CHAPTER TEST 1.

In the titration of a certain H2SO4 solution, 60 mL of Assertion-Reason Type

5.0 M NaOH solution was used to completely
Following two questions have assertion followed by
neutralise 75 mL of the acid. The molarity of the acid the reason. Answer them according to the following
solution may be expressed as options.
5 M ´ 60 mL 5 M ´ 75 mL ´ 2 (a) Both assertion and reason are correct and reason is
(a) (b)
2 ´ 75 mL 60 mL the correct explanation of the assertion,
75 mL ´ 2 60 mL ´ 75 mL ´ 2 (b) Both assertion and reason are correct but reason is
(c) (d)
5.0 M ´ 60 mL 5.0 M not the correct explanation of assertion.
(c) Assertion is correct but reason is incorrect.
2. 20 mL of a solution containing equal moles of Na2CO3 (d) Assertion is incorrect but reason is correct.
and NaHCO3 required 16 mL of a 0.16 M HCl solution
7. Assertion If certain volume of a basic solution require
to reach the phenolphthalein end point. What volume
x mL of HCl, 2x mL of H2SO4 of same molarity would
of a 0.10 M H2SO4 solution would have been required be required.
had methyl orange been used as indicator?
Reason HCl is a monobasic acid while H2SO4 is a
(a) 38.40 mL (b) 24.60 mL dibasic acid.
(c) 19.20 mL (d) 0.30 mL
8. Assertion If 10 mL of a H2O2 solution required 8.00 mL
3. When aqueous solution of Na2S is titrated with dilute of 0.02 M acidified KMnO4 solution for complete
and acidified KMnO4 solution, Na2SO3 is formed. In oxidation, 12.50 mL of same H2O2 will oxidise completely
this reaction, moles of KMnO4 reduced per mole of to 5.00 mL of 0.10 M Na2C2O4 solution.
Na2S is
Reason H2O2 act as both oxidising as well as
(a) 0.833 (b) 1.2 (c) 1.50 (d) 1.8
reducing agent.
4. For the following metals A, B, C, D react with each
other : (NR = No reaction) 9. The alkenes are compounds of carbon and hydrogen
+ + with the general formula CnH2n. If 0.561 g of any alkene
A + B ¾® NR B + C ¾® NR
is burned in excess oxygen, what number of moles of
B + D + ¾® B + + D C + D + ¾® C + + D H2O is formed?
+ +
A + C ¾® C + A D + A+ ¾® D + + A (a) 0.0400 mol (b) 0.0600 mol
Which is the order of the metals in increasing reducing (c) 0.0800 mol (d) 0.400 mol
strength? 10. What is the density (in g mL -1) of a 3.60 M aqueous
(a) B < D < A< C (b) C < B < D < A sulphuric acid solution that is 29.0% H2SO4 by mass?
(c) A < D < B < C (d) < C < A< B
(a) 1.22 (b) 1.45
5. 40 mL 0.05 M solution of sodium sesquicarbonate (c) 1.64 (d) 1.88
dehydrate (Na2CO3·NaHCO3·2H2O) is titrated against 11. Magnetite, Fe3O4, can be converted into metallic iron
0.05 M HCl solution, x mL of acid is required to reach by heating with carbon monoxide as represented by
the phenolphthalein end point while y mL of same acid this equation:
were required when methyl orange indicator was used Fe3O4 (s) + CO (g) ¾® Fe (s) + CO2 (g)
in a separate titration. Which of the following is(are) The kilograms of Fe3O4 which must be processed in
correct statements? this way to obtain 5.00 kg of iron, if the process is 85%
(a) y - x = 80 mL efficient is closest to? [M : Fe = 56]
(b) y + x = 160 mL
(a) 6.92 kg (b) 8.15 kg
(c) If the titration is started with phenolphthalein indicator
(c) 20.8 kg (d) 24.4 kg
and methyl orange is added at the end point, 2 x mL of
HCl would be required further to reach the end point 12. How many H2O molecules are there in a snowflake
(d) If the same volume of same solution is titrated against that weighs 4.0 ´ 10 - 4 g?
0.10 M NaOH, x/2 mL of base would be required
(a) 1.3 ´ 1019 (b) 2.4 ´ 10 20
6. Which of the following regarding oxalate compound -5
(c) 2.2 ´ 10 (d) 6.02 ´ 10 23
is/are true?
(a) Oxalic acid (H 2 C 2 O 4 ) can be estimated by titrating 13. Atomic weight of an element X is 120 when one amu is
against either KOH or KMnO 4 solution. defined as 1/18th part by weight of an element of C12.
(b) KHC 2 O 4 can be estimated by titrating against either On the same scale, atomic weight of another element
KOH or K 2 CrO 4 and in both analyses equivalent
Y is 72. Which of the following statement regarding X
weight of KHC 2 O 4 is 64. (MW of KHC 2 O 4 = 128)
(c) K 2 C 2 O 4 can be estimated by titrating against either and Y is(are) correct?
HCl or KClO 3 and in both analyses equivalent weight (a) On conventional scale, atomic weight of X is 80
of K 2C 2O 4 is 83. (MW of K 2 C 2 O 4 = 166) (b) On conventional scale, atomic weight of Y is 108
(d) If 10 mL of a K 2 C 2 O 4 solution required 8.0 mL of a (c) On a scale when an amu is defined to be 1/30th of the
0.12 M HCl solution, 10 mL of the same K 2 C 2 O 4 weight of an atom of C12, atomic weight of X is 200
solution would require 9.60 mL of a 0.02 M acidified (d) On a scale when an amu is defined to be 1/15th of the
KMnO 4 solution. weight of an atom of C12, atomic weight of Y is 90
 14. Which of the following statement regarding Avogadro Assertion-Reason Type
number is(are) correct? Following two questions have assertion followed by the
(a) It is 6.023 ´ 10 23 reason. Answer them according to the following options.
(b) It is the number of atoms present in exactly 12 g of C-12 (a) Both assertion and reason are correct and reason is the
isotope correct explanation of the assertion.
(c) It is the number of atoms present in 1.0 mole of any (b) Both assertion and reason are correct but reason is not
substance the correct explanation of assertion.
(d) It is the number of atoms of deuterium present in its 2.0 g (c) Assertion is correct but reason is incorrect.
(d) Assertion is incorrect but reason is correct.
Passage for Q. Nos. 15 to 17
18. Assertion The average mass of an atom of Mg is
4.0 g of a mixture of NaCl and an unknown metal iodide MI 2 was
dissolved in water to form its aqueous solution. To this aqueous 24.305 u, which is not the actual mass of an atom of
solution, aqueous solution of AgNO 3 was added gradually so Mg.
that silver halides are precipitated. The precipitates were Reason This is the average mass determined
weighed at regular interval and following curve for the mass of considering different isotopes of Mg present in natural
precipitate versus volume of AgNO 3 added was obtained. With Mg.
the knowledge of the fact that halides are precipitated
successively, i.e. when less soluble halide is precipitating, the 19. Assertion A 8.0 g N2H4 (M = 32) has more atoms than
other halide remain in the solution, answer the following 6.0 g H2O.
questions: (Molar mass of Ag = 108, I = 127, Na = 23).
Reason N2H4 has more atoms per molecule than
9 water.
8 20. Match the statements of Column I with values of
7 Column II.
Mass of precipitate (in g)

6 Column I Column II
5 A. Different number of p. 4.25 g NH3 and
4 atoms 4.5 g of H2O
B. Same number of q. 2.20 g CO2 and
3 molecules 0.90 g H2O
2 C. Same numbers of atoms r. 4.0 g CH3Cl and
1 as well as molecules 5.0 g NH3
D. Different numbers of s. 4.80 g O2 and
0
5 10 15 20 25 30 35 40 45 50 atoms as well as 2.80 g CO
Volume of AgNO3 molecules

21. On a conventional scale, atomic weight of sulphur is 32.

15. What is the approximate mass percentage of MI2? If on a new scale, an amu is defined as one-third by
(a) 25 (b) 40 weight of an atom of C-12 isotope, what would be the
(c) 60 (d) 75 atomic weight of sulphur on this new scale?
16. What is the approximate molarity of AgNO3 solution?
22. If equal volumes of 3.5 M CaCl2 and 3.0 M NaCl are
(a) 0.1 (b) 0.5
(c) 1.0 (d) 1.5
mixed, what would be the molarity of chloride ion in the
final solution?
17. What is the approximate molar mass of unknown metal M?
(a) 20 (b) 40 (c) 56 (d) 60
Answers
1. (a) 2. (c) 3. (b) 4. (c) 5. (a, b, c, d) 6. (a, c, d) 7. (d) 8. (b) 9. (a) 10. (a)
11. (b) 12. (a) 13. (b, c) 14. (a, b, d ) 15. (d) 16. (c) 17. (b) 18. (a) 19. (b)
20. A ® s; B ® p; C ® q; D ® r 21. (8) 22. (5)