BEHRENBRUCH, GODA 2 PHASE KR PREDIC A COMPAR OF MODIF BROOKS COREY METHOD WITH A NEW CK BASED FLOW FORMULATION SPE-101150-MS
BEHRENBRUCH, GODA 2 PHASE KR PREDIC A COMPAR OF MODIF BROOKS COREY METHOD WITH A NEW CK BASED FLOW FORMULATION SPE-101150-MS
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information contained in an abstract submitted by the author(s). Contents of the paper, as
                                                                                                   Introduction
presented, have not been reviewed by the Society of Petroleum Engineers and are subject to         Unlike conventional core analysis, involving the measurement
correction by the author(s). The material, as presented, does not necessarily reflect any
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                                                                                                   existing depositional environments and flow zone units
                                                                                                   adequately and leading to poor reservoir representation.
Abstract                                                                                               Prediction models provide a means to augment a data set
The prediction of relative permeability has been in the past                                       and to validate the latter, allowing the characterization of a
and is currently a very active research area, with theoretical,                                    reservoir. In a more abstract sense, capillary pressure and
experimental and empirical approaches under consideration.                                         statistical models for relative permeability have their own
However, it is fair to say that the complexities of relative                                       assumptions and rely purely on theory, making them less
permeability have to date eluded researchers and practitioners                                     practical. Network models may be highly plug-specific. It is
alike, in that there is no universal formulation that is able to                                   also difficult to translate results from experiments performed
predict two-phase relative permeability for the wide range of                                      on standard core material, such as Berea sandstone, to other
rock and wettability characteristics observed. This paper                                          types of reservoir rock. Purely empirical models, on the other
presents a new, generalised formulation, one that is truly                                         hand, are perhaps the most widely used in the petroleum
predictive, and compares the same with the industry standard                                       industry, but they may not be universally applicable. Finally,
– the modified Brooks-Corey (MBC) formulation.                                                     empirical models based on theoretical concepts tend to be
    The MBC formulation is perhaps the most widely used,                                           more satisfactory and may lead to greater universality(1).
practical method describing laboratory-derived relative                                                Research in the area of single-phase flow and flow zone
permeability relationships in terms of simple power functions.                                     unit identification have led to the conclusion that the
The shortcomings of this formulation are that it has no real                                       theoretical Carman-Kozeny equation(2, 3) is an ideal
predictive capability and the relative contributions due to pore                                   formulation for bridging the gap between the views of
structure components as compared to variation in wettability                                       geologists and engineers. Good results obtained in previous
cannot be resolved. The new two-phase flow formulation                                             research(4) utilizing the Carman-Kozeny (C-K) equation was
presented is based on a phenomenological approach related to                                       then the impetus for investigating two-phase flow using a
the Carman-Kozeny equation, and is able to resolve the above                                       modified C-K formulation. The modification required for a
mentioned shortcomings.                                                                            two-phase formulation involved adaptation of certain
    Included are several laboratory examples and the results of                                    parameter groups, to allow the inclusion of the second phase.
a comparison of the two formulations is presented. It is shown                                     The new model was tested using a large number of relative
how the new formulation is able to predict “the curvature” of                                      permeability data sets which were generated by service
relative permeability curves when only the endpoints are                                           laboratories, several hundred relationships, mainly for
known, duplicating observed behaviour from steady-state                                            Australian fields.
relative permeability experiments. Alternatively, if the                                               The purpose of the research described, part of a larger
endpoints can be derived, correlated or estimated with the use                                     objective, is to compare the performance of a new mechanistic
of more fundamental data, the entire prediction of relative                                        model, based on the Carman-Kozeny equation, with the
permeability is possible.                                                                          Brooks and Corey model. Before presenting results from such
    In conclusion, the formulation presented is able to predict                                    comparison, a summary of respective formulations is given,
two-phase relative permeability under steady-state conditions,                                     for the Modifed Brooks and Corey model and the new relative
not just merely fit data. The second advantage of this method                                      permeability model.
is that it is theoretically based and does not involve any fitting
2                                                                                                                         SPE 101150
The Modified Brooks and Corey Model (MBC)                           indication for a plug’s degree of homogeneity) was found to
In a previous study by the authors(5), background and               change over a narrow range of 2.3 – 3.7(8).
equations for the modified Brooks and Corey model were                  As can be seen, Corey’s original model and the Brooks and
presented and discussed. Corey’s orginal model(6), presented        Corey model have some theoretical foundation. However, the
here as in equations 1 and 2 was primarly based on laboratory       most utilized model by the petroleum industry is the so called
results.                                                            modified Brooks and Corey (MBC) model(9, 10, 11), or the
                                                                    power law model(9). This model is explicitly a function of
k ro = (S oe )                                                      relative permeability endpoints, i.e. endpoint relative
                 4
                                                             (1)
                                                                    permeability to oil at irreducible water saturation, and
                                                                    endpoint relative permeability to water at residual oil
k rg = (1 − S oe ) 1 − S oe2
                          2
                              (       )                      (2)    saturation. The model may be presented as given by equations
                                                                    7 and 8, where a linear relationship between normalized phase
                                                                    saturation and normalized relative permeability is defined on a
                         S o − S or                                 log-log plot, asuming valid relative permeability
where S oe =                                                 (3)
                         1 − S or                                   measurements.
and
                                                                                                                            n
                                                                                                    ⎛ 1 − S w − S or     ⎞ o
So:     Oil saturation
                                                                             '
                                                                    k ro = k ro (S on )n o = k ro' ⎜⎜                    ⎟⎟     (7)
Sor:    Residual oil saturation                                                                     ⎝ 1 − S wir − S or    ⎠
kro:    Relative permeability to oil
krg:    Relative permeability to gas                                                                                      n
                                                                                              ' ⎛⎜    S w − S wir      ⎞ w
Later, Brooks and Corey(7, 8) defined a general relationship that
                                                                             '
                                                                    k rw = k rw (S wn )nw = k rw ⎜                     ⎟⎟       (8)
could correlate normalized oil saturation (equation 3) to                                         ⎝ 1 − S wir − S or    ⎠
capillary pressure and entry pressure.                              where,
Pd:     Entry pressure                                               kro’:   End point relative permeability to oil normalized to
P c:    Capillary pressure                                                   absolute plug air permeability
λ:      Pore size distribution index
                                                                     krw’:   End point relative permeability to water normalized
Using λ and normalised oil saturation from equation 3, Brooks                to absolute plug air permeability
and Corey introduced another general formulation for relative
permeability determination, equations 5 and 6.                       Son:    Normalized oil saturation
influential parameter apart from saturation itself, affecting the   Quality Index (RQI), Porosity Group (PG) and Flow Zone
shape of relative permeability curves(12). Based on a review of     indicator (FZI).
an extensive data set for Australian basins, Goda and
                                                                                               k
Behrenbruch (2005) proposed a wettability matrix based on           RQI = 0.0314                                                               (11)
Corey exponents, see Table 1.                                                                φe
    While the MBC model has many good features, it suffers
from a number of shortcomings. These shortcomings may be
summarized as follows:                                                           φe
                                                                    PG =                                                                       (12)
                                                                               1 − φe
     1.   The model is a direct function of the endpoints, and
          as such biased towards endpoint data, being less
          influenced by the remaining data As such the method             ⎛  1   ⎞
          is less suitable in actually validating a particular      FZI = ⎜      ⎟                                                             (13)
          relative permeability data set.                                 ⎜ FτS ⎟
                                                                          ⎝ s gv ⎠
     2.   In case one or both endpoints are not available, the
          model fails to work properly.                             Substituting these definitions into equation 10, and taking
                                                                    logarithms, a linar relationship with unit slope results, with a
     3.   The model cannot predict a relative permeability          specific relationship defined for each separate geological
          relationship, rather it is intended to smooth and         entity, or flow zone unit, with a unique FZI index.
          extend an existing relationship.
                                                                        log RQI = log PG + log FZI                                             (14)
The Carman-Kozeny Equation for Single-Phase Flow
and the Modified Carman-Kozeny Formulation for                          While this equation was initially postulated, the validity of
Two-Phase Flow (C – K Model)                                        this equation could be confirmed by numerous studies,
The so called Carman-Kozeny equation is the result of               demonstrating the applicability of the underlying assumptions
combining the early work conducted by Kozeny (1927)(2) and          used in the establishment of the Carman-Kozeny equation. For
Carman (1937)(3), to study the problem of single phase flow.        further information, the reader is referred to publication by
Kozeny (1927) studied the dependency between permeability           Barr and Altunby (1992)(13) and Amaefule et al. (1993)(14).
and porosity. He originated the concept of a textural property,     Recent applications may be found in Behrenbruch and
correlating factors such as shape factor, tortuosity, and           Biniwale (2005)(15), and Biniwale and Behrenbruch (2004)(16).
specific surface area to permeability. Later, Carman (1937)             Most recently, a semi-empirical model to predict relative
developed the direct relationship between permeability and          permeability was established (Behrenbruch, 2006)(4). In
porosity. The Carman-Kozeny equation may be written as              principle, the model can be considered as an extension of the
follows:                                                            Carman-Kozeny equation. In other words, parameters such as
        φ e3        ⎛ 1 ⎞                                           reservoir quality index (equation 11) and porosity group
k=                  ⎜           ⎟                            (9)    (equation 12) were re-defined to allow the presence of a
     (1 − φ e ) 2   ⎜ F τ 2S 2 ⎟
                    ⎝ s      gv ⎠                                   second phase. It was found that with extended definitions of
                                                                    RQI and PG, relative permeability relationships take on the
where k is the absolute permeability in µm2 , φe is the effective   form of a straight line when plotted in the two-phase Carman-
porosity, Fs is the shape factor (2 for circular openings), τ is    Kozeny space. In final form, the model may be shown as
tortuosity and Sgv is the surface area per unit grain volume in     follows:
µm-1.
                                                                                  2 3                                               2
    While equation 9 may be used in estimating absolute                    1014 m w φe S w ⎡ S w           S wir ⎤
                                                                    k rw =                             −                                       (15)
permeability, the equation is often used to correlate properties                           ⎢                          ⎥
for a fundamental geological unit (facies). The product Fs τ2
                                                                                  k        ⎣1 − φ e S w 1 − φ e S wir ⎦
(known as Kozeny constant) is believed to be constant within
each single flow zone unit, and different from one zone to                                                                                 2
                                                                             1014 mo2 φ e3 (1 − S w ) ⎡ 1 − S w              S or ⎤            (16)
another. This aspect was further studied by Barr and Altunby        k ro =                            ⎢                  −             ⎥
(1992)(13) and later by Amaefule et al.(1993)(14), and equation                       k               ⎣1 − φ e (1 − S w ) 1 − φ e S or ⎦
1 was proposed as a modified form, as follows:
                                                                    In the above equations, mw and mo are the slopes of linear
                                                                    relationships in the Carman-Kozeny space, generally thought
             k             φ e ⎛⎜       1        ⎞
                                                 ⎟          (10)    to be representative of wettability.
0 .0314             =
           φe           (1 − φ e ) ⎜ Fs τ S gv   ⎟                      The validity of the model was tested by Behrenbruch
                                   ⎝             ⎠                  (2006)(4) using a large number of data sets, mainly for
                                                                    Australian fields. Two examples are given below (Figures 1
where 0.0314 is a conversion factor (millidarcy to µm2).            and 2). As is the case with the MBC model, the new model
Furthermore, certain terms were grouped, defining Reservoir         may also be used to calculate a new, more representative Sor
4                                                                                                                                                            SPE 101150
for a relative permeability curve. An example that compares                                       Simplifying and re-arranging equation 20:
both models in predicting a new (“true”) Sor is shown in Fig. 3
                                                                                                                                                 2
Comparison Studies                                                                                                        2 ⎛⎜1−φ ⎛⎜1−S ⎞⎟ ⎞⎟
                                                                                                  krw    ⎛    S −S      ⎞          ⎝      or ⎠ ⎠       Sw
Due to the frequent employment of the modified Brooks and                                             = ⎜⎜ w wir ⎟⎟ ⎝                                             (21)
Corey model (MBC) in smoothing and correcting relative                                             '
                                                                                                  krw ⎝    1 − S    − S
                                                                                                                 wir or ⎠          1 − S or        ⎛⎜1−φS ⎞⎟
                                                                                                                                                             2
permeability curves, this section presents a detailed                                                                                               ⎝    w ⎠
comparison study, carried out to investigate the relative
performance of both the new methodology to predict relative                                       Taking a similar approach, the equation for oil may be
permeability (equations 15 and 16, also known as the new C-K                                      derived:
relative permeability model) and the MBC model. Three
different approaches were explored. First of all, an attempt to                                                                              2
                                                                                                                         2 ⎛⎜1−φ⎛⎜1−S ⎞⎟⎞⎟
find an analytical expression that correlates both models is                                      kro    ⎛ 1− Sw − Sor ⎞              wir ⎠⎠       1−Sw
presented. In other words, the aim was to investigate the                                             = ⎜⎜             ⎟⎟ ⎝ ⎝                                (22)
possibility of finding an analytical formulation connecting no
                                                                                                   '
                                                                                                  kro ⎝ 1− Swir − Sor ⎠          1 −Swir       (1−φ(1− Sw))2
(and/or nw) with mo (and/or mw). Secondly, a comparison was
made using synthetic data. Finally, a comparison was made
using real data.                                                                                  From equations 17 and 21,
    In summary, the comparison studies investigated the
following approaches:
                                                                                                                     n −2
                                                                                                  ⎛ Sw − Swi ⎞ w
                                                                                                  ⎜⎜               ⎟⎟
                                                                                                                            (1−φ(1−Sor ))2 Sw
     1.        analytical equations                                                                                       =                                       (23)
                                                                                                   ⎝ 1− Swir − Sor ⎠            1−Sor     (1−φSw)2
     2.        noise-free data
plugs. In their paper, λ was an indication of the degree of plug   3 Comparison Study No. 3: Actual Laboratory/Field Data
heterogeneity (sorting). Hence, no and nw may be considered        In order to obtain a more comprehensive coverage, and as a
as measures of plug heterogeneity. In other words, higher          final test, the comparison between the two formulations was
values for no and nw may be due to plugs being more                extended to actual measured data on a variety of core plugs.
heterogenous (or faulty experimental procedure). Some                  Three samples, two from the Bonaparte Basin, and one
researchers have also indicated that the value of these            from the Carnarvon basin are presented here. For such
exponents may be influenced by wettability(5, 17).                 comparisons, the intermediate saturation range was fitted in
    Finally, no direct relationship could be established           case of the C-K relative permeability formulation, with the
between no (and nw) and mo (and mw).                               aim to demonstrate the ability of the new model to predict
                                                                   endpoints. For each sample, profiles are plotted on both
2. Comparison Study No. 2: Noise-Free Data                         normal and semi-log scale. It may be concluded that (see
To further show similarities and differences between the           Figures 19 through 24):
models, a number of experimental data sets were studied. In
this approach the new methodology is used to predict relative
                                                                       1.   Good agreement exists between results obtained from
permeability curves from experimental measurements. The
                                                                            the MBC and the new methodology models.
predicted curve is then believed to be accurate and may be
taken as a synthetic curve that is noise free. The Modified
                                                                       2.   Endpoint relative permeabilities predicted from the
Brooks and Corey model was then used to fit the data. Four
                                                                            new methodology demonstrate slight deviation from
different profiles were compared:
                                                                            measured values. This is not the case with MBC, as
                                                                            the latter uses endpoints as input and does not predict
    1.   Profile from the new methodology (synthetic curve).
                                                                            these.
    2.   Profile from the MBC model implementing no and nw
         as constants (conventional model, no and nw are
         obtained from a log-log plot).                            Conclusions
                                                                      1. A comparison study was conducted between a new,
    3.   Profile from the MBC model implementing nw and no               Carman-Kozeny based relative permeability model
         as constants determined by averaging nw and no,                 and the modified Brooks and Corey model. Three
         obtained from equations 23 and 24 at different                  comparisons were made: mathematical, using noise-
         saturation values.                                              free data and using actual lab/field data.
    4.   Profile from the MBC model implementing nw and no             2.   No direct relationship exists between no and nw
         as variables determined from equations 23 and 24,                  (Corey exponents) and mo and mw (characteristic
         corresponding to different saturation values.                      slopes for the new model). Also, no and nw are not
                                                                            constants in equations comparing the formulations,
                                                                            but a function of Sw. It was found that no and nw
Three examples from the Bonaparte Basin are presented. For
                                                                            change over the range 2.6 – 3.5. This range is similar
reference, Figure 6 is a location map showing major
                                                                            to the range across which λ (in the Brooks and Corey
Australian Hydrocarbon basins(18). The result for each example
                                                                            model for relative permeability) changes. This would
is shown on a cartesian plot and a semi-log plot (Figures 7
                                                                            tend to support the view that Corey exponents are a
through 18). In these figures, the “New Model” refers to the
                                                                            measure of the degree of heterogeneity of plugs,
new C-K relative permeability methodology and “MBC”
                                                                            rather than wettability.
signifies the modified Brooks and Corey model.
                                                                       3.   Other comparisons between the two models showed
   From these figures and profiles the following may be                     very good performance of the C-K model, where the
observed:                                                                   latter has the advantage of being a predictive tool,
    1. A very good match is indicated between profiles                      rather than just fitting the data.
        generated from the new methodology and the MBC
        model using average no and nw obtained from                Acknowledgments
        equations.                                                 The authors would like to gratefully acknowledge the
                                                                   sponsors: BHP Billiton, Chevron, Santos Ltd and Woodside
    2.   When using values of nw and no determined from            Energy for their financial support and permission to publish
         equations 23 and 24 at different saturations, the         their data and the presented analysis results. The Australian
         profile became identical to that of the new               Postgraduate Award, APA, granted by the Australian
         methodology, as could be expected.                        Government to the second author is also acknowledged.
6                                                                                                                                 SPE 101150
References                                                              12.   Stiles, J. H. and Hutfilz, J. M.: “The Use of Routine and Special
1.    Honarpour, M., Koederitz, L. F., and Harvey, A. H.: Relative            Core Analysis in Characterizing Brent Group Reservoirs, U. K.
      Permeability of Petroleum Reservoir, CRC Press, Inc, Boca               North Sea,” JPT, pp. 704, (June, 1992)
      Raton (1986)                                                      13.   Barr, D.C., Altunbay, M.: “Identifying hydraulic units as an aid
2.    Kozeny, J.: “Uber Kapillare Leitung des Wassers im Boden,               to quantifying depositional environments and diagenetic facies.
      Sitzungsberichte,” Royal Academy of Science, Vienna (1927)              Geology of Malaysia, Symp. Res. Eval./Form. Damage, Kuala
3.    Carman, P. C.: “Fluid Flow Through Granular Beds,” AIChE                Lumpur, Malaysia, (1992)
      (1937) 15, 150                                                    14.   Amaefule, J.O., Altunbay, M., Tiab, D., Kersey, D.G., Keelan,
4.    Behrenbruch, P.: “Two-Phase Relative Permeability Prediction:           D.K.:Enhanced reservoir description: using core and log data to
      A New Semi-Empirical Model Based on a Modified Carman-                  identify hydraulic (flow) units and predict permeability in
      Kozeny Equation.”, to be published                                      uncored intervals/wells. SPE 26436, presented at the Annu.
5.    Goda, H. and Behrenbruch, P.: ”Using a modified Brooks-                 Tech. Conf. Exhib., Houston, Tex. (1993)
      Corey Model to Study Oil-Water Relative Permeability for          15.   Behrenbruch, P. and Biniwale, S.: “Two-Phase Relative
      Diverse Pore Structures,” SPE 88538, presented at the SPE               Permeability Prediction: A New Semi-Empirical Model Based
      Asia-Pacific Annual Technical Conference and Exhibition,                on a Modified Carman-Kozeny Equation.” Journal of
      Perth, Australia, 18 – 20 Oct, (2004)                                   Petroleum Science andEngineering, Vol. (47), pp. 175 – 196,
6.    Corey, A.T.: “The Interrelation Between Gas and Oil Relative            (2005)
      Permeability,” Producers Monthly (1954)                           16.   Biniwale, S. and Behrenbruch P.:”The Mapping of Hydraulic
7.    Brooks, R. H., and Corey, A. T.: “Hydraulic Properties of               Flow Zone Units and Characterization of Australian Geological
      Porous Media,” Hydrology Papers, Colorado State University,             Depositional Environments,” SPE 88521, to be presented at
      Colorado (1964)                                                         The Asia Pacific Oil and Gas Conference and Exhibition, Perth,
8.    Brooks, R. H., and Corey, A. T.: “Properties of Porous Media            Australia, Oct. 18 –20, (2004)
      Affecting Fluid Flow,” Journal of Irrigation and Drainage         17.   Stiles, J.: “Using Special Core Analysis in Reservoir
      Division, (June 1966) 61.                                               Engineering – Relative Permeability & Capillary Pressure,”
9.    Lake, L. W.: Enhanced Oil Recovery, Chapter 3, Prentice Hall,           Course Notes, England, (1994)
      Inc. (1989)                                                       18.   Ruth, P. V.: “Overpressure in the Cooper and Carnarvon
10.   Embid, S. M.: “Modelling Capillary Pressure and Relative                Basins, Australia,” PhD Dissertation, the University of
      Permeability for Systems with Heterogeneous Wettability,”               Adelaide, Australia, (2003).
      Ph.D. Dissertation, The University of Texas at Austin (1997)
11.   Alpak, F. O., Lake, L. W. and Embid, S. M.: “ Validation of a
      Modified Carman-Kozeny Equation to Model Two-Phase
      Relative Permeability,” SPE 56479, Presented at the Annual
      Technical Conference and Exhibition, Texas, Oct. 3 – 6 (1999)
Table 1: Corey Exponents Matrix for Wettability – after Goda and Behrenbruch (2004)
Porosity (φ) 5 35
                   1.0
                                kro (measured)                                           kabs = 5.07 md
                   0.9
                                krw (measured)                                           φ = 15.1%
                   0.8          kro (predicted)                                          Swir = 45.1%
                   0.7          krw (predicted)                                          kom = 2.72 md
                                                                                         Sor = 14.1%
                   0.6
                   0.5
              kr
                   0.4
                   0.3
                   0.2
                   0.1
                   0.0
                         0.0    0.1      0.2      0.3    0.4    0.5        0.6    0.7    0.8    0.9       1.0
                                                                Sw
                   1.0
                                                         kro (measured)                  kabs = 481 md
                   0.9
                                                         krw (measured)                  φ = 17.4%
                   0.8
                                                         kro (predicted)                 Swir = 12.2%
                   0.7
                                                         krw (predicted)                 kom = 384 md
                   0.6
                                                                                         Sor = 22.7%
                   0.5
              kr
                   0.4
                   0.3
                   0.2
                   0.1
                   0.0
                          0.0     0.1      0.2     0.3    0.4    0.5        0.6    0.7    0.8     0.9      1.0
                                                                Sw
                                                          Sw
                  0.0   0.1       0.2     0.3      0.4        0.5     0.6      0.7     0.8   0.9       1.0
              1
          0.1
    kr
0.01
                                                krw (MBC)
       0.001                                    kro (MBC)
                                                krw (New Model)
                                                kro (New Model)
                                                krw (Experimental Data)
                                                kro (Experimental Data)
     0.0001
Fig. 3: “True” Sor Estimated from MBC and the New Model
          4
     no
          1
              1               2            3              4              5             6           7
                                                         nw
                   7
                           Results obtained for the range specified
                           Results for porosity = 0.0
                   6       Results for porosity = 1.0
                   4
             no
                   1
                       1        2           3           4         5           6       7          8         9
                                                                 nw
              Fig. 5: Range of Distribution for no and nw as Obtained from Equations 23 and 24 for Porosity = 0.0 and
                      Porosity = 1.0
                                                                                ga
                                                                              an
                                                                            om
                                                                          Er
                                                                              COOPER
                                                                              BASIN
             1.0
                                              kabs = 1411 md                krw (new Model)
             0.9                                                            kro (new Model)
                                              φ = 15.7%
                                                                            krw (MBC)
             0.8                              Swir = 10.2%                  kro (MBC)
                                              kom = 1091 md                 krw (Average nw )(Eq. 4.34))
             0.7                                                            kro (Average no )(Eq. 4.35))
                                              Sor = 22.6%
             0.6
        kr
0.5
0.4
0.3
0.2
0.1
             0.0
                0.0        0.1       0.2      0.3       0.4       0.5        0.6     0.7       0.8       0.9      1.0
                                                              Sw
     Fig. 7: Synthetic Data: Comparison between Different Profiles for Sample 1 – Bonaparte Basin (Normal Scale, Average
             no and nw)
                                                                 Sw
                     0.0       0.1      0.2      0.3       0.4        0.5     0.6     0.7       0.8      0.9      1.0
          1.0E +00
          1.0E -01
                                                                                              kabs = 1411 md
                                                                                              φ = 15.7%
          1.0E -02                                                                            Swir = 10.2%
     kr
                                                                                              kom = 1091 md
                                                                                              Sor = 22.6%
          1.0E -03
                                               krw (new Model)
                                               krok(new
                                                   rw (new  methodology)
                                                          Model)
                                                  k
                                               krw ro (new
                                                   (MBC)    methodology)
          1.0E -04                                k   (MBC)
                                               kro (MBC)
                                                   rw
     Fig. 8: Synthetic Data: Comparison between Different Profiles for Sample 1 – Bonaparte Basin (Semi-log Scale,
             Average no and nw)
SPE 101150                                                                                                                            11
                   1.0
                                                      kabs = 1411 md                krw (new Model)
                   0.9                                                              kro (new Model)
                                                      φ = 15.7%
                                                                                    krw (MBC)
                   0.8                                Swir = 10.2%
                                                                                    kro (MBC)
                                                      kom = 1091 md                 krw (Varying nw )(Eq. 4.34))
                   0.7
                                                      Sor = 22.6%                   kro (Varying no )(Eq. 4.35))
                   0.6
              kr
0.5
0.4
0.3
0.2
0.1
                   0.0
                         0.0     0.1       0.2       0.3       0.4       0.5       0.6       0.7       0.8       0.9        1.0
                                                                         Sw
             Fig. 9: Synthetic Data: Comparison between Different Profiles for Sample 1 – Bonaparte Basin (Normal Scale, Varying no
                     and nw)
Sw
                           0.0      0.1       0.2      0.3       0.4       0.5       0.6       0.7      0.8       0.9       1.0
             1.0E +00
1.0E -01
                                                                                                        kabs = 1411 md
              1.0E -02
                                                                                                        φ = 15.7%
        kr
                                                                                                        Swir = 10.2%
                                                                                                        kom = 1091 md
              1.0E -03
                                                                                                        Sor = 22.6%
                                                      krw (new Model)
                                                      kro (new Model)
              1.0E -04                                krw (MBC)
                                                      kro (MBC)
                                                      krw (Varying nw)(Eq. 4.34))
                                                      kro (Varying no )(Eq. 4.35))
              1.0E -05
       Fig. 10: Synthetic Data: Comparison between Different Profiles for Sample 1 – Bonaparte Basin (Semi-log Scale, Varying
               no and nw)
12                                                                                                                          SPE 101150
             1.0
                                           kabs = 1345 md                       krw (new Model)
             0.9                                                                kro (new Model)
                                           φ = 15.3%
                                                                                krw (MBC)
             0.8                           Swir = 9.6%
                                                                                kro (MBC)
                                           kom = 719 md                         krw (Average nw )(Eq. 4.34))
             0.7
                                           Sor = 19.8%                          kro (Average no )(Eq. 4.35))
             0.6
             0.5
       kr
             0.4
             0.3
             0.2
             0.1
             0.0
                0.0        0.1       0.2         0.3      0.4        0.5         0.6    0.7      0.8       0.9        1.0
                                                                     Sw
     Fig. 11: Synthetic Data: Comparison between Different Profiles for Sample 2 – Bonaparte Basin (Normal Scale, Average no
             and nw)
                                                                     Sw
                        0.0      0.1       0.2      0.3        0.4        0.5     0.6    0.7     0.8       0.9      1.0
            1.0E+00
1.0E-01
1.0E-02
             1.0E-03
        kr
1.0E-04
             1.0E-05
                                                 kabs = 1345 md                  krw (new Model)
                                                 φ = 15.3%                       kro (new Model)
             1.0E-06                                                             krw (MBC)
                                                 Swir = 9.6%
                                                                                 kro (MBC)
             1.0E-07                             kom = 719 md                    krw (Average nw)(Eq. 4.34))
                                                 Sor = 19.8%                     kro (Average no )(Eq. 4.35))
             1.0E-08
        Fig. 12: Synthetic Data: Comparison between Different Profiles for Sample 2 – Bonaparte Basin (Semi-log Scale,
                  Average no and nw)
SPE 101150                                                                                                                     13
                  1.0
                                                  kabs = 1345 md                  krw (new Model)
                  0.9                                                             kro (new Model)
                                                  φ = 15.3%
                                                                                  krw (MBC)
                  0.8                             Swir = 9.6%
                                                                                  kro (MBC)
                  0.7                             kom = 719 md                    krw (Varying nw) (Eq. 4.34))
                                                  Sor = 19.8%                     kro (Varying no)(Eq. 4.35))
                  0.6
                  0.5
         kr
                  0.4
                  0.3
                  0.2
                  0.1
                  0.0
                     0.0       0.1       0.2      0.3         0.4         0.5     0.6     0.7       0.8       0.9       1.0
                                                                          Sw
        Fig. 13: Synthetic Data: Comparison between Different Profiles for Sample 2 – Bonaparte Basin (Normal Scale, Varying
                  no and nw)
                                                                      Sw
                             0.0      0.1      0.2      0.3         0.4     0.5     0.6     0.7      0.8       0.9      1.0
                  1.0E+00
1.0E-01
1.0E-02
                  1.0E-03
             kr
                  1.0E-04
                                                     kabs = 1345 md               krw (new Model)
                  1.0E-05                            φ = 15.3%                    kro (new Model)
                                                     Swir = 9.6%                  krw (MBC)
                                                                                  kro (MBC)
                  1.0E-06                            kom = 719 md
                                                                                  krw (Varying nw)(Eq. 4.34))
                                                     Sor = 19.8%                  kro (Varying no )(Eq. 4.35))
                  1.0E-07
             Fig. 14: Synthetic Data: Comparison between Different Profiles for Sample 2 – Bonaparte Basin (Semi-log Scale,
                      Varying no and nw)
14                                                                                                                     SPE 101150
            1.0
                                                       kabs = 557 md              krw (new Model)
            0.9                                        φ = 16.6%                  kro (new Model)
                                                       Swir = 18.7%               krw (MBC)
            0.8                                                                   kro (MBC)
                                                       kom = 477 md               krw (Average nw )(Eq. 4.34))
            0.7
                                                       Sor = 18.9%                kro (Average no)(Eq. 4.35))
            0.6
            0.5
       kr
0.4
0.3
0.2
0.1
            0.0
                  0.0         0.1         0.2         0.3     0.4      0.5        0.6    0.7    0.8    0.9       1.0
                                                                       Sw
     Fig. 15: Synthetic Data: Comparison between Different Profiles for Sample 3 – Bonaparte Basin (Normal Scale,
              Average no and nw)
                                                                       Sw
                        0.0         0.1         0.2     0.3      0.4        0.5    0.6    0.7    0.8   0.9       1.0
        1.00E+00
          1.00E-01
                              kabs = 557 md
          1.00E-02            φ = 16.6%
                              Swir = 18.7%
          1.00E-03            kom = 477 md
     kr
                              Sor = 18.9%
          1.00E-04
                                                              krw (new Model)
          1.00E-05                                            kro (new Model)
                                                              krw (MBC)
          1.00E-06                                            kro (MBC)
                                                              krw (Average nw )(Eq. 4.34))
                                                              kro (Average no )(Eq. 4.35))
          1.00E-07
      Fig. 16: Synthetic Data: Comparison between Different Profiles for Sample 3 – Bonaparte Basin (Semi-Log Scale,
               Average no and nw)
SPE 101150                                                                                                                       15
             1.0
                                                    kabs = 557 md               krw (new Model)
             0.9                                    φ = 16.6%                   kro (new Model)
                                                                                krw (MBC)
             0.8                                    Swir = 18.7%
                                                                                kro (MBC)
                                                    kom = 477 md                krw (Varying nw)(Eq. 4.34))
             0.7
                                                    Sor = 18.9%                 kro (Varying no)(Eq. 4.35))
             0.6
             0.5
       kr
0.4
0.3
0.2
0.1
             0.0
                   0.0      0.1       0.2       0.3         0.4      0.5        0.6       0.7       0.8       0.9       1.0
                                                                     Sw
       Fig. 17: Synthetic Data: Comparison between Different Profiles for Sample 3 – Bonaparte Basin (Normal Scale, Varying no
               and nw)
                                                                     Sw
                          0.0      0.1       0.2      0.3      0.4        0.5     0.6      0.7      0.8      0.9       1.0
             1.00E+00
              1.00E-01
                                kabs = 557 md
                                φ = 16.6%
              1.00E-02
                                Swir = 18.7%
                                kom = 477 md
              1.00E-03
         kr
Sor = 18.9%
        Fig. 18: Synthetic Data: Comparison between Different Profiles for Sample 3 – Bonaparte Basin (Semi-Log Scale, Varying
                no and nw)
16                                                                                                                   SPE 101150
               1
                                                         kabs = 1345 md             kro (measured)
             0.9                                                                    krw (measured)
                                                         φ = 15.3%
             0.8                                         Swir = 9.6%
                                                                                    kro (MBC)
                                                                                    krw (MBC)
             0.7                                         kom = 719 md
                                                                                    kro (New Model)
                                                         Sor = 19.8%
             0.6                                                                    krw (New Model)
             0.5
       kr
0.4
             0.3
             0.2
             0.1
               0
                   0       0.1         0.2     0.3     0.4       0.5       0.6     0.7       0.8      0.9        1
                                                                Sw
        Fig. 19: Real Data: Comparison between New Model and MBC for Sample 1 – Bonaparte Basin (Normal Scale)
                                                                Sw
                       0         0.1     0.2     0.3      0.4        0.5    0.6      0.7      0.8      0.9       1
         1.00E+00
          1.00E-01
     kr
          1.00E-02
                                                         kro (measured)
                           kabs = 1345 md                krw (measured)
          1.00E-03         φ = 15.3%                     kro (MBC)
                           Swir = 9.6%                   krw (MBC)
                           kom = 719 md                  kro (New Model)
                           Sor = 19.8%                   krw (New Model)
          1.00E-04
     Fig. 20: Real Data: Comparison between New Model and MBC for Sample 1 – Bonaparte Basin (Semi-Log Scale)
SPE 101150                                                                                                            17
                   1
                                                kro (measured)                 kabs = 1411 md
                  0.9
                                                krw (measured)                 φ = 15.7%
                  0.8                           kro (MBC)                      Swir = 10.2%
                  0.7                           krw (MBC)                      kom = 1091 md
                                                kro (New Model)
                  0.6                                                          Sor = 22.6%
                                                krw (New Model)
                  0.5
             kr
                  0.4
                  0.3
                  0.2
                  0.1
                   0
                        0       0.1     0.2      0.3      0.4       0.5      0.6       0.7      0.8      0.9      1
                                                                   Sw
        Fig. 21: Real Data: Comparison between New Model and MBC for Sample 2 – Bonaparte Basin (Normal Scale)
                                                                  Sw
                            0     0.1     0.2      0.3      0.4        0.5     0.6     0.7       0.8      0.9     1
             1.00E+00
             1.00E-01
       kr
             1.00E-02
                                                         kro (measured)
                                                                                               kabs = 1411 md
                                                         krw (measured)
                                                         kro (MBC)                             φ = 15.7%
             1.00E-03
                                                         krw (MBC)                             Swir = 10.2%
                                                         kro (New Model)                       kom = 1091 md
                                                         krw (New Model)                       Sor = 22.6%
             1.00E-04
       Fig. 22: Real Data: Comparison between New Model and MBC for Sample 2 – Bonaparte Basin (Semi-Log Scale)
18                                                                                                                  SPE 101150
             1
                                                       kabs = 2.92 md                kro (measured)
           0.9
                                                       φ = 26.0%                     krw (measured)
           0.8                                         Swir = 66.1%
                                                                                     kro (MBC)
                                                                                     krw (MBC)
           0.7                                         kom = 1.2 md
                                                                                     kro (New Model)
                                                       Sor = 12.6%
           0.6                                                                       krw (New Model)
     kr
           0.5
           0.4
           0.3
           0.2
           0.1
             0
                 0         0.1     0.2         0.3         0.4     0.5      0.6      0.7     0.8      0.9       1
                                                                   Sw
     Fig. 23: Real Data: Comparison between New Model and MBC for Sample 1 – Carnarvon Basin (Normal Scale)
Sw
          1.00E-01
     kr
1.00E-02