DIRECTORATE OF GOVERNMENT EXAMINATIONS, CHENNAI-6

HIGHER SECONDARY FIRST YEAR EXAMINATION MARCH - 2019

CHEMISTRY ANSWER KEY (NS)
NOTE:-
1. Answer written only in BLACK or BLUE should be evaluated.
2. Choose the correct answer and write with option code.
3. If one of them (option or answer) is wrong, then award zero mark only.

MAXIMUM MARKS : 70

Part - I

15×1=15

Q. Q.
A - TYPE B - TYPE
No No
1 (c) Covalent nature 1 (a) Kp< Kc

2 (a) Kp< Kc 2 (c) Covalent nature

3 (a) CaC2 3 (d) CaF2

4 (b)Stark effect 4 (a) Argon

5 (b) C6H5N+H3 5 (b)Stark effect

6 (d) (1) - (iv),(2) - (i),(3) - (ii),(4) - (iii) 6 (d) 30%

7 (c) Boyle’s Law 7 (b) H2O

8 (a) 5.6 8 (a) JK-1 mol-1

9 (d) CaF2 9 (d) (1) - (iv),(2) - (i),(3) - (ii),(4) - (iii)

10 (a) Argon 10 =

11 (b) H2O 11 (c) Boyle’s Law

12 (c) propene 12 (a) 5.6

13 (a) JK-1 mol-1 13 c) propene

14 (d) 30% 14 (a) CaC2

15 = 15 (b) C6H5N+H3

1
 Part - II

Answer any SIX questions. Question No. 24 is compulsory 6 x 2 =12

Q.
No. ANSWERS Marks

16 Pauli’s exclusion principle

“No two electrons in an atom can have the same set of 2

values of all four Quantum numbers. (or) suitable example.

17 Valency
It is equal to the total number of electrons in the valence
2
shell. .

18 Ideal gases
Gases that obey the equation PV=nRT (or) Gaseous laws
under all conditions are called Ideal gases. 2
(or)
Any relevant explanation.
19 Third law of Thermodynamics
The entropy of pure crystalline substance at absolute Zero 2
is Zero.
20 Bond length
The distance between the nuclei of the two covalently 1
bonded atoms is called bond length.
2
Determining Techniques
Spectroscopic or X-ray diffraction or Electron-diffraction
techniques. (any one) 1

21 Detection of Nitrogen by Lassaignes method

Suitable description.
(or) 2
Correct equations 4×½

22 Preparation of Alkane from Grignard reagent

+ → +
2
(or)
+ → +

2
 23 Acid rain
When the PH of rain water becomes lower than 5.6 It is
called acid rain.
(or)
Acid rain is a byproduct of various human activities that 2
emit sulphur oxides and nitrogen oxides in atmosphere.
(or)
Any suitable explanation referring sulphur and nitrogen
oxides.
24 Method of Detection of nitrogen in food and fertilizers
2
Kjeldahl Method.

Part - III

Answer any SIX questions. Question No. 33 is compulsory 6×3=18

Q.
Answers Marks
No.
25 Equivalent mass of H2SO4

molar mass of the acid

=
1
%&'()(*+ ,- *ℎ/ &)(

98
3
01&2 /34(5&6/ * 2&'' ,- 7 = 1
2

01&2 /34(5&6/ * 2&'' ,- 7 = 49 /3 <= ,1 49 1

26 Diagonal relationship
The similarity in properties existing between the diagonally
placed elements present in second and third period is 2
called “diagonally relationship”
3
Eg: Li Be B

Mg Al Si
1
any one pair
27 Preparation of Tritium
6 3
3Li + 0n1 2He
4
+1T3

28 Le Chatliers principle
Correct Definition 3

3
 29 Isotonic solutions
Two solutions having same osmotic pressure at a given
3
temperature.

30 C2H2 and CO2 have same structure

In Both of these compounds carbon undergoes ‘SP’
hybridization. So C2H2 and CO2 have same shape. 3

Linear structure only. -------------------------- (1)

31
Williamson’s synthesis

%1 + >& → + >&%1
3

32 Ca(OH)2 is used in white washing

3
In white wash due to its disinfectant nature.
33 Correct Structures for a,b and c 1+1+1
3

Part - IV
Answer All the Questions 5 × 5 = 25
Q. ANSWERS
MARKS
No.
34) (i)
a) 2 +1 + 2@ = 0
1
2@ = −2

@ = −1
5
1
D D
(ii) C = or C=
EF EG
3
(or)
b) i) Dobereiner’s triads
The atomic weight of the middle element is nearly equal
to the arithmetic mean of the atomic weights of the 2
remaining two elements
5
Example 1

ii) >& + 7 → >& 7 + (or) 7 only 2

4
35) (i) BeO is insoluble in water
a) BeO is covalent in nature, While other alkaline earth 2
metal oxides are ionic in nature

(ii) Diffusion law

The rate of diffusion (or) effusion is inversely 5
proportional to the square root of molar mass. This is 3
called diffusion. (or)
HI LJ
=K
HJ LI

(or)
b) i) Calculation of entropy change
∆TUVWXYZ
∆7NOPQRS =
[UVWXYZ 1

6008
∆7NOPQRS =
1
273 5

∆7NOPQRS = 22.007 `a <= 2,6<= ½ +½

ii) & P ⇌ & P + c 2

36) i) NH3 and HCl do not obey Henry’s law

a) NH3 and HCl reacts with solvent water (or)

3
> + ⇋ > e
+ <
5
(ii) (A) Pyramidal (or) Structure 1

(B) Trigonal Planar (or) Structure 1

(or)
b) (i) (A) Cis (or) Cis isomer 1
(B) Trans (or) Trans isomer 1

(ii) Positive Mesomeric effect 5

Correct Explanation
2
Example
1

5
37) i) (A) 2 – methyl butane 1
a) (B) 2, 2 – dimethyl propane 1

ii) Nucleophiles and Electrophiles

Nucleophiles : Correct explanation. 1 5
Example ½
Electrophiles : Correct explanation 1
Example ½
(or)
b)
Red hot Fe tube
i) (A) 3 CH ≡ CH 1
873 K

(B) g + h g g +h 1

5
(C) g g + 6 & ℎ+ i6 63 g + 6 1

Explanation only ---------------------- (½+½+½)

ii) Fractional distillation of coal tar

Any two components with correct temperature. 1+ 1

38) (i)Calculation of molecular formula

a)
mass of empirical formula
= 6(12) + 6(1) + 16
= 94 ½
Molar mass = 2 x Vapour density
= 2 x 47 ½
= 94
jRklH jlPP
= ½
mnQcop RN njqQHQrlkNRHjOkl

s
=
s ½ 5
=1
2,6/)46&1 -,1246& = @ /2t(1()&6 -,1246& ½
= 1 @ g g
= g g ½

ii) A) Benzene or Structure or formula 1

B) Bromo Benzene or Structure or formula ½
C) Cyclo hexane or structure or fourmula ½

(or)
6
b) i) Calculation of standard entropy change

∆7Hu = ∑ 7 R t1, 4)*' − ∑ 7 R 1/&)*& *' (or)

1
∆7Hu = w7rR
R
x
y − z7rR + 7RR {

∆7Hu = 213.6 − |5.74 + 205~ 1

∆7Hu = 213.6 − 210.74

5
∆7Hu = 2.86 `• <= ½+½

H2O / H+ H2 O / H+
ii) R-C ≡ N R CO NH2 R COOH

A- Amide (or) RCONH2 1

B- Carboxylic acid (or) RCOOH 1