PVC TUBE MSDS - (2019) - Eng
PVC TUBE MSDS - (2019) - Eng
Product Name
All. Supplier information (in the case of imported goods, information on the domestic supplier which can be urgently contacted)
Pictogram
Precautionary statements
P235 + P410 Keep cool and away from direct sunlight.
P260 Do not breathe dust / fume / gas / mist / vapors / spray.
P264 Wash thoroughly after handling.
prevention P270 Do not eat, drink or smoke when using this product.
P273 Do not discharge into the environment.
P280 Wear protective gloves / protective clothing / eye protection / face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water / (...).
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if
possible. Keep washing.
P308 + P311 If exposed or concerned: Get medical attention.
Response P314 If you feel unwell, seek medical advice / advice.
P321 (…) Get medical attention.
P332 + P313 If skin irritation occurs: Get medical advice / attention.
P337 + P313 If eye irritation persists, get medical advice / attention.
P362 + P364 Take off contaminated clothing and wash before reuse.
Disposal P501 Dispose of contents container (according to the description in the related regulation).
Carbon black
Health
2 25
fire
Reactivity no data
Health
fire no data
Reactivity
Calcium Stearate
Health
fire
Reactivity
Aluminum hydroxide
Health
fire no data
Reactivity
Calcium carbonate
Health
fire
Reactivity
Health
fire
Reactivity
POLYVINYL CHLORIDE
Health
fire
Reactivity
CAS content
Material name Tinnitus (common name)
number (%)
Carbon black
MAGNESIUM ALUMINUM HYDROXY CARBONATE Magnesium, (Carbonato (2-)) hexadecahydroxybis (aluminum) hexa- (MAGNESIUM,
Aluminum hydroxide
Calcium carbonate Carbonic acid, calcium salt (CARBONIC ACID, CALCIUM SALT);
end. When you get into your eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if possible. Keep washing.
I. When in contact with skin If skin irritation occurs: Get medical advice / attention.
hemp. Other physician precautions Ensure medical personnel are aware of the material and take protective measures
5. FIRE-FIGHTING MEASURES
Suitable (Inappropriate) Extinguishing Media Use alcohol foam, carbon dioxide or water spray when extinguishing with this material.
Use dry sand or earth for asphyxiation
I. Specific hazards arising from the chemical
In the event of a tank fire, use unmanned fire extinguishing equipment for large fires and, if not possible,
withdraw.
MAGNESIUM ALUMINUM HYDROXY CARBONATE Move containers from fire area if you can do it without risk.
Some can be transported at high temperatures
Leaks can cause contamination
Contact may cause skin and eye burns
Dig a ditch to dispose of extinguishing water and keep material from scattering
Move containers from fire area if you can do it without risk.
Cool containers with flooding quantities of water after fire is out in the event of a tank fire.
In case of tank fire, withdraw immediately in case of tremor or discoloration of pressure relief device
Get out of flame-filled tanks in case of tank fire
Calcium Stearate Move containers from fire area if you can do it without risk.
In the event of a tank fire, use unmanned fire extinguishing equipment for large fires and, if not possible,
withdraw.
In the event of a tank fire, use unmanned fire extinguishing equipment for large fires and, if not possible,
withdraw.
end. Personal precautions, protective equipment and emergency procedures Do not breathe dust / fume / gas / mist / vapors / spray.
Wipe up spills immediately and follow protective precautions.
Remove all ignition sources.
Stop the leak if it is not dangerous.
Do not touch damaged containers or spills without wearing appropriate protective clothing.
end. Personal precautions, protective equipment and emergency procedures Wear full-face protection when not in a fire.
Cover with plastic sheet to prevent diffusion
Prevent dust formation
Pay attention to the materials and conditions to avoid
I. Measures necessary to protect the environment Do not discharge to the environment.
Prevent entry into waterways, sewers, basements or confined areas.
All. Purification or Removal Method Pile up the embankment and collect the water for digestion.
Absorb spills with inert material (eg dry sand or soil) and place in chemical waste containers.
Absorb liquid and rinse contaminated area with detergent and water.
Cover with dry sand / soil, other non-combustible materials, and then cover with plastic sheet to prevent
diffusion and contact with rain.
In case of large spill, create a ditch away from liquid spills.
Use clean explosion-proof tool to collect spillage and place in loosely covered plastic container.
Place spills in clean dry container with clean shovel, close loosely and remove container from spill area.
Cover powder with plastic sheet to prevent spreading and keep dry
Small spills Absorb with sand, non-combustible material and place in container.
Domestic Regulation
I. Appropriate engineering controls Equipment for storing and using this material should be worn and fitted with a safety shower.
All. Personal protective equipment
Respiratory protection
Carbon black
If exposure concentration is lower than 87.5 mg / m3, wear a loose-fitting hood / helmet electric respirator or
continuous flow dust mask with the appropriate type of filter.
Carbon black
If exposure concentration is lower than 175 mg / m3, wear full face or powered mandatory or air-fed continuous
flow / pressure-required mandrel respirator with appropriate filter.
Carbon black
If exposure concentration is lower than 3500 mg / m3, wear full face or helmet / hood type, pressure-required
blow mask with appropriate filter.
Carbon black
If exposure concentration is lower than 35000 mg / m3, wear self-contained air pressure (SCBA) or pressure-
required self-contained air supply (SCBA) respirators with suitable filters.
25
MAGNESIUM ALUMINUM HYDROXY CARBONATE Wear respiratory protective equipment certified by the Occupational Safety and Health Agency according to the
physical and chemical properties of the exposed particulate matter.
MAGNESIUM ALUMINUM HYDROXY CARBONATE
In case of particulate matter, the following respiratory protection is recommended:
-Face dust filter or air filter dust mask (high-efficiency particulate filter) or electric fan dust mask (dust, mist,
fume filter)
Calcium Stearate
Wear respiratory protective equipment certified by the Occupational Safety and Health Agency according to the
physical and chemical properties of the exposed particulate matter.
Calcium Stearate
In case of particulate matter, the following respiratory protection is recommended:
-Face dust filter or air filter dust mask (high-efficiency particulate filter) or electric fan dust mask (dust, mist,
fume filter)
Calcium Stearate If oxygen is lacking (<19.6%), wear a ventilation mask or self-contained breathing apparatus
Aluminum hydroxide
Wear respiratory protective equipment certified by the Occupational Safety and Health Agency according to the
physical and chemical properties of the exposed particulate matter.
Aluminum hydroxide
In case of particulate matter, the following respiratory protection is recommended:
-Face dust filter or air filter dust mask (high-efficiency particulate filter) or electric fan dust mask (dust, mist,
fume filter)
Aluminum hydroxide If oxygen is lacking (<19.6%), wear a ventilation mask or self-contained breathing apparatus
Calcium carbonate Notice 2018-62
Calcium carbonate
Wear respiratory protective equipment certified by Korea Occupational Safety and Health Agency according to
the physical and chemical properties of the exposed particulate matter.
Calcium carbonate
If exposure concentration is lower than 100mg / m3, wear appropriate respirator with appropriate type of filter.
Calcium carbonate
If exposure concentration is lower than 250mg / m3, wear loose-fitting hood / helmet electric respirator or
continuous flow dust mask with appropriate type of filter.
Calcium carbonate
If exposure concentration is lower than 500 mg / m3, wear full face or electric mandatory or air-fed continuous
flow / pressure-required mandrel respirator with appropriate filter.
Calcium carbonate
If exposure concentration is lower than 10000 mg / m3, wear full face or helmet / hood type, pressure-required
blow mask with appropriate filter.
Calcium carbonate
If exposure concentration is lower than 100000mg / m3, wear self-contained air pressure (SCBA) or pressure-
required self-contained air supply (SCBA) respirators with suitable filters.
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE)
Wear respiratory protective equipment certified by the Occupational Safety and Health Agency according to the
physical and chemical properties of the gas / liquid exposed.
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE)
For gas / liquid substances the following respiratory protection is recommended:
-Isolation type full face respirator (for organic compounds (for acidic gases)) or sequesterable respirator (for
organic compounds (for acidic gases) Acid gas)) or direct-type full face gas mask (for organic compounds (for
acid gases)) or other gas masks (for organic compounds (for acid gases)) or powered gas masks.
POLYVINYL CHLORIDE
Wear respiratory protective equipment certified by the Occupational Safety and Health Agency according to the
physical and chemical properties of the exposed particulate matter.
POLYVINYL CHLORIDE
In case of particulate matter, the following respiratory protection is recommended:
-Face dust filter or air filter dust mask (high-efficiency particulate filter) or electric fan dust mask (dust, mist,
fume filter)
POLYVINYL CHLORIDE If oxygen is lacking (<19.6%), wear a ventilation mask or self-contained breathing apparatus
end. Exterior
Appearance no data
color no data
I. smell no data
la. pH no data
Carbon black
end. Exterior
color black
I. smell Odorless
la. pH no data
Ha. importance
end. Exterior
Appearance solid
color White
I. smell Odorless
la. pH no data
Ha. importance
Calcium Stearate
end. Exterior
color White
bar. Initial boiling point and boiling point range (Not applicable)
car. Upper / lower limit of flammable or explosive range -/-(Lower limit: 0.025 g / L)
Aluminum hydroxide
end. Exterior
I. smell Odorless
la. pH no data
Get. Solubility (Insoluble (solvent solubility: soluble: sulfuric acid, hydrochloric acid))
Calcium carbonate
end. Exterior
25
color White
I. smell Odorless
la. pH
Ha. importance
end. Exterior
Appearance Liquid
color Transparency
I. smell Odorless
la. pH no data
Ha. importance
It is. Viscosity
POLYVINYL CHLORIDE
end. Exterior
Appearance solid
I. smell Odorless
la. pH no data
Ha. importance
Carbon black May explode or explode with powder, dust, debris, perforation, lathes, cutting, etc.
Carbon black Contact with molten material may cause severe skin and eye burns
MAGNESIUM ALUMINUM HYDROXY CARBONATE Stable under normal temperature and pressure conditions
MAGNESIUM ALUMINUM HYDROXY CARBONATE Some can ride, but not easily ignite
MAGNESIUM ALUMINUM HYDROXY CARBONATE May cause irritating or toxic gases in fire
MAGNESIUM ALUMINUM HYDROXY CARBONATE Some liquids may cause dizziness and vapors that cause asphyxiation
Calcium Stearate Some liquids may cause dizziness and vapors that cause asphyxiation
Calcium carbonate Inflammable, the material itself does not burn, but may decompose on heating to produce corrosive / toxic fumes
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) Some can ride, but not easily ignite
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) May cause irritating or toxic gases in fire
POLYVINYL CHLORIDE Inflammable, the material itself does not burn, but may decompose on heating to produce corrosive / toxic fumes
I. Conditions to avoid
Carbon black Generation of dust and debris, including perforation, lathes and cutting
MAGNESIUM ALUMINUM HYDROXY CARBONATE Ignition sources such as heat, sparks, flames
Calcium carbonate Pyrolysis or combustion may produce irritating and very toxic gases during burning
MAGNESIUM ALUMINUM HYDROXY CARBONATE Absorbs body through inhalation of aerosol through skin, digestive system
MAGNESIUM ALUMINUM HYDROXY CARBONATE Possible to absorb the body by inhalation of steam
MAGNESIUM ALUMINUM HYDROXY CARBONATE Absorbs body by inhalation, skin and extinguisher
Acute toxicity
oral-
Carbon black LD50> 8000 mg / kg Rat (no death, OECD Guideline 401)
MAGNESIUM ALUMINUM HYDROXY CARBONATE LD50> 2000 mg / kg Rat (EEC-Directive 92/69 B.1)
Aluminum hydroxide LD50> 2000 mg / kg Rat (female, no death (OECD TG 423, GLP))
Transdermal
inhale
Carbon black Dust LC50> 4.6 / 4 hr Rat (No mortality to maximum concentration)
MAGNESIUM ALUMINUM HYDROXY CARBONATE Dust LC50> 5.16 mg / l 4 hr Rat (OECD TG 403, GLP)
Carbon black No skin irritation results from rabbit skin corrosion / irritation test (OECD Guideline 404)
MAGNESIUM ALUMINUM HYDROXY CARBONATE Skin irritation / irritation test in rabbits did not show irritation OECD Guideline 404, GLP
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) Intermittent skin exposure in humans causes mild irritation
25
Carbon black Severe eye damage / irritation in rabbits did not result in mild irritation (OECD Guideline 405)
MAGNESIUM ALUMINUM HYDROXY CARBONATE Severe eye damage / irritation in rabbits showed no eye irritation
Aluminum hydroxide Serious eye damage / irritation test in rabbits, no irritation (OECD TG 405, GLP)
Calcium carbonate Extreme stimulation of the Rabbit-Draize tes, showing slight stimulation to humans
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) No data on eye irritation available but should be considered as skin irritant
Respiratory sensitization
Skin sensitization
Carbon black Skin sensitization test using guinea pigs does not cause skin sensitization (OECD Guideline 406, GLP)
MAGNESIUM ALUMINUM HYDROXY CARBONATE Skin sensitization was not observed using guinea pigs. OECD TG 406, GLP
Aluminum hydroxide Skin sensitization test using guinea pig (male), non-sensitization (OECD TG 406, GLP)
Carcinogenic
Carbon black
Carbon black
POLYVINYL CHLORIDE
Carbon black
Calcium Stearate
POLYVINYL CHLORIDE
Carbon black Voice, regardless of the system in vitro sister chromatid exchange assay results metabolic activity using My
mammalian existence (OECD Guideline 479)
in vitro gene mutation tests metabolic activity-based presence with My mammals and negative (OECD Guideline
476), regardless of
in vitro microbiological Negative metabolic activity with or without metabolic activity (OECD Guideline 471,
25
GLP)
Sex Link recessive lethality test using Drosophila in vivo (OECD Guideline 477)
MAGNESIUM ALUMINUM HYDROXY CARBONATE In vitro reverse mutation test and mutation test resulted in negative and in vivo regardless of metabolic activity
Calcium carbonate Negative with or without metabolic activity in in vitro Salmonella typhimurium Ames test
POLYVINYL CHLORIDE In vitro Salmonella typhimurium Ames test, negative with or without metabolic activity in mouse lymphoma
Reproductive toxicity
Carbon black Teratogenicity / Maternal Toxicity / Development Toxicity Test in Rats Does Not Reproductive Toxicity (OECD
Guideline 414)
Carbon black Repeated exposure of the human body for more than 10 years results in decreased airway resistance and exhaled
flow, cough, sputum, chronic bronchitis, pulmonary dysfunction, pneumoconiosis, emphysema, impaired
pulmonary perfusion, obstructive gout, carcinogenic effects Do not apply to classifications in this column
MAGNESIUM ALUMINUM HYDROXY CARBONATE No adverse effects were observed in repeated oral toxicity studies using rats NOAEL = 50 mg / kg bw / day
EEC-Directive 92/69 B.7, GLP
Calcium carbonate Exposure may cause blood system disorders, gastrointestinal disorders, and Hochmon system disorders
POLYVINYL CHLORIDE Repeated lungs, prolonged exposure to dust particles can cause fibrosis
Aspiration hazard
end. Ecotoxicity
Pisces
MAGNESIUM ALUMINUM HYDROXY CARBONATE LC50> 100 mg / l 96 hr Cyprinus carpio (similar substance, OECD Guideline 203, GLP)
Aluminum hydroxide LC50> 218.6441 mg / l 96 hr Pimephales promelas (ring formula, ASTM 2000, GLP)
shellfish
Carbon black EC50> 5600 mg / l 24 hr Daphnia magna (OECD Guideline 202, GLP)
MAGNESIUM ALUMINUM HYDROXY CARBONATE EC50> 100 mg / l 48 hr Daphnia magna (similar substance, OECD TG 202, GLP)
Birds
Carbon black ErC50> 10000 mg / l 72 hr others (Desmodesmus subspicatus, OECD Guideline 201, GLP)
MAGNESIUM ALUMINUM HYDROXY CARBONATE EC50> 18 mg / l 72 hr Selenastrum capricornutum (Similar substance, OECD TG 201, GLP)
Aluminum hydroxide ErC50 0.0455 ~ 0.6999 mg / l 72 hr others (Pseudokirchneriella subcapitata, exponential, OECD Guideline 201)
Persistence
Aluminum hydroxide
Degradable
All. Biocompatibility
Concentration
Calcium Stearate
Calcium carbonate
Biodegradable
Carbon black Algae: Desmodesmus subspicatus: NOEC, 72h,> 10000 mg / L, OECD Guideline 201, GLP
MAGNESIUM ALUMINUM HYDROXY CARBONATE Alga Selenastrum capricornutum: NOEC72hr = 10 mg / LOECD TG 201, GLP-like substance
Aluminum hydroxide Fish: Pimephales promelas, NOEC, 7d, = 1 156.5 μg / L, ring formula, EPA 2002, GLP,
crustacean: Ceriodaphnia dubia, EC50, 7d, = 250 μg / L, ring index, USEPA 2002,
algae: Pseudokirchneriella subcapitata, NOErC, 72 h, ≥ 4 μg / L, exponential, OECD Guideline 201, GLP,
Calcium Stearate Dispose of contents and container in accordance with local regulations.
Calcium carbonate Dispose of contents and container in accordance with local regulations.
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) Dispose of contents and container in accordance with local regulations.
POLYVINYL CHLORIDE Dispose of contents and container in accordance with local regulations.
I. DISPOSAL CONSIDERATIONS
Carbon black Dispose of contents container (according to the description in the related regulation).
MAGNESIUM ALUMINUM HYDROXY CARBONATE Dispose of contents container (according to the description in the related regulation).
Calcium Stearate Dispose of contents container (according to the description in the related regulation).
Aluminum hydroxide Dispose of contents container (according to the description in the related regulation).
Calcium carbonate Dispose of contents container (according to the description in the related regulation).
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) Dispose of contents container (according to the description in the related regulation).
POLYVINYL CHLORIDE Dispose of contents container (according to the description in the related regulation).
end. UN Number
Carbon black
Dioctyl terephthalic acid (DIOCTYL TEREPHTHALATE) UN Transport Dangerous Goods Classification Information
Carbon black
Carbon black
bar. Special safety measures that the user needs or needs to know about transportation or transportation
Emergency measures in case of fire
Carbon black
Carbon black
Calcium carbonate Substances to be measured in the working environment (Measuring cycle: other mineral dust)
Calcium carbonate Special Health Examination Subjects (Diagnostic Cycle: Mineral Dust)
25
Domestic Regulation
Foreign Regulation
Carbon black
HSDB (Appearance)
HSDB (color)
25
ECHA (oral)
ECHA (dermal)
NITE (Fish)
EHCA (Bird)
ECHA (oral)
ECHA (dermal)
ECHA (suction)
Reproductive toxicity
ECHA (Fish)
ECHA (Crustaceans)
ECHA (bird)
Calcium Stearate
ECOSAR (fish)
ECOSAR (crustacean)
ECOSAR
QSAR (concentration)
Aluminum hydroxide
ECHA (oral)
ECHA (suction)
ECHA (Fish)
ECHA (Crustaceans)
ECHA (bird)
Molbase
Calcium carbonate
ICSC (Appearance)
ECHA (color)
International Uniform ChemicaL Information Database (IUCLID) (http://ecb.jrc.it/esis) (e. Melting point / freezing point)
Calculated Value by Molecular Weight and Average Molecular Weight of Air (P. Vapor Density)
ChemIDplus
International Uniform ChemicaL Information Database (IUCLID) (http://ecb.jrc.it/esis) (skin corrosion or irritation)
International Uniform ChemicaL Information Database (IUCLID) (Severe Eye Damage or Irritation)
National Library of Medicine / Chemical Carcinogenesis Research Information System (NLM / CCRIS) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?CCRIS) (germ cell mutagenicity)
ECOTOX (Fish)
The Chemical Database, The Department of Chemistry at the University of Akron (http://ull.chemistry.uakron.edu/erd)
The Chemical Database, The Department of Chemistry at the University of Akron (http://ull.chemistry.uakron.edu/erd) (color)
National Library of Medicine (NLM) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?CHEM) (e. Initial boiling point and boiling range)
National Library of Medicine / Hazardous Substances Data Bank (NLM / HSDB) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB)
The Chemical Database, The Department of Chemistry at the University of Akron (http://ull.chemistry.uakron.edu/erd)
National Library of Medicine / Hazardous Substances Data Bank (NLM / HSDB) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB)
National Library of Medicine (NLM) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?CHEM) (G. n-octanol / water partition coefficient (Kow))
The Chemical Database, The Department of Chemistry at the University of Akron (http://ull.chemistry.uakron.edu/erd)
National Library of Medicine / Hazardous Substances Data Bank (NLM / HSDB) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB)
POLYVINYL CHLORIDE
ICSC (Appearance)
ICSC (color)
Calculated Value by Molecular Weight and Average Molecular Weight of Air (P. Vapor Density)
ChemIDplus
National Library of Medicine / Chemical Carcinogenesis Research Information System (NLM / CCRIS) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?CCRIS) (germ cell mutagenicity)
25
National Library of Medicine / Hazardous Substances Data Bank (NLM / HSDB) (http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB) (specific target organ toxicity (single exposure))
International Chemical Safety Cards (ICSC) (http://www.ilo.org/public/english/protection/safework/cis/products/icsc/dtasht/index.htm) (specific target organ toxicity (repeated exposure))
la. Etc