Page 1/9

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

* SECTION 1: Identification of the substance/mixture and of the company/legal entity

· 1.1 Product identifier
· Trade name tesa 60022 Spray Glue EXTRA STRONG
· Article number: tesa 60022 (500ml)
· 1.2 Relevant identified uses of the
substance or mixture and uses
advised against No further relevant information available.
· Application of the substance / the
mixture Adhesives
· 1.3 Manufacturer/Supplier:
tesa SE Tel.: +49-40-88899-101
Hugo-Kirchberg-Strasse 1
D-22848 Norderstedt
Germany
· Informing department: tesa SE, quality management/environment/occupational safety, Dr. Dirk Lamm
[email protected], Tel.: +49-40-88899-2977
tesa SE, quality management/environment/occupational safety, Dr. Anja Koeth
[email protected], Tel.: +49-40-88899-3938
· 1.4 Emergency telephone number:
tesa SE, Hugo-Kirchberg-Str. 1, D-22848 Norderstedt
Security Center Phone +49-40-88899-0
or +49-40-88899-9111
UNITED KINGDOM:
The UK National Poisons Emergency number is 0870 600 6266
London:
Emergency 24 hour telephone: +44 (0)20 7188 0100
Guy's & St Thomas' Poisons Unit
Medical Toxicology Information Services
Mary Sheridan House, Guy's Hospital, Great Maze Pond, London SE1 9RT

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements
· Labelling according to Regulation
(EC) No 1272/2008 The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS02 GHS07
· Signal word Danger
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 1)
· Hazard-determining components of
labelling: 64742-49-0 Naphtha (petroleum), hydrotreated light (Note P)
methyl acetate
cyclohexane
n-hexane
· Hazard statements H222-H229 Extremely flammable aerosol. Pressurised container: May burst if
heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P410+P412 Protect from sunlight. Do not expose to temperatures
exceeding 50 °C/122 °F.
P501 Dispose of contents/container in accordance with local/
regional/national/international regulations.
· 2.3 Other hazards The preparation contains no elualable organic halogene compounds, which
increases the AOX values
· Results of PBT and vPvB assessment
· PBT: Not classified
· vPvB: Not classified

* SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture consisting of the following components.
· Dangerous components:
CAS: 79-20-9 methyl acetate <50%
EINECS: 201-185-2 Flam. Liq. 2, H225
Reg.nr.: 01-2119459211-47-xxxx Eye Irrit. 2, H319; STOT SE 3, H336
CAS: 106-97-8 butane, pure <25%
EINECS: 203-448-7 Flam. Gas 1, H220
Reg.nr.: 01-2119474691-32-xxxx Press. Gas C, H280
CAS: 74-98-6 propane liquefied <25%
EINECS: 200-827-9 Flam. Gas 1, H220
Reg.nr.: 01-2119486944-21-xxxx Press. Gas C, H280
EINECS: 265-151-9 64742-49-0 Naphtha (petroleum), hydrotreated light (Note P) <25%
Reg.nr.: 01-2119486291-36-xxxx Flam. Liq. 2, H225
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; STOT SE 3, H336
CAS: 141-78-6 ethyl acetate <2.5%
EINECS: 205-500-4 Flam. Liq. 2, H225
Reg.nr.: 01-2119475103-46-XXXX Eye Irrit. 2, H319; STOT SE 3, H336
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 2)
CAS: 75-28-5 isobutane <2.5%
EINECS: 200-857-2 Flam. Gas 1, H220
Reg.nr.: 01-2119485395-27-xxxx Press. Gas C, H280
CAS: 110-82-7 cyclohexane <2.5%
EINECS: 203-806-2 Flam. Liq. 2, H225
Reg.nr.: 01-2119463273-41-XXXX Asp. Tox. 1, H304
Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Skin Irrit. 2, H315; STOT SE 3, H336
CAS: 110-54-3 n-hexane <1%
EINECS: 203-777-6 Flam. Liq. 2, H225
Reg.nr.: 01-2119480412-44-xxxx Repr. 2, H361f; STOT RE 2, H373; Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; STOT SE 3, H336
· SVHC Free of any SVHC substances or < 0.1 %
· Regulation (EC) No 648/2004 on
detergents / Labelling for contents not applicable
· Additional information For the wording of the listed hazard phrases refer to section 16.

* SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation Supply fresh air or oxygen; call for doctor.
In case of unconsciousness bring patient into stable side position for transport.
· After skin contact Instantly rinse with water.
· After eye contact Rinse opened eye for several minutes under running water. If symptoms persist,
consult doctor.
· After swallowing Instantly call physician.
· 4.2 Most important symptoms and
effects, both acute and delayed Dazedness
· 4.3 Indication of any immediate
medical attention and special
treatment needed If swallowed, gastric irrigation with added, activated carbon.

* SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable
extinguishing agents
Water.

Water with a full water jet.

· 5.2 Special hazards arising from the
substance or mixture Nitrogen oxide (NOx)
Carbon monoxide (CO)
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.
· Additional information Cool endangered containers with water spray jet.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective
equipment and emergency
procedures Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions: Inform resposible authorities in case of spilling into water or sewage system.
· 6.3 Methods and material for
containment and cleaning up: Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 3)
· 6.4 Reference to other sections See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

* SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Keep away from heat and direct sunlight.
Ensure good ventilation/exhaustion at the workplace.
Open and handle container with care.
· Information about protection
against explosions and fires: Do not spray on flames or red-hot objects.

Keep ignition sources away - Do not smoke.

Protect against electrostatic charges.

Beware: Container is pressurized. Keep away from direct sun exposure
and temperatures over 50°C. Do not open by force or throw into fire
even after use.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by
storerooms and containers: Store in cool location.
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one
common storage facility: Store away from flammable substances.
· Further information about storage
conditions: Keep container tightly sealed.
Do not seal container gastight.
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection

· Additional information about design
of technical systems: No further data; see item 7.
· 8.1 Control parameters
· Components with critical values that require monitoring at the workplace:
79-20-9 methyl acetate
WEL Short-term value: 770 mg/m³, 250 ppm
Long-term value: 616 mg/m³, 200 ppm
106-97-8 butane, pure
WEL Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
141-78-6 ethyl acetate
WEL Short-term value: 400 ppm
Long-term value: 200 ppm
110-82-7 cyclohexane
WEL Short-term value: 1050 mg/m³, 300 ppm
Long-term value: 350 mg/m³, 100 ppm
110-54-3 n-hexane
WEL Long-term value: 72 mg/m³, 20 ppm
· Additional information: The lists that were valid during the compilation were used as basis.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 4)
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic
measures Keep away from foodstuffs, beverages and food.
Instantly remove any contaminated garments.
Wash hands before breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
· Breathing equipment: Not necessary if room is well-ventilated.
Use breathing filter A2
In case of short term exposure use respiratory protection. In case of
intensive or longer exposure use respiratory protection equipment
independent from ambient air.

Use respiratory protection in case of insufficient ventilation.

· Protection of hands:
Solvent resistant gloves

· Material of gloves Nitrile rubber, NBR

· Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
· Eye protection:
Safety glasses

· Body protection: Protective work clothing.

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: Light yellow
· Smell: Solvent-like
· Change in condition
Melting point/freezing point: Not determined
Initial boiling point and boiling range: -44 °C
· Flash point: -97 °C
· Ignition temperature: 245 °C
· Self-inflammability: Product is not selfigniting.
· Explosive properties: In use, may form flammable/explosive vapour-air mixture.
· Critical values for explosion:
Lower: 1,0 Vol %
Upper: 16,0 Vol %
· Steam pressure at 20 °C: 8,300 hPa
· Density at 20 °C 0,72 g/cm³
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix
· Viscosity:
dynamic: Not determined.
kinematic: Not determined.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 5)
· Solvent content:
Organic solvents: 78,4 %
Solids content: 20,0 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions
to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous
reactions No dangerous reactions known
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition
products: No dangerous decomposition products known

* SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values that are relevant for classification:
64742-49-0 Naphtha (petroleum), hydrotreated light (Note P)
Oral LD50 2,000 mg/kg (Ratte)
Dermal LD50 4,000 mg/kg (Rabbit)
Inhalative LC50/ 4 h 54 mg/l (Ratte)
110-82-7 cyclohexane
Oral LD50 12,705 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation Causes skin irritation.
· Serious eye damage/irritation Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard May be fatal if swallowed and enters airways.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· According to recipe contains the
following heavy metals and
compounds according to EC
guideline NO. 76/464 EC: Free of heavy metals (Pb, Cd, Hg, Cr6+)
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 6)
· General notes: Harmful to aquatic organisms
Do not allow undiluted product or large quantities of it to reach ground water,
water bodies or sewage system.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

* SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage.
Do not allow product to reach sewage system.

· European waste catalogue (recommendation)

16 05 04* gases in pressure containers (including halons) containing hazardous substances
HP 3 Flammable
HP 4 Irritant - skin irritation and eye damage
HP 5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
HP 14 Ecotoxic
· Additional information about the
European waste catalogue: The assignment of a waste key number according to EC Decision 2000/532/EC in
connection with EU Directive 75/442/EC has to follow specific industry
requirements. The obove mentioned classification is only one possible proposal.
· Uncleaned packagings:
· Recommendation: Disposal according to official regulations.
· Recommended cleaning agent: ethyl acetate

* SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR, IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR

· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA

· Class 2.1
· Label 2.1
(Contd. on page 8)
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according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 7)
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Gases.
· Page: -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4. For AEROSOLS with a capacity above
1 litre: Segregation as for the appropriate subdivision of class
2. For W ASTE AEROSOLS: Segregation as for the
appropriate subdivision of class 2.
· 14.7 Transport in bulk according to Annex II of Marpol
and the IBC Code Not applicable.
· Transport/Additional information: Limited quantity regulations concerning ADR and IMDG for
packages up to 30 kg (gross weight).
ID 8000 Consumer commoditiy for airtransport of finished
goods in packages up to 30 kg possible (gross weight).
DOT: ORM-D consumer commoditiy for road transport inside
US
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOLS, 2.1

* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances -
ANNEX I None of the ingredients is listed.
· Seveso category P3a FLAMMABLE AEROSOLS
· Qualifying quantity (tonnes) for the
application of lower-tier
requirements 150 t
· Qualifying quantity (tonnes) for the
application of upper-tier
requirements 500 t
· REGULATION (EC) No 1907/2006
ANNEX XVII Conditions of restriction: 3, 57
(Contd. on page 9)
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according to 1907/2006/EC, Article 31
Printing date 27.02.2018 Version number 51 Revision: 27.02.2018

Trade name tesa 60022 Spray Glue EXTRA STRONG

(Contd. of page 8)
· National regulations
· Technical instructions (air): Class Share in %
I 0.3
III 11.3
NK 66.6

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This data is based on our present knowledge. However, they shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
· Relevant phrases H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
· Department issuing data
specification sheet: tesa SE, Quality Management/Environment/Safety
· Contact: tesa SE: Dr. D. Lamm, Phone: +49-40-88899-2977, Email: [email protected]
tesa SE: Dr. A. Koeth, Phone: +49-40-88899-3938, Email: [email protected]
· Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Gas 1: Flammable gases – Category 1
Aerosol 1: Aerosols – Category 1
Press. Gas C: Gases under pressure – Compressed gas
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Repr. 2: Reproductive toxicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous
version altered.
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