SAFETY DATA SHEET

INTERNATIONAL FLAVORS & FRAGRANCES

Product EVYCLASS

Print Date 13.12.2013 Page 1 (12)

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name : EVYCLASS

IFF Code : SD104762

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture : Fragrance for consumer product
1.3 Details of the supplier of the safety data sheet
Company : IFF (NEDERLAND) BV
ZEVENHEUVELENWEG 60
5048 AN TILBURG
Telephone : +31134642211
Telefax : +31134636032
E-mail address : [email protected]
Responsible/issuing person
1.4 Emergency telephone number
+31 13 4642 211

2. Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Skin sensitization, Category 1 H317: May cause an allergic skin reaction.
Aspiration hazard, Category 1 H304: May be fatal if swallowed and enters airways.
Chronic aquatic toxicity, Category 2 H411: Toxic to aquatic life with long lasting effects.
Classification (67/548/EEC, 1999/45/EC)
Harmful R65: Harmful: may cause lung damage if swallowed.
Sensitising R43: May cause sensitization by skin contact.
Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-
term adverse effects in the aquatic environment.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :

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Signal word : Danger

Hazard statements : H304 May be fatal if swallowed and enters airways.

H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements : Prevention:

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/
spray.
P273 Avoid release to the environment.
P280 Wear protective gloves.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical
advice/ attention.

Hazardous components which must be listed on the label:

 586-62-9 p-mentha-1,4(8)-diene
 138-86-3 limonene

2.3 Other hazards

None reasonably foreseeable.

3. Composition/information on ingredients
3.1 Substances
Not applicable, product is a mixture.
3.2 Mixtures
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION (EC) [%]
Registration number No 1272/2008)
p-mentha-1,4(8)-diene 586-62-9 R10 Asp. Tox.1; H304 25 - 50
209-578-0 N; R51/53 Aquatic Chronic2; H411
01-2119982324-34 Xn; R65 Flam. Liq.3; H226

3a,4,5,6,7,7a-hexahydro-4,7- 54830-99-8 R52/53 Aquatic Chronic3; H412 2,5 - 10

methano-1H-indenyl acetate 911-369-0

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01-2119488219-26

limonene 138-86-3 R10 Flam. Liq.3; H226 5 - 10

601-029-00-7 Xi; R38 Skin Sens.1B; H317
R43 Aquatic Chronic1; H410
N; R50/53 Skin Irrit.2; H315
Asp. Tox.1; H304
Aquatic Acute1; H400

4-tert-butylcyclohexyl 32210-23-4 N; R51/53 Aquatic Chronic2; H411 2,5 - 10

acetate 250-954-9
01-2119976286-24

2-tert-butylcyclohexyl 88-41-5 N; R51/53 Aquatic Chronic2; H411 0,25 - 2,5

acetate 201-828-7
01-2119970713-33

1,3,4,6,7,8-hexahydro- 1222-05-5 N; R50/53 Aquatic Acute1; H400 0,25 - 2,5

4,6,6,7,8,8- 214-946-9 Aquatic Chronic1; H410
hexamethylindeno[5,6- 01-2119488227-29
c]pyran
hexyl acetate 142-92-7 R10 Aquatic Chronic2; H411 0,25 - 2,5
205-572-7 N; R51/53 Flam. Liq.3; H226

cinnamyl alcohol 104-54-1 R43 Skin Sens.1B; H317 0,1 - 1

203-212-3

diphenyl ether 101-84-8 N; R51/53 Aquatic Chronic2; H411 0,25 - 2,5

202-981-2 Xi; R36

dodecanal 112-54-9 N; R51/53 Skin Irrit.2; H315 0,25 - 1

203-983-6 Xi; R38 Aquatic Chronic2; H411

3,4,5,6,6-pentamethyl-2- 87118-95-4, 862107- N; R51/53 Aquatic Chronic2; H411 0,25 - 2,5

heptanol 86-6
401-030-0
01-0000015093-78

3-methyl-4-(2,6,6-trimethyl- 127-51-5 R43 Skin Sens.1B; H317 0,1 - 0,25

2-cyclohexen-1-yl)-3-buten- 204-846-3 N; R51/53 Aquatic Chronic2; H411
2-one Xi; R36/38 Skin Irrit.2; H315

For the full text of the R-phrases mentioned in this Section, see Section 16.

Components with workplace control parameters

Components EC-No. Concentration [%]
limonene 601-029-00-7 0 - 10
diethyl phthalate 201-550-6 0 - 10

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benzyl acetate 205-399-7 0 - 10

4. First aid measures

4.1 Description of first aid measures
General advice : Take Risk and Safety phrases (section 15) into account.

If inhaled : Remove from exposure site to fresh air and keep at rest. Obtain
medical advice.

In case of skin contact : Remove contaminated clothes. Wash thoroughly with water (and
soap). Contact physician if symptoms persist.

In case of eye contact : Flush immediately with water for at least 15 minutes. Contact
physician if symptoms persist.

If swallowed : Rinse mouth with water and obtain medical advice.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.

Risks : No information available.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No information available.

5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Carbondioxide, dry chemical, foam.

Unsuitable extinguishing media : Do not use a direct waterjet on burning material.

5.2 Special hazards arising from the substance or mixture

Specific hazards during : Water may be ineffective.
firefighting
5.3 Advice for firefighters
Further information : Standard procedure for chemical fires.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

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Personal precautions : Avoid inhalation and contact with skin and eyes. A self-contained
breathing apparatus is recommended in case of a major spill.

6.2 Environmental precautions

Environmental precautions : Keep away from drains, surface- and groundwater and soil.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Clean up spillage promptly. Remove ignition sources. Provide
adequate ventilation. Avoid excessive inhalation of vapours. Gross
spillages should be contained by use of sand or inert powder and
disposed of according to the local regulations.

6.4 Reference to other sections

Prevent spreading over a wide area (e.g. by containment or oil barriers).
7. Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : Avoid excessive inhalation of concentrated vapors. Follow good
manufacturing practices for housekeeping and personal hygiene.
Wash any exposed skin immediately after any chemical contact,
before breaks and meals, and at the end of each work period.
Contaminated clothing and shoes should be thoroughly cleaned
before re-use.

If appropriate, procedures used during the handling of this material

should also be used when cleaning equipment or removing residual
chemicals from tanks or other containers, especially when steam or
hot water is used, as this may increase vapor concentrations in the
workplace air. Where chemicals are openly handled, access should
be restricted to properly trained employees.
Keep all heated processes at the lowest necessary temperature in
order to minimize emissions of volatile chemicals into the air.

Advice on protection against : Keep away from ignition sources and naked flame.
fire and explosion
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas : Store in a cool, dry, ventilated area away from heat sources. Keep
and containers containers upright and tightly closed when not in use.

7.3 Specific end uses

Specific use(s) : No information available.

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8. Exposure controls/personal protection

8.1 Control parameters
Components with workplace control parameters
Components EC-No. Exposure limit(s)
limonene 601-029-00-7 STEL 50 ppm 300 mg/m3
TWA 25 ppm 140 mg/m3
diethyl phthalate 201-550-6 STEL 5 mg/m3
TWA 0,5 mg/m3
benzyl acetate 205-399-7 TWA 10 ppm

8.2 Exposure controls

Engineering measures
Where appropriate, use closed systems to transfer and process this material.
If appropriate, isolate mixing rooms and other areas where this material is used or openly handled. Maintain
these areas under negative air pressure relative to the rest of the plant.

Personal protective equipment

Respiratory protection : Use local exhaust ventilation around open tanks and other open
sources of potential exposures in order to avoid excessive inhalation,
including places where this material is openly weighed or measured.
In addition, use general dilution ventilation of the work area to
eliminate or reduce possible worker exposures.
No respiratory protection is required during normal operations in a
workplace where engineering controls such as adequate ventilation,
etc. are sufficient.

If engineering controls and safe work practices are not sufficient, an

approved, properly fitted respirator with organic vapor cartridges or
canisters and particulate filters should be used:

a)while engineering controls and appropriate safe work practices

and/or procedures are being implemented; or
b)during short term maintenance procedures when engineering
controls are not in normal operation or are not sufficient; or
c)if normal operational workplace vapor concentration in the air is
increased due to heat ;
d)during emergencies; or
e)if engineering controls and operational practices are not sufficient
to reduce airborne concentrations below an established occupational
exposure limit.

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Hand protection : Avoid skin contact. Use chemically resistant gloves.

Eye protection : Use tight-fitting goggles, face shield or safety glasses with side
shields if eye contact might occur.

Hygiene measures : To the extent deemed appropriate, implement pre-placement and

regularly scheduled ascertainment of symptoms and spirometry
testing of lung function for workers who are regularly exposed to
this material.
To the extent deemed appropriate, use an experienced air sampling
expert to identify and measure volatile chemicals that could be
present in the workplace air to determine potential exposures and to
ensure the continuing effectiveness of engineering controls and
operational practices to minimize exposure.

Environmental exposure controls

General advice : Keep away from drains, surface- and groundwater and soil.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance : liquid
Odour : conforms to standard
Odour Threshold : not determined
Flash point : 64 °C
Lower explosion limit : not determined
Upper explosion limit : not determined
Flammability (solid, gas) : not determined
Oxidizing properties : not determined
Autoignition temperature : not determined
pH : not determined
Melting point : not determined
Boiling point : not determined
Vapour pressure : 0,36 hPa Calculated

Density : not determined

Water solubility : not determined
Partition coefficient: n- : not determined
octanol/water
Solubility in other solvents : not determined
Viscosity, dynamic : not determined
Viscosity, kinematic : not determined
Relative vapour density : not determined
Evaporation rate : not determined

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9.2 Other information

Refractive index : not determined
Relative density : 0,9430 - 0,9530
10. Stability and reactivity
10.1 Reactivity
No hazards to be specially mentioned.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Note: Presents no significant reactivity hazard, by itself or in contact
with water. Avoid contact with strong acids, alkali or oxidizing
agents.

10.4 Conditions to avoid

Conditions to avoid : Direct sources of heat.

10.5 Incompatible materials

Materials to avoid : Avoid contact with strong acids, alkali or oxidizing agents.

10.6 Hazardous decomposition products

Hazardous decomposition : Carbon monoxide and unidentified organic compounds may be
products formed during combustion.

11. Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Skin corrosion/irritation
limonene : Species: rabbit
Result: Skin irritation
Exposure time: 4 h
Test substance:(undiluted)

Serious eye damage/eye irritation

No lead substance

Respiratory or skin sensitization

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limonene : LLNA
Species: mouse
Result: Causes sensitization.
Test substance: 22% in ethanol/DEP (75:25)

Germ cell mutagenicity

Information on ingredients with chronic toxicity hazard(s) is available upon request.

Carcinogenicity
Information on ingredients with chronic toxicity hazard(s) is available upon request.

Reproductive toxicity
Information on ingredients with chronic toxicity hazard(s) is available upon request.

Target Organ Systemic Toxicant - Single exposure

Information on ingredients with chronic toxicity hazard(s) is available upon request.

Target Organ Systemic Toxicant - Repeated exposure

Information on ingredients with chronic toxicity hazard(s) is available upon request.

Aspiration hazard
No test data available. Ingredients with an aspiration hazard are identified in section 3.

12. Ecological information

12.1 Toxicity
Toxicity to fish
limonene :
Remarks:
no data available

M-Factor
dipentene : 1
12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

Mobility : no data available

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12.5 Results of PBT and vPvB assessment

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)., This product
contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

12.6 Other adverse effects

Additional ecological : There is no data available for this product.
information
13. Disposal considerations
13.1 Waste treatment methods
Product : Dispose of according to local regulations. Avoid disposing into
drainage systems and into the environment.

Contaminated packaging : Empty containers should be taken to an approved waste handling

site for recycling or disposal.

14. Transport information

ADR
UN number : 3082
Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(D-LIMONENE)
Labels : 9
Packing group : III
Environmentally hazardous : yes

IATA
UN number : 3082
Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(D-LIMONENE)
Labels : 9
Packing group : III
Environmentally hazardous : yes

IMDG
UN number : 3082
Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(D-LIMONENE)
Labels : 9
Packing group : III
Marine pollutant : yes

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Special precautions for : No special precautions required.

user

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Labelling — EU Directives 67/548/EEC or 1999/45/EC—
Symbol(s) : Xn Harmful
N Dangerous for the environment

R-phrase(s) : R43 May cause sensitization by skin contact.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.

S-phrase(s) : S24 Avoid contact with skin.

S37 Wear suitable gloves.
S61 Avoid release to the environment. Refer to special instructions/
Safety data sheets.
S62 If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.

Water contaminating class : WGK 3 highly water endangering

(Germany)
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has not been carried out for this product.

16. Other information

Full text of R-phrases referred to under sections 2 and 3
R10 Flammable.
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 Harmful: may cause lung damage if swallowed.

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Full text of H-Statements referred to under sections 2 and 3.

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Further information
In December 2003, the National Institute for Occupational Safety and Health ("NIOSH") published an Alert
on preventing lung disease in workers who use or make flavorings [NIOSH Publication Number 2004-110].
In August 2004 (Updated in 2012), the United States Flavor and Extract Manufacturers Association (FEMA)
issued a report entitled "Respiratory Safety in the Flavor Manufacturing Workplace".
Both of these reports provide recommendations for reducing employee exposure and for medical surveillance
in the workplace. The recommendations in these reports are generally applicable to the use of any chemical in
the workplace and you are strongly urged to review both of these reports.
The report published by FEMA also contains a list of "high priority" chemicals. If any of these chemicals are
present in this product at a concentration >= 1.0% due to an intentional addition by IFF, the chemical(s) will
be identified in this safety data sheet.

According to Regulation (EC) No. 1907/2006 the information in this safety data sheet is based on the properties
of the material known to IFF at the time the data sheet was issued. The safety data sheet is intended to provide
information for a health and safety assessment of the material and the circumstances, under which it is packaged,
stored or applied in the workplace. For such a safety assessment International Flavors & Fragrances holds no
responsibility. This document is not intended for quality assurance purposes.

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