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ChE 125: Chemical Reaction Engineering

This document provides an introduction to a chemical reaction engineering course. It defines chemical reaction engineering as the design and operation of chemical reactors on an industrial scale. It discusses the key foundations of chemical reaction engineering, including thermodynamics, kinetics, transport phenomena, and reactor design. It also classifies different types of reactions and reactors, and outlines the methodology that will be used to design reactors in the course.

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347 views23 pages

ChE 125: Chemical Reaction Engineering

This document provides an introduction to a chemical reaction engineering course. It defines chemical reaction engineering as the design and operation of chemical reactors on an industrial scale. It discusses the key foundations of chemical reaction engineering, including thermodynamics, kinetics, transport phenomena, and reactor design. It also classifies different types of reactions and reactors, and outlines the methodology that will be used to design reactors in the course.

Uploaded by

googley71
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
  • Introduction
  • Chemical Reaction Engineering Overview
  • Biodiesel Production Process
  • Fundamentals of Chemical Reaction Engineering
  • Foundations of CRE
  • Reactor Design Essentials
  • Classification of Reactions
  • Chemical Reactors
  • Reactor Design Methodology
  • Questions and Homework

University of the Philippines – Diliman

Department of Chemical Engineering

Introduction
ChE 125
Chemical Reaction Engineering I
AY 2015 – 2016
MSPDEANG
January 20, 2015
Chemical Reaction Engineering
In Chemistry
A + B → Products
In Chemical Engineering

REACTOR

MSPDEANG
Chemical Reaction Engineering
Ø  What is Chemical Reaction Engineering?

Chemical reaction engineering (CRE) is that engineering


activity concerned with the exploitation of chemical
reactions on a commercial scale. Its goal is the successful
design and operation of chemical reactors, and probably
more than any other activity, it sets Chemical Engineering
apart as a distinct branch of the engineering profession.

Octave Levenspiel (2004)

MSPDEANG
Chemical Reaction Engineering
Ø  Every industrial chemical process is designed to
economically produce a desired product from a variety of
starting materials through a succession of treatment steps

Physical Chemical Physical


Raw
treatment treatment treatment Products
Materials
steps steps steps

Recycle

Example:
Biodiesel Production

MSPDEANG
Biodiesel Production

h"p://[Link]/Biodiesel/SmallScale/[Link]  
MSPDEANG
Biodiesel Production
Ø  For Large Scale Production
Physical Chemical Physical
treatment treatment treatment
steps steps steps

Chemical Biodiesel
Oil Purification
Reaction Purification

Ø  Filtration Ø  Agitation Ø  Distillation

Ø  Evaporation Ø  Extraction

MSPDEANG
Chemical Reaction Engineering
Ø  Thermodynamics and Ø  Chemical Kinetics
Equilibria

MSPDEANG
Chemical Reaction Engineering
Ø  Fluid Mechanics Ø  Heat Transfer

MSPDEANG
Chemical Reaction Engineering
Ø  Mass Transfer Ø  Economics

MSPDEANG
Foundations of CRE

MSPDEANG
Foundations of CRE
What you know so far
Ø  Mass Balance and Stoichiometry
–  c/o Chem 16, Chem 28, ChE 101
Ø  Thermodynamics and Energy Balance
–  c/o Chem 17, Physics 73, ChE 101, ChE 122
Ø  Chemical Kinetics
–  c/o Chem 17
Ø  Computational Methods
–  c/o Math series, ChE 26, ChE 106

MSPDEANG
Foundations of CRE
What you will need in the future
Ø  Transport Phenomena (for heterogenous reactions)
–  c/o ChE 131
Ø  Reaction equilibrium
–  c/o ChE 123, introduced in Chem 17

MSPDEANG
Reactor Design
Ø  Lab Scale vs Industrial Scale

MSPDEANG
Reactor Design

MSPDEANG
Reactor Design Preliminaries
Chemical Data
Ø  Kinetics
–  Reaction rates
–  Reaction mechanism
–  Catalyst stability

Ø  Thermodynamics
–  Heats of reaction and Energy Balance
–  Equilibrium conversion

MSPDEANG
Reactor Design Preliminaries
Physical Data
–  Mass, heat and momentum transfer rates
–  Heat capacities, density, viscosity etc

Material Data
–  Strength of Materials

Economics
–  Costs
–  Efficiency of system

MSPDEANG
Classification of Reactions
Ø  Number of phases

MSPDEANG
Classification of Reactions
Elementary vs Non Elementary

aA + bB → cC r=k[A] m [B] n

Single vs Multiple
Ø  Single
A → B
Ø  Series
A → B→C
Ø  Parallel
A → B
A → C
Ø  Mixed
MSPDEANG
Chemical Reactors
Ø  Mode of Operation
–  Batch
–  Continuous
–  Semibatch

Ø  Geometric Configuration


–  Stirred Tank
–  Tubular

MSPDEANG
Chemical Reactors
Ø  Heat Transfer Operation
–  Isothermal
–  Adiabatic
–  Non-Isothermal

Ø  Contacting Patterns between phases

MSPDEANG
Reactor Design Methodology
In ChE 125

MSPDEANG
QUESTIONS?
Homework!
3x5 index card

Last Name, First Name, MI 1x1 ID pic


Student Number
Email address
Contact number(s) Nickname
PTCICOE (relation to PTCICOE)
Contact number of PTCICOE

MSPDEANG

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