MONSTER CONFIDENTIAL* (SULIT*) AYSE: Fen MAAK MAJLISPEPERIS A ANI. ANSI al ie A AAIESPEPERIRS A 4 UAILISPEPERINS- MATLISPEPERIC: Ae SILISPEPERIK TILISPEPERIBSA. AT HISPEPERIKS: MWe Ue We Ie MW ML. 3 AILISPEPL WLS N; MALE MAL UIs MAJLISPRPERT 4 4 A ai a 4 A 4 4 4 MA/LISPEPERIKS: i vA VAILSPEPERIRSAA SS aN ee eee Ai CHEMISTRY (KIMIA) /LISPEPERIKSAA, ALA) SIA HE aie careers ed UA HU PAPERS 2 (ERAS 2) UA: ne and a half hours (Satu jam setengah) #///: ALA) MAJLISPEPERIA SAILISPEPERIKSAANMALA YSIAMAJLISPEPERIK. ALAYS MAJLIS PEPERIKSAAN MALAYSIA (MALAYSIAN EXAMINATIONS COUNCIL) SIJIL TINGGI PERSEKOLAHAN MALAYSIA (MALAYSIA HIGHER SCHOOL CERTIFICATE) Instructions to candidates: DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE ALLOWED TO DO SO. Answer all questions in Section A, Answer all questions in Seétion B. Answer two questions only in Section C. All working should be shown. For numerical answers, units should be quoted wherever appropriate, Answers may be written either in English or Malay. Fill in your personal details on page 1. Arahan kepada calon: JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT DEMIKIAN. Jawab semua soalan dalam Bahagian A. Jawab semua soalan dalam Bahagian B. Jawab dua soalan sahaja dalam Bahagian C. Semua kerja hendaklah ditunjukkan. Bagi jawapan berangka, unit hendaklah dinyatakan di ‘mana-mana yang sesuai. Jawapan boleh ditulis dalam bahasa Inggeris atau bahasa Melayu. Jsi maklumat diri anda pada halaman 11 ‘This question paper consists of 20 printed pages and 4 blank pages. (Kertas soalan ini terdiri daripada 20 halaman bercetak dan 4 halaman Kosong.) ‘© Majlis Peperiksaan Malaysia 2019 STPM 2019 - 962/2 [Turn over (Lihat halaman sebelah) *This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL* (*Kertas soalan ini SULIT sehingga peperiksaan kertas ini tamat,) (SULIT*)CONFIDENTIAL* 2 Section A [15 marks] Answer all questions. Indicate the correct answer on the Multiple-choice Answer Sheet provided. 1 The standard enthalpy of combustion of hydrogen is -286 kJ mol”. Which statement is true about the information given? A. The thermochemical equation is H.(g) + 50.8) ——> 018). B_ The enthalpy of vaporisation of water is 286 kJ mol". The standard enthalpy of formation of water is -286 kJ mol” D_ The energy required to dissociate 1 mole of water at 25 °C is 286 kJ. 2 The standard enthalpy of formation of C,H, is +226.7 KJ mol". The standard enthalpies of combustion of C and H, are ~393.5 kJ mol" and ~285.9 KI mot" respectively. What is the standard enthalpy of combustion of C,H,? A 119.1 kT mol B ~452.7 kd mol? C ~906.1 kJ mot" D ~1299.6 KJ mol" 3. The thermodynamic cycle of solubility of sulphates of Group 2 is shown below. 50,6) fag + 80,00 AH, ‘ant, M*(g) + $O."(g) Which statement is true about the eycle? A. Aftyis the lattice energy. B_ The value of AH, is negative. The value AH, of BaSO, is more negative than that of MgSO,. D_ The values of AH, and AMY, decrease going down the group. STPM 2019 - 962 *This question paper is CONFIDENTIAL until the examination is ever. CONFIDENTIAL*CONFIDENTIAL* 4 4 The cell diagram for galvanic cell is shown below. Fe(s)|Fe™(aq)|| (aq), H,0() |O.(g)[Pt(s) Which statement is true about the cell? A Theemf. B_ A colourless solution is observed at the anode. f the cell is positive, The concentration of H” increases at the cathode. D_ Electrons flow from the platinum electrode to the iron electrode. 5 The e.m-f. of the following cell under standard conditions is +2.46 V. AIG) AP"(aq)] | Ag'(aq) | Azts) Which statement is true about the cell? [E°serg = 40.80 V] A. Alacts as the cathode. B_ Ag‘ acts as an oxidising agent. The standard reduetion potential of Al half-cell is +1.66 V. D_ The dissolved mass of Al is the same as the produced mass of Ag. 6 Nest equation is given below. bo -W2 ig 0 Which statement is tue about the —_ non-standard Mg(s)|Mg"(0.25 mol dm*)||Mg°"(1.0 mol dm*)|Ma(s)? A. The value of B° is 0 V. B Theem£ of the cell is—0.018 V. C The electrolyte used is Mg(OH),. D The half-cell with a higher concentration of Mg™ is the anode. 7 Which element in Period 3 does not react with oxygen? A Aluminium B Chlorine C Phosphorus STPM 2019 - 962/2 *This question paper is CONFIDENTIAL until the examination is over. cell potential of D Sulphur CONFIDENTIAL*CONFIDENTIAL* 6 1d SO, are stable oxides of sulphur. Why is SO, used as a food preservati A. SO, is a polar molecule while SO, is a non-polar molecule. B_ SO, has a lower boiling point than $O, € so, D_ SO, forms a weak acid while SO, forms a strong acid in water. a reducing agent while SO, is an oxidising agent. 9 The value of AH for the decomposition of MCO, is given in the table below, Carbonate | MgCo, | Caco, | srco, | BaCo, AHS mor! +101 | +178 | +235 | +269 Which factors does not infiuence the trend down the group? A. The charge density of B_ The polarising power of M” C_ The melting point of MCO, D_ The strength of jonie bond of A 10 SnC\, is liquid at room temperature. Why does SnCl, forms white fumes when exposed to moist ait? A. Evaporates to SnCl,(g) B_ Decomposes to SnCl,(s) and C(g) at room temperature C_ Reacts with water vapour to form SnO,(s) and HCI(g) D_ Reacts with oxygen to form SnO(s) and Chg) LL Part ofa structure of silicate is given below Which statement is true about the silicate? A. The silicate is a chain silicate. B_ The structure is found in amphiboles. Two chains of silicate are joined to form mica, D_ Each tetrahedron is bonded to four oxygen atoms. STPM 2019 - 962/2 *This question paper is CONFIDENTIAL until the examination is over, CONFIDENTIAL*CONFIDENTIAL* 8 12. Pand@ are non-radioactive elements in Group 17 of the Periodic Table. P is a dark coloured solid that sublimes when heated and sparingly soluble in water. Which is true about Q? A. Asolid at room temperature B_ Sublimes at room conditions C Less soluble in water than P D_ Astronger oxidising agent than P 13. H, reacts with X, to form a thermally unstable HY. X,is AR BC, c Br Di, 44. The standard reduction potentials for selected metal(III) ions are shown in the diagram below. TT VG Mn Fe Co Ni Cu Element Which statement is true about the above diagram? A. The strongest oxidising agent is Cr” B_ Mn™, Fe™ and Co” react with H,0. CC reacts with V" in acidic solution. D Ti is able to oxidise H,. 15 Which complex possesses metal ion with the same charge as the central metal in K,[Fe(CN).]? A. [CrNH,),C] B_ [Mn(NH,},JCl C [Co(H,0),(NH,).]Cl, D_ [Ni(H,0),(OH),] STPM 2019 - 962/2 This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL*CONFIDENTIAL* 12 Section B [15 marks] Answer all questions. Write the answers in the spaces provided. 16 (a) The first seven ionisation energies of element X are given in the table below, Tonisation energy!k} mol First | Second | Third | Fourth | Fifth | Sixth | Seventh i402 | 2856 | 4578 | 7475 | 944s | 53267 | 64360 By using the above data, deduce the group for element in the Periodic Table. B () The melting points of the oxides of Period 3 elements are shown in the table below. Oxide NaO | MgO | ALO; | SiO, | PO. | SO; Melting point*C | 1275 | 2852 | 2072 | 1703 | 300 =10 Based on the above data, (determine the type of structures of AI,O,, SiO; and SO,, (3 (a) STPM 2019 - 962/2 *This question paper is CONFIDENTIAL uniil the examination is over. CONFIDENTIAL* Please tear off along the perforated lineCONFIDENTIAL* 4 17 The reaction of halide ions with concentrated sulphuric acid can be used as a chemical test of halide ions. The result of halide ions, X, ¥ and Z, react with concentrated sulphuric acid are shown in the table below. Halide ion Observation x White fumes Purple vapour Zz Brown vapour (a) Identify X, Yand Z. Bl (b) Write the equations involve in the formation of the brown vapour. 2 (©) Arrange the halogen halides, HX, HY and HZ in ascending order of t (d) Why X forms only white fumes? a1 STPM 2019 - 962/2 *This question paper is CONFIDENTIAL until the examination is over. | CONFIDENTIAL* Please fear off along ihe perforated TavaCONFIDENTIAL* 16 Section C [30 marks] Answer two questions only. You may answer all the questions, but only the first two answers will be marked. Write the answers on the answer sheets provided. Begin each answer gn a new page of the answer sheet. 18 The data of enthalpies, electron affinities and energies for AgCl, a white crystalline solid, and AgBr, a pale yellow crystalline solid, are shown below, AH*/kJ mot! Enthalpy of formation for AgCl 127 Enthalpy of formation for AgBr 100 Enthalpy of hydration for Ag* ions 464 Enthalpy of hydration for Cl ions 304 Enthalpy of hydration for Br ions 337 Enthalpy of atomisation for Ag +285 First electron affinity of Cl 394 First electron affinity of Br 325 First ionisation energy of Ag +731 Bond energy of CCI 4243 Bond energy of BrBr +194 (@ @ Based on the above data, construct the energy cycle for AgCl and calculate the enthalpy of solution of AgCL 7 i) Compare the enthalpies of solutions of AgBr and AgCl. 3) (6) The reaction between an acid and a base produces salt and water, A mixture of 100.0 cm’ of 0.431 mol dm“ HCI solution and 100.0 cm’ of 0.216 mol da? Ba(OH), solution is added into a constant-pressure calorimeter. Determine the final temperature of the mixture if the initial temperature of both solutions is 20.5 °C. [5] [Specific heat capacity of water is 4.18 J g' °C~ and heat of neutralisation is 56.2 kJ mot] STPM 2019 - 962/2 “This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL*CONFIDENTIAL* 18 19 (a) The atomic radius and melting points of Group 2 elements are given in the table below. Element | Atomie radius (pm) | Melting point °C) Mg 145 650 Ca 194 "842 Sr 219 ™m Ba 253 m Explain the trend in the melting points of Group 2 elements. 15} (D) Compare the thermal stability of Mg(NO,), with that of Mg(OH). (61 (©) An aqueous solution of BeCl, contains [Be(H,O),]" and Cl’. Identify whether the solution is acidic or basic. Explain the properties of the solution. (4) 20 (@) Silicon, a semiconductor material used for the production of silicon chips. Why is silicon a semiconductor while diamond is not? Explain your answer in terms of energy band. 7 (b) Explain the differences between carbon dioxide and silicon dioxide in terms of their structure and physical properties. [8] STPM 2019 - 962/2 *This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL*