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SE-8043
B, E. - If (Sem. Ill) (Chemical) Examination
April/May - 2011
Process Calculation
(New Syllabus)
Time : 3 Hours]
Instructions :
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Th alka g Rardanl fend Geel we mane anal,
Fillup strety the detalle of signs on your answer book
Name ofthe Examination
[Total Marks ; 100
Seat No.
B.E, -2 (SEM. 3) (CHEMICAL)
Name ofthe Subject
PROCESS CALCULATION (NEW)
subjectCodeno [8 |] 0 ][ 4 |[ 3] «-SectionNo.(1,2,...) [NIL
Answer all the questions.
Figures on right indicate full marks.
Atomic weights are : C=12, H=1, O=16, N=
Use of Scientific calculator is permitted.
(a) Give the answer :
(1) What is limiting component ?
@) What is excess reactant ?
(8) Define : Mole
@ Lkg=_ Ib,
Students Signature
14, S=32
(6) Find molecular weight of monoethanol amine
(NH,CH,CH,OH)
(6) What is conversion ?
(7) What is yield ?
(8) What is stoichiometric number ?
SE-8043] 1
[Contd... ()
In the preparation of cooking liquor for a sulphite 10
pulp mill, an absorption column is used to absorb SO.
in a weak liquor. The weak liquor enters the top of the
fe of 20 L/S with SO, concentration of
0.5% (by mass) and leaves with SO, concentration of
1.0% (by mass). The gas stream entering the bottom of
the column passing in the counter-current direction to
the liquor stream contains 17.0% (by volume) SO»,
When the gas leaves the top of the column, 75% of SO
gets absorbed. the pressure in the column becomes
50 KPa g and operates isothermally at 308 K. Assuming
that the liquor has a specific gravity of 1.0, calculate :
(a) the molar flow rate of entering gas
(b) the volumetric flow rate of entering gas in dm*/sec.
column at the
2 Attempt any two : 16
(a)
SE-8043]
In a textile industry it is desired to make a 24% solution 8
(by mass) of caustic soda for a mercerizations process.
Due to the very high heat of dissolution of causti
in water, the above solution is prepared by two-step
pro
First, in a dissolution tank, caustic soda is dissolved in
the correct quantity of water to produce 50% (by mass)
solution, After complete dissolution and cooling, the
solution is taken to dilution tank where some more water
is added to produce 24% solution. The two step process
is shown in below figure
_ ByPaes (wo)
“guid Ned H
oda
Dissolution soynadty
tone Telation
wy
Fig.
Assuming no evaporation loss in the dissolution tank,
calculate the mass ratio w;/w,
2 [Contd... () Slabs of buildings boards contain 16% moisture. They 8
are dried to a water contain of 0.5% by circulating hot
air over them. The fresh air contains 0.02 kg water
vapour per kg dry air. The exhaust air contains 0.09
kg water vapour per kg dry air. If the fresh air is
supplied at 28°C and 760 mm Hg. Flow chart to
alculate the quantity of fresh air (in m®/hr) required
per 1000 kg/hr. net dry board is given below. List out
the steps followed for above calculation.
Start
|
Basi
1
Tie Material
1
Material Balance]
1
Moles of Air Supplied
I
Volumetric flow rate of Air
i
End
(© A spent lye sample obtained from a soap-making unit 8
contains 9.6% glycerol and 10.3% salt (NaCl). It is
concentrated at the rate of 50,000 kg/hr in a double
effect evaporator until the final solution contains 80%
glycerol and 6% salt. Assume that about 4.5% glycerol
is lost by entrainment. All percentage are by mass,
Find
(@ The evaporation taken place in the system.
Gi) The amount of salt crystalised out in the salt box
of the evaporator.
SE-8043] 3 [Contd... 3 Attempt any two : 16
(a)
)
©
SE-8043]
What will be the composition of gases obtained by 6
burning pure FeS, with 60% excess air ? Assume that
the reaction proceeds in the following manner.
4FeS, +110, =2Fe,0, +8 SO,
Dinitro-o butyl phenol (DNOSBP) is manufactured 10
by the nitration of sec-butyl phenol (SBP) in presence
of zinc chloride and hydrogen chloride.
ec
~ 4
cH 4 cH
é-c.He ONS ZN 6 -GHe
: 4 AHA, = i 1 + 2420
are
BAPSBP
After the reaction is complete, a sample from the reactor
is analysed as follows
Component mass %
Nitric Acid 15
Sec-Butyl phenol 65
4, 6 Dinitro-o-see-butyl phenol 18
3, 6 Dinitro-p-sec-butyl phenol 2
Calculate
(@) Conversion
(b) Yield of ortho and para products
(1) Discuss methods of solving material balance
problems without chemical reaction.
2) Discuss the importance of recycling and by passing
operation.
4 [Contd... 4 a)
(b)
©
SE-8043]
Answer the following questions briefly 4x1=4
(1) State the first law of thermodynami
2) Write Bernoullie equation.
(3) Define : Net calorific value of fuel.
(4) Enumerate the applications of Hess's law of heat
summation,
Answer the followings : 2x3=6
@
The gross calorific value of gaseous propane is
2219.7 kJ/mol at 298 K. Calculate its net calorific
value if the latent heat of vaporization of water is
2442.5 kJ/kg at this temperature.
(2) What is fuel ? Classify it with examples.
Solve the followings 2x5=10
(@) Calculate standard heat of reaction at 298 K when
@)
gaseous ammonia is dissolved in water to form 2%
(by weight) solution of ~— ammonia.
The standard heat of formation of ammonia, water
and ammonia hydroxide are —45.94 kJ/mol;
285.83 kJ/mol; —361.20 kJ/mol respectively.
Temperature of 1 ml. of oxygen is raised from
350 K to 1500 K. Calculate heat required using
cl) data.
Cl) sa4bT eT? +475 (kJ/kmol K)
where a=26.0257
b=11.7551x10
e=-2.3426x10-°
d=-0,5623x10-9
5 [Contd... 5 Attempt any two : 2xT=14
(a)
0)
©
SE-8043]
A heat exchanger for cooling a hot hydrocarbon liquid
uses 10,000 kg/hr of the cooling water. ‘The hydrocarbon
liquid enters the exchanger at 423 K and leaves at
338 K at the rate of 5000 kg/hr. Cooling water is
available at 294 K. Calculate the outlet temperature of
water.
Data :
heat capacity of hydrocarbon oil = 2.57 ki/kgK
4.186 kd/kgK
heat capacity of water
A mixture of aniline and water containing 11.8% (by
weight) aniline is subcooled into the overhead condenser
of a distillation column from 373 K to 313 K with the
help of cooling water at the rate of 8000 kg mixture per
hy. Find the heat removed per hour in the condenser.
Heat capacity data :
C, =a+bT+eT? +473 (kJ/kmol K)
Compound] a bx103 exl0® | dx10%
Aniline | 206.27 |-211.5065 | 564.2902 | 0
Water | 50.845 | 213.08 _| -631.398 | 648.746
—» Molecular weight of aniline is 93.12 kg/kmol
> Molecular weight of water is 18 kg/kmol.
Flue gases from a boiler-chimney has following
composition. Assume complete combustion of fuel.
___ | Composition by
Species
volume (%)
CO; 11.4%
Ny 84.4%
0, 4.2%
(1) Calculate % excess air used for the combustion.
@) Find C/H ratio of fuel.
6 [Contd... 6 Attempt any two : 2x8=16
(a) A sample of coal is found to have 65% carbon and 12.7%
ash by weight. The refuse obtained after burning fuel
has 8.6% carbon, Assume that negligible oxygen is
present in the coal, Flue gas analysis shows the following
compositions by volume.
Composition by
volume (%)
10.6%
8.7%
80.7%
Calculate actual weight of dry air used to burn the
coal.
2 Weight of flue gases produced by burning the coal.
1
(b) Evaluate heat of reaction for : SO, +50, > SO; occurring
ve and 775 K. The heat capacity follows
C0)
