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S I L V E R: Reaction of Silver Group Reagent Formula Color and Nature HCL

This document summarizes the reaction of silver, lead, and mercury group cations with various reagents. For silver, salts such as AgCl and AgOH are formed upon the addition of HCl and NH4OH, respectively. Lead salts produced include PbCl2, Pb(OH)2, and PbCrO4. Mercury reacts to form compounds like Hg2Cl2, HgO, and Hg2CrO4. The color and solubility of the precipitates formed in each reaction are also noted.

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230 views

S I L V E R: Reaction of Silver Group Reagent Formula Color and Nature HCL

This document summarizes the reaction of silver, lead, and mercury group cations with various reagents. For silver, salts such as AgCl and AgOH are formed upon the addition of HCl and NH4OH, respectively. Lead salts produced include PbCl2, Pb(OH)2, and PbCrO4. Mercury reacts to form compounds like Hg2Cl2, HgO, and Hg2CrO4. The color and solubility of the precipitates formed in each reaction are also noted.

Uploaded by

Pharma
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Reaction of Silver Group

Reagent Formula Color and Nature


HCL AgCl white curdy ppt to gray ppt when exposed to light
S a) boiling water   insoluble
I b) Excess
Ag(NH3)2+ or Ag(NH3)2 Cl colorless solution
NH4OH
L NH4OH AgOH white ppt
V a) excess Ag(NH3)2+ or Ag(NH3)2 OH soluble- colorless solution
NaOH AgOH to Ag2O white to brown ppt
E a) excess   insoluble
R K2CrO4 Ag2CrO4 brownish red ppt
Ag+ a) NaOH   insouble
KI AgI canary yellow ppt
a) excess   insoluble

Reagent Formula Color and Nature


HCL PbCl2 white crystal ppt
a) boiling water Aqueous Solution of PbCl2 soluble- colorless solution
L b) Excess
insoluble
NH4OH
E NH4OH Pb(OH)2 white ppt
A a) excess insoluble
NaOH Pb(OH)2 white amorphous ppt
D a) excess Pb(OH)42- or Na2PbO2 soluble-colorless solution
Pb2+ K2CrO4 PbCrO4 yellow ppt
a) NaOH Na2PbO2 soluble- yellow solution
KI PbI2 yellow ppt
a) excess insoluble

Reagent Formula Color and Nature


M HCL Hg2Cl2 white curdy ppt
a) boiling water insoluble
E b) Excess
Hg2NH2 and HgO white and black ppt
R NH4OH
NH4OH HgO.HgNH2NO3 and HgO white and black ppt
C a) excess insoluble
U NaOH Hg2O black ppt
R a) excess insoluble
K2CrO4 Hg2CrO4 orange red ppt but brownish red on boiling
Y a) NaOH insoluble
Hg22+
KI Hg2I2 greenish yellow or green ppt
a) excess Hg2I4- and HgO / K2HgI and HgO colorless solution with black ppt

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