2
2n
2
39. Let S    1  k  2n 
k
 2n
Ck  1
k 0
2n 2

 S    1
2 n k
 2n  k   2n
C2 n  k 
k 0
Writing the terms in S in the reverse order, we get
2n
2
S    1 k
k
 n
Ck  2
k 0

Adding 1 and  2  we get

2n 2
k
2S  2n  1  2n
Ck   2nA
k 0
S   nA
40. We know that, lines perpendicular to the same line are parallel to each other.
Therefore, slope of both the lines will be same.
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
i.e., 
p p2  1   p 2  1     p  1
 There is exactly one value of p .
f 0  h   f 0
41. f 1  0   lt
h 0 h
  h  3e  4 
1/ h
  1 
 lt   0    2
n 0  2  e1/ h  h 
 
f  0  h   f  0
Rf 1  0   lt
h 0 h
 h  3e  4 
1/ h
 1 
 lt   0 
h 0  2  e1/ h  h 
 
1/ h
 3  4e 
 lt  1/ h   3
h 0 2 e
 1 
Since Lf 1  0   Rf 1  0 
 f  x  is differentiable at x=0. But f  x  is continuous at x =0
42. Using the sum property, we get
m m m

  2r  1
r 0

r 0
m
Cr 1
r 0
m
2 m
Δ
r 0
r  m 1 2 m 1
sin 2 m 2  sin 2  m sin 2  m  1

m
1
But   2r  1  2  m  1 2m  1  1  m
r 0
2
 1,
m m
m
 Cr  2 m and 1  m  1.
r 0 r 0

m
m2  1 2m m 1
2 m
 Δ
r 0
r  m 1 2 m 1 0
sin 2 m2   sin 2  m sin 2  m  1
x  2 y 1 z  2
43. Line   (1)
3 5 5
Lies in the plane x  3 y  αz  β  0 (2)
D.R.’s of line are 3, 5, 2 .
 3  1  5  3  α  2  0  α  6
And point  2,1, 2 lies in the plane(2).
 2  3  2α  β  0  β  7
 Roots of the equation are α  β  1,αβ  42

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
 Required quadratic equation is x 2  x  42  0
44. Equation of the line passing through P 1,4,3 is:
x 1 y  4 z  3
 
a b c
x 1 y  3 z  2 x  2 y  4 z 1
Since eq. (i) is perpendicular to   and  
2 1 4 3 2 2
Hence 2a  b  4c  0
And 3a  2b  2c  0
a b c
  
2  8 12  4 4  3
a b c
  
10 16 1
Hence the equation of the lines is
x 1 y  4 z  3
 
10 16 1
Now any point Q on  2  can be taken as
   10 ,16  4,   3
2 2
 Distance of Q from P 1,4,3  10   16    2  357

 100  256  1  2  357

   1 or  1

 Q is  9,20,4  or 11, 12,2 

Hence a1  a2  a3  15 or 1
45. Contrapositive of p  q is ~ q  ~ p.  A is true R is not true.
46. The number of multiples of 11 from 000 to 999 is 91.
3
 91  7 3  133
The required probability   
 1000  109
   
47. Given 
c  2a  b  3b 
    

b.c  b 2a  b  3b  
 2
b.c  3 b
  2  2 2   2
Now a  b  a b  a.b  
 16  4  12
2    2

And c  2a  b  3b  

Sec: Sr. ICON ALL Page 11

Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
2  2 2   
c  4 a  b  9b  6b. 2a  b

 
zero
 48  144  192

c 8 3
 2 
b.c 3 b 3 b 3  4 
Now, cos         
b c b c c 8 3
 3

2
  5
Hence b, c 
6
 
48.
1. 2 . 3. 4 5. 6 .7 T T
3
C2 .2!. 4C4 .4!  6  120  720
49. n  A  B  C   n  A  n  B   n  C   n  A  B  n  A  C    n  B  C   n  A  B  C  
 20  15  12  7  9   n  B  C   n  A  B  C  
 31   n  B  C   n  A  B  C  
 31  A  B  C  B  C 
Also n  A  B   20  15  7  28
n  A  C   20  12  9  23
n  A  B  C   n  A  B , n  A  C 
 n  A  B  C   28
Hence 28  n  A  B  C   31 .
πx πx
tan tan
50. lim  2  x  2  lim 1  1  x  2
x 1 x 1
πx
lim 1 x tan
2
e x 1

 π πx 
lim 1 x cot   
x 1 2 2 
e
lim
1 x
x 1  π πx 
tan   
2 2
e
π
2 1 x
lim 2
π x 1 π 
tan  1 x 
2 
e
 e2 / π
51. A adjA  A I
A  xyz  8 x  3  z  8  2  2  2 y 
A  xyz   8 x  3z  4 y   28

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
 60  20  28
 68
1 0 0  68 0 0 
 A adj A  68 0 1 0    0 68 0 
   
0 0 1   0 0 68

52.

y 8

A   y1/ 3 dy  12
0

dy x 2  y 2
53. x 2
 xy  dy   x 2  y 2  dx  
dx x 2  xy
y dy d
Let v v x
x dx dx
Therefore equation reduces to
dv 1  v 2
x  v
dx 1  v
1  v2  v  v2

1 v
1

1
1 dx
 d  
1 x
 2  dx
   1   d  
 1  x
   2log 1     log x  log c
y x y
  2log    log x  log c
x  x 
y
  2log  x  y   2log x  log x  log c
x
y
 log x  2log  x  y    k where k  log c
x
EF 28.5
54. From BFE ,cot 600  , EF 
28.5 3

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
BE
From BDE ,cot 300  , BE  28. 3
28.5

BF  BE  EF
28.5
 28.5 3 
3

 1 
 28.5  3  
 3

 2  57
 28.5     19 3
 3 3
D

28.5

B 1300 600
E
1.5 1.5
A C

55. sin  sin 4  cos 4.cos 

cos 5  0

5   2n  1
2

   2n  1 n  Z
10
 3 5 7 9
 , , , ,
10 10 10 10 10
No. Of solutions = 5
56. CA  CB  2 2.OC  2  OA  OB  2
 A  2  0i, B  2  0i

Clearly, BCA 
2

 BPA 
4
 z  2 
 arg  
 z  2  4

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s

/4e x .sec 2 xdx

57. Let I  
/ 4 e2x  1
e x sec 2 x
If f  x  2 x
e 1
e sec 2 x
x
 f   x  2 x
e 1
x 2
e sec x

1  e2 x
e x sec 2 x
  2x
e 1
  f  x
 I = 0 ( f(x) is odd function)
1
58. x 1  1  d   1  2 d   ....  1  100d  
101 
1 101
  1  1  100 d    1  50d .
101 2 
 Mean deviation from mean
1
  1  1  50d   1  d  
101  

1  50d  ....  1  100d  1  50d 

2d
255  1  2  .......  50
101
d 50  51 2550
 2  d
101 2 101
2550
d  10.1
Now 101

59. Using AM  GM ,
1
a 5  a 4  a 3  a 3  a 3  1  a 8  a10
8

 a 5 .a 4 .a 3 .a 3 .a 3.1.a8 .a10  8

 a  a  3a 3  1  a8  a10  8.1
5 4

Hence, minimum value is 8.

60. Since, a1 , a2 , a3 ,........, a10 are in AP.

Now, a10  a1  9d
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
 3  2  9d
 d  1/ 9 and a4  a1  3d
 a4  2  31/ 9  2  1/ 3  7 / 3
Also, h1 , h2 , h3 ,........, h10 are in HP.
1 1 1 1
 , , ,......, are in AP .
h1 h2 h3 h10
Given, h1  2, h10  3
1 1
   9d
h10 h1
1 1
   9d1
3 2
1
   9d1
6
1
 d1  
54
1 1
And   6d1
h7 h1
1 1 6 1
  
h7 2 54
1 1 1
  
h7 2 9
18
 h7 
7
7 18
 a4 h7    6
3 7
PHYSICS
BV
61. i
RR
r 1 2
R1  R2

This current equivalent to the following diagram

62. The equation can be written as i  2sin100 t  2sin 100 t  1200 

So phase difference   1200

I m ) res  A12  A22  2 A1 A2 cos 

 1
 4  4  2  2  2     2, so effective value or rms value  2 / 2  2A
 2

63. Due to symmetry of the circuit, field will be zero at centre.

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
mv 2 mv 2 Km
64. Bev  or 
r Be Be
As, the electron has been accelerated from rest through a potential difference of V
volt, then K  eV
2meV 2mV
 r 2 2

Be B 2e
t sin  i  r 
65. d
cos r

10sin  600  450 


cos 450
10sin150

cos 450
 10 2 sin150 cm

66.

3
N '  100cos300  100.  50 3 N
2
 1 
Net driving force  100   30  20 N  upward 
 2 
1
f limiting
3
 
50 3  50 N

 Friction  20 N  downward

67.

Let the mass of a block is m. it will remain stationary if forces acting on it are in
equilibrium i.e., ma cos   mg sin   a  g tan 
Here ma  Pseudo force on block, mg  Weight .
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
1
68. Diameter d  1  48   1.48mm
100
r  0.74 mm  0.074 cm
V   r 2h h  5 cm
2
69. U  2  20 x  5 x
dU
F  20  10 x
dx
At equilibrium position; F  0
20  10 x  0
 x2
Since particle is released at x  3 , therefore amplitude of particle is 5.
5 5
3 0 2 7
It will oscillate about x  2 with an amplitude of 5.
 Maximum value of x will be 7
70. uB  uE

1 1 2
 ε 0 E02   8.854  1012   2
4 4
 8.86  1012 J / m2
RAB  0 16  12
71. RAB  16, VAB   8 V
R  RAB 8  16
Current in the loop of 1 and  2 :
 2  1 4  2 3
I   A
r1  r2 2  6 4
AN 3 AN 1
1  Ir1  VAB  VAB  or 2   2   8 or AN  m  25 cm
AB 4 4 4
72. effective resistance 2+4+6=12
Current in the circuit is 2A
Potential difference across AB is 20V
6
VB  Vy  20   12V
10
VB  Vx  5V
From above equations Vx  Vy  7V

73. The effective circuit is shown in figure

Sec: Sr. ICON ALL Page 18

Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s

7
CAB  F
8

1 21 1
74.  R  Z  b  2  2 
 K 1 2 
1 2 1 1
 R  Z  b  2  2 
 K 1 3 
 K  3/ 4  3  9  27 27 27 
 or  K    K   0.32  0.27 A
 K 8 / 9 4 8 32 32 32
3 5
Let Z X A  Z 6 Y 
A12
 Z 1 Y ' 
A12
75.
No.of neutrons A  12   Z  1 A  Z  11
  
No.of protons Z 1 Z 1

76. Here, i p  60 ,   ?
c
   tan i p  tan 60  3

c 3  108
    3  108 ms 1
3 3
77. Phosphorous is a pentavalent atom. Its doping will increase the number of electrons.
So number of holes will be equal to number of intrinsic carrier concentration
  1.41  1016 / m3  .
78. Given υ  k x  υ2  k 2 x . Differentiating, we have
dυ dx  dx 
2υ  k 2  k 2υ   υ  
dt dt dt
2
dυ k
 
dt 2
k2
  d υ 
2 
dt

k 2t
 υ
2
dx k 2t
 
dt 2
2
k
  dx  2  t dt
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
k2 2
 x t
4
Thus x  t 2 .
79. 2TCu  TFe  mg
mg
But TCu  TFe  TCu  TFe  T
3
15kg
T  10ms 2  50 N
3
As the bar is supported symmetrically.
The elongations are same
Fl Fl
Y or AY.   constant
AΔl Δl
1
2 2
 πd 
Fe
 πd  d Cu  YFe 
Cu
2

 4  .YFe   4  .YCu  d   Y 
Fe  Cu 
1
11 2
1.9  10 Nm  2
 11 2 
 1.3
 1.1  10 Nm 
TCu TCu

TFe

mg
a b c
80. M   h  c   G 
a 1 b c

M  ML2T 1   LT   M 1 3
L T 2 
1 1
And solve for a  b  , c  
2 2
th
81. Let 420 Hz be the n harmonic of the wire.
n T
 420  ... i 
2L 

Now, 490 
 n  1 T
2L 
Dividing (ii) by (i)
490 n  1 70 1
 1 1
420 n 420 n
1 1
 or n  6
6 n
Substituting the value of n in the equation of nth harmonic.

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
6 450 N
420s 1 
2 L 5  103 kg m1
900
420s 1  m s 1  L  2.1m .
L
82. WAB  0, WBC  P  V 

 nRT  6  8.31  2200  800 

 69.8kJ .
WCD  0, WDA   P  V 

 nR T  6  8.31  600  1200 

= -29.9 kJ.
W  WAB  WBC  WCA  WDA

= 40 kJ
Q1 T1 400
83.  
Q2 T2 300

3 3
 Q2  Q1  1200  900 cal
4 4
Pi  Pf 100  300 
84. Pav     103 Pa  200  103 Pa
2  2 

And V  100 103 m3

W  Pav V  200  103  100  10 3

=20kJ
85. In the device when free end of the string is pulled by  , the block will rise by  / 2. So
increase in potential energy U  mg / 2 .
1 1
86.  200  22  0.5   60 10  x  200 x 2
2 2
 x  1m

87. We know the relation between field and potential

V    E.dr    Ex .dx   E y .dy   20 x  20 y
 
 V  0 at the origin (0, 0)

88. Find potential at A and C due to charge at B, then the required work done is
W  q V A  VC  .

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Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-D(10th Jan)_Key & Sol’s
89.  R   R
2

 2  
2
Or  t 

1 1
 t 
 4

a
90. Angular momentum, mv  I
2
Moment of inertia (I) of cubical block is given by
 a2  a  2 
I  m    
 6  2 
a
m.2
  2
a  a 2
2
m    
 6  2  
12 3 10
     5 rad / s
8a 2  0.3 2

Sec: Sr. ICON ALL Page 22