Interactive
Interactive Example Candidate Responses
Paper 22 (May/June 2016), Question 4
Cambridge International AS & A Level
Chemistry 9701
Version 1.0
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Print Script Page 17 of 25
Select QHIGH
page HIGH Middle LOW
Your
Mark Q4 Mark scheme
(a) CH3CH2CH2COOH [1]
4(a) (CH3)2CHCOOH / CH3CH(CH3)COOH [1]
[2]
(b)(i) Two from
1. CH3CH2COOCH3 2. CH3COOCH2CH3 3.HCOOCH2CH2CH3
[max 2]
(b)(ii) icorrect acid + alcohol for either ester [1]
1. methanol + propanoic acid
4(b)(i) 2. ethanol + ethanoic acid
3. propan-1-ol + methanoic acid
(conc)H2SO4 / (conc)H3PO4 AND heat / warm / reflux; [1]
[2]
(c) Peak at 1710–1750 (for ester) due to C(=)O [1]
Peak at 1500–1680 (for X) due to C(=)C / alkene [1]
Peak at 3200–3650 (for X) due to (alcohol) O(–)H [1]
[3]
4(b)(ii) [Total: 9]
4(c)
Examiner MARK
comments SCHEME
Select
page HIGH Middle LOW
Your
Mark Q4 Mark scheme
(a) CH3CH2CH2COOH [1]
4(a) (CH3)2CHCOOH / CH3CH(CH3)COOH [1]
[2]
(b)(i) Two from
1. CH3CH2COOCH3 2. CH3COOCH2CH3 3.HCOOCH2CH2CH3
[max 2]
(b)(ii) icorrect acid + alcohol for either ester [1]
1. methanol + propanoic acid
4(b)(i) 2. ethanol + ethanoic acid
3. propan-1-ol + methanoic acid
(conc)H2SO4 / (conc)H3PO4 AND heat / warm / reflux; [1]
[2]
(c) Peak at 1710–1750 (for ester) due to C(=)O [1]
Peak at 1500–1680 (for X) due to C(=)C / alkene [1]
Peak at 3200–3650 (for X) due to (alcohol) O(–)H [1]
[3]
4(b)(ii) [Total: 9]
4(c)
Examiner MARK
comments SCHEME
Print Script Page 10 of 15
Select QMID
page HIGH Middle LOW
Your
Mark Q4 Mark scheme
(a) CH3CH2CH2COOH [1]
4(a) (CH3)2CHCOOH / CH3CH(CH3)COOH [1]
[2]
(b)(i) Two from
1. CH3CH2COOCH3 2. CH3COOCH2CH3 3.HCOOCH2CH2CH3
[max 2]
(b)(ii) icorrect acid + alcohol for either ester [1]
1. methanol + propanoic acid
4(b)(i) 2. ethanol + ethanoic acid
3. propan-1-ol + methanoic acid
(conc)H2SO4 / (conc)H3PO4 AND heat / warm / reflux; [1]
[2]
(c) Peak at 1710–1750 (for ester) due to C(=)O [1]
Peak at 1500–1680 (for X) due to C(=)C / alkene [1]
Peak at 3200–3650 (for X) due to (alcohol) O(–)H [1]
[3]
4(b)(ii) [Total: 9]
4(c)
Examiner MARK
comments SCHEME
Print Script Page 11 of 15
Select
page HIGH Middle LOW
Your
Mark Q4 Mark scheme
(a) CH3CH2CH2COOH [1]
4(a) (CH3)2CHCOOH / CH3CH(CH3)COOH [1]
[2]
(b)(i) Two from
1. CH3CH2COOCH3 2. CH3COOCH2CH3 3.HCOOCH2CH2CH3
[max 2]
(b)(ii) icorrect acid + alcohol for either ester [1]
1. methanol + propanoic acid
4(b)(i) 2. ethanol + ethanoic acid
3. propan-1-ol + methanoic acid
(conc)H2SO4 / (conc)H3PO4 AND heat / warm / reflux; [1]
[2]
(c) Peak at 1710–1750 (for ester) due to C(=)O [1]
Peak at 1500–1680 (for X) due to C(=)C / alkene [1]
Peak at 3200–3650 (for X) due to (alcohol) O(–)H [1]
[3]
4(b)(ii) [Total: 9]
4(c)
Examiner MARK
comments SCHEME
Print Script Page 10 of 17
Select QLOW
page HIGH Middle LOW
Your
Mark Q4 Mark scheme
(a) CH3CH2CH2COOH [1]
4(a) (CH3)2CHCOOH / CH3CH(CH3)COOH [1]
[2]
(b)(i) Two from
1. CH3CH2COOCH3 2. CH3COOCH2CH3 3.HCOOCH2CH2CH3
[max 2]
(b)(ii) icorrect acid + alcohol for either ester [1]
1. methanol + propanoic acid
4(b)(i) 2. ethanol + ethanoic acid
3. propan-1-ol + methanoic acid
(conc)H2SO4 / (conc)H3PO4 AND heat / warm / reflux; [1]
[2]
(c) Peak at 1710–1750 (for ester) due to C(=)O [1]
Peak at 1500–1680 (for X) due to C(=)C / alkene [1]
Peak at 3200–3650 (for X) due to (alcohol) O(–)H [1]
[3]
4(b)(ii) [Total: 9]
4(c)
Examiner MARK
comments SCHEME
Print Script Page 12 of 17
Select
page HIGH Middle LOW
Your
Mark Q4 Mark scheme
(a) CH3CH2CH2COOH [1]
4(a) (CH3)2CHCOOH / CH3CH(CH3)COOH [1]
[2]
(b)(i) Two from
1. CH3CH2COOCH3 2. CH3COOCH2CH3 3.HCOOCH2CH2CH3
[max 2]
(b)(ii) icorrect acid + alcohol for either ester [1]
1. methanol + propanoic acid
4(b)(i) 2. ethanol + ethanoic acid
3. propan-1-ol + methanoic acid
(conc)H2SO4 / (conc)H3PO4 AND heat / warm / reflux; [1]
[2]
(c) Peak at 1710–1750 (for ester) due to C(=)O [1]
Peak at 1500–1680 (for X) due to C(=)C / alkene [1]
Peak at 3200–3650 (for X) due to (alcohol) O(–)H [1]
[3]
4(b)(ii) [Total: 9]
4(c)
Examiner MARK
comments SCHEME
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