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Chemistry (BI) T3 MDCAT Entry Test 2019

(Test Series II)
Chapter#5+6
Q.1 What is correct for Cathode rays and Positive rays?
A) Pressure = 0.01 atm C) Pressure = 0.01 torr
B) Pressure = 0.01 Nm–2 D) Both B and C

Q.2 Positive rays are produced in the modified gas discharge tube from / by
A) Anode electrode C) Cathode electrode
B) Conversions of Molecules to Anions D) Conversion of Molecules to cations

Q.3 What is correct for the quantum numbers?

N l m
A 1 1 1
B 1 0 0
C 2 0 –1,0,+1
D 3 3 –2,–1,0,+1,2

Q.4 There are only two electrons can be placed in an orbital with same spin, this is the statement of ………………..
A) Pauli’s exclusion principle C) (n+l) rule
B) Hund’s Rule D) None of these

Q.5 Which of the following statements about First energy (I.E) is correct.
A) He has maximum I.E in the periodic table C) Among Li, Be, B,----------- B has greater I. E
B) Among C,N, O,---------- O has greater I.E D) Among Na, K, Cs---------- Na has smaller I.E

Q.6 Carbon and silicon are both in Group IV of the Periodic Table, but at room temperature CO 2 is a gas whereas SiO2 is
a solid. Which statement explains this?
A) Covalent bonding is weaker in CO2.
B) Covalent bonds in CO2 are double bonds and in SiO2 the covalent bonds are single bonds.
C) CO2 is a covalent compound and SiO2 is ionic.
D) CO2 is a simple covalent molecule and SiO2 is a macromolecule.

Q.7 According to VSEPR theory, SO2 belongs to

A) AB type molecules C) AB2 Type molecules
B) AB3 type molecules D) AB4 type molecules

Q.8 How many of the molecules shown contain only one covalent bond?
Cl2 H2 HCl N2 O2
A) 2 C) 4
B) 3 D) 5

Q.9 Percentage covalent character of NaCl is

A) 28% C) 72%
B) 76% D) 100%

Q.10 The difference between covalent and co–ordinate covalent bond vanishes in
+ +
A) NH4 C) H3 O
+
B) PH4 D) All of these

Q.11 Element X has the electronic structure 2,8,5. Element Y has the electronic structure 2,8,7. What is the likely
formula of a compound containing only X and Y’?
A) XY3 C) X3Y
B) X2Y3 D) X3Y2

Q.12 In ionic bond, element forming cation should have

A) High electron affinity C) Low electron affinity
B) Low ionization energy D) Both B and C
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Q.13 Which of the following has zero dipole moment?

A) H2S C) SO2
B) CO D) CS2

Q.14 A covalent bond is formed by

A) electron sharing between metals and non-metals C) electron transfer between non-metals
B) electron sharing between non-meta D) electron transfer from metals to non-metals

Q.15 Which of following compound is insoluble in water?

A) Compound having lattice energy greater than hydration energy
B) Compound having hydration energy greater than lattice energy
C) A compound which is polar
D) An organic compound which can form H–bond with water.

Q.16 In Higher alkenes C to C Sigma() bond is formed by overlapping

A) sp2–sp3 C) sp2–sp2
B) sp–sp D) Both A and C

Q.17 Which of the following has highest value of dipole moment?

A) SO2 C) H2S
B) H2O D) CH4

Q.18 Which of following has same trend in periodic table as that of ionization energy?
A) electronegativity C) electron affinity
B) atomic radius D) Both A and C

Q.19 Calcium reacts with phosphorus to form the ionic compound calcium phosphide Which ions will this compound
contain?
A) Ca2+ and P3– C) Ca2- and P3+
B) Ca2+ and P5– D) Ca2– and P5+

Q.20 Hydrogen can form both H+ ions and H– ions. Which one of the statements below correct?
A) An H+ ion has more protons than an H- ion C) An H- ion has one more electron than an H+ ion
+
B) An H ion has no electrons D) An H- ion is formed when a hydrogen atom loses an electron

Q.21 Each sigma bond in benzene possesses how much p – character?

A) 66.7% C) 50%
B) 75% D) 25%

Q.22 Number of bond angles in methane are

A) 4 C) 12
B) 6 D) 8

Q.23 In Fluorine molecule the sigma bond is formed by the overlapping of?
A) pz to pz C) sp2 to sp2
B) py to pz D) px to px

Q.24 Which of following is correct?

A) Angle is 109.5° but Geometry is not tetrahedral
B) Angle is 109.5° but Geometry is always tetrahedral
C) Angle is 109.5° but shape is trigonal bipyramide
D) Angle is 120° but Geometry is not triangular planner

Q.25 The nature of bond between Ligands and Central metal atom in transition metal complexes is …………
A) covalent C) Covalent polar
B) Non Polar Covalent D) Dative

Q.26 An element X forms a positive ion with the electronic structure 2,8,8. What is the proton (atomic) number of X?
A) 16 C) 17
B) 18 D) 19

Q.27 The number of bonds in nitrogen molecule

A) One sigma and one Pi C) Three sigma only
B) One sigma and two Pi D) Two sigma and one Pi
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Q.28 Which of the following molecules has zero dipole moment?

A) NH3 C) H2O
B) CHCl3 D) BF3

Q.29 Which of the hydrogen halides has the lowest % age of ionic character?
A) HI C) HBr
B) HF D) HCI

Q.30 In one molecule of carbon dioxide. CO 2, what is the total number of electrons present and how many are involved
in bonding between the carbon and oxygen atoms?

Total number of electrons Electrons involved in bonding

A) 16 4
B) 16 8
C) 22 4
D) 22 8
Q.31 The hybridization of C – C in the molecule CH2 = CH – CH = CH2
A) sp3 – sp3 C) sp2 – sp2
3 2
B) sp – sp D) sp – sp

Q.32 Which compound has highest value of dipole moment?

A) CH3Cl C) CH3Br
B) CH3F D) All have same

Q.33 Which bond possesses highest value of bond energy?

A) Si - O C) Cl – O
B) O – I D) O – O

Q.34 The H – S – H bond angle in H2S is

A) 98° C) 109.5°
B) 92° D) 107.5°

Q.35 Elements X and Y react to form an ionic compound of formula XY. What could be the proton
(atomic) numbers of X and Y?
A B C D
X 3 6 8 12
Y 8 8 16 16

Q.36 Which compound has both ionic and covalent bonds?

A) Ammonium chloride C) Ethyl ethanoate
B) Carbon dioxide D) Sodium Chloride

Q.37 The ion XH4+ can be represented by the ‘dot and cross’ diagram shown.

+
 H 
H   H
  X  
 H 
To which Group in the Periodic Table does X belong?
A) I C) III
B) IV D) V

Q.38 which electron arrangement is that of a metallic element?

A) 2,1 C) 2,4
B) 2,5 D) 2,7
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Q.39 Which molecules have the same number of protons?

A) O2 and N2 C) CO2 and SO2
B) Cl2 and Br2 D) CH4 and NH3

Q.40 The diagram shows the arrangement of electrons in a particle.

What is the symbol for the particle?

A) N3– C) F–
B) O2– D) Ne

Q.41 Which ion has the most shells that contain electrons?
A) Al3+ C) Be2+
3–
B) N D) S2–

Q.42 How does a magnesium atom form a bond with an oxygen atom?
A) By giving one pair of electrons to the oxygen atom
B) By sharing one pair of electrons, by electrons provided by the magnesium atom
C) By sharing two pairs of electrons, both pairs provided by the oxygen atom
D) By sharing two pairs of electrons, each atoms donating one pair of electrons

Q.43 Elements X and Y combine to form the gas XY2 what are X and Y?
X Y
A) Calcium Chlorine
B) Carbon Hydrogen
C) Carbon Oxygen
D) Hydrogen Oxygen

Q.44 Which of the following contains the same number of electrons as an atom of neon?
A) Cl– C) Li+
B) Li D) O2–

Q.45 The outer shell electrons in compound YZ, are shown

Key  O electrons of Y atom X electrons of Z atom

Use the Periodic Table to find the number of neutrons in atom Y, which is in the Period Li to Ne.
A) 6 C) 10
B) 8 D) 12
7
Q.46 An atom of element X is represented by 3 X . Which statement about an atom of X is correct?
A) It is in Group III of the Periodic Table. C) The total number of protons and electrons is 6.
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B) It is in Group VII of the Periodic Table. D) The total number of protons and neutrons is 10.

Q.47 How many electrons are shared in the covalent bonding of a methane molecule?
A) 2 C) 6
B) 4 D) 8

Q.48 Two particles X and Y have the composition shown in the table.

Particle Number of electrons Number of neutrons Number of protons

X 8 10 8
Y 18 18 17

The particles X and Y are

A) metal atoms C) negative ions
B) non-metal atoms D) positive ions

Q.49 Ethane has the structure shown.

H H
| |
HCCH
| |
H H
How many of the electrons in a molecule of ethane, C2H6, are not involved in bonding?
A) 0 C) 4
B) 2 D) 8

Q.50 Which two statements about a covalent bond are correct?

1 It can be formed between two metal atoms.
2 It can be formed between two non-metal atoms.
3 It is formed by the transfer of than an H+ ion. electrons between atoms.
4 It is formed by sharing electrons between atoms.
A) 1 and 3 C) 2 and 3
B) 1 and 4 D) 2 and 4

Q.51 The symbols and electronic structures for some elements are sown below.

Silicon, Si (2,8,4) Oxygen, O (2,6) Hydrogen, H (1) Fluorine, F (2,7) Nitrogen, N (2,5)

Which formula is correct for a compound containing silicon?

A) Si4F C) SiN5
B) SiH4 D) Si2O

Q.52 Rubidium is in Group I and bromine is in Group VII of the Periodic Table. How is a compound formed between
rubidium and bromine?
A) Each atom of bromine shares an electron with an atom of rubidium.
B) Each atom of bromine shares a pair of electrons with an atom of rubidium.
C) Each atom of bromine gives an electron to an atom of rubidium.
D) Each atom of bromine receives an electron from an atom of rubidium.

Q.53 Which compound contains three elements?

A) Aluminum chloride C) Potassium oxide
B) Iron(III) oxide D) Sodium carbonate

Q.54 An ionic compound (BA) is most likely to be formed when

A) The ionization energy of A is high and electron affinity of B is low
B) The ionization energy of A is low and electron affinity of B is high
C) Both the ionization energy and electron affinity of B are high
D) Both the ionization energy of A and electron affinity of B are low

Q.55 Which of the following statements is not correct regarding bonding molecular orbitals?
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A) Bonding molecular orbitals possess less energy than atomic orbitals from which they are formed
B) Bonding molecular orbitals have low electron density between the two nuclei
C) Every electron in the bonding molecular orbitals contributes to the attraction between atoms
D) Bonding molecular orbitals are formed when the electron waves undergo constructive interference

Q.56 Which of the following involve ionic bonding only?

A) Li3N C) NaCl
B) NCl3 D) O2

Q.57 H2S has a net dipole moment while BeF2 has zero dipole moment, because
A) H2S molecule is linear while BeF2 is angular C) H2S molecule is Linear, while BeF2 molecule is Angular
B) Fluorine has more electronegativity than S D) H2S possesses 2 bond pairs and 2 lone pairs, while BeF2
possesses 2 bond pairs

Q.58 Which type of the orbital hybridization and geometry is used by the central atom of NH 2 ?
A) sp hybridization and Linear C) sp2 hybridization and tetrahedral geometry
B) sp3 hybridization and trigonal planar D) sp3 hybridization and tetrahedral geometry

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