CHEMISTRY MARKING SCHEME

DELHI -2014
SET -56/1/3

Q Answers Marks
n
1 Lyophilic Sol : gum, gelatin, starch, rubber . ½

Lyophobic Sol : Metal Sol, metal sulphides / hydroxides (or any other, any one example in ½

each case)

2 4-hydroxypentan – 2 – one 1

3 Hydrogen bonding 1

4 [Co(en)3]3+ : because (en) is a chelating ligand / bidentate ligand ½+ ½

5 C6H5NH2< C6H5 NHCH3< C6H5N (CH3)2 1

6. Glucose and fructose 1

7. o – nitrophenol 1

8. Hydrogen / Iron 1

9. For the solution containing volatile components, the partial vapour pressure of each 1
component is directly proportional to its mole fraction.
In both cases, p ∝ x / Henry’s Law is a special case of Raoults Law. 1
10 Rate constant (k) : is rate of the reaction when the concentration of reactant/s is unity.
Half life period of the reaction : is the time in which the concentration of the reactant is 1+1
reduced to half of its initial concentration.
11 (i) Froth floatation method : This is based upon the preferential wetting of mineral/ore 1+1
particles by oil while the gangue particles by water.
(ii) Electrolytic refining : is based on the principle of deposition of pure metal on cathode.
12 d=11.2 g/cm3
z=4
a=4x10-8 cm
ZxM ½
d=N 3
ax a

4x M
11.2 = 6.022x1023 x(4x10-8)3

1
 11.2 x 6.022 x 1023 x 4 x 10−8 x 4x10−8 x 4x10−8 1
M= 4

M = 11.2 x 6.022 x 16 x 10-1

M = 107.9gmol-1 or 107.9 u
½
13 (i) Schottky defect 1
(ii) Decreases ½
(iii Alkali metal halides / Ionic substances having almost similar size of cations and anions ½
(NaCl /KCl )
K f x w2 x 1000 ½
14 ∆Tf = w1 x M 2
W
0.48K = 5.12Kkgmol-1x 75 x 2256x 1000
1
0.48 x 75 x 256
w2 = 5.12 x 1000

w2= 1.8g ½

15 (i) (b) is chiral 1

OR
(a) undergoes faster SN2
(ii) (a) SN2
(b) SN1 ½, ½
16 (i) 1
Cl

(ii) CH2 – CH2 – CH2 Br 1

17 (i) Ca3 P2 + 6H2O → 3Ca(OH)2 + 2PH3 1
(ii) Cu + 2H2 SO4→ CuSO4 + 2H2O+ SO2 1
(give full credit even if correct products are mentioned)
OR

17 (i) HI < HBr < HCl < HF 1

(ii) H2O < H2S < H2Se < H2Te 1
18 (i) Tetraamminedichloridochromium (III) ion 1
(ii) Geometrical isomerism / cis – trans 1
19 (a) HBr → H+ + Br-

2
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 ½

Or

( where R = -CH3)
(b)

20 a) (i) (ii)

1+1

b) White phosphorus Red phosphorus

It exists as discrete tetrahedral P4unit It exist in the form of polymeric chain. 1
OR correct structures
21 (a) ½+½+½
CH3 Br KCN CH3 CN LiAlH4 CH3 CH2 NH2 HNO2 CH3 CH2 OH
A B 273K C

½+½+½
(b) CH3 COOH NH3 CH3 CONH2 Br2 CH3 NH2 CHCl3 CH3 NC
∆ A KOH B NaOH C

3
 OR
21 (i) 1
NO2 NH2
Sn/HCl

(ii) CH3 COOH CH3 CONH2 Br2 CH3 NH2

NH3 +KOH 1

O
(iii) ∥
NH2 NH – C- CH3
(CH3CO)2O 1
( Or by any other suitable method.)
22 (i) Because in vapour form sulphur (S2) contains unpaired electrons. 1
(ii) Because of higher oxidation state (+4) / high charge to size ratio / high polarizing
power. 1
(iii) Because of the two P – H bonds in H3 PO2 whereas in H3 PO3there isone P-H bond 1
.

23 (i) Disinfectants are the chemicals which kill or prevent the growth of micoorganisms. ½+½
Example : 1% phenol, SO2, Cl2 (or any other.)
(ii) Carbohydrates, lipids, protein, nucleic acids, enzymes (any two) ½+½
(iii) Anionic detergents are sodium salts of suphonated long chain alcohols or
hydrocarbons / In anionic detergents, the anionic part of the molecule is involved in the
cleansing action. ½+½
Example : soduim lauryl sulphate,sodium dodecylbenzene sulphonate (any one)
24 (a) Vitamin C 1
(b) Peptide linkage 1
(c) n-hexane or its structure 1
25 (a) 𝑚𝑥 = K p 1⁄n or log (x/m)= log K + 1/n log p 1

4
 (b) Reversible in nature/ stable sol/ solvent loving (or any other) 1
(c) Associated colloid – Soap/ micelles ; Multimolecular colloid - S8/ gold sol. (or any other) ½, ½

26 SO2 Cl2→ SO2 + Cl2

At t = 0s 0.4 atm 0 atm 0 atm
At t = 100s (0.4 – x) atm x atm x atm
Pt = 0.4 – x + x + x
Pt = 0.4 + x
0.7 = 0.4 + x
x = 0.3
2.303 𝑝𝑖 1
k= log
t 2𝑝𝑖 −𝑝𝑡
2.303 0.4
k= log
t 0.8-0.7
2.303 0.4
k= log 0.1 1
100
2.303 1
k= x 0.6021 = 1.39 x 10-2s-1
100

27 (i) Concern towards environment / caring / socially aware / team work. (atleast two values) 1
(ii) Polymers which can be degraded by the action of microorganisms. Eg. PHBV , Nylon -2- ½+½
nylon- 6/ any natural polymer
(iii) Addition polymer. 1
28 1
(a) (i)
1
(ii)

(b) (i) Because of 3d5(half filled) stable configuration of Mn2+ 1

(ii) Because in zinc there is no unpaired electron / there is no contribution from the inner d
electrons. 1
(iii) Because of comparable energies of 7s, 6d and 5f orbitals 1
OR
28 (i) Mn , because of presence of 5 unpaired electrons in 3d subshell ½+½
(ii) Cu , because enthalpy of atomization and ionisation enthalpy is not compensated by enthalpy ½+½

of hydration.
½+½
(iii) Mn3+ , because Mn2+ is more stable due to its half filled (3d5) configuration
1
(iv) Eu+2 (Eu)

5
 (v) 1

29 (a)
(i)

(ii)

(iii) Cl - CH2 - COOH 1

(b) (i) Add NaHCO3, benzoic acid will give brisk effervescence whereas benzaldehyde will not
1
give this test. (or any other test)
(ii) Add tollen’s reagent , propanal will give silver mirror whereas propanone will not give this
1
test. (or any other test)
OR
29 (a) (i) Because the positve charge on carbonyl carbon of CH3 CHO decreases to a lesser extent 1
due to one electron releasing (+I effect) CH3 group as compared to CH3 COCH3 (two electron
releasing CH3 group) and hence more reactive.
(ii) Because carboxylate ion (conjugate base) is more resonance stablized than phenoxide ion. 1
(b) (i)

(ii)

1
(or any other example)
(iii)

1
(or any other example)

6
30 (a) (i) Limiting molar conductivity – when concentration approches zero the conductivity is 1
known as limiting molar conductivity
(ii) Fuel cell – are the cells which convert the energy of combustion of fuels to electrical energy. 1
(b)

OR
30 (a) The amount of substance deposited at any electrode during electrolysis is directly 1
proportional to the quantity of electricity passed through the electrolyte. (aq. solution or melt)
Charge = Q = 2F 1
0.059 [Mg 2+ ] 1
(b) E cell = E0 cell – log
n [Cu2+ ]
½
0.059 0.10
E cell = 2.71 - log
2 0.01
0.059
E cell = 2.71 – log 10 ½
2

= 2.71 – 0.0295 = 2.68 V 1

Sr. Name Sr. Name

No. No.
1 Dr. (Mrs.) Sangeeta Bhatia 9 Sh. Partha Sarathi Sarkar

2 Dr. K.N. Uppadhya 10 Mr. K.M. Abdul Raheem

3 Prof. R.D. Shukla 11 Mr. Akileswar Mishra

4 Sh. S.K. Munjal 12 Mrs. Maya George

5 Sh. Rakesh Dhawan 13 Sh. Virendra Singh Phogat

6 Sh. D.A. Mishra 14 Dr. (Mrs.) Sunita

Ramrakhiani
7 Sh. Deshbir Singh 15 Ms. Garima Bhutani

8 Ms. Neeru Sofat

7
8
Class 12 Chemistry
NCERT Solutions NCERT Exemplar CBSE Notes
Chapter 1 The Solid State Solid State The Solid State
Chapter 2 Solutions Solutions Solutions
Chapter 3 Electro chemistry Electrochemistry Electro chemistry
Chapter 4 Chemical Kinetics Chemical Kinetics Chemical Kinetics
Chapter 5 Surface Chemistry Surface Chemistry Surface Chemistry
Chapter 6 General Principles and General Principles and Processes General Principles and Processes
Processes of Isolation of Elements of Isolation of Elements of Isolation of Elements
Chapter 7 The p Block Elements The p-Block Elements The p Block Elements
Chapter 8 The d and f Block Elements The d- and f-Block Elements The d and f Block Elements
Chapter 9 Coordination Compounds Coordination Compounds Coordination Compounds
Chapter 10 Haloalkanes and
Haloalkanes and Haloarenes Haloalkanes and Haloarenes
Haloarenes
Chapter 11 Alcohols Phenols and
Alcohols, Phenols and Ethers Alcohols Phenols and Ethers
Ethers
Chapter 12 Aldehydes Ketones and Aldehydes, Ketones and Aldehydes Ketones and
Carboxylic Acids Carboxylic Acids Carboxylic Acids
Chapter 13 Amines Amines Amines
Chapter 14 Biomolecules Biomolecules Biomolecules
Chapter 15 Polymers Polymers Polymers
Chapter 16 Chemistry in Everyday
Chemistry in Everyday Life Chemistry in Everyday Life
Life

JEE Main Chemistry Chapter wise Previous Year Questions

Basic Concepts and Stoichometry Haloalkenes and Haloarenes
States of Matter: Gases,Liquids and Solids Alcohols,Ethers,Carobonyls and Carboxylic Acids
Atomic Structure and Electronic Configuration Nitro,Amine and Azo Compounds
Periodic Classification and Properties Solutions and Colligative Properties
Chemical Bonding and Molecular Structure Kinetics,Catalysis and Surface Chemistry
Elements of S-Block : Hydrogen,Group 1 and 2 Chemical and Lonic Equilibrium
Elements of p-Block: Groups 13,14,15,16,17 and 18 Redox Reactions and Electrochemistry
Elements of d-Block,f-Block and Complexes Thermodynamics and Chemical Energitics
Metallurgy and Environmental Chemistry Biomolecules and Polymers
General Organic Chemistry Chemistry in Everyday Life and Miscellaneous
Alkanes ,Alkenes ,Alkynes and Arenes

CBSE Sample Papers NCERT Solutions LearnCBSE.in

Class 12 Chemistry Lab Manual
1. Introduction to Basic Laboratory Equipment
1. Viva Questions with Answers.
2. Surface Chemistry
1. Exp-2.1 : To prepare colloidal solution (sol) of starch.
2. Exp-2.2 : To prepare a colloidal solution of gum.
3. Exp-2.3 : To prepare colloidal solution (or sol) of egg albumin.
4. Exp-2.4 : To prepare ferric hydroxide, [Fe(OH)3] sol.
5. Exp-2.5 : To prepare aluminium hydroxide, [Al(OH)3] sol.
6. Exp-2.6 : To prepare colloidal solution of arsenious sulphide, [As2 S3].
7. Exp-2.7 :To study the dialysis of starch sol containing sodium chloride through a cellophane or
parchment paper.
8. Exp-2.8 : Compare the precipitation values of sodium chloride, barium chloride and aluminium
chloride for arsenious sulphide sol.
9. Exp-2.9 : To study the effectiveness of different common oils (castor oil, cotton seed oil,
coconut oil, kerosene oil, mustard oil) in forming emulsions.
10. Exp-2.10 : To compare the effectiveness of a number of emulsifying agents in forming
emulsions.
11. Surface Chemistry Viva Questions with Answers.
3. Chemical Kinetics
1. Exp-3.1 : To study the effect of concentration on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
2. Exp-3.2 : To study the effect of change in temperature on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
3. Exp-3.3 : To study the reaction rate of reaction of iodide ions with hydrogen peroxide at
different concentrations of iodide ions.
4. Exp-3.4 : To study the reaction rate of the reaction between potassium iodate (KIO3) and
sodium sulphite (Na2S03) using starch solution as indicator.
5. Chemical Kinetics Viva Questions with Answers.
4. Thermochemistry
1. Exp-4.1 : Determine the calorimeter constant (W) of calorimeter (polythene bottle).
2. Exp-4.2 : Determine the enthalpy of dissolution of given solid copper sulphate (CuS04.5H20) in
water at room temperature.
3. Exp-4.3 : Determine the enthalpy of neutralisation of hydrochloric acid with sodium hydroxide
solution.
4. Exp-4.4 : Determine the enthalpy change during the interaction (hydrogen bond formation)
between acetone and chloroform.
5. Thermochemistry Viva Questions with Answers.
5. Electrochemistry
1. Exp-5.1 : To set up simple Daniell cell and determine its emf .
2. Exp-5.2 : To set up simple Daniell cell using salt bridge and determine its emf .
3. Exp-5.3 : To study the variation of cell potential in Zn | Zn2+ || Cu2+ | Cu cell with change in
concentration of electrolytes (CuS04 and ZnS04) at room temperature.
4. Electrochemistry Viva Questions with Answers.
6. Chromatography
1. Exp-6.1 : Separate the coloured components present in the mixture of red and blue inks by
ascending paper chromatography and find their Rf values .
2. Exp-6.2 : Separate the coloured components present in the given grass/flower by ascending
paper chromatography and determine their Rf values .
3. Exp-6.3 : Separate Co2+ and Ni2+ ions present in the given mixture by using ascending paper
chromatography and determine their Rf values .
4. Chromatography Viva Questions with Answers.
7. Preparation of Inorganic Compounds
1. Exp-7.1 : To prepare a pure sample of ferrous ammonium sulphate (Mohr’s salt), [FeSO4 .
(NH4)2 SO4.6HO20] .
2. Exp-7.2 : To prepare a pure sample of potash alum (Fitkari), [K2SO4.Al2 (SO4)3. 24H20] .

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 3. Exp-7.3 : To prepare a pure sample of the complex potassium trioxalatoferrate(III),
Kg[Fe(C2O4)3l . 3H20 .
4. Preparation of Inorganic Compounds Viva Questions with Answers.
8. Preparation of Organic Compounds
1. Exp-8.1 : To prepare a sample of acetanilide from aniline.
2. Exp-8.2 : To prepare a sample of dibenzalacetone.
3. Exp-8.3 : To prepare a sample of p-nitroacetanilide from acetanilide .
4. Exp-8.4 : To prepare 2-naphthol aniline or phenyl-azo-β-naphtholdye .
5. Preparation of Organic Compounds Viva Questions with Answers.
9. Tests for the Functional Groups Present in Organic Compounds
1. Exp-9.1 : Identify the functional group present in the given organic compound.
2. Tests for the Functional Groups Present in Organic Compounds Viva Questions with Answers.
10. Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of Their Presence in Given
Food Stuffs
1. Exp-10.1 : To study some simple tests of carbohydrates .
2. Exp-10.2 : To study some simple tests of oils and fats .
3. Exp-10.3 : To study some simple tests of proteins .
4. Exp-10.4 : To detect the presence of carbohydrates, fats and proteins in the following food
stuffs : Grapes, potatoes, rice, butter, biscuits, milk, groundnut, boiled egg .
5. Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of Their Presence in
Given Food Stuffs Viva Questions with Answers.
11. Volumetric Analysis
1. Exp-11.1 : Prepare 250 ml of M/10 solution of oxalic acid from crystalline oxalic acid .
2. Exp-11.2 : Prepare 250 ml of a N/10 solution of oxalic acid from crystalline oxalic acid .
3. Exp-11.3 : Preparation of 250 ml of M/20 solution of Mohr’s salt .
4. Exp-11.4 : Preparation of 250 ml of N/20 solution of Mohr’s salt .
5. Exp-11.5 : Prepare M/20 solution of ferrous ammonium sulphate (Mohr’s salt). Using this
solution find out the molarity and strength of the given KMn04 solution.
6. Exp-11.6 : Prepare a solution of ferrous ammonium sulphate (Mohr’s salt) containing exactly
17.0 g of the salt in one litre. With the help of this solution, determine the molarity and the
concentration of KMnO4 in the given solution.
7. Exp-11.7 : Prepare M/20 ferrous ammonium sulphate (Mohr’s salt) solution. Find out the
percentage purity of impure KMnO4 sample 2.0 g of which have been dissolved per litre .
8. Exp-11.8 : Determine the equivalent mass and number of molecules of water of crystallisation
in a sample of Mohr’s salt, FeSO4(NH4)2 SO4 . nH20. Provided KMnO4.
9. Exp-11.9 : Prepare M/50 solution of oxalic acid. With its help, determine 50 the molarity and
strength of the given solution of potassium permanganate (KMnO4).
10. Exp-11.10 : Find out the percentage purity of impure sample of oxalic acid. You are supplied
M/100 KMnO4 solution.
11. Exp-11.11 : The given solution has been prepared by dissolving 1.6 g of an alkali metal
permanganate per litre of solution. Determine volumetrically the atomic mass of the alkali
metal. Prepare M/20 Mohr’s salt solution for titration.
12. Exp-11.12 : Determine the percentage composition of a mixture of sodium

oxalate and oxalic acid . Provided M/100

KMnO4 solution.
13. Exp-11.13 : You are provided with a partially oxidised sample of ferrous sulphate
(FeSO4.7H20) crystals. Prepare a solution by dissolving 14.0 g of these crystals per litre and
determine the percentage oxidation of the given sample. Given M/100 KMnO4 solution.
14. Exp-11.14 : Calculate the percentage of Fe2+ ions in a sample of ferrous sulphate. Prepare a
solution of the given sample having strength exactly equal to 14.0 g/litre. Provided M/100
KMnO4 .
15. Exp-11.15 : Prepare N/20 Mohr’s salt solution. Using this solution, determine the normality
and strength of the given potassium permanganate solution.

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 16. Exp-11.16 : Prepare N/20 solution of oxalic acid. Using this solution, find out strength and
normality of the given potassium permanganate solution .
17. Exp-11.17 : Determine the percentage purity of the given sample of oxalic acid. Ask for your
requirement .
18. Exp-11.18 : Determine the percentage composition of a mixture of sodium

oxalate and oxalic acid . Provided N/20 KMnO4 .

19. Exp-11.19 : Determine the equivalent mass and number of molecules of water of
crystallisation in a sample of Mohr’s salt FeSO4 (NH4)2 SO4.nH20. Provided N/20 KMnO4.
20. Volumetric Analysis Viva Questions with Answers.
12. Chemistry Qualitative Analysis
1. Exp-12.1 : To analyse the given salt for acidic and basic radicals .
2. Exp-12.2 : To analyse the given salt for acidic and basic radicals CO, Zn.
3. Qualitative Analysis Viva Questions with Answers.

NEET Chemistry Chapter wise Important Questions

Some Basic Concepts of Chemistry Chemical Kinetics

Atomic Structure Concept of Chemical Kinetics
Classification and Periodicity of Elements Order of Reaction
Chemical Bonding and Molecular Structure Effect of Temperature on Rate of Reactions
States of Matter ( Gaseous and Liquid State) Surface Chemistry
Unit Test 1(General Chemistry) Concept of Surface Chemistry
Chemical Thermodynamics Factors Affecting Adsorption of Gases on Solids
Thermodynamics Promoters and Inhibitors
First Law of Thermodynamics Preparation of Lyophobic Solution
Hess’s Law of Constant Heat Summation Unit Test 5(Physical Chemistry II)
Second Law of Thermodynamics General Principles and Processes of Isolation of Metals
Equilibrium Earth Crust
Equilibrium State Extraction of Crude Metal from Concentrated Ore
Le-Chatelier's Principle Thermodynamics of Metallurgy
Acids and Bases p-Block Elements
Salt Hydrolysis Group-15 Elements: Nitrogen Family
Redox Reactions Dinitrogen
Concepts of Oxidation and Reduction Phosphorus
Oxidation Number Group-16 Elements: Oxygen Family
Redox Reactions Allotropic forms of Sulphur
Unit Test 2(Physical Chemistry I) Group-17 Elements: Halogens
Hydrogen Group-18 Elements: Noble Gases
Occurrence of Hydrogen The d- and f- Block Elements
Compounds of Hydrogen d-Block Elements

CBSE Sample Papers NCERT Solutions LearnCBSE.in

Hard and Soft Water General Properties of the Transition Elements
s-Block Elements Some Important Compounds of Transition Elements
General Introduction of S-Block Elements Coordination Compounds
Anomalous Properties of Lithium Complex or Coordination Compounds
Biological Importance of Sodium and Potassium Effective Atomic Number Rule
p-Block Elements (Inorganic Chemistry) Bonding in Coordination Compounds
Concept of p-Block Elements Crystal Field Theory (CFT)
Group 13 Elements: Boron Family Unit Test 6(Inorganic Chemistry II)
Some Important Compounds of Group 13
Haloalkanes and Haloarenes
Elements
Group 14 Elements: Carbon Family Alkyl and Aryl Halides
Unit Test 3(Inorganic Chemistry I) Preparation of Aryl Halides
Stereochemical Aspects of Nucleophilic Substitution
Some Basic Principles and Techniques
Reactions
Concept of Organic Chemistry Polyhalogen Compounds
Representation of Different Formula Alcohols, Phenols and Ethers
Isomerism Alcohols and Phenols
Free Radicals Chemical Properties of Alcohols
Types of Organic Reactions Phenols
Chromatography Ethers
Hydrocarbons Aldehydes, Ketones and Carboxylic Acids
Concept of Hydrocarbons Aldehydes and Ketones
Chemical Properties of Alkanes Preparation of Aldehydes
Alkenes Preparation of Ketones
Alkynes Properties
Aromatic Hydrocarbons Uses of Aldehydes and Ketones
Environmental Chemistry Organic Compounds Containing Nitrogen
Environmental Pollution Amines
Air Pollution Properties of Amines
Tropospheric Pollution Hofmann Mustard Oil Reaction
Water Pollution Cyanides
Unit Test 4(Oreganic and Environmental
Biomolecules
Chemistry I)
Solid State Concept of Biomolecules
Concept of Solids Structure of Fructose
Packing Efficiency Proteins
Defects or Imperfections in Solids Nucleic Acids
Magnetic Properties of Solids Polymers
Solutions Concept of Polymers

CBSE Sample Papers NCERT Solutions LearnCBSE.in

Solutions in Chemistry Polymerisation
Vapour Pressure Vulcanisation of Rubber
Ideal Solutions Polyesters
Electrochemistry Chemistry in Everyday life
Concept of Electrochemistry Chemicals in Medicines
Electrochemical Cell Antimicrobials
Representation of a Cell Soaps
Nernst Equation Unit Test 7(Organic Chemistry II)
Mock Test 1
Mock Test 2
Mock Test 3

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