Sl No.

Question  Correct Answer

    
    If f(x) is a continuous and injective function for
x
x
x ≥ 0 and ∫ f (t)dt < (f (0) + f (x)) , then which of the following may be
0
2

correct
    
1
    (A)   f’(x) < 0, f’’(x) < 0
    (B)  f’(x) < 0, f’’(x) > 0
    (C)  f’(x) > 0, f’’(x) < 0
    (D)  f’(x) > 0, f’’(x) > 0
B;D

    
    The maximum and minimum values of p2 2
+ q – 14p– 6q + 57 if
p
2
+ 4q
2
= 24q– 32 ∀p, q ∈ R are ℓ1 and ℓ2 respectively, then
    
ℓ1 10
    (A)   =
2 ℓ2 3

    (B)  ℓ1 ℓ2 = 30

    (C)  ℓ1 − ℓ2 = 14

    (D)  ℓ1 + ℓ2 = 104

A;D

    
    The variable line mx – y + 2 = 0 ∀m ∈ R either touches or intersects the curves
2
y
y = x
2
and x2 = 1 + in total three distinct points then the possible values
4

of m can be
    
3 –
    (A)   2√2
–
    (B)  −2√2
    (C)  2
    (D)  -2
A;B;C;D

    
    A set of parabola( s) has their vertex at (-9, 3) and it touches the x-axis at origin
then the equation of axis of such parabola( s) can be
    
    (A)   x – y + 12 = 0
4
    (B)  x – 2y + 15 = 0
    (C)  2x – y + 3 = 0
    (D)  x + y + 12 = 0
A;B
     
    The family of circles passing through two fixed points
z1 = 1 + 2i and z2 = 2 + i is orthogonal to family of circles passing through
two fixed points zα and zβ then
    
∣ ∣ –
    (A)   ∣zα + zβ ∣ = 6√2
∣ ∣
5
∣ ∣
    (B)  ∣zα + zβ ∣ = 6
∣ ∣

    (C)  zα and zβ will lie on (1– i)z = (1 + i)z̄

Re(zα ) + Re(zβ )
    (D)  = 1
I m(zβ ) + I m(zα )

A;C;D

    
1/2 4
1
    Let I = ∫ (
2
– x ) dx, then
0
4

    
1/2

    (A)   I = ∫
4
x (1– x) dx
4

1
6     (B)  I =
1
4
∫ x (1– x) dx
4

2 0

π/2

    (C)  I = ∫
9
sin θcos θdθ
9

1
    (D)  I =
1260
A;B;C;D

    
    If cos−1 x + cos−1 y + cos−1 z = 3π , then the value of
6
x
2012
+ y
2012
+ z
2012
+ is
2011 2011 2011
x + y + z

    
7     (A)   0
    (B)  1
    (C)  -1
    (D)  2
B
     
    Two straight lines u = 0 and v = 0 passes through the origin and angle between
them is tan−1 (7/9). If the ratio of the slope of v = 0 and u = 0 is 9/2, then their
equations are
    
8     (A)   y = 3x and 3y = 2x
    (B)  2y = 3x and 3y = x
    (C)  y + 3x = 0 and 3y + 2x = 0
    (D)  2y + 3x = 0 and 3y + x = 0
A;B;C

    
    The number of integers belonging to the interval [-3, 30] but not belonging to
the range of the function f (x) = x{x}– x[−x], x ∈ R , is (where [.] and {.}
9
denote the greatest integer function and fractional part respectively)
8_8

    
β − α
    Find the maximum possible integral value of , where
−1 −1
tan β– tan α
10 –
0 < α < β < √3 , is
3_3

    
    If α, β are roots of equation x2 – 6x + 12 = 0 , then value of
−−−−−−−−−−−−−−−−−−−−
8
∣ 12 β − 6 ∣
11 ∣√(α– 2)
24
− ( ) + 1∣ = ____
∣ α ∣

4_4

    
49
1 –
    If ∑
−−−−−−−−−−
= a + b√2 for some integers a and b then (a3 5
+ b )
−−−−−
n=1 √n + √n2 − 1
12
= ____
368_368

    
    One vertex of a cube is (0, 0, 0) and the sides are parallel to x , y and z-axis.
13 Three planes x = y, y = z and z = x cut the cube in n parts. The value of n is
6_6

    
    Let y = f(x) be a function such that (f (x))2 = 1∀x ∈ [0, 4] . If there are n such
functions which are discontinuous at integral points. Then number of prime
14
divisors of n is
2_2
     
    Let y = f(x) and y = g(x) be two differentiable functions such that f’(x) = g(x) and
g’(x) = f(x) ∀x . If f(0) = 0, g(0) = 2 and I then [I]
1
∈ R = ∫ (f (x) + g(x))dx
15 0

equals ([.] is GIF).

3_3

    
2x − 3
    Let y = f(x) be a function such that, f (x) + f ( ) = x , then number of
x − 2
16
integers in the domain of f(x) is/are
2_2

    

    

17
    
    (A)   A – P,Q,R; B – P,Q; C – Q, S; D – Q,S
    (B)  A – S,R,Q; B – R,P,S ;C – Q,P,R; D – P,RQ
    (C)  A – P,S; B - Q,R; C – R,S,P; D – S,R
    (D)  A – Q,R; B - P,S; C – R,S; D – Q,S
A

    

    

18
    
    (A)   A - S; B - R; C - Q; D - P
    (B)  A – S,R,Q; B – R,P,S; C – Q,P,R; D – P,RQ
    (C)  A – P,S; B - Q,R; C – R,S,P; D – S,R
    (D)  A – P; B – Q,R; C – P,Q,R,S; D – S
D
     

    

19

    
    (A)   A – R; B – S; C – R, S; D – P,Q
    (B)  A - S; B – R,S; C – Q,R; D – P,R
    (C)  A – S,R,Q; B – R,P,S; C – Q,P,R; D – P,RQ
    (D)  A – P,S; B - Q,R; C – R,S,P; D – S,R
A

    

    

20

    
    (A)   A - S; B – R,S; C – Q,R; D – P,R
    (B)  A – S,Q,R; B – P,S; C – P,Q,R; D – P,R,Q
    (C)  A - S B - S; C – P,S; D - R
    (D)  A - Q; B - P,R; C - R; D – P,S
C
     
    A car C of mass m1 rests on a plank P of mass m2 . The plank rests on a smooth
floor. The string and pulley are ideal. The car starts and moves towards the pulley
with acceleration.

    

21
    
    (A)   If m1 > m2 , then the string will remain under tension.
    (B)  If m1 < m2 , then the string will become slack.
    (C)  If m1 = m2 , then the string will have no tension, and C and P will have
acceleration of equal magnitude.
    (D)  C and P will have acceleration of equal magnitude if m1 ≥ m2

A;B;C;D

    
    A simple pendulum has a bob of mass m and swings with an angular amplitude
ϕ . The tension in the thread is T. At a certain time, the string makes an angle θ
with the vertical (θ ≤ ϕ)

    
    (A)   At T = mg cosθ , for all values of θ
22
    (B)  At T = mg cos θ , only for θ = ϕ

1
    (C)  T = mg, for θ = cos
−1
[ (2 cosϕ + 1)]
3

    (D)  T will increase as θ decrease

B;C;D

    
    A body totally immersed in water is raised in the water by a height h. The
density of the body is d and the density of water is d0 while the volume of the
body is V and d > d0 . Which of the given statement will be true? (neglect
viscosity)
    
    (A)   The net work done by the external agent on raising the body slowly is
23
V gh(d– d0 )

    (B)  The increase in the potential energy of the body is V gh(d– d0 )

    (C)  The potential energy of water is increased by raising the body
    (D)  The work done on the body by the gravitational force is equal and opposite
to the work done by the hydrostatic force so that net work done is zero.
A;B
     
    The network shown in figure is part of the some bigger circuit. Charge on
capacitor (C = 1F) at any time t is q = 3(2– e
−t
) in coulombs. If at t = 0 the
potential of points A and B is 20V each, then at t = 0 choose the correct statements

    

24

    
    (A)   Current through 1Ω in branch AP is 3A.
    (B)  Current through R is 7A
    (C)  Value of R is 2Ω
    (D)  Value of R is 1Ω
A;B;C

    
    For two satellites at a distance R and 7R above the earth’s surface revolving in
circular orbits, the ratio of their
    
    (A)   Total energies is 4
25
    (B)  Potential energies is 4
    (C)  Kinetic energies is 4
    (D)  Total energies is 4 and potential and kinetic energies is 2
A;B;C

    
    Work function of a metal X equal the ionization energy of Li2+ ion in second
excited state. Work function of another metal Y equal the ionization energy of
He
+
ion with electron in n = 4. Now photons of energy E fall separately on both
the metals such that maximum kinetic energy of photoelectron emitted from
metal X is half that of photoelectron emitted from metal Y. Choose the correct
statement (Eo = potential energy of electron in ground state of hydrogen
atom)
26     
    (A)   E = −3.5Eo

    (B)  −7Eo /8
    (C)  If E is increased, difference in maximum kinetic energies of photo electrons
emitted from X and Y increases.
    (D)  If E is increased, difference in maximum kinetic energies of photoelectrons
emitted from X and Y remains constant.
B;D
     
    An external magnetic field is decreased to zero, due to which a current is
induced in a circular wire loop of radius r and resistance R placed in the field. This
current will not become zero.
    
    (A)   at the instant when external magnetic field stops changing ( t = 0), the
current in the loop as a function of time for t > 0 is given by i0 e−2Rt/μ0
πr

    (B)  at the instant when B stops changing (t = 0) the current in the loop as a
μ0 I R
27 function of time t > 0 is given by
2r

    (C)  The time in which current in loop decreases to 10−3 I0 (from t = 0) for
2
3π ln10
R = 100Ω and r = 5cm is given by
10
10

    (D)  The time in which current in loop decreases to 10−3 I0 (from t = 0) for
2
3π
R = 100Ω and r = 5cm is given by s
6
10
A;C

    
    Two parallel lights A and B with wavelength 5000A
˚
travel parallel to each other
in air .Ray A encounters a 1mm thick layer of glass with refractive index μ = 1.5 .
Then,
    
28     (A)   ray B will complete more oscillation than ray A
    (B)  both rays will complete same number of oscillations
    (C)  ray A will complete more oscillations than ray B
    (D)  the actual two waves over the 1mm distance is 1000.
C;D

    
    A system of trolley and child of total mass 200kg is moving with a uniform speed
of 36km/hr on a frictionless track. The child of mass 40kg starts running on the
trolley from one end to the other (10m away) with a speed of 10m/sec relative to
29
the trolley in the direction of the trolley’s motion and jumps out of the trolley with
the same relative velocity. What is the final speed of the trolley?
8_8
     
    For the arrangement shown in figure, mass of block A is 50kg and mass of block
B is 70kg. Coefficient of static friction between all plane surfaces is μs = 0.3 . The
largest value of mass of block C is 9x (in kg) so that block A and B remain at rest.
(Neglect friction in the pulleys), then x =

30

    

81_81

    
    Water is filled in a uniform container of area of cross-section A. A hole of cross
sectional area a(< < A) is made in the container at the height of 20m above the
base. Water stream coming out of hole hits a small block on surface at some
distance form container. The block is moved on the surface in such a way that the
stream always hits on the block. The initial velocity of the block (in m/sec) is (Given
a 1
= take g 2
= 10m/s )
A 20

31

    

1_1

    
    A piece of ice (specific heat = 0.5cal/gm/°C and latent heat 80cal/gm ) of mass m
gram is at -5°C at atmospheric pressure. It is given 420J of heat so that the ice
starts melting. Finally when the ice water mixture is in equilibrium, it is found that
32
1 gm of ice has melted. Assuming, there is no other heat exchange in the process,
the value of m is (J = 4.2J/cal)
8_8
     
    In a race between two cars, sound signals emitted by the two cars are detected
by the detector on the straight track at the end point of the race. Frequencies
received by the detector from the two cars are 330Hz and 360Hz respectively, and
the original frequency emitted is 300Hz from both the cars. The race ends with the
33
separation of 100m between the cars. Assume that both cars move with constant
velocities and the velocity of sound is 330m/sec. Find the time taken (in sec) by the
wining car.
4_4

    
1
    The pressure and volume of a monoatomic ideal gas are related as P ∝
2
V
R
for a process A → C is . Find x . (R gas constant)
x

34
    

2_2

    
    Two identical wires are stretched by the same tension of 100N, and each emits
a note of frequency 200cycles/sec. The tension in one wire is increased by 1 N.
35
The number of beats heard in cycle per second when the wires are plucked is
1_1

    
    A box is kept on a rough horizontal surface. A horizontal force just strong
enough to move the box is applied. This force is maintained for 2 sec, and is then
9
36 removed. The total distance moved by the box is s m. Then find the value of s
5

(take μs = 0.2 and μk = 0.15 )

3_3
     

    

37

    
    (A)   A-R, B-P, C-Q, D-S
    (B)  A-S, B-P, C-Q, D-R
    (C)  A-R, B-S, C-Q, D-P
    (D)  A-P, B-P, C-Q, D-R
A

    

    

38

    
    (A)   A-R, B-P, C-QS, D-QS
    (B)  A-R, B-QS, C-P, D-QS
    (C)  A-S, B-QS, C-QS, D-P
    (D)  A-S, B-QS, C-P, D-QS
B
     

    

39

    
    (A)   A-R, B-Q, C-S, D-P
    (B)  A-R, B-P, C-Q, D-S
    (C)  A-R, B-S, C-P, D-Q
    (D)  A-R, B-Q, C-P, D-S
C
     

    

40

    
    (A)   A-R, B-R, C-S, D-P
    (B)  A-R, B-Q, C-R, D-
    (C)  A-R, B-R, C-Q, D-P
    (D)  A-R, B-R, C-R, D-P
D
     

     The reactant A can be

    

    (A)       

    (B)      
41

    (C)      

    (D)      

A;B;D
     
    A mixture of two inorganic salts gives following chemical reactivity (i) mixture on
reaction with dilute H2 S O4 produces a colourless and unpleasant gas which
turns acidified potassium dichromate paper green (ii) Mixture on reaction with
concentrated H2 S O4 gives reddish brown gas which does not produce orange
red spots on starch paper (iii) The mixture gives white precipitate with barium
chloride solution which is soluble in dilute HCl (iv) The sodium carbonate extract
42 of mixture responds to brown ring best. The mixture contains
    
    (A)   S O2−
3
and N O
−
3
anions

    (B)  S 2− −
and N O anions
3

    (C)  S O2−
3
and N O
−
2
anions

    (D)  S O3 2−
and Br
−
anions

A;C

    
    Decomposition of 3A(g) → 2B(g) + 2C(g) follows 1st order kinetics. Initially
only A is present in the container. Pressure developed after 20 min and infinite
time are 3.5 and 4atm respectively. Which one is correct?
    
43     (A)   t50% = 20min

    (B)  t75% = 40min

    (C)  t99% = 64/3min

    (D)  t87.5% = 60min

A;B;D

    
    'A' is a sample of 0.1M C H3 C OOH [Ka = 10
−5
] ; 'B' is a sample of 0.1 M
NaOH. Identify the correct matches at 25°C
    
    (A)   (20ml of A + 10 ml of B) ⇒ pH of the solution is 5
    (B)  Reduction potential of the hydrogen electrode obtained by using the
44
solution of (20ml of A + 10 ml of B) at 1 atm pressure of H2 gas is -0.295volts
    (C)  (20ml of A + 20ml of B) ⇒ pH of the solutions is 8.85(approx)
    (D)  (20ml of A + 20ml of B) ⇒ osmotic pressure of solution at 25°C is 2.447
atm.
A;B;C;D

    
    Which of the following chloride will not give Chromyl chloride test?
    
    (A)   AgCl
45     (B)  H g2 C l2
    (C)  S nC l4
    (D)  P bC l4
A;B;C;D
     
    Identify the reactions which will yield aromatic hydrocarbons as product?
    

    (A)  

    (B)      

46

    (C)      

    (D)      

A;B;D

    
    Amongst following the right statements are
    
    (A)   In SN 1 reactions if reactant has R configurations the product will have S
configuration
47     (B)  In SN 2 reactions the configurations of reactant gets inverted
    (C)  In SN 2 reactions if reactants is dextrorotatory the product is laevorotatory
    (D)  In SN 1 reactions if reactant has R configurations the product can have R
and S configurations
B;D
     
    Hydrolysis of which of the following will NOT give halogen acid (HX) as a final
product?
    
    (A)   BF3
48
    (B)  S iC l4
    (C)  S iF4
    (D)  N C l3
A;C;D

    
    How many of the following disproportionate on treatment with NaOH (under
49 sui conditions) i) B ii) C iii) Si iv) F2 v) C l2 vi) Br2 vii) I2 viii) P4 ix) S
5_5

    
    In the tetranuclear unit of borax, [B4 O5 (OH )4 ] , the number of B-O-B
2−

bridges formed between S P 3

boron and S P 2
boron is ‘x’ and the number B-O-B
50
bridges formed between S P 3
boron and S P 3
boron is ‘y’. Then (x – y) is ___.
3_3

    
    A chemical reaction occurs in three paths having rate constants
K 1 , K 2 and K 3 respectively. If Ea1 , Ea2 and Ea3 are 4,5 and 8kJ respectively
K1 K3 A1 A3
51 and overall rate constant K = Assuming Aav = , the overall
K2 A2

energy of activation in kJ is___.

7_7

    
    A cell C u/C u2+ //Ag + /Ag initially contained 2M Ag + and 2M C u2+ ions in
1 L solution each. The change in cell potential after it has supplied 1A current for
52
96500 S was found to be x × 10−2 V. Here x is:
2_2
     
    Number of compounds which can give Haloform reaction, are….

53

    
5_5

    
    A solution of isopropyl alcohol and propyl alcohol has a vapour pressure
200mm of Hg if it has 25% mole of isopropyl alcohol. Another solution of same
54 components containing 25% mole propyl alcohol has vapour pressure 300 mm of
Hg. Then vapour pressure of isopropyl alcohol in mm of Hg is
350.00_350.00

    
    If the sum of oxidation numbers of nitrogen in compounds X,Y,Z,W,U,V,Tis a
then find (a/2)

55
    

8_8
     

    
56

9_9

    

    

57
    
    (A)   A - Q; B - P; C - S; D - R
    (B)  A – S,T; B – Q,R,S; C - Q; D – P,Q,R,S
    (C)  A – P,S; B - Q,R; C – R,S; D – Q,S
    (D)  A – Q,R; B - P,Q,R; C – Q,R; D – P,R,S
B

    

    

58
    
    (A)   A – Q,R; B – S; C - P,Q; D – R,S
    (B)  A – R,S; B – P,Q; C – R,S; D – Q
    (C)  A – P,R; B - P,S; C – Q,S; D – R,S
    (D)  A – P,R; B - Q,R; C – P,Q,S; D – P,S
D
     

    

59

    
    (A)   A – R; B – P.R; C - Q,S; D – S
    (B)  A – S; B – Q,R; C – R; D – P
    (C)  A – R; B - Q,T; C – P,T; D – S
    (D)  A – P; B - R,S; C – P,Q; D – S
C

    

    

60

    
    (A)   A-R,T B-P,R C-P,R D-Q,R,S
    (B)  A – S,R B – Q,R C – R,S D – P,Q,R,S
    (C)  A – Q,S B - S C – P,R D – P,Q,R
    (D)  A – P,Q,R B - R,S C – Q,R,S D – P,R,S
A