Large Stationary Diesel Engine (>600 hp)

Purpose

This spreadsheet was designed to assist with estimating the releases of NPRI substances from the diesel fuel combustion in
a large stationary diesel engine (greater than 600 horse power [hp]) . All NPRI substances, where emission factors are
available, are considered in this activity.

How to Use the Estimation Tool

By selecting the "Input Information" tab in this workbook you may enter all of the relevant data required to perform the release
estimates calculated in the following four tabs. Cells highlighted in yellow are required values. Once you have entered all the
required values you can view the generated release estimates, which will appear in red bold font, by selecting one of the
following four tabs: "Part 1 Releases", "Part 2 - 3 Releases", "Part 4 Releases", and "Part 5 Releases". Part 1 releases
include the core NPRI substances with a 10-tonne manufacture, process or otherwise use threshold, along with other
selected metal compounds with 5-kg and 50-kg thresholds. Part 2 and 3 releases include PAHs and dioxins and furans,
respectively. The Part 2 substances have an incidentally manufactured reporting threshold and Part 3 substances have an
activity based reporting threshold. Part 4 releases include the seven Criteria Air Contaminants which have release-based
thresholds. Part 5 releases include the 75 selected VOCs with additional reporting requirements, also referred to as
"speciated VOC's".

Since the NPRI reporting thresholds are for the facility as a whole the air releases calculated in this spreadsheet must be
added to the NPRI releases from other sources (air releases) and activities at the facility.

Before using the number calculated with this spreadsheet ensure that only the processes used at your facility are represented
in the respective tab. If you notice that a process has been included in the release calculation that is not present at your
facility replace the emission factor for that process with the number 0. This will remove the releases due to that process from
your release calculation.

Applicable Source Classification Code used for Emission Factor determination in the US EPA's WebFIRE database
SCC Code - 20200401
Level 1 - Internal Combustion Engines
Level 2 - Industrial
Level 3 - Large Bore Engine
Level 4 - Diesel

Sources of Information
Part 1,2,3,4,5 Substance emission factors from the US EPA WebFIRE (version December 2005) database and AP 42
Chapter 3.4
Additional Information
To maintain consistency with the NPRI reporting software, this workbook generates values to three decimal places, except for
D-F releases which are extended to six decimal places.

The spreadsheet has been populated with default emission factors, however if you have a site specific emission factor you
would prefer to use you may enter it in the emission factor column. If you choose to insert your own emission factor ensure
that the units have been converted accordingly.
The emission factors used in this spreadsheet are based on uncontrolled emissions. If you are using an emission control
device you will have to adjust the emissions calculated by this spreadsheet according to the following formula:
Controlled Emissions = Uncontrolled emission x ((100 - control efficiency)/100))

Emission factor ratings have been provided for each emission factor in the column following the emission factor units. For
more information on what these ratings mean, refer to the FAQs in the AP-42 document:
http://www.epa.gov/ttn/chief/faq/ap42faq.html#ratings
 Input Data

Enter the amount of Diesel Fuel consumed in liters or m3.

Activity Rate Units

Diesel Fuel Burned Liters
m3
0 m3
Note: 1,000 liters = 1m3

Note: This spread sheet uses a default Heating Value for Diesel Fuel of 38.184 GJ/m3. This value may be changed if a site specific value is available.

The same applies for the sulfur content of diesel, for which a default value of 0.1% (1000
ppm) can be used. This correponds with the Maximum Limits for large stationary engines
under the Sulphur in Diesel Fuel Regulations. If you are using diesel fuel purchased for on-
road vehicles, a default value of 0.0015 (15 ppm) would be appropriate. Ref:
https://www.ec.gc.ca/energie-energy/default.asp?lang=En&n=7A8F92ED-1

Heating Value 38.184 GJ/m3

Sulfur content 0.1 %
 Part 1A Substance Releases

Substance Name CAS Number Emission Factor EF* Units EF RatingActivity Rate from Input Tab
Total Release to 3 deci Units
Acetaldehyde 75-07-0 4.137E-04 kg/m 3
E 0 0.000 tonnes
Anthracene 120-12-7 2.019E-05 kg/m3 E 0 0.000 tonnes
Acrolein 107-02-8 1.294E-04 kg/m3 E 0 0.000 tonnes
Benzene 71-43-2 1.274E-02 kg/m 3
E 0 0.000 tonnes
Formaldehyde 50-00-0 1.295E-03 kg/m3 E 0 0.000 tonnes
Naphtalene 91-20-3 2.134E-03 kg/m3 E 0 0.000 tonnes
Propylene 115-07-1 4.580E-02 kg/m 3
E 0 0.000 tonnes
Toluene 108-88-3 4.613E-03 kg/m3 E 0 0.000 tonnes
Isomers of Xylene 1330-20-7 3.168E-03 kg/m 3
E 0 0.000 tonnes

* EF = Emission Factor
For the description of the EF ratings, refer to the NPRI website under Toolbox, Tool, Spreadsheet for Various Processes, Description of Emissions Factor (EF) Ratings.
 Part 2 Substance Releases

Substance Name CAS Number Emission Factor EF** Units EF RatingActivity Rate from input tabTotal Release to 3 decimals Units
Acenaphthene 83-32-9 7.683E-05 kg/m3 E 0 0.000 kg
Acenaphthylene 208-96-8 1.515E-04 kg/m3 E 0 0.000 kg
Benzo (a) anthracene 56-55-3 1.021E-05 kg/m 3
E 0 0.000 kg
Benzo (b) fluoranthene 205-99-2 1.822E-05 kg/m3 E 0 0.000 kg
Benzo (k) fluoranthene 207-08-9 1.789E-06 kg/m3 E 0 0.000 kg
Benzo (a) pyrene 50-32-8 2.109E-06 kg/m3 E 0 0.000 kg
Benzo (a) phenanthrene (Chrysene) 218-01-9 2.512E-05 kg/m3 E 0 0.000 kg
Benzo (g,h,i) perylene 191-24-2 4.564E-06 kg/m 3
E 0 0.000 kg
Dibenzo (a,h) anthracene 53-70-3 2.840E-06 kg/m3 E 0 0.000 kg
Fluoranthene 206-44-0 6.616E-05 kg/m3 E 0 0.000 kg
Fluorene 86-73-7 2.101E-04 kg/m3 E 0 0.000 kg
Indeno(1,2,3-c,d)pyrene 193-39-5 3.398E-06 kg/m3 E 0 0.000 kg
Phenanthrene 85-01-8 6.698E-04 kg/m3 E 0 0.000 kg
Pyrene 129-00-0 6.090E-05 kg/m3 E 0 0.000 kg

Part 3 Substance Releases

Substance Name CAS Number Emission Factor EF** Units EF RatingActivity Rate from input tabTotal Release Units

No Emission Factors can be found for Part 3 substances.

* No single CAS Number applies to this substance

** EF = Emission Factor
For the description of the EF ratings, refer to the NPRI website under Toolbox, Tool, Spreadsheet for Various Processes, Description of Emissions Factor (EF) Ratings.
 Part 4 Criteria Air Contaminants (CAC) Releases

Activity Rate from Total Release to 3

Substance Name CAS Number Emission Factor EF** Units EF Rating Units
Input Tab decimals
Carbon Monoxide (CO) 630-08-0 13.954 kg/m3 C 0 0.000 tonnes
Sulphur Dioxide (SO2) 7446-09-5 1.658 kg/m3 B 0 0.000 tonnes
Oxides of Nitrogen, expressed as NO2 (NOx) 11104-93-1 52.532 kg/m3 B 0 0.000 tonnes
Volatile Organic Compounds (VOCs) * 1.344 kg/m3 E 0 0.000 tonnes
Total Particulate Matter (TPM) * 1.018 kg/m3 E 0 0.000 tonnes
Particulate Matter less than or equal to 10 µm (PM10) * 0.814 kg/m 3
E 0 0.000 tonnes
Particulate Matter less than or equal to 2.5 μm (PM2.5) * 0.786 kg/m3 E 0 0.000 tonnes

* No single CAS Number applies to this substance

** EF = Emission Factor
For the description of the EF ratings, refer to the NPRI website under Toolbox, Tool, Spreadsheet for Various Processes, Description of Emissions Factor (EF) Ratings.
 Part 5 Selected Volatile Organic Compounds Releases

Substance Name CAS Number Emission Factor EF** Units EF Rating Activity Rate from Input Tab Total Release to 3 decimals Units
Benzene 71-43-2 1.274E-02 kg/m3 E 0 0.000 tonnes
Formaldehyde 50-00-0 1.295E-03 kg/m3 E 0 0.000 tonnes
Propylene 115-07-1 4.580E-02 kg/m3 E 0 0.000 tonnes
Toluene 108-88-3 4.613E-03 kg/m 3
E 0 0.000 tonnes
Isomers of Xylene 1330-20-7 3.168E-03 kg/m 3
E 0 0.000 tonnes

** EF = Emission Factor
For the description of the EF ratings, refer to the NPRI website under Toolbox, Tool, Spreadsheet for Various Processes, Description of Emissions Factor (EF) Ratings.
Document History/Histoire du document
Date/date Item/item By/Par
2/4/2009 Calculator workbook created / document créé C.S.

Reviewed EFs against AP-42 Chapter 3.4. Adjusted default value for Sulphur content
of Diesel fuel to reflect Sulphur in Diesel Fuel Regulations. / Revision de les F-E
contre AP- 42 Chapitre 3.4. Révisé la valeur implicite pour le contenu de soufre dans
2/23/2016 le carburant diesel afin de refléter le Règlement sur le soufre dans le carburant diesel. J.G.