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Name A B C D T T: Vapor Pressure - Wagner Constants

The document lists Wagner constants for the vapor pressure equation of various substances. The Wagner equation uses constants A, B, C and D to calculate reduced vapor pressure (Pr) as a function of reduced temperature (Tr), where Tr is the ratio of temperature to critical temperature and Pr is the ratio of vapor pressure to critical pressure. The constants are determined for different substances to apply the Wagner equation over given temperature ranges.
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0% found this document useful (0 votes)
545 views2 pages

Name A B C D T T: Vapor Pressure - Wagner Constants

The document lists Wagner constants for the vapor pressure equation of various substances. The Wagner equation uses constants A, B, C and D to calculate reduced vapor pressure (Pr) as a function of reduced temperature (Tr), where Tr is the ratio of temperature to critical temperature and Pr is the ratio of vapor pressure to critical pressure. The constants are determined for different substances to apply the Wagner equation over given temperature ranges.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Wagner Constants Página 1 de 2

General Atomic Properties


Weight Data Files
Table

Vapor Pressure - Wagner Constants

Wagner Equation : P = Pc x Pr Where


1.5 3 6
ln Pr = A ( 1 - Tr )/Tr + B ( 1 - Tr ) /Tr + C ( 1 - Tr ) /Tr + D ( 1 - Tr ) /Tr
And Tr = T/Tc A, B, C, D are Wagner Constants
Pc & Tc are critical Pressure and Critical Temperature respectively
TL and TH are the lower and upper temperature bounds for application of the equation
Name A B C D TL TH
ACETALDEHYDE -7.046870 1.214200E-01 -2.660370E-02 -5.903000 273 461.10

ACETIC ACID -7.831830 5.519290E-04 2.470900E-01 -8.504620 304 592.71

ACETONE -7.497450 1.317380 -2.675420 -2.677400 247 508.10

ACETYLENE -6.901280 1.268730 -2.091130 -2.756010 192 308.33

AMMONIA -7.264810 1.435240 -3.444900 2.959790E+01 328 405.50

BENZENE -6.974000 1.318500 -2.633700 -3.258800 278 562.16

BUTADIENE,1-2 -8.231900 3.559500 -5.047100 4.050700 200 443.70

BUTADIENE,1-3 -7.249100 2.017300 -3.076600 -1.465500 164 425.00

BUTANE -7.026900 1.519900 -2.809600 -1.957e-03 253 425.18

BUTYL ACETATE -8.366580 2.409850 -6.425110 -1.957000E-03 333 579.10

CARBON DIOXIDE -6.956260 1.196950 -3.126140 4.859390 217 304.10

CARBON MONOXIDE -6.207980 1.278850 -1.345330 2.994480 71 132.91

CARBON TETRACHLORIDE -6.976410 1.439570 -2.341820 -2.568420 253 556.60

CHLORINE -6.340740 1.150370 -1.404160 -3.845790 206 416.90

CHLOROFORM -6.504190 1.011700E-02 -3.735900E-01 -2.232200 215 536.40

CHLOROMETHANE -6.541530 9.062110E-01 -1.486000 -6.448610 191 416.25

DICHLOROMETHANE -6.443900 4.715300E-01 -2.076810 -2.673590 210 510

DIETHYL ETHER -7.299160 1.248280 -2.919310 -3.539000 250 466.70

ETHANE -6.343070 1.016300 -1.191160 -3.367400 133 305.42

ETHYL ACETATE -7.685210 1.365110 -4.089800 -2.035390 289 523.20

ETHYL ALCOHOL -8.424600 2.863800E-02 -4.792600 3.789300 229 513.92

ETHYLBENZENE -7.398500 1.228600 -2.979500 -3.219300 263 617.20

ETHYLENE -6.320550 1.168190 -1.559350 -1.835520 105 282.34

ETHYLENE GLYCOL NA NA NA NA NA NA

ETHYLENE OXIDE -6.562340 4.269600E-01 -1.256380 -3.181330 238 469.10

FORMIC ACID NA NA NA NA NA NA

GLYCEROL NA NA NA NA NA NA

HEPTANE -8.149000 2.506400 -5.263600 3.423900E-03 185 540.30

HEXANE -7.534700 1.415300 -2.290600 -1.169400E+01 322 507.50

HYDROGEN -5.579290 2.600120 -8.550600E-01 1.705030 14 33.00

ISOPROPYL ALCOHOL -8.347400 3.878600E-01 -9.326900 1.357000E+01 273 508.30

ISOPROPYLBENZENE -7.314900 8.170600E-01 -2.713500 -4.527100 264 631.10

M-XYLENE -7.594900 1.385100 -3.169000 -2.420800 264 617.05

METHANE -6.004350 1.188500 -8.340800E-01 -1.228330 91 190.58

METHYL ACETATE -8.054060 2.563750 -5.129940 1.612500E-01 275 506.80

METHYL ALCOHOL -8.536900 7.328700E-01 -3.025000 1.363500 206 512.64

N-BUTYL ALCOHOL -8.039800 5.741500E-01 -9.197500 4.913200 293 563.05

N-BUTYRIC ACID -1.003920E+01 3.156790 -7.726040 5.276300 364 624.00

N-PROPYL ALCOHOL -8.198700 4.038100E-01 -8.319300 1.043400E+01 273 536.78

NITRIC OXIDE NA NA NA NA NA NA

NITROGEN -6.096760 1.136700 -1.040720 -1.933060 63 126.20

NITROGEN DIOXIDE NA NA NA NA NA NA

NITROUS OXIDE NA NA NA NA NA NA

O-XYLENE -7.644800 1.693600 -3.638800 -1.402000 269 630.30

OCTANE -8.162200 2.105200 -5.416400 -1.583000E-01 216 568.83

OXYGEN -6.282750 1.736190 -1.813490 -2.536450E-02 54 154.58

P-XYLENE -7.654700 1.571500 -3.344900 -2.212400 287 616.20

PENTANE -7.243000 1.440200 -2.895600 -2.086200 144 469.70

PHENOL -8.168300 1.405100 -3.488400 -8.789000 345 694.20

PHOSGENE -7.081770 1.604610 -2.571530 -1.883770 216 455.00

PROPANE -6.687700 1.248800 -1.974500 -2.053900 212 369.82

PROPYLENE -6.642310 1.218570 -1.810050 -2.482120 140 364.85

STYRENE -7.159810 1.788610 -5.103590 1.637490 303 636.80

SULFUR DIOXIDE NA NA NA NA NA NA

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Wagner Constants Página 2 de 2

SULFUR TRIOXIDE NA NA NA NA NA NA

TOLUENE -7.373300 1.586900 -2.950600 -2.739400 195 591.79

WATER -7.764510 1.458380 -2.775800 -1.233030 275 647.14


NA - Not Available

http://www.echeguru.com/html_data_files/Wagner_Constants.html 13/05/2014

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