I. MODIFIED TRUE OR FALSE.

Write TRUE if the statement written is true; write FALSE

otherwise.
__________1. Internal energy is a state function.
__________2. 337. 4 g of NH3 would be produced upon reaction of 40.00 g N2 and 60.00 g H2. (N:14.01
g/mol; H: 1.01 g/mol)
__________3. There are exactly 6.022 × 1023 H atoms in 1.00 mol of C6H12O6.
__________4. A system’s ΔE is equal to -12.4 kJ when the system does 2.8 kJ of work and is heated to
absorb 15.2 kJ afterwards.
__________5. The actual yield is always greater than the theoretical yield for any given reaction.
__________6. When ΔH < 0 and ΔS < 0, the reaction is nonspontaneous at low temperatures.
__________7. Mass is always conserved in all chemical reactions.
__________8. The values of the enthalpy of decomposition of water to H2 and O2 and the reverse reaction
is equal.
__________9. The empirical formula of a compound containing 40.92% C, 4.58% H, and 54.50% O is
CHO. (C: 12.01 g/mol; H:1.01 g/mol; O: 16.00 g/mol)
__________10. The compound C7H14O2 is 10.86% H.
__________11. The products when Mn2+(aq) and Zn(s) are mixed in a solution are Mn(s) and Zn2+(aq).
__________12. The ΔH for the reaction 2 H2O(g) → 2 H2O(l) is -88 kJ; hence, the ΔH for the reaction H2O(g)
→ H2O(l) is -88 kJ.
__________13. Empirical formula indicates the actual whole number ratio of atoms present in a molecule
of a compound
__________14. There are 3.011x1024atoms of O in 0.50 moles of P4O10.
__________15. Sr(OH)2 is considered as a weak base.
__________16. The specific heat capacity of an object is defined as the amount of heat required to raise its
temperature by 1K \

__________17. The molecular weight of glucose, C6H12O6, is 180.15 g/mol. (C: 12.01 g/mol; H: 1.01
g/mol; O: 16.00 g/mol)
__________18. An ideal primary standard must be insoluble in the solvent of interest.
__________19. Ion removal is the driving force of metathesis reactions.
__________20. Calcium is a stronger reducing agent than copper.

II. MULTIPLE CHOICE. Choose the letter of the best answer.

1. Which of the following are considered as state functions?
I. Internal Energy II. Pressure
III. Temperature IV. Entropy
a. I only
b. I, IV
c. I, III, IV
d. I, II, III, IV
2. In order to open his lab at Stark Laboratories, Spiderman has to select the elements that are
arranged in increasing strength as an oxidizing agent. Which of these should he select?
a. F2 > Cl2 > Br2 > I2
b. Li > Al > Pb > H2
c. I2 > Br2 > Cl2 > F2
d. H2 > Pb > Al > Li
3. Which of the following is False?
a. H<0: S>0: spontaneous at all T’s
b. H>0: S>0: spontaneous at low T’s
c. H>0: S>0: spontaneous at high T’s
d. H<0: S<0: spontaneous at low T’s
4. What mass of O2 is required to react with 175 g of carbon disulfide?
CS2 + 3O2 → CO2 + 2SO2
a. 24.5 g
b. 221 g
c. 139 g
d. 41.8 g
5. All are exothermic reactions EXCEPT
a. increase in entropy on the surroundings
b. release of heat by system to surroundings
c. decrease of temperature in the surroundings
d. absorption of heat by surroundings from system
6. Which of the following does not lead to the decrease in entropy?
I.Vaporization II. Condensation III.Freezing IV. Melting
a. II only
b. I, IV
c. II, III
d. I, II, III, IV
7. What is the maximum mass of iron that can be produced from the reaction of 55.0 g of iron (III)
oxide and 32.3 g of carbon monoxide?
Fe2O3 + 3 CO → 2 Fe + 3 CO2
a. 22.6 g
b. 38.5 g
c. 42.9 g
d. 73.1 g
8. Which of the following is not an example of a strong acid?
a. Hydrocyanic acid
b. Chloric acid
c. Hydrobromic acid
d. Nitric acid
9. Which of the following reactions is incorrectly paired with its type of aqueous reaction?
a. Precipitation: 2Na3PO4 + 3MgCl2 -> 6NaCl + Mg3(PO4)2
b. Neutralization: H2CO3 + 2KOH -> K2CO3 + 2H2O
c. Redox: CuSO4 + Pb(NO3)2 -> Cu(NO3)2 + PbSO4
d. Precipitation: AlBr3 + 3NaOH -> 3NaBr + Al(OH)3
10. How many moles of He are present in a 3.00 L cylinder containing He gas (ρ = 0.179
g/L)?
a. 0.0224 moles
b. 0.0895 moles
c. 0.358 moles
d. 0.134 moles
11. Use Hess’s Law to determine ΔHo for the reaction
C3H4(g) + 2 H2(g) → C3H8(g)
• (1) H2(g) + ½O2(g) → H2O(l) ΔHo = -285.8 kJ
• (2) C3H4(g) + 4O2(g) → 3CO2(g) + 2H2O(l) ΔHo = -1937 kJ
• (3) C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(l) ΔHo = -2219.1 kJ
a. -3.7 kJ
b. -289.5 kJ
c. -853.7 kJ
d. -4728 kJ
12. The first law of thermodynamics states that the total change of internal energy , ΔU is dependent
on
a. Heat and work
b. Force
c. Work but not heat
d. Heat
13. What type of formula indicates the simplest positive integer ratio of atoms present in
a compound
a. Chemical Formula
b. Empirical Formula
c. Molecular Formula
d. None of the above
14. In the titration of acid A with base B, the equivalence point of 0.5 M of acid A was known to be 12
mL of 0.25 M B. How much of acid A should be titrated?
a. 0.24 L
b. 0.06 L
c. 6 mL
d. 24 mL
15. In the equation KO2 + CO2 → K2CO3 + O2, how many grams of KO2 are consumed per
100g of CO2?
a. 2.28 grams
b. 6.84 grams
c. 162 grams
d. 323 grams
16. Which of the following has the greatest mass of C?
a. 2.568 g CO2
b. 0.987 C6H6
c. 0.3 mol C12H22O11
d. 3.00 mol C
17. How many particles are there in 3.20 g of HClO?
a. 3.60 x 1022
b. 1.93 x 1022
c. 1.01 x 1023
d. 1.93 x 1023
18. A salt solution containing 36% NaCl has how many moles of H2O?
a. 5.55 mol
b. 3.56 mol
c. 2.00 mol
d. 2.55 mol
18. A reaction is spontaneous if
a. It occurs fast.
b. It is endothermic and has negative change in entropy
c. It doesn’t need energy to start
d. It has a free energy less than zero.
19. An element X forms a compound with chloride in 1:2 ratio. What is element X if the compound is
59.6% Cl?
a. Ti
b. Br
c. Co
d. Ca
20. What is the concentration of titrant A if 25.0 mL of titrant A is consumed to reach the endpoint of
the titration of 32.0 mL analyte B of concentration 0.150M?
a. 0.125 M
b. 0.150 M
c. 0.192 M
d. 0.216 M
21. Which of the following is the correct overall standard enthalpy change of the combustion reaction
of methanol, CH3OH?
Values for bond enthalpies:
C-H: 413 kJ/mol; C-O: 358 kJ/mol; O-H:463 kJ/mol; O=O: 498 kJ/mol; C=O: 799 kJ/mol
a. 423 kJ/mol
b. -423 kJ/mol
c. 643 kJ/mol
d. -643 kJ/mol
22. Which of the following is an endothermic process?
a. Reaction of HCl with Na(s)
b. Condensation of ethanol in ethanol distillation
c. Formation of ice crystals
d. Sublimation of benzoic acid
23. Which of the following statements is false?
a. The enthalpy change for the vaporization of water is different from the enthalpy change for the
sublimation of ice.
b. The vaporization of water releases more heat than the condensation of water.
c. If the vaporization of water is an endothermic reaction, then its condensation is an exothermic
process.
d. Hess’s Law states that if a reaction is carried out in a stepwise fashion, the enthalpy change of the
reaction will be equal to the sum of the changes for the individual steps.
24. Bond breaking is always
a. Exothermic
b. Endothermic
c. Adiabatic
d. Isothermic

III. PROBLEM SOLVING. Give what is asked and solve for the values required.
1. Given the following data at 298 K:
ΔHfo (kJ mol-1) ΔGfo (kJ mol-1)

NH3(g) -46.11 -16.48

HCl(g) -92.31 -95.30

NH4Cl(s) -314.4 -202.9

a. Determine ΔSorxn for the reaction NH3(g) + HCl(g) → NH4Cl(s).

b. Will the reaction be spontaneous at high temperatures? Explain.
c. At what temperature will the reaction be in equilibrium?

2. A 94.5 g sample of an unknown hydrated magnesium sulfate compound was heated to remove all
water. The resulting weight of anhydrous magnesium sulfate was found to be 54.0 grams.
a. What is the molecular formula of the hydrated magnesium sulfate compound?
b. What is the hydrate’s molar mass? Report answer until the third decimal place.
 c. How much of the hydrate will be needed to obtain 94.5 grams of anhydrous magnesium
sulfate?
3. A 1.00 g unknown hydrocarbon containing only C, H, and O underwent combustion analysis. It
was found that 2.767 grams of CO2 and 0.396 grams of H2O were formed.
a. How many moles of oxygen are present in the sample?
b. Determine the empirical formula of the compound.
c. Given that the molecular weight of the compound is 318.33 g/mol, write the balanced
chemical equation for its combustion reaction with the smallest integer coefficient. No need
to indicate states.
4. Xylose is a sugar composed of 39.99% C, 6.73% H, and 53.28% O.
a. Find the empirical formula of xylose.
b. Find the molecular formula of xylose if its molecular weight is 150.15 g/mol.
c. Write the balanced chemical equation for the combustion of xylose.
d. A bomb calorimetry experiment is conducted using 1.183 g of xylose. If the final
temperature of calorimeter is 27.19oC from its initial temperature of 23.29oC. What is the
heat of combustion of xylose? ccal=4.278 kJ/oC
5. When ammonia is reacted with sulfuric acid, ammonium sulfate is formed.
a. Write the balanced chemical equation for the reaction above.
b. Indicate the limiting reactant if Jiro reacts 2.50 g ammonia and 3.08 g of the acid.
c. How many moles of ammonium sulfate is formed?
d. If the mass of the product formed is 3.97 g, calculate for the percent yield of the reaction.
6. Lysine, an amino acid, contains the elements C, H, O, N. Jane conducted an experiment where she
produced 3.94 g CO2 and 1.89 g H2O from 2.175 g lysine. Her lab partner, Melissa, obtained 0.436
g NH2 upon combustion of 1.873 g lysine in a separate experiment. If the molar mass of lysine is
150 g/mol, determine the empirical and molecular formula of lysine.